CN105174489B - A kind of grease type sewage-treating agent - Google Patents
A kind of grease type sewage-treating agent Download PDFInfo
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- CN105174489B CN105174489B CN201510573857.7A CN201510573857A CN105174489B CN 105174489 B CN105174489 B CN 105174489B CN 201510573857 A CN201510573857 A CN 201510573857A CN 105174489 B CN105174489 B CN 105174489B
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 60
- 239000004519 grease Substances 0.000 title claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 108090000790 Enzymes Proteins 0.000 claims abstract description 21
- 102000004190 Enzymes Human genes 0.000 claims abstract description 21
- 229940123973 Oxygen scavenger Drugs 0.000 claims abstract description 16
- 238000005189 flocculation Methods 0.000 claims abstract description 16
- 230000016615 flocculation Effects 0.000 claims abstract description 16
- 239000008396 flotation agent Substances 0.000 claims abstract description 16
- 239000004088 foaming agent Substances 0.000 claims abstract description 16
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 16
- 239000000417 fungicide Substances 0.000 claims abstract description 16
- -1 polyethylene Polymers 0.000 claims description 39
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 21
- 229940088598 enzyme Drugs 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 14
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 14
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 14
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 14
- 239000004367 Lipase Substances 0.000 claims description 13
- 102000004882 Lipase Human genes 0.000 claims description 13
- 108090001060 Lipase Proteins 0.000 claims description 13
- 235000019421 lipase Nutrition 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 claims description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 7
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical group CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 7
- 229940120146 EDTMP Drugs 0.000 claims description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 229940037003 alum Drugs 0.000 claims description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 7
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 7
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- HFZBBUZOFCWNDE-UHFFFAOYSA-O dodecylazanium;nitrate Chemical compound [O-][N+]([O-])=O.CCCCCCCCCCCC[NH3+] HFZBBUZOFCWNDE-UHFFFAOYSA-O 0.000 claims description 7
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- 229920000768 polyamine Polymers 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 7
- 235000010413 sodium alginate Nutrition 0.000 claims description 7
- 239000000661 sodium alginate Substances 0.000 claims description 7
- 229940005550 sodium alginate Drugs 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 235000010265 sodium sulphite Nutrition 0.000 claims description 7
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 claims description 7
- 239000001828 Gelatine Substances 0.000 claims description 6
- 229920000159 gelatin Polymers 0.000 claims description 6
- 235000019322 gelatine Nutrition 0.000 claims description 6
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 150000003009 phosphonic acids Chemical class 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 108010059892 Cellulase Proteins 0.000 claims description 2
- 229940106157 cellulase Drugs 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 239000010865 sewage Substances 0.000 abstract description 9
- 238000012545 processing Methods 0.000 abstract description 7
- 230000009972 noncorrosive effect Effects 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 12
- 239000002351 wastewater Substances 0.000 description 8
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 6
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 6
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 6
- 241001614291 Anoplistes Species 0.000 description 5
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 108090000604 Hydrolases Proteins 0.000 description 1
- 102000004157 Hydrolases Human genes 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000003745 glyceroyl group Chemical group C(C(O)CO)(=O)* 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- RJQRSXSVTJIKOH-UHFFFAOYSA-N hexadecyl(trimethyl)azanium;nitrate Chemical compound [O-][N+]([O-])=O.CCCCCCCCCCCCCCCC[N+](C)(C)C RJQRSXSVTJIKOH-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses a kind of grease type sewage-treating agents, belong to sewage-treating agent preparing technical field.The grease type sewage-treating agent is as unit of parts by weight, including following raw material：40 80 parts of enzyme agent, 40 80 parts of demulsifier, 30 60 parts of flocculant, 30 60 parts of flocculation aid, 30 60 parts of foaming agent, 20 50 parts of flotation agent, 20 50 parts of fungicide, slow rotten 10 20 parts of antisludging agent, 10 20 parts of oxygen scavenger.The beneficial effects of the invention are as follows：The existence form of " Water-In-Oil ", " oil-in-water " can be broken in water body, quickly remove a large amount of SS, grease, COD, it is efficient, it is non-corrosive, secondary pollution will not be caused to later stage sewage, reduces processing cost.
Description
【Technical field】
The present invention relates to sewage-treating agent preparing technical fields, and in particular to a kind of grease type sewage-treating agent.
【Background technology】
Oil wastewater have water is big, variation water quality is very big, oil content high (oil emulsion, dissolubility oil, phosphatide, soap stock),
The features such as COD high, suspension content are big, acidity is strong, complicated component.Current processing method is based on biological treatment, simultaneously
Necessary pretreatment and physical chemistry advanced treating need to be aided with.Materilization freatment method mainly by addition flocculant, makes water body
Middle grease, suspension polymerization by way of precipitating or floating, realize that grease, suspended matter are detached with water body.The wadding of background technology
Solidifying agent is mainly polyaluminium salts and molysite, but in practical water body, and the existence form of oil and water only has " oil-in-water " or " Water-In-Oil "
Two kinds of situations, the flocculant by current background technology are difficult to be completely separated, and water body color does not have apparent desalination, and its is water-soluble
Liquid is acidity, has certain corrosivity to equipment such as pipelines, and can increase subsequent processing cost.Therefore, it researches and develops a kind of high
Efficiency, corrosion-free, environmentally friendly grease type sewage-treating agent are development trends.
【Invention content】
The present invention provides a kind of grease type sewage-treating agent, with solve existing inorganic agent processing grease type sewage effect it is poor, into
The problems such as this is high.The sewage-treating agent of the present invention can thoroughly break in water body the existence form of " Water-In-Oil ", " oil-in-water ", soon
Speed removes a large amount of SS, grease, COD, efficient, non-corrosive, will not cause secondary pollution to later stage sewage, reduction is processed into
This.
For solution more than technical problem, the present invention uses following technical scheme：
A kind of grease type sewage-treating agent, as unit of parts by weight, including following raw material：40-80 parts of enzyme agent, demulsifier
40-80 parts, 30-60 parts of flocculant, 30-60 parts of flocculation aid, 30-60 parts of foaming agent, 20-50 parts of flotation agent, fungicide 20-50
Part, slow rotten 10-20 parts of antisludging agent, 10-20 parts of oxygen scavenger.
Preferably, the enzyme agent is as unit of parts by weight, including following raw material：20-40 parts of Whole-cell lipase, three acyl groups
- 20 parts of glyceroyl hydrolase 10,10-20 parts of cellulase.
Preferably, the demulsifier is as unit of parts by weight, including following raw material：10-20 parts of fatty alcohol polyoxyethylene ether,
10-20 parts of polyethylene polyamine polyoxyethylene polyoxypropylene ether, 8-16 parts of secondary octyl phenol polyethenoxy ether, propylene oxide 6-12
Part, 3-6 parts of ethylene oxide, 3-6 parts of potassium hydroxide.
Preferably, the flocculant is as unit of parts by weight, including following raw material：12-30 parts of zirconium sulfate, aluminum sulfate 10-
16 parts, 8-14 parts of alum.
Preferably, the flocculation aid is as unit of parts by weight, including following raw material：10-20 parts of polyacrylamide, polypropylene
Sour sodium 10-20 parts, 5-10 parts of activated silicic acid, 3-6 parts of gelatine, 2-4 parts of sodium alginate.
Preferably, the foaming agent is as unit of parts by weight, including following raw material：8-16 parts of alkyl propanesulfonate, alkyl
8-16 parts of sodium sulfonate, 4-10 parts of cetyl trimethyl ammonium nitrate, 10-18 parts of water.
Preferably, the flotation agent is as unit of parts by weight, including following raw material：The double dodecyl ammonium nitrate 6- of dimethyl
20 parts, 8-20 parts of sodium carbonate, 6-10 parts of thio urea.
Preferably, the fungicide is as unit of parts by weight, including following raw material：5-15 parts of propylene oxide, butanediol 4-
10 parts, 4-10 parts of glycerine, -5 parts of Catechol 2,2-5 parts of resorcinol, 2-5 parts of three octyl tertiary amine.
Preferably, the slow rotten antisludging agent is as unit of parts by weight, including following raw material：4-8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid,
3-6 parts of ethylene diamine tetra methylene phosphonic acid, 3-6 parts of diethylenetriamine pentamethylphosphonic acid.
Preferably, the oxygen scavenger is as unit of parts by weight, including following raw material：3-6 parts of sodium sulfite, ammonium bisulfite
2-4 parts, 2-4 parts of sulfur dioxide, 2-4 parts of hydrazine, 1-2 parts of sodium hydrogensulfite.
Grease type sewage-treating agent of the present invention uses conventional method mixed preparing, and a certain amount of water is taken to add in enzyme by proportioning
Agent, demulsifier, flocculant, flocculation aid, foaming agent, flotation agent, fungicide, slow rotten antisludging agent, oxygen scavenger, are stirred at room temperature,
All it can be used after dissolving.
The technology of the present invention feature：
(1) have a wide range of application, suitable for any greasy chemical wastewater, including edible oil waste water, the refinement of gutter oil, oils
The waste water such as chemical products manufacture waste water, biodiesel；
(2) properties of product are reliable, temperature change is required it is low, it is non-corrosive without hardened, later stage sewage can't be caused
Secondary pollution；
(3) in use, ton water process dosage is low, and molecule content is high, is 2.5-3 times of common flocculant, cotton-shaped
Body surface area is common 3-4 times；
(4) water body molecular surface tension can be broken, the quick suspended matter for realizing polymerization sinks or floats.
The invention has the advantages that：
(1) inorganic agent of the present invention is suitable for the oily wastewater of processing grease type, after adding in inorganic agent of the present invention in sewage, hangs
Float is flocculated at once, and precipitation is quick, and Floc strength is high, and hydrophobic performance is good, and conducive to press filtration, the filter cake moisture content after press filtration is low, matter
Measure excellent, 25%-35% of the cost for conventional treatment agent cost needed for every cube of sewage of processing；
(2) pH value of solution after inorganic agent treated sewage of the present invention is used to be similar to neutrality for 6.7-7.3, without chlorine from
Son after water reuse is handled, can effectively protect the steel construction in aqueous systems, make it from corrosion, equipment maintenance cost reduces 3 times
More than；
(3) inorganic agent of the present invention has many advantages, such as non-toxic, safe and environment-friendly, on health without influence, handles grease type
Oily wastewater after non-secondary pollution the problems such as, reduce 2-3 times of cost of post-processing.
【Specific embodiment】
It is specifically described with reference to specific embodiment.
Embodiment 1
A kind of grease type sewage-treating agent, as unit of parts by weight, including following raw material：40 parts of enzyme agent, 40 parts of demulsifier,
30 parts of flocculant, 30 parts of flocculation aid, 30 parts of foaming agent, 20 parts of flotation agent, 20 parts of fungicide, slow rotten 10 parts of antisludging agent, oxygen scavenger
10 parts,
The enzyme agent includes following raw material：20 parts of Whole-cell lipase, 10 parts of Lipase, cellulose
10 parts of enzyme；
The demulsifier includes following raw material：10 parts of fatty alcohol polyoxyethylene ether, polyethylene polyamine polyoxypropylene polyoxy
10 parts of vinethene, 8 parts of secondary octyl phenol polyethenoxy ether, 6 parts of propylene oxide, 3 parts of ethylene oxide, 3 parts of potassium hydroxide；
The flocculant includes following raw material：12 parts of zirconium sulfate, 10 parts of aluminum sulfate, 8 parts of alum；
The flocculation aid includes following raw material：10 parts of polyacrylamide, 10 parts of Sodium Polyacrylate, 5 parts of activated silicic acid, gelatine
3 parts, 2 parts of sodium alginate；
The foaming agent includes following raw material：8 parts of alkyl propanesulfonate, 8 parts of sodium alkyl sulfonate, cetyl trimethyl nitre
Sour 4 parts of ammonium, 10 parts of water；
The flotation agent includes following raw material：Double 6 parts of the dodecyl ammonium nitrate of dimethyl, 8 parts of sodium carbonate, thio urea 6
Part；
The fungicide includes following raw material：5 parts of propylene oxide, 4 parts of butanediol, 4 parts of glycerine, Catechol 2 part, isophthalic
2 parts of diphenol, 2 parts of three octyl tertiary amine；
The slow rotten antisludging agent includes following raw material：4 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 3 parts of ethylene diamine tetra methylene phosphonic acid, two Asias
3 parts of ethyl triamine pentamethyl phosphonic acids；
The oxygen scavenger includes following raw material：3 parts of sodium sulfite, 2 parts of ammonium bisulfite, 2 parts of sulfur dioxide, 2 parts of hydrazine,
1 part of sodium hydrogensulfite.
Embodiment 2
A kind of grease type sewage-treating agent, as unit of parts by weight, including following raw material：80 parts of enzyme agent, 80 parts of demulsifier,
60 parts of flocculant, 60 parts of flocculation aid, 60 parts of foaming agent, 50 parts of flotation agent, 50 parts of fungicide, slow rotten 20 parts of antisludging agent, oxygen scavenger
20 parts,
The enzyme agent includes following raw material：40 parts of Whole-cell lipase, 20 parts of Lipase, cellulose
20 parts of enzyme；
The demulsifier includes following raw material：20 parts of fatty alcohol polyoxyethylene ether, polyethylene polyamine polyoxypropylene polyoxy
20 parts of vinethene, 16 parts of secondary octyl phenol polyethenoxy ether, 12 parts of propylene oxide, 6 parts of ethylene oxide, 6 parts of potassium hydroxide；
The flocculant includes following raw material：30 parts of zirconium sulfate, 16 parts of aluminum sulfate, 14 parts of alum；
The flocculation aid includes following raw material：20 parts of polyacrylamide, 20 parts of Sodium Polyacrylate, 10 parts of activated silicic acid, bone
6 parts of glue, 4 parts of sodium alginate；
The foaming agent includes following raw material：16 parts of alkyl propanesulfonate, 16 parts of sodium alkyl sulfonate, cetyl trimethyl
10 parts of ammonium nitrate, 18 parts of water；
The flotation agent includes following raw material：Double 20 parts of the dodecyl ammonium nitrate of dimethyl, 20 parts of sodium carbonate, thio urea
10 parts；
The fungicide includes following raw material：15 parts of propylene oxide, 10 parts of butanediol, 10 parts of glycerine, 5 parts of catechol,
5 parts of resorcinol, 5 parts of three octyl tertiary amine；
The slow rotten antisludging agent includes following raw material：8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 6 parts of ethylene diamine tetra methylene phosphonic acid, two Asias
6 parts of ethyl triamine pentamethyl phosphonic acids；
The oxygen scavenger includes following raw material：6 parts of sodium sulfite, 4 parts of ammonium bisulfite, 4 parts of sulfur dioxide, 4 parts of hydrazine,
2 parts of sodium hydrogensulfite.
Embodiment 3
A kind of grease type sewage-treating agent, as unit of parts by weight, including following raw material：60 parts of enzyme agent, 60 parts of demulsifier,
45 parts of flocculant, 45 parts of flocculation aid, 45 parts of foaming agent, 35 parts of flotation agent, 35 parts of fungicide, slow rotten 15 parts of antisludging agent, oxygen scavenger
15 parts,
The enzyme agent includes following raw material：30 parts of Whole-cell lipase, 15 parts of Lipase, cellulose
15 parts of enzyme；
The demulsifier includes following raw material：15 parts of fatty alcohol polyoxyethylene ether, polyethylene polyamine polyoxypropylene polyoxy
15 parts of vinethene, 12 parts of secondary octyl phenol polyethenoxy ether, 8 parts of propylene oxide, 5 parts of ethylene oxide, 5 parts of potassium hydroxide；
The flocculant includes following raw material：20 parts of zirconium sulfate, 13 parts of aluminum sulfate, 12 parts of alum；
The flocculation aid includes following raw material：15 parts of polyacrylamide, 15 parts of Sodium Polyacrylate, 9 parts of activated silicic acid, gelatine
4 parts, 2 parts of sodium alginate.
The foaming agent includes following raw material：12 parts of alkyl propanesulfonate, 12 parts of sodium alkyl sulfonate, cetyl trimethyl
8 parts of ammonium nitrate, 13 parts of water；
The flotation agent includes following raw material：Double 13 parts of the dodecyl ammonium nitrate of dimethyl, 14 parts of sodium carbonate, thio urea
8 parts；
The fungicide includes following raw material：10 parts of propylene oxide, 8 parts of butanediol, 8 parts of glycerine, catechol 3 part,
3 parts of benzenediol, 3 parts of three octyl tertiary amine；
The slow rotten antisludging agent includes following raw material：6 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 5 parts of ethylene diamine tetra methylene phosphonic acid, two Asias
4 parts of ethyl triamine pentamethyl phosphonic acids；
The oxygen scavenger includes following raw material：5 parts of sodium sulfite, 3 parts of ammonium bisulfite, 3 parts of sulfur dioxide, 3 parts of hydrazine,
1 part of sodium hydrogensulfite.
Embodiment 4
A kind of grease type sewage-treating agent, as unit of parts by weight, including following raw material：50 parts of enzyme agent, 50 parts of demulsifier,
40 parts of flocculant, 40 parts of flocculation aid, 40 parts of foaming agent, 30 parts of flotation agent, 30 parts of fungicide, slow rotten 12 parts of antisludging agent, oxygen scavenger
12 parts,
The enzyme agent includes following raw material：25 parts of Whole-cell lipase, 13 parts of Lipase, cellulose
12 parts of enzyme.
The demulsifier includes following raw material：12 parts of fatty alcohol polyoxyethylene ether, polyethylene polyamine polyoxypropylene polyoxy
12 parts of vinethene, 10 parts of secondary octyl phenol polyethenoxy ether, 8 parts of propylene oxide, 4 parts of ethylene oxide, 4 parts of potassium hydroxide；
The flocculant includes following raw material：18 parts of zirconium sulfate, 12 parts of aluminum sulfate, 10 parts of alum；
The flocculation aid includes following raw material：14 parts of polyacrylamide, 13 parts of Sodium Polyacrylate, 6 parts of activated silicic acid, gelatine
4 parts, 3 parts of sodium alginate.
The foaming agent includes following raw material：12 parts of alkyl propanesulfonate, 10 parts of sodium alkyl sulfonate, cetyl trimethyl
6 parts of ammonium nitrate, 12 parts of water；
The flotation agent includes following raw material：Double 10 parts of the dodecyl ammonium nitrate of dimethyl, 13 parts of sodium carbonate, thio urea
7 parts；
The fungicide includes following raw material：8 parts of propylene oxide, 7 parts of butanediol, 7 parts of glycerine, 3 parts of catechol, isophthalic
3 parts of diphenol, 2 parts of three octyl tertiary amine；
The slow rotten antisludging agent includes following raw material：5 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 4 parts of ethylene diamine tetra methylene phosphonic acid, two Asias
3 parts of ethyl triamine pentamethyl phosphonic acids；
The oxygen scavenger includes following raw material：3 parts of sodium sulfite, 3 parts of ammonium bisulfite, 3 parts of sulfur dioxide, 2 parts of hydrazine,
1 part of sodium hydrogensulfite.
Embodiment 5
A kind of grease type sewage-treating agent, as unit of parts by weight, including following raw material：70 parts of enzyme agent, 70 parts of demulsifier,
50 parts of flocculant, 50 parts of flocculation aid, 50 parts of foaming agent, 40 parts of flotation agent, 40 parts of fungicide, slow rotten 18 parts of antisludging agent, oxygen scavenger
18 parts,
The enzyme agent includes following raw material：35 parts of Whole-cell lipase, 18 parts of Lipase, cellulose
17 parts of enzyme.
The demulsifier includes following raw material：18 parts of fatty alcohol polyoxyethylene ether, polyethylene polyamine polyoxypropylene polyoxy
18 parts of vinethene, 14 parts of secondary octyl phenol polyethenoxy ether, 10 parts of propylene oxide, 5 parts of ethylene oxide, 5 parts of potassium hydroxide；
The flocculant includes following raw material：26 parts of zirconium sulfate, 12 parts of aluminum sulfate, 12 parts of alum；
The flocculation aid includes following raw material：18 parts of polyacrylamide, 18 parts of Sodium Polyacrylate, 6 parts of activated silicic acid, gelatine
5 parts, 3 parts of sodium alginate.
The foaming agent includes following raw material：14 parts of alkyl propanesulfonate, 14 parts of sodium alkyl sulfonate, cetyl trimethyl
8 parts of ammonium nitrate, 14 parts of water；
The flotation agent includes following raw material：Double 16 parts of the dodecyl ammonium nitrate of dimethyl, 16 parts of sodium carbonate, thio urea
8 parts；
The fungicide includes following raw material：12 parts of propylene oxide, 8 parts of butanediol, 8 parts of glycerine, catechol 4 part,
4 parts of benzenediol, 4 parts of three octyl tertiary amine；
The slow rotten antisludging agent includes following raw material：7 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 6 parts of ethylene diamine tetra methylene phosphonic acid, two Asias
5 parts of ethyl triamine pentamethyl phosphonic acids；
The oxygen scavenger includes following raw material：5 parts of sodium sulfite, 4 parts of ammonium bisulfite, 4 parts of sulfur dioxide, 3 parts of hydrazine,
2 parts of sodium hydrogensulfite.
Processing examination is carried out to Baise of Guangxi oils chemical products manufacture waste water using grease type sewage-treating agent of the present invention
It tests, the results are shown in table below.
As seen from the above table, after being handled with grease type sewage-treating agent of the present invention grease type sewage, pH value reaches substantially
To neutrality, SS values are reduced to 0.8-1.1mg/L, and except SS rates are up to 99.37%-99.54%, COD value is reduced to 5.4-6.2mg/L,
Except COD rates are up to 99.33-99.71%, oil content is reduced to 2.0-2.6mg/L, and oil removal rate reaches 99.28%-99.45%, and explanation is adopted
Good with the grease type sewage-treating agent processing grease type sewage effect of the present invention, effluent quality is excellent.
More than content is it cannot be assumed that present invention specific implementation is confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of present inventive concept is not departed from, several simple deduction or replace can also be made, all should
When being considered as belonging to present invention scope of patent protection determined by the appended claims.
Claims (1)
1. a kind of grease type sewage-treating agent, which is characterized in that as unit of parts by weight, including following raw material：80 parts of enzyme agent is broken
80 parts of emulsion, 60 parts of flocculant, 60 parts of flocculation aid, 60 parts of foaming agent, 50 parts of flotation agent, 50 parts of fungicide, slow rotten antisludging agent 20
Part, 20 parts of oxygen scavenger,
The enzyme agent includes following raw material：40 parts of Whole-cell lipase, 20 parts of Lipase, cellulase 20
Part；
The demulsifier includes following raw material：20 parts of fatty alcohol polyoxyethylene ether, polyethylene polyamine polyoxyethylene polyoxypropylene
20 parts of ether, 16 parts of secondary octyl phenol polyethenoxy ether, 12 parts of propylene oxide, 6 parts of ethylene oxide, 6 parts of potassium hydroxide；
The flocculant includes following raw material：30 parts of zirconium sulfate, 16 parts of aluminum sulfate, 14 parts of alum；
The flocculation aid includes following raw material：20 parts of polyacrylamide, 20 parts of Sodium Polyacrylate, 10 parts of activated silicic acid, gelatine 6
Part, 4 parts of sodium alginate；
The foaming agent includes following raw material：16 parts of alkyl propanesulfonate, 16 parts of sodium alkyl sulfonate, cetyl trimethyl nitric acid
10 parts of ammonium, 18 parts of water；
The flotation agent includes following raw material：Double 20 parts of the dodecyl ammonium nitrate of dimethyl, 20 parts of sodium carbonate, thio urea 10
Part；
The fungicide includes following raw material：15 parts of propylene oxide, 10 parts of butanediol, 10 parts of glycerine, 5 parts of catechol, isophthalic
5 parts of diphenol, 5 parts of three octyl tertiary amine；
The slow rotten antisludging agent includes following raw material：8 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 6 parts of ethylene diamine tetra methylene phosphonic acid, diethylidene
6 parts of triamine pentamethyl phosphonic acids；
The oxygen scavenger includes following raw material：6 parts of sodium sulfite, 4 parts of ammonium bisulfite, 4 parts of sulfur dioxide, 4 parts of hydrazine, sulfurous
Sour 2 parts of hydrogen sodium.
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| CN105481044A (en) * | 2016-01-19 | 2016-04-13 | 张锐 | Efficient sewage treating tablets and preparation method thereof |
| CN105936548A (en) * | 2016-05-26 | 2016-09-14 | 广西瑞兴环境工程有限公司 | Domestic sewage biological fermentation treatment agent |
| CN105819525A (en) * | 2016-05-26 | 2016-08-03 | 许婷 | Grease wastewater treating agent and preparing method thereof |
| CN105967345A (en) * | 2016-05-26 | 2016-09-28 | 广西瑞兴环境工程有限公司 | Biological fermentation treating agent for medical waste water |
| CN105884043A (en) * | 2016-06-25 | 2016-08-24 | 张莘蔓 | Method for preparing biological fermentation treatment agents for sewage |
| CN105884044A (en) * | 2016-06-25 | 2016-08-24 | 张莘蔓 | Preparation method of organic biological fermentation treating agent for wastewater |
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| CN107827250A (en) * | 2017-12-19 | 2018-03-23 | 周炳杰 | A kind of grease type sewage-treating agent |
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| CN115159698A (en) * | 2022-07-12 | 2022-10-11 | 广州航耀环保科技有限公司 | Grease sewage treatment agent and preparation method thereof |
| CN115477349B (en) * | 2022-10-17 | 2024-03-05 | 山东银汉水处理技术有限公司 | Wastewater treatment agent and preparation method thereof |
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