CN105175621A - Normal-temperature-self-crosslinking woodenware paint emulsion and preparation method therefor - Google Patents
Normal-temperature-self-crosslinking woodenware paint emulsion and preparation method therefor Download PDFInfo
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- CN105175621A CN105175621A CN201510671622.1A CN201510671622A CN105175621A CN 105175621 A CN105175621 A CN 105175621A CN 201510671622 A CN201510671622 A CN 201510671622A CN 105175621 A CN105175621 A CN 105175621A
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- 239000000839 emulsion Substances 0.000 title claims abstract description 33
- 238000004132 cross linking Methods 0.000 title claims abstract description 25
- 239000003973 paint Substances 0.000 title abstract description 11
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 238000004945 emulsification Methods 0.000 title description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003999 initiator Substances 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000002023 wood Substances 0.000 claims description 17
- 239000004922 lacquer Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 6
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 125000005336 allyloxy group Chemical group 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- FIHPJYMQCLZZJG-UHFFFAOYSA-N diazanium ethenoxyethene sulfate Chemical compound S(=O)(=O)([O-])[O-].[NH4+].C(=C)OC=C.[NH4+] FIHPJYMQCLZZJG-UHFFFAOYSA-N 0.000 claims description 6
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 230000003472 neutralizing effect Effects 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- 239000004159 Potassium persulphate Substances 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 13
- 239000011248 coating agent Substances 0.000 abstract description 11
- -1 acetyl acetoxyl ethyl Chemical group 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 235000010894 Artemisia argyi Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 244000030166 artemisia Species 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229940079938 nitrocellulose Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of coating materials and particularly relates to a normal-temperature-self-crosslinking woodenware paint emulsion and a preparation method therefor. The normal-temperature-self-crosslinking woodenware paint emulsion is characterized by being prepared from the following constituents in parts by weight: 20-120 parts of methyl methacrylate, 20-120 parts of styrene, 80-120 parts of butyl acrylate, 6-30 parts of acetyl acetoxyl ethyl methacrylate, 4-15 parts of methacrylate, 3-15 parts of adipic dihydrazide, 3-15 parts of emulsifier, 1-10 parts of initiator, 3-8 parts of neutralizer, 0.5-2 parts of molecular weight regulator and 300-500 parts of deionized water. Compared with the prior art, the normal-temperature-self-crosslinking woodenware paint emulsion and the preparation method therefor have the advantages that cross-linking reaction for acetyl acetoxyl ethyl methacrylate and adipic dihydrazide is adopted, and the properties of a coating film of the woodenware paint emulsion are excellent.
Description
Technical field
The present invention relates to technical field of coatings, specifically a kind of ambient self-crosslinking wood lacquer emulsion and preparation method thereof.
Background technology
Along with environmental legislation is to the attention of VOC discharge quantitative limitation and popular environmental pollution in coating, environmentally friendly woodwork coating has become the development trend of coating industry.The requirement to coating material production producer and Furniture manufacturing producer of state's laws, regulation is all improving gradually.From 1 day February in 2015, country imposed the excise of 4% to production coatings enterprises.In furniture woodwork coating field, China has started to promote water-borne wood coating, the very high pyroxylin(e)finish of former usage quantity proportion being replaced by water-based silently.But China's water-borne wood coating also exists limitation in gordian technique, its paint film is caused to also have a certain distance compared with solvent based coating in the performances such as hardness, water tolerance, stability.The acrylic ester emulsion that in aqueous woodware paint, usage quantity is maximum due to cross-linking density not high, " heat glutinous cold short ", in use, is easy to occur to scratch, wounds, ftractures, bubbles, wrinklingly even to come off.Its basic reason is that acrylic ester emulsion belongs to thermoplastic resin, and film-forming temperature is high, and low temperature film is more crisp, and the resistance to bond of difference of hardness, particularly initial stage is poor, is not suitable for preparation high-quality woodwork coating.By introducing crosslinked group, and then formed the film of stereoscopic three-dimensional structure by the generation of crosslinking reaction in film process, thus limit the motion of film Middle molecule segment, the performance improving aqueous woodware paint is very helpful.
Patent 201410238123.9 1 kinds of room-temperature self crosslinking wood lacquer emulsions and preparation method thereof propose diacetone-acryloamide(DAA) and adipic dihydrazide as the application of room-temperature self crosslinking monomer in wood lacquer emulsion.Compared to 201410238123.9, the cross-linking system of acetoacetoxyethyl methacrylate and adipic dihydrazide composition has rate of crosslinking faster, and the rate of drying of paint film is fast, excellent performance.
Summary of the invention
The present invention, for overcoming the deficiencies in the prior art, provides a kind of room-temperature self crosslinking wood lacquer emulsion and preparation method thereof, to overcome the shortcoming and defect existing for prior art.The present invention can be used as aqueous wooden ware seal coat.
For achieving the above object, design a kind of ambient self-crosslinking wood lacquer emulsion, it is characterized in that: be made up of following composition and parts by weight, methyl methacrylate: 20 ~ 120 parts; Vinylbenzene: 20 ~ 120 parts; Butyl acrylate: 80 ~ 120 parts; Acetoacetoxyethyl methacrylate: 6 ~ 30 parts; Methacrylic acid: 4 ~ 15 parts; Adipic dihydrazide: 3 ~ 15 parts; Emulsifying agent: 3 ~ 15 parts; Initiator: 1 ~ 10 part; Neutralizing agent: 3 ~ 8 parts; Molecular weight regulator: 0.5 ~ 2 part; Deionized water: 300 ~ 500 parts.
Described emulsifying agent is the combination of reactive emulsifier allyloxy fatty alcohol oxygen Vinyl Ether ammonium sulfate or reactive emulsifier allyloxy fatty alcohol oxygen Vinyl Ether ammonium sulfate and Sodium styrene sulfonate.
Described initiator is any one or combination of ammonium persulphate, Sodium Persulfate, Potassium Persulphate.
Described neutralizing agent is any one or combination of ammoniacal liquor, sodium hydroxide, potassium hydroxide.
Described molecular weight regulator is any one or combination of n-dodecyl mercaptan, tertiary lauryl mercaptan.
Prepare a kind of method of ambient self-crosslinking wood lacquer emulsion, it is characterized in that:
(1) in reactor, add the emulsifier aqueous solution of 10-50%, stir, be warming up to 75 DEG C, stop heating;
(2) in emulsifying kettle, monomer material is joined successively in the residual emulsifier aqueous solution under high speed dispersion state, stir 30 ~ 40 minutes;
(3) then the monomer pre-emulsion of 5% being joined in reactor, add initiator solution and be incubated 15 minutes, when temperature of reaction kettle is to starting when 80 DEG C to drip residue emulsion and initiator solution, dripping off in 3 ~ 3.5 hours;
(4) 80 ~ 84 DEG C of inside holding 1 ~ 1.5 hour after being added dropwise to complete, then, reactor starts to be cooled to 35 ~ 40 DEG C;
(5) in reactor, add neutralizing agent, adipic dihydrazide, stir and filter and package after 30 ~ 40 minutes.
The present invention compared with the existing technology, adopts the crosslinking reaction of acetoacetoxyethyl methacrylate and adipic dihydrazide, the excellent performance of its film.
Embodiment
The experimental technique of unreceipted actual conditions in the following example, usually conveniently condition, or the condition that manufacturer provides is carried out.
Embodiment 1
A preparation method for room-temperature self crosslinking wood lacquer emulsion, comprises the following steps:
(1) be equipped with in the 1000ml four-hole boiling flask of whipping appts, thermometer and logical nitrogen protection at one successively and add 3.75g emulsifying agent (SR-10) and 200g deionized water, stir, be warming up to 75 DEG C, stop heating;
(2) in emulsifying kettle, 4.5g emulsifying agent (SR-10), 3.5g Sodium styrene sulfonate are dissolved in 150g deionized water, then 98g methyl methacrylate, 100g vinylbenzene, 122g butyl acrylate, 5.6g methacrylic acid, 8 grams of acetoacetoxyethyl methacrylate, the tertiary lauryl mercaptans of 0.8g are joined successively in emulsifier aqueous solution under high speed dispersion state, stir 30 ~ 40min, obtained monomer pre-emulsion;
(3) the monomer pre-emulsion of 5% is joined in reactor, add 0.6g Sodium Persulfate (being dissolved in the 5g deionized water) aqueous solution, be incubated 15 minutes;
(4) when temperature of reaction kettle is to starting when 80 DEG C to drip residue emulsion and 1.2g Sodium Persulfate (being dissolved in the 30g deionized water) aqueous solution, dripped off in 3 ~ 3.5 hours; 80 ~ 84 DEG C of inside holding 1 ~ 1.5 hour after being added dropwise to complete;
(5) reactor starts to be cooled to 35 ~ 40 DEG C; In reactor, add 4.8g ammoniacal liquor successively, 4g adipic dihydrazide, stir and filter and package after 30 ~ 40 minutes.
In an embodiment of the present invention, deionized water is company's self-control or commercially available, and SR-10 is the allyloxy fatty alcohol oxygen Vinyl Ether ammonium sulfate product that Chinese mugwort Dicon A/S of Japan produces, and all the other are commercially available prod.
Embodiment 2
A preparation method for room-temperature self crosslinking wood lacquer emulsion, comprises the following steps:
(1) be equipped with in the 1000ml four-hole boiling flask of whipping appts, thermometer and logical nitrogen protection at one successively and add 3.5gSR-10 and 200g deionized water, stir, be warming up to 75 DEG C, stop heating;
(2) in emulsifying kettle, 8.25gSR-10 is dissolved in 150g deionized water, then 93.8g methyl methacrylate, 80g vinylbenzene, 102g butyl acrylate, 10g acetoacetoxyethyl methacrylate, 5.9g methacrylic acid, 1g n-dodecyl mercaptan are joined successively in emulsifier aqueous solution under high speed dispersion state, stir 30 ~ 40min, obtained monomer pre-emulsion;
(3) the monomer pre-emulsion of 5% is joined in reactor, add 0.5g Sodium Persulfate (being dissolved in the 5g deionized water) aqueous solution, be incubated 15 minutes;
(4) when temperature of reaction kettle is to starting when 80 DEG C to drip residue emulsion and 1.1g Sodium Persulfate (being dissolved in the 30g deionized water) aqueous solution, dripped off in 3 ~ 3.5 hours; 80 ~ 84 DEG C of inside holding 1 ~ 1.5 hour after being added dropwise to complete;
(5) reactor starts to be cooled to 35 ~ 40 DEG C; In reactor, add 5g ammoniacal liquor successively, 4.5g adipic dihydrazide, stir and filter and package after 30 ~ 40 minutes.
In an embodiment of the present invention, deionized water is company's self-control, and SR-10 is the allyloxy fatty alcohol oxygen Vinyl Ether ammonium sulfate product that Chinese mugwort Dicon A/S of Japan produces.All the other are commercially available prod.
Embodiment 3
The preparation of aqueous woodware paint: the emulsion adding 160g synthesis in Scattered Kettle, under agitation add 1gpH value conditioning agent AMP-95, pH value is adjusted to 8-9, adds 0.8g defoamer BYK-093,0.8g thickening material PU337,1500r/min disperses 15 minutes, add 8g butyl, 8g dipropylene, 1000r/min disperses 10 minutes, then adds 1.2gBYK349 substrate wetting agents, 0.2gBYK-028, water use regulation viscosity, 1000r/min disperses 15 minutes.
The test of water tolerance, alkali resistance, alcohol resistance: test according to GB GB/T23999-2009.As shown in table 1, table 1 is the properties test result of the aqueous woodware paint of embodiment 1 ~ 2.
Table 1
| Project | Embodiment 1 | Embodiment 2 |
| Appearance of film | Normally | Normally |
| Sticking power | 0 grade | 0 grade |
| Surface drying time | 15 minutes | 12 minutes |
| Hardness | 2B | B |
| Water tolerance | Without exception | Without exception |
| Alcohol resistance | Without exception | Without exception |
| Alkali resistance | Without exception | Without exception |
More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.
The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.
Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (6)
1. an ambient self-crosslinking wood lacquer emulsion, is characterized in that: be made up of following composition and parts by weight, methyl methacrylate: 20 ~ 120 parts; Vinylbenzene: 20 ~ 120 parts; Butyl acrylate: 80 ~ 120 parts; Acetoacetoxyethyl methacrylate: 6 ~ 30 parts; Methacrylic acid: 4 ~ 15 parts; Adipic dihydrazide: 3 ~ 15 parts; Emulsifying agent: 3 ~ 15 parts; Initiator: 1 ~ 10 part; Neutralizing agent: 3 ~ 8 parts; Molecular weight regulator: 0.5 ~ 2 part; Deionized water: 300 ~ 500 parts.
2. a kind of ambient self-crosslinking wood lacquer emulsion according to claim 1, is characterized in that: described emulsifying agent is the combination of reactive emulsifier allyloxy fatty alcohol oxygen Vinyl Ether ammonium sulfate or reactive emulsifier allyloxy fatty alcohol oxygen Vinyl Ether ammonium sulfate and Sodium styrene sulfonate.
3. a kind of ambient self-crosslinking wood lacquer emulsion according to claim 1, is characterized in that: described initiator is any one or combination of ammonium persulphate, Sodium Persulfate, Potassium Persulphate.
4. a kind of ambient self-crosslinking wood lacquer emulsion according to claim 1, is characterized in that: described neutralizing agent is any one or combination of ammoniacal liquor, sodium hydroxide, potassium hydroxide.
5. a kind of ambient self-crosslinking wood lacquer emulsion according to claim 1, is characterized in that: described molecular weight regulator is any one or combination of n-dodecyl mercaptan, tertiary lauryl mercaptan.
6. prepare the method for a kind of ambient self-crosslinking wood lacquer emulsion as claimed in claim 1, it is characterized in that:
(1) in reactor, add the emulsifier aqueous solution of 10-50%, stir, be warming up to 75 DEG C, stop heating;
(2) in emulsifying kettle, monomer material is joined successively in the residual emulsifier aqueous solution under high speed dispersion state, stir 30 ~ 40 minutes;
(3) then the monomer pre-emulsion of 5% being joined in reactor, add initiator solution and be incubated 15 minutes, when temperature of reaction kettle is to starting when 80 DEG C to drip residue emulsion and initiator solution, dripping off in 3 ~ 3.5 hours;
(4) 80 ~ 84 DEG C of inside holding 1 ~ 1.5 hour after being added dropwise to complete, then, reactor starts to be cooled to 35 ~ 40 DEG C;
(5) in reactor, add neutralizing agent, adipic dihydrazide, stir and filter and package after 30 ~ 40 minutes.
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| CN201510671622.1A CN105175621A (en) | 2015-10-13 | 2015-10-13 | Normal-temperature-self-crosslinking woodenware paint emulsion and preparation method therefor |
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| CN201510671622.1A CN105175621A (en) | 2015-10-13 | 2015-10-13 | Normal-temperature-self-crosslinking woodenware paint emulsion and preparation method therefor |
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Cited By (7)
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| CN105949375A (en) * | 2016-07-12 | 2016-09-21 | 深圳市长辉新材料科技有限公司 | Resin for carpentry paint and carpentry paint |
| CN106280828A (en) * | 2016-09-14 | 2017-01-04 | 四川力久云智知识产权运营有限公司 | A kind of elastic water proofing paint |
| CN106433373A (en) * | 2016-10-19 | 2017-02-22 | 黄远明 | Room-temperature crosslinked type waterborne paint and preparation method thereof |
| CN110305545A (en) * | 2018-03-20 | 2019-10-08 | 河北晨阳工贸集团有限公司 | A kind of quick-dry type woodenware sealing wax seal coat and preparation method thereof |
| CN110951006A (en) * | 2019-12-26 | 2020-04-03 | 山西省应用化学研究所(有限公司) | Preparation method of room-temperature self-crosslinking water-based alkyd resin |
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Cited By (8)
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| CN106433373A (en) * | 2016-10-19 | 2017-02-22 | 黄远明 | Room-temperature crosslinked type waterborne paint and preparation method thereof |
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