CN105174840A - Diatomite and fly ash type caulking agent composition and application thereof - Google Patents
Diatomite and fly ash type caulking agent composition and application thereof Download PDFInfo
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- CN105174840A CN105174840A CN201510548821.3A CN201510548821A CN105174840A CN 105174840 A CN105174840 A CN 105174840A CN 201510548821 A CN201510548821 A CN 201510548821A CN 105174840 A CN105174840 A CN 105174840A
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000010881 fly ash Substances 0.000 title claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 title abstract 5
- 239000004568 cement Substances 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001913 cellulose Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 11
- 239000004113 Sepiolite Substances 0.000 claims abstract description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 10
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 4
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims abstract description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 4
- 239000000919 ceramic Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 5
- 238000005192 partition Methods 0.000 claims description 4
- 229940071826 hydroxyethyl cellulose Drugs 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000003469 silicate cement Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 abstract 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 abstract 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 abstract 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 230000006835 compression Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 7
- 239000006004 Quartz sand Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000000035 biogenic effect Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000206761 Bacillariophyta Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention provides a diatomite and fly ash type caulking agent composition and application thereof. The composition is composed of the following components by weight: (1) 20 to 40 parts of diatomite; (2) 10 to 15 parts of fly ash; (3) 0.5 to 2.5 parts of bentonite; (4) 4 to 6 parts of heavyweight calcium carbonate; (5) 1 to 2 parts of sodium silicate; (6) 10 to 20 parts of calcite powder; (7) 4 to 8 parts of sepiolite powder; (8) 2 to 4 parts of titanium dioxide; (9) 1 to 2 parts of cellulose, wherein the cellulose is at least one selected from the group consisting of hydroxyethyl cellulose, hydroxyethyl methyl cellulose and hydroxypropyl methyl cellulose; and (10) 30 to 40 parts of cement. The invention also provides the application of the composition in caulking operation. The cement-based caulking agent composition provided by the invention has various advantages of the diatomite, such as performances of the diatomite itself of light weight, sound insulation, wear resistance, etc.; meanwhile, the fly ash can be utilized to prepare the caulking agent in the invention, thereby reducing production cost of the caulking agent.
Description
Technical field
The present invention relates to building material field, especially relate to spackling and application thereof.
Background technology
Diatomite is a kind of biogenic silicastone, be the remains of the diatoms grown in ocean or lake at subaqueous deposit, a kind of non-metallic minerals formed gradually through physical environment effect.Diatomite is mainly distributed in the states such as China, the U.S., Denmark, France, Romania.Be a kind of biogenic silicastone, it formed primarily of the remains of diatom in ancient times.China's diatomite reserves 3.2 hundred million tons, prospective reserves reaches more than 20 hundred million tons, mainly concentrates on East China and the Northeast, wherein larger, and what reserves were more has the provinces such as Jilin (54.8%), Zhejiang, Yunnan, Shandong, Sichuan.
Diatomite tool has the following advantages.(1) pH value is neutral, nontoxic, and suspension property is good, and absorption property is strong, and unit weight is light, and mixing uniformity is good; (2) diatomite makes additive in cement, can improve intensity, makes SiO2 in cement become active; (3) diatomite has excellent extensibility, has the aspect high-quality effects such as the soft wear resistance of higher shock strength, tensile strength, tear strength, light weight is good, ultimate compression strength is good.
Flyash is the powder collected from coal-powder boiler flue gas.Shi Ge big coal country of China take coal as the basic fuel of electrical production.The energy industry stable development of China, power generation capacity annual growth is 7.3%, developing rapidly of power industry, bring the sharply increase of flyash quantity discharged, annual the discharged flyash total amount of Hazards in Power Plant increases year by year, nineteen ninety-five flyash quantity discharged reach 1.25 hundred million tons, within 2000, be about 1.5 hundred million tons, 300,000,000 tons will be reached by 2010, cause huge pressure to the development of the national economy of China and ecotope.On the other hand, China is again the limited country of a per capita resource reserve, the comprehensive utilization of flyash, turn waste into wealth, turn bane into boon, to become in China's economic construction an important techno-economic policy, solve China electrical production environmental pollution, the important means of contradiction between resource shortage, be also electrical production one of the task of facing solution.
Spackling is all products being applicable to fill seam between ceramic tile.Spackling can be divided into cement based spackling, reactive resin spackling and liquid form mixt or emulsion admixture.Wherein cement based spackling generally could mix with water or liquid form mixt before use.Spackling mainly contains cement based spackling and reactive resin type spackling on the market at present.Cement based spackling has two large inferior positions: (1) water proof anti-seepage ability, and water easily penetrates into, and causes mouldy, makes ceramic tile easily shrink hollowing; (2) surface abrasion resistance is not good enough, and easy contaminated thing is stained, and cleans difficulty, causes decorative effect poor, affect ceramic tile attractive in appearance.Though reactive resin spackling can overcome above inferior position, material, packing cost are too high, produce, mixing procedure is loaded down with trivial details, in addition containing toxic and harmfuls such as volatile organic compoundss, make it apply and are restricted.
Although diatomite has above-mentioned plurality of advantages, due to its porosity and extensibility high and make it be generally considered improper for spackling.
Summary of the invention
In cement based spackling, using existing problem in order to solving diatomite, the invention provides a kind of diatomite-flyash type underfill composition and application thereof.
First aspect present invention provides a kind of diatomite-flyash type underfill composition, wherein, and described composition composed as follows:
The diatomite of (1) 20 weight part to 40 weight part;
The flyash of (2) 10 weight part to 15 weight parts, or the quartz sand of 20 weight part to 40 weight parts;
The wilkinite of (3) 0.5 weight part to 2.5 weight parts;
The water-ground limestone of (4) 4 weight part to 6 weight parts;
The water glass of (5) 1 weight part to 2 weight parts;
The calcite in powder of (6) 10 weight part to 20 weight parts;
The sepiolite powder of (7) 4 weight part to 8 weight parts;
The titanium dioxide of (8) 2 weight part to 4 weight parts;
The Mierocrystalline cellulose of (9) 1 weight part to 2 weight parts, described Mierocrystalline cellulose selects at least one in free hydroxy ethyl cellulose, hydroxyethylmethyl-cellulose, Vltra tears; With
The cement of (10) 30 weight part to 40 weight parts.
The present invention provides composition described in first aspect present invention as the application in partition wall spackling in second aspect.
The invention enables and diatomite can be used as spackling, the various advantages making spackling can have diatomite thus to bring, such as (1) pH value is neutral, nontoxic, and unit weight is light, and mixing uniformity is good; (2) diatomite makes additive in cement, can improve intensity, makes SiO2 in cement become active; (3) diatomite has the aspect high-quality effects such as the soft wear resistance of higher shock strength, tensile strength, tear strength, light weight is good, ultimate compression strength is good, can reduce and cause flexible because of humidity change.Therefore, diatomite of the present invention-flyash type underfill composition is a kind of spackling with excellent properties, is particularly suitable for the joint filling operation of indoor partition wall ceramic surface tile.
Embodiment
The present invention provides a kind of diatomite-flyash type underfill composition in first aspect, wherein, and described composition composed as follows:
The diatomite of (1) 20 weight part to 40 weight part (being such as 20,30 or 40 weight parts);
The flyash of (2) 10 weight part to 15 weight parts (being such as 10,11,12,13,14 or 15 weight parts), or the quartz sand of 20 weight part to 40 weight parts (being such as 20,30 or 40 weight parts);
The wilkinite of (3) 0.5 weight part to 2.5 weight parts (being such as 0.5,1,1.5,2 or 2.5 weight parts);
The water-ground limestone of (4) 4 weight part to 6 weight parts (being such as 4,5 or 6 weight parts);
(5) 1 weight part to 2 weight parts can be such as 1,1.5 or 2 weight parts) water glass;
The calcite in powder of (6) 10 weight part to 20 weight parts (being such as 10,15 or 20 weight parts);
The sepiolite powder of (7) 4 weight part to 8 weight parts (being such as 4,6 or 8 weight parts);
The titanium dioxide of (8) 2 weight part to 4 weight parts (being such as 2,3 or 4 weight parts);
The Mierocrystalline cellulose of (9) 1 weight part to 2 weight parts (can be such as 1,1.5 or 2 weight parts), described Mierocrystalline cellulose selects at least one in free hydroxy ethyl cellulose, hydroxyethylmethyl-cellulose, Vltra tears; With
The cement of (10) 30 weight part to 40 weight parts (can be such as 30,35 or 40 weight parts).
The present inventor finds, if diatomaceous consumption is too low, then after freeze-thaw cycle, folding strength and ultimate compression strength may be not enough; If consumption is excessive, then may not reach the requirement of linear shrinkage and water-absorbent aspect.In addition, if do not use wilkinite and sepiolite, the requirement of linear shrinkage and water-absorbent aspect cannot be obtained equally.If adopt above-mentioned system, then can use diatomite in the preparation of spackling, make obtained spackling have diatomaceous many premium propertiess thus.And the present inventor enters a discovery, utilizes above-mentioned system, flyash can also be applied to the preparation of spackling, thus with low cost and eco-friendly mode obtained meet each performance index require spackling.
Some preferred embodiment in, described composition is by the diatomite of 30 weight parts; The flyash of 15 weight parts; The wilkinite of 1.5 weight parts; The water-ground limestone of 5 weight parts; The water glass of 1.5 weight parts; The calcite in powder of 15 weight parts; The sepiolite powder of 6 weight parts; The titanium dioxide of 3 weight parts; With the described Mierocrystalline cellulose of 1.5 weight parts and the cement composition of 35 weight parts.
Some preferred embodiment in, the particle diameter of described diatomite and/or described flyash is 20 microns to 80 microns, such as, be 20,30,40,50,60,70 or 80 microns.
Some preferred embodiment in, the particle diameter of described sepiolite powder is 20 microns to 40 microns, such as 20,30 or 40 microns.
Some preferred embodiment in, described diatomaceous dioxide-containing silica is more than 80 quality %, such as, can be the silicon-dioxide of 80,85,90,95,99 quality %.
Some preferred embodiment in, described cement is I type silicate cement.
Some preferred embodiment in, 200 mesh sieve margins of described composition are less than 2 quality %, such as, can be less than 2 quality %, 1 quality % or 0.5 quality %.
The present invention provides composition described in first aspect present invention as the application in partition wall spackling in second aspect.Some preferred embodiment in, it is the joint filling operation in the gap being less than or equal to 5mm that described composition is used for width.Other preferred embodiment in, described composition is used for the joint filling operation in ceramic surface tile gap.
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
Underfill composition of the present invention is prepared according to the combination shown in following table 1 and consumption.Wherein, the particle diameter of described diatomite and described quartz sand or described flyash is about 40 microns, and described diatomaceous dioxide-containing silica is about 80 quality %, and described flyash is require (namely according to the table 2 in (GB/T1596-2005) standard satisfied 4.2, loss on ignition % is not more than 5%, water content % is not more than 1%, sulphur trioxide % is not more than 3%, and within 28 days, compressive strength rate % is not more than 75%) manufacture of cement in make the I level flyash of active addition; The particle diameter of described sepiolite powder is about 30 microns; Described cement is I type silicate cement; 200 mesh sieve margins of other raw materials are less than 1 quality %, and Mierocrystalline cellulose is Natvosol.By above raw material with the rotating speed ground and mixed 10 minutes of 200rmp, obtain underfill composition of the present invention.
Then, measured the folding strength under the wearability of resulting composition, standard conditions maintenance, the folding strength after freeze-thaw cycle, the ultimate compression strength under standard conditions maintenance, ultimate compression strength after freeze-thaw cycle, linear shrinkage, the water regain after 30 minutes and the water regain after 240 minutes by method shown in following table 2 and judge gained combines whether meet JC/T1004-2006 standard, each experiment repetition 3 times, and being identified as that 3 judgements all meet meets, as long as 3 judgements are once incongruent, regard as and do not meet, the results are shown in Table 3.
Embodiment 2 to 16
Except content shown in table 1, prepare composition in the mode identical with embodiment and measure each performance index.
Component and consumption (weight part) that underfill composition uses is manufactured in table 1 embodiment 1 to 16
Table 2 cement based spackling standard
| Performance index | Requirement | Testing method |
| Wearability | ≤2000mm 3 | The test of water regain |
| Folding strength under standard conditions maintenance | ≥3.5N/mm 2 | Folding strength and intensity test |
| Folding strength after freeze-thaw cycle | ≥3.5N/mm 2 | Folding strength and intensity test |
| Ultimate compression strength under standard conditions maintenance | ≥15N/mm 2 | Folding strength and intensity test |
| Ultimate compression strength after freeze-thaw cycle | ≥15N/mm 2 | Folding strength and intensity test |
| Linear shrinkage | ≤2mm/m | The test of linear shrinkage |
| Water regain after 30min | ≤5g | The test of water regain |
| Water regain after 240min | ≤10g | The test of water regain |
Note: according to the classification of JC/T1004-2006 standard, diatomite of the present invention-flyash type underfill composition belongs to cement based spackling type.
The performance of cement based underfill composition obtained in table 3 embodiment 1 to 16
Embodiment 17 to 25
Based on the result in embodiment 1 to 16, and see the nominal price of flyash and the needs of utilization of waste material, the present inventor uses flyash to replace quartz sand, manufactures spackling in a manner similar to example 1 and detects the performance index (see table 4 and 5) of spackling.
Component and consumption (weight part) that underfill composition uses is manufactured in table 4 embodiment 17 to 25
The performance of cement based underfill composition obtained in table 5 embodiment 17 to 25
As can be seen from the result of table 5, although in above-mentioned system, the utilization of flyash is mainly limited to the problem of undercapacity, and it is possible for using flyash to manufacture spackling, such as, can use flyash with 10 weight part to 15 weight parts.
Claims (10)
1. diatomite-flyash type underfill composition, wherein, described composition composed as follows:
The diatomite of (1) 20 weight part to 40 weight part;
The flyash of (2) 10 weight part to 15 weight parts;
The wilkinite of (3) 0.5 weight part to 2.5 weight parts;
The water-ground limestone of (4) 4 weight part to 6 weight parts;
The water glass of (5) 1 weight part to 2 weight parts;
The calcite in powder of (6) 10 weight part to 20 weight parts;
The sepiolite powder of (7) 4 weight part to 8 weight parts;
The titanium dioxide of (8) 2 weight part to 4 weight parts;
The Mierocrystalline cellulose of (9) 1 weight part to 2 weight parts, described Mierocrystalline cellulose selects at least one in free hydroxy ethyl cellulose, hydroxyethylmethyl-cellulose, Vltra tears; With
The cement of (10) 30 weight part to 40 weight parts.
2. composition according to claim 1, wherein, described composition is by the diatomite of 30 weight parts; The flyash of 15 weight parts; The wilkinite of 1.5 weight parts; The water-ground limestone of 5 weight parts; The water glass of 1.5 weight parts; The calcite in powder of 15 weight parts; The sepiolite powder of 6 weight parts; The titanium dioxide of 3 weight parts; With the described Mierocrystalline cellulose of 1.5 weight parts and the cement composition of 35 weight parts.
3. composition according to claim 1 and 2, wherein, the particle diameter of described diatomite and/or described flyash is 20 microns to 80 microns.
4. composition according to any one of claim 1 to 3, wherein, the particle diameter of described sepiolite powder is 20 microns to 40 microns.
5. composition according to any one of claim 1 to 4, wherein, described diatomaceous dioxide-containing silica is more than 80 quality %.
6. composition according to any one of claim 1 to 5, wherein, described cement is I type silicate cement.
7. the composition according to any one of a claim 1 to 5, wherein, 200 mesh sieve margins of described composition are less than 2 quality %.
8. the composition according to any one of claim 1 to 7 is as the application in partition wall spackling.
9. application according to claim 8, wherein, described composition is used for the joint filling operation that width is the gap being less than or equal to 5mm.
10. method as claimed in claim 8 or 9, wherein, described composition is used for the joint filling operation in ceramic surface tile gap.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510548821.3A CN105174840B (en) | 2015-08-31 | 2015-08-31 | A kind of kieselguhr-flyash type underfill composition and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510548821.3A CN105174840B (en) | 2015-08-31 | 2015-08-31 | A kind of kieselguhr-flyash type underfill composition and application thereof |
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| CN105174840A true CN105174840A (en) | 2015-12-23 |
| CN105174840B CN105174840B (en) | 2016-07-06 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107140914A (en) * | 2017-06-20 | 2017-09-08 | 合肥市淑芹美装饰工程有限公司 | A kind of stain resistant flashing compound and preparation method thereof |
| CN107473654A (en) * | 2017-08-01 | 2017-12-15 | 合肥广民建材有限公司 | A kind of antibacterial resistant tile grout and preparation method thereof |
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| CN101774787A (en) * | 2010-01-11 | 2010-07-14 | 南京工业大学 | Joint mixture for color or color-change ceramic wall and floor tiles |
| CN101817666A (en) * | 2009-02-26 | 2010-09-01 | 北京东方雨虹防水技术股份有限公司 | Dry-powder color tile grout and preparation process thereof |
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| CN104556908A (en) * | 2014-12-31 | 2015-04-29 | 长安大学 | Fiber-reinforced plastering mortar and preparation method thereof |
| CN104844080A (en) * | 2015-04-03 | 2015-08-19 | 四川雅豪房地产开发有限公司 | Crack-resistant long-life door and window joint filling and sealing mortar manufacturing method |
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| CN101817666A (en) * | 2009-02-26 | 2010-09-01 | 北京东方雨虹防水技术股份有限公司 | Dry-powder color tile grout and preparation process thereof |
| CN101774787A (en) * | 2010-01-11 | 2010-07-14 | 南京工业大学 | Joint mixture for color or color-change ceramic wall and floor tiles |
| CN102140025A (en) * | 2010-01-29 | 2011-08-03 | 郭太宗 | Alkali-resistant high-class ceramic tile sealant |
| CN104556908A (en) * | 2014-12-31 | 2015-04-29 | 长安大学 | Fiber-reinforced plastering mortar and preparation method thereof |
| CN104844080A (en) * | 2015-04-03 | 2015-08-19 | 四川雅豪房地产开发有限公司 | Crack-resistant long-life door and window joint filling and sealing mortar manufacturing method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107140914A (en) * | 2017-06-20 | 2017-09-08 | 合肥市淑芹美装饰工程有限公司 | A kind of stain resistant flashing compound and preparation method thereof |
| CN107473654A (en) * | 2017-08-01 | 2017-12-15 | 合肥广民建材有限公司 | A kind of antibacterial resistant tile grout and preparation method thereof |
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| Publication number | Publication date |
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| CN105174840B (en) | 2016-07-06 |
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