CN105176184A - Activated transferring solvent, active transferring texture calcium carbonate resin material and manufacturing method - Google Patents
Activated transferring solvent, active transferring texture calcium carbonate resin material and manufacturing method Download PDFInfo
- Publication number
- CN105176184A CN105176184A CN201510460831.1A CN201510460831A CN105176184A CN 105176184 A CN105176184 A CN 105176184A CN 201510460831 A CN201510460831 A CN 201510460831A CN 105176184 A CN105176184 A CN 105176184A
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- transfer printing
- calcium carbonate
- carbonate resin
- resin material
- surface layer
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- Laminated Bodies (AREA)
- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides an activated transferring solvent. The activated transferring solvent comprises the following raw materials, by weight, 1.5-2.8% of cyclohexanone, 49-55% of xylene, 3.2-6.8% of ethyl ester, 2.1-3.9% of CAC and 1.4-2.6% of isophoron, the balance being butyl ester. The provided activated transferring solvent can dissolve a transferring film in a transferring tank, the transferring film floats on a water surface in a transferring printing ink state, and basis is provided for transferring of transferring printing ink on the calcium carbonate resin material.
Description
Technical field
The present invention relates to building decoration field, particularly relate to a kind of resin building material.
Background technology
For a long time, in family expenses decoration, metope and ground all adopt ceramic tile or timber floor, and the equal cost of above-mentioned materials is high, frangible or yielding, and strength property is all inadequate.Current resin material does not have wood grain.
Therefore, need badly and propose a kind of type material, make up the deficiencies in the prior art.
Summary of the invention
Object of the present invention provides a kind of active transfer printing texture calcium carbonate resin material, to solve in above-mentioned prior art problem one or more.
On the one hand, the invention provides a kind of activation transfer printing solvent, comprise the raw material of following weight percent;
Surplus is butyl ester.
Transfer film can be dissolved in transfer printing pool by activation transfer printing solvent provided by the invention, floats on the water surface with the state of transfer ink, for transfer ink be needed on calcium carbonate resin material formed active transfer printing texture calcium carbonate resin material provide basis.Active transfer printing texture is preferably wood grain, attractive in appearance.
In some embodiments, the raw material of weight percent is preferably as follows:
Surplus is butyl ester.
The present invention proposes a kind of active transfer printing texture calcium carbonate resin material on the other hand, comprise stratum basale and surface layer,
Stratum basale comprises the raw material of following parts by weight: Paris white 62 ~ 70 parts, PVC standard substance 17 ~ 24 parts, ASA2 ~ 8 part, ACR1 ~ 3 part, stratum basale stablizer 1.8 ~ 6 parts;
Surface layer comprises the raw material of following parts by weight: Paris white 80 ~ 88 parts, ABS10 ~ 15 part, ASA2 ~ 7 part, surface layer stablizer 1 ~ 5 part;
Transferred with transfer ink on surface layer;
The particle diameter of the Paris white in stratum basale and surface layer is more than 400 orders.
Active transfer printing texture calcium carbonate resin material provided by the invention, the stratum basale with good strength performance provides the imitative enamel coating of ceramic-like, has the advantages that surface luster property is good, attractive in appearance, anti-permeability is good, surface abrasion resistance is good.And transfer ink is printed on imitative enamel coating, reach effect attractive in appearance.
In some embodiments, the stratum basale stablizer of 1.8 ~ 6 parts comprise the stearic acid of 0.5 ~ 2 part, 0.3 ~ 1 part CPE and 1 ~ 3 part PEL cured.
In some embodiments, surface layer stablizer be stearic acid, CPE, PEL cured in one or more.
In some embodiments, stratum basale also comprises fire retardant 1 ~ 3 part.
Again on the one hand, the invention allows for the making method of above-mentioned a kind of active transfer printing texture calcium carbonate resin material, comprise the steps:
The each raw material of stratum basale of a kind of active transfer printing texture calcium carbonate resin material of A, preparation claim 3, high-temperature stirring at least 13 minutes in input high mixer, and reach 200 DEG C;
B, the material through steps A high-temperature stirring to be dropped in low mixed machine cooling and stirring to temperature 60 C;
C, by through step B low temperature stir after material add Bitruder, maintain extrusion temperature be 200 DEG C, extrusion pressure is 15 ~ 22MPa;
D, on the die head of Bitruder, open overflow port, singe screw material-extruding machine is separately provided, by the merging core of singe screw material-extruding machine access overflow port, each for the surface layer of a kind of active transfer printing texture calcium carbonate resin material of claim 1 raw material is dropped into the feeding port of singe screw material-extruding machine, maintaining extrusion temperature is 200 DEG C, and extrusion pressure is the extrusion pressure being greater than Bitruder;
E, transfer film is layed in transfer printing pool, the one of claim 1 or 2 activation transfer printing solvent is added transfer printing pool and makes transfer film melt as transfer ink, then step D products obtained therefrom is put into transfer printing pool, utilize hydraulic pressure that transfer ink is imprinted on product surface.
In some embodiments, from Bitruder feed intake place screw rod to Bitruder merging core, the screw rod of Bitruder is divided into 5 sections, in time between step B and step C and the time of step C, on the flow direction of material, 5 sections of temperature control to be 192 ~ 198 DEG C, 182 ~ 188 DEG C, 177 ~ 182 DEG C, 172 ~ 177 DEG C, 158 ~ 162 DEG C successively; The temperature of merging core controls to be 182 ~ 188 DEG C, and the temperature of the die head be connected with merging core controls to be 200 DEG C.
In some embodiments, the present invention also comprises step F, step e sprays the transparent gloss oil of PU after obtaining product drying, drier obtained product.
Embodiment
On the one hand, the invention provides a kind of activation transfer printing solvent, comprise the raw material of following weight percent:
Surplus is butyl ester.
Preferably, above-mentioned activation transfer printing solvent has the raw material comprising following weight percent: pimelinketone 2%,
Surplus is butyl ester.
Transfer film can be dissolved in transfer printing pool by activation transfer printing solvent provided by the invention, floats on the water surface with the state of transfer ink, for transfer ink be needed on calcium carbonate resin material formed active transfer printing texture calcium carbonate resin material provide basis.
The present invention also provides a kind of active transfer printing texture calcium carbonate resin material, comprises stratum basale and surface layer,
Stratum basale comprises the raw material of following parts by weight: Paris white 62 ~ 70 parts, PVC standard substance 17 ~ 24 parts, ASA2 ~ 8 part, ACR1 ~ 3 part, stratum basale stablizer 1.8 ~ 6 parts;
Surface layer comprises the raw material of following parts by weight: Paris white 80 ~ 88 parts, ABS10 ~ 15 part, ASA2 ~ 7 part, surface layer stablizer 1 ~ 5 part;
Transferred with transfer ink on surface layer;
The particle diameter of the Paris white in stratum basale and surface layer is more than 400 orders.
PVC standard substance are the SG5 type acceptable end product that quality standard meets national standard " the universal polyvinyl chloride (PVC) RESINS of suspension method (GB/T5761-2006) ".Best, the preferred whiteness of Paris white is more than 95.
Active transfer printing texture calcium carbonate resin material provided by the invention, the stratum basale with good strength performance provides the imitative enamel coating of ceramic-like, has the advantages that surface luster property is good, attractive in appearance, anti-permeability is good.
ABS is by vinyl cyanide, the terpolymer of divinyl and vinylbenzene composition.Its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties, also have the features such as easy processing, product size is stable, surface luster property is good.
ASA is a kind of ter-polymers by vinyl cyanide (Acrylonitrile), vinylbenzene (Styrene), acrylate rubber like body (Acrylate), belongs to impact modification resin.
ACR (Acryliccopolymer) is the acrylic acid esters co-polymer with core-shell structure, is a kind of PVC anti-impact modifier of high comprehensive performance.Usual people call anti-impact modifier to improve the auxiliary agent used for the purpose of plastics toughness, are called modifier to improve the auxiliary agent used for the purpose of processing characteristics.ACR is the additives for plastics having impact modification and processing modified dual-use function concurrently, because it has core-shell structure, make its PVC product have excellent shock resistance, low-temperature flexibility, with PVC consistency, weathering resistance, stability, processibility, and performance and cost ratio moderate, can obviously improve PVC fluidity of molten, deformability, promote plasticizing, product surface is bright and clean attractive in appearance.
In stratum basale, applicant is by a large number of experiments show that, when ACR and ASA shares, the acrylic ester compound in ACR with the acrylate rubber like body copolyreaction in ASA, can improve shock resistance of the present invention greatly; And better water resistance is provided.
Further, the stratum basale stablizer of 1.8 ~ 6 parts comprise the stearic acid of 0.5 ~ 2 part, 0.3 ~ 1 part CPE and 1 ~ 3 part PEL cured.
Stearic acid is PVC heat stabilizer, has good oilness and good light, heat stabilization.Contribute to " coking " that prevent in the course of processing, can defend cruelly to be placed in the caused finished films variable color of sulfide simultaneously.
Chlorinatedpolyethylene (CPE) is saturated macromolecular material, and outward appearance is white powder, nonpoisonous and tasteless, has excellent weather resisteant, resistance to ozone, chemical-resistant resistance and ageing-resistant performance, has good oil-proofness, flame retardant resistance and tinctorial property.
PEL is cured, i.e. polyethylene wax, the one package stabilizer in PVC profile, in PVC, PE, PP molding process, do dispersion agent, lubricant and brightening agent, strengthens plasticizing rate, improves toughness and the surface flatness of plastics.
Further, surface layer stablizer be stearic acid, CPE, PEL cured in one or more.
In addition, stratum basale also comprises fire retardant 1 ~ 3 part.The fire resistance of art work for building is provided.In the cognition of those skilled in the art, as long as the fire retardant that can merge with PVC all can implement the present invention, therefore do not repeat.
Further, stratum basale of the present invention also comprises dispersion agent 2 ~ 4 parts.Dispersion agent is the supply of material producer of BYK-130 auxiliary agent is Kunshan Chang Ling Chemical Industry Science Co., Ltd, and this auxiliary agent encloses distinctive avidity to acidic groups, can make stably dispersing, shortens jitter time, prevents from hazing, avoid loose colour, increases gloss.
Present invention also offers the making method of above-mentioned a kind of active transfer printing texture calcium carbonate resin material, comprise the steps:
The each raw material of stratum basale of a kind of active transfer printing texture calcium carbonate resin material of A, preparation claim 3, high-temperature stirring at least 13 minutes in input high mixer, and reach 200 DEG C;
B, the material through steps A high-temperature stirring to be dropped in low mixed machine cooling and stirring to temperature 60 C;
C, by through step B low temperature stir after material add Bitruder, maintain extrusion temperature be 200 DEG C, extrusion pressure is 15 ~ 22MPa;
D, on the die head of Bitruder, open overflow port, singe screw material-extruding machine is separately provided, by the merging core of singe screw material-extruding machine access overflow port, each for the surface layer of a kind of active transfer printing texture calcium carbonate resin material of claim 1 raw material is dropped into the feeding port of singe screw material-extruding machine, maintaining extrusion temperature is 200 DEG C, and extrusion pressure is the extrusion pressure being greater than Bitruder;
E, transfer film is layed in transfer printing pool, the one of claim 1 or 2 activation transfer printing solvent is added transfer printing pool and makes transfer film melt as transfer ink, then step D products obtained therefrom is put into transfer printing pool, utilize hydraulic pressure that transfer ink is imprinted on product surface.The transfer film that the present invention adopts is the MA486-1 of great Ze Chemical Co., Ltd..
Further, from Bitruder feed intake place screw rod to Bitruder merging core, the screw rod of Bitruder is divided into 5 sections, in time between step B and step C and the time of step C, on the flow direction of material, 5 sections of temperature control to be 192 ~ 198 DEG C, 182 ~ 188 DEG C, 177 ~ 182 DEG C, 172 ~ 177 DEG C, 158 ~ 162 DEG C successively; The temperature of merging core controls to be 182 ~ 188 DEG C, and the temperature of the die head be connected with merging core controls to be 200 DEG C.
In addition, the present invention can also comprise step F, step e sprays the transparent gloss oil of PU after obtaining product drying, drier obtained product.
In stratum basale of the present invention, adopt above manufacture craft and material, applicant shows and has located following examples:
Surface abrasion resistance is tested with the flat sheet mould method of GB/T17657-1999, wherein gauze 2404/0
#, horizontal rotating speed (60 ± 2) r/min;
24h water-intake rate take GB/T17657-1999 as test foundation.
Shock resistance falls rear without cracking height with 1kg solid steel ball.
Above embodiment is visible, ASA and ACR acting in conjunction in Paris white and PVC standard substance time, intensity index, shock resistance, water tolerance all have and significantly improve.
In addition, in burst size of methanal (condensed steam water) test of GB185580-2001, above-described embodiment is all less than 0.1mg/L, meets state compulsion standard.
The stratum basale example provided with embodiment 5, stratum basale to cover the surface layer of the high following formula of 2mm, has following embodiment:
Surface abrasion resistance is tested with the flat sheet mould method of GB/T17657-1999, wherein gauze 2404/0
#, horizontal rotating speed (60 ± 2) r/min;
Visible, surface layer provided by the invention drastically increases the surface abrasion resistance of active transfer printing texture calcium carbonate resin material provided by the invention.
In step e, transfer printing solvent can have following examples:
Embodiment 13:
Transfer printing solvent comprises the raw material of following weight percent: pimelinketone 2.8%, dimethylbenzene 55%, ethyl ester 6.8%, CAC3.9%, different fluorine that ketone 2.6%, surplus are butyl ester.
Embodiment 14:
Transfer printing solvent comprises the raw material of following weight percent: pimelinketone 1.5%, dimethylbenzene 49%, ethyl ester 3.2%, CAC2.1%, different fluorine that ketone 1.4%, surplus are butyl ester.
Embodiment 15:
Transfer printing solvent comprises the raw material of following weight percent: pimelinketone 2%, dimethylbenzene 52%, ethyl ester 5%, CAC3%, different fluorine that ketone 2%, surplus are butyl ester.
The above is only optimal way of the present invention; it should be pointed out that to those skilled in the art, without departing from the concept of the premise of the invention; can also make some similar distortion and improvement, these also should be considered as within protection scope of the present invention.
Claims (9)
1. activate a transfer printing solvent, it is characterized in that, comprise the raw material of following weight percent:
2. one activation transfer printing solvent according to claim 1, is characterized in that, comprise the raw material of following weight percent:
3. an active transfer printing texture calcium carbonate resin material, is characterized in that, comprise stratum basale and surface layer,
Described stratum basale comprises the raw material of following parts by weight: Paris white 62 ~ 70 parts, PVC standard substance 17 ~ 24 parts, ASA2 ~ 8 part, ACR1 ~ 3 part, stratum basale stablizer 1.8 ~ 6 parts;
Described surface layer comprises the raw material of following parts by weight: Paris white 80 ~ 88 parts, ABS10 ~ 15 part, ASA2 ~ 7 part, surface layer stablizer 1 ~ 5 part;
Transferred with transfer ink on described surface layer;
The particle diameter of the Paris white in described stratum basale and described surface layer is more than 400 orders.
4. one according to claim 3 active transfer printing texture calcium carbonate resin material, is characterized in that, the stratum basale stablizer of described 1.8 ~ 6 parts comprise the stearic acid of 0.5 ~ 2 part, 0.3 ~ 1 part CPE and 1 ~ 3 part PEL cured.
5. one according to claim 4 active transfer printing texture calcium carbonate resin material, is characterized in that, described surface layer stablizer be stearic acid, CPE, PEL cured in one or more.
6. one according to claim 5 active transfer printing texture calcium carbonate resin material, is characterized in that, described stratum basale also comprises fire retardant 1 ~ 3 part.
7. a making method for active transfer printing texture calcium carbonate resin material, is characterized in that, comprise the steps:
A, prepare each raw material of stratum basale of a kind of active transfer printing texture calcium carbonate resin material according to claim 3, to drop in high mixer high-temperature stirring at least 13 minutes, and reach 200 DEG C;
B, the material through steps A high-temperature stirring to be dropped in low mixed machine cooling and stirring to temperature 60 C;
C, by through step B low temperature stir after material add Bitruder, maintain extrusion temperature be 200 DEG C, extrusion pressure is 15 ~ 22MPa;
D, on the die head of described Bitruder, open overflow port, singe screw material-extruding machine is separately provided, by the merging core of singe screw material-extruding machine access overflow port, each for the surface layer of a kind of active transfer printing texture calcium carbonate resin material according to claim 1 raw material is dropped into the feeding port of singe screw material-extruding machine, maintaining extrusion temperature is 200 DEG C, and extrusion pressure is the extrusion pressure being greater than described Bitruder;
E, transfer film is layed in transfer printing pool, the one activation transfer printing solvent described in claim 1 or 2 is added transfer printing pool and makes transfer film melt as transfer ink, then step D products obtained therefrom is put into transfer printing pool, utilize hydraulic pressure that transfer ink is imprinted on product surface.
8. the making method of a kind of active transfer printing texture calcium carbonate resin material according to claim 7, it is characterized in that, from Bitruder feed intake place screw rod to Bitruder merging core, the screw rod of described Bitruder is divided into 5 sections, in time between step B and step C and the time of step C, on the flow direction of material, described 5 sections of temperature control to be 192 ~ 198 DEG C, 182 ~ 188 DEG C, 177 ~ 182 DEG C, 172 ~ 177 DEG C, 158 ~ 162 DEG C successively; The temperature of described merging core controls to be 182 ~ 188 DEG C, and the temperature of the die head be connected with described merging core controls to be 200 DEG C.
9. the making method of a kind of active transfer printing texture calcium carbonate resin material according to claim 7, also comprises step F, step e sprays the transparent gloss oil of PU after obtaining product drying, drier obtained product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510460831.1A CN105176184B (en) | 2015-07-30 | 2015-07-30 | One kind activation transfer solvent, activity transfer texture calcium carbonate resin material and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510460831.1A CN105176184B (en) | 2015-07-30 | 2015-07-30 | One kind activation transfer solvent, activity transfer texture calcium carbonate resin material and preparation method |
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| CN105176184A true CN105176184A (en) | 2015-12-23 |
| CN105176184B CN105176184B (en) | 2018-03-27 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108162624A (en) * | 2017-12-26 | 2018-06-15 | 浙江王斌装饰材料有限公司 | A kind of PVC lines water transfer prepares processing technology |
| CN108162626A (en) * | 2018-01-31 | 2018-06-15 | 柳州市万菱科技有限责任公司 | A kind of water transfers activator |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108162624A (en) * | 2017-12-26 | 2018-06-15 | 浙江王斌装饰材料有限公司 | A kind of PVC lines water transfer prepares processing technology |
| CN108162626A (en) * | 2018-01-31 | 2018-06-15 | 柳州市万菱科技有限责任公司 | A kind of water transfers activator |
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| Publication number | Publication date |
|---|---|
| CN105176184B (en) | 2018-03-27 |
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