CN105884044A - Preparation method of organic biological fermentation treating agent for wastewater - Google Patents

Preparation method of organic biological fermentation treating agent for wastewater Download PDF

Info

Publication number
CN105884044A
CN105884044A CN201610468559.6A CN201610468559A CN105884044A CN 105884044 A CN105884044 A CN 105884044A CN 201610468559 A CN201610468559 A CN 201610468559A CN 105884044 A CN105884044 A CN 105884044A
Authority
CN
China
Prior art keywords
agent
preparation
units
raw material
weight portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610468559.6A
Other languages
Chinese (zh)
Inventor
张莘蔓
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610468559.6A priority Critical patent/CN105884044A/en
Publication of CN105884044A publication Critical patent/CN105884044A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a preparation method of an organic biological fermentation treating agent for wastewater and belongs to the technical field of wastewater treating agent preparation. The organic biological fermentation treating agent for the wastewater comprises Nocardia, charcoal, humic acid, biological growth stimulants, biological nutrients, coagulant aids, demulsifying agents, bactericides, deoxidants, enzyme agents, flotation agents and foaming agents, and is prepared by the steps of humic acid preparation, culture solution preparation, pH value regulation, mixing and the like. The organic biological fermentation treating agent for the wastewater has the advantages that the organic biological fermentation treating agent is free of toxicity, safe, environment friendly and the like, thereby having no effect on human health; the organic biological fermentation treating agent is thorough in wastewater treatment, treated wastewater is clear and can meet the discharge requirements, and new garbage or pollutants cannot be produced during treatment.

Description

A kind of preparation method of organic sewage biofermentation inorganic agent
Technical field
The present invention relates to sewage-treating agent preparing technical field, be specifically related to the preparation method of a kind of organic sewage biofermentation inorganic agent.
Background technology
It is currently used for the processing method that the main method of sewage disposal has physico-chemical process, biochemical process, chemical method and several technique to combine.The sewage not only organic concentration that the industries such as pesticide, pharmacy, fine chemistry industry, dyestuff are discharged is high, and toxicity is big, the most biodegradable, mostly is persistent organism (POPs), very big to environment, harm; being referred to as " three cause " (teratogenesis, carcinogenic, mutagenesis) material, Environmental Hormone (EDCs) material, thus this pollutant becomes " priority pollutants " of environmental conservation.
A class in technology, is the effective technology most likely entering commercial Application.Along with our people's economic activity is the most frequent, the pollution caused water body by soil erosion, production and sanitary sewage is increasingly severe, its pollutant component includes lot of trace organic pollution, and heavy metal ion pollutant, possibly together with the macromole natural organic matter of higher concentration.Simple dependence increases coagulant charging quantity can not solve problem.Organic and inorganic polymer flocculation aid (such as poly-propionic acid amide., activated silicic acid etc.) though can be by the adsorption bridging effect between de-steady colloidal solid be increased flco size, reach to increase heavy speed, the purpose of raising separating effect, application effect is obvious aborning, but steady colloid is taken off for difficulty, ammonia nitrogen, heavy metal ion excessive problem, high molecular effect is relatively poor, and treatment effect is inconspicuous.Low-temperature and low turbidity faced by the water treatment technology of routine is described, micro quantity organic pollutant, heavy metal ion exceed standard, and stink seriously waits complicated problem, has seemed unable to do what one wishes, it is impossible to adapt to the change of current water quality.Therefore, research and develop a kind of high efficiency, corrosion-free, environmental protection, the sewage fermentation process agent of safety are development trends.
Summary of the invention
The present invention provides the preparation method of a kind of organic sewage biofermentation inorganic agent, to solve existing fermentation process agent process sewage weak effect, high in cost of production problem.The organic sewage biofermentation inorganic agent of the present invention has avirulence, the advantage such as safe and environment-friendly, on health without impact;It is thorough that the organic sewage biofermentation inorganic agent of the present invention processes sewage, and the water quality after process is limpid, it is possible to meet emission request, and processing procedure will not produce new rubbish or pollutant.
For solve above technical problem, the present invention by the following technical solutions:
The preparation method of a kind of organic sewage biofermentation inorganic agent, comprises the following steps:
S1: vinegar factory waste liquid is stood clarification, obtain supernatant, then described supernatant being heated to 72-82 DEG C be evaporated concentrating, being concentrated into pH value is 2.4-3.6, stops heating, left at room temperature activation 12-16h, it is subsequently adding ammonium carbonate regulation pH value to 6.2-7.6, it is thus achieved that humic acid solution, humic acid solution is dried to water content≤6% at 85-105 DEG C, cross 100-300 mesh sieve after pulverizing, prepare humic acids;
S2: mixed homogeneously with Nocard's bacillus, biological growth stimulant, biological nutritive agent, water by the humic acids that step S1 prepares, cultivates 4-8h at temperature is 30-35 DEG C, prepares culture fluid;
S3: culture fluid akaline liquid regulation pH step S2 prepared is 6.7-6.9, stirs, prepare organic sewage biofermentation inorganic agent after adding Linesless charcoal, flocculation aid, demulsifier, antibacterial, oxygen scavenger, enzyme agent, flotation agent, foaming agent mixing;
Described organic sewage biofermentation inorganic agent, in units of weight portion, including following raw material: Nocard's bacillus 120-220 part, Linesless charcoal 15-30 part, humic acids 15-20 part, biological growth stimulant 10-15 part, biological nutritive agent 8-12 part, flocculation aid 6-10 part, demulsifier 6-10 part, antibacterial 4-8 part, oxygen scavenger 4-8 part, enzyme agent 3-6 part, flotation agent 2-4 part, foaming agent 2-4 part.
Further, biological growth stimulant described in step S2 is in units of weight portion, including following raw material: cerous sulfate 2-5 part, aluminum sulfate 8-10 part.
Further, described in step S2, biological nutritive agent is in units of weight portion, including following raw material: sodium gluconate 3-5 part, ethanedioic acid potassium 3-4 part, sodium phosphate 2-3 part.
Further, described in step S3, flocculation aid is in units of weight portion, including following raw material: polyacrylamide 3-4 part, activated silicic acid 2-3 part, potassium alginate 1-3 part.
Further, described in step S3, demulsifier is in units of weight portion, including following raw material: polyethylene polyamine polyoxyethylene polyoxypropylene ether 3-4 part, secondary octyl phenol polyethenoxy ether 1-2 part, expoxy propane 1-2 part, oxirane 0.5-1 part, sodium hydroxide 0.5-1 part.
Further, described in step S3, antibacterial is in units of weight portion, including following raw material: butanediol 2-4 part, glycerol 1-2 part, hydroquinone 0.5-1 part, three octyl tertiary amine 0.5-1 parts.
Further, described in step S3, oxygen scavenger is in units of weight portion, including following raw material: ammonium bisulfite 2-4 part, sulfur dioxide 1-2 part, hydrazine 0.5-1 part, sodium sulfite 0.5-1 part.
Further, enzyme agent described in step S3 is in units of weight portion, including following raw material: lipase 2-4 part, Triacylglycerol acylhydrolase 0.5-1 part, cellulase 0.5-1 part.
Further, described in step S3, flotation agent is in units of weight portion, including following raw material: alkyl dithiocarbonic acids sodium 1-2 part, thioamides 1-2 part.
Further, described in step S3, foaming agent is in units of weight portion, including following raw material: isomery hexanol or pungent liquor-saturated 1-2 part, phenolic acid mixed fatty alcohol 1-2 part.
The method have the advantages that
(1) inorganic agent of the present invention has avirulence, the advantage such as safe and environment-friendly, on health without impact;
(2) inorganic agent of the present invention processes sewage thoroughly, and the water quality after process is limpid, it is possible to meet emission request, and processing procedure will not produce new rubbish or pollutant;
(3) after sewage being processed with organic sewage biofermentation inorganic agent of the present invention, pH value basically reaches neutrality, SS value is reduced to 1.52-1.56mg/L, reaches 99.1%-99.11% except SS leads, and COD value is reduced to 8.66-8.91mg/L, 99.04-99.05% is reached except COD leads, oil content is reduced to 3.48-3.53mg/L, and oil removal rate reaches 99.05%-99.06%, it is seen that, it is effective that the organic sewage biofermentation inorganic agent of the present invention processes sewage, and effluent quality is excellent.
Detailed description of the invention
For ease of being more fully understood that the present invention, being illustrated by following instance, these examples belong to protection scope of the present invention, but are not intended to protection scope of the present invention.
A kind of organic sewage biofermentation inorganic agent, in units of weight portion, including following raw material: Nocard's bacillus 120-220 part, Linesless charcoal 15-30 part, humic acids 15-20 part, biological growth stimulant 10-15 part, biological nutritive agent 8-12 part, flocculation aid 6-10 part, demulsifier 6-10 part, antibacterial 4-8 part, oxygen scavenger 4-8 part, enzyme agent 3-6 part, flotation agent 2-4 part, foaming agent 2-4 part.
Described biological growth stimulant is in units of weight portion, including following raw material: cerous sulfate 2-5 part, aluminum sulfate 8-10 part.
Described biological nutritive agent is in units of weight portion, including following raw material: sodium gluconate 3-5 part, ethanedioic acid potassium 3-4 part, sodium phosphate 2-3 part.
Described flocculation aid is in units of weight portion, including following raw material: polyacrylamide 3-4 part, activated silicic acid 2-3 part, potassium alginate 1-3 part.
Described demulsifier is in units of weight portion, including following raw material: polyethylene polyamine polyoxyethylene polyoxypropylene ether 3-4 part, secondary octyl phenol polyethenoxy ether 1-2 part, expoxy propane 1-2 part, oxirane 0.5-1 part, sodium hydroxide 0.5-1 part.
Described antibacterial is in units of weight portion, including following raw material: butanediol 2-4 part, glycerol 1-2 part, hydroquinone 0.5-1 part, three octyl tertiary amine 0.5-1 parts.
Described oxygen scavenger is in units of weight portion, including following raw material: ammonium bisulfite 2-4 part, sulfur dioxide 1-2 part, hydrazine 0.5-1 part, sodium sulfite 0.5-1 part.
Described enzyme agent is in units of weight portion, including following raw material: lipase 2-4 part, Triacylglycerol acylhydrolase 0.5-1 part, cellulase 0.5-1 part.
Described flotation agent is in units of weight portion, including following raw material: alkyl dithiocarbonic acids sodium 1-2 part, thioamides 1-2 part.
Described foaming agent is in units of weight portion, including following raw material: isomery hexanol or pungent liquor-saturated 1-2 part, phenolic acid mixed fatty alcohol 1-2 part.
The preparation method of described organic sewage biofermentation inorganic agent, comprises the following steps:
S1: vinegar factory waste liquid is stood clarification, obtain supernatant, then described supernatant being heated to 72-82 DEG C be evaporated concentrating, being concentrated into pH value is 2.4-3.6, stops heating, left at room temperature activation 12-16h, it is subsequently adding ammonium carbonate regulation pH value to 6.2-7.6, it is thus achieved that humic acid solution, humic acid solution is dried to water content≤6% at 85-105 DEG C, cross 100-300 mesh sieve after pulverizing, prepare humic acids;
S2: mixed homogeneously with Nocard's bacillus, biological growth stimulant, biological nutritive agent, water by the humic acids that step S1 prepares, cultivates 4-8h at temperature is 30-35 DEG C, prepares culture fluid;
S3: culture fluid akaline liquid regulation pH step S2 prepared is 6.7-6.9, stirs, prepare organic sewage biofermentation inorganic agent after adding Linesless charcoal, flocculation aid, demulsifier, antibacterial, oxygen scavenger, enzyme agent, flotation agent, foaming agent mixing.
Below by more specifically embodiment, the present invention will be described.
Embodiment 1
A kind of organic sewage biofermentation inorganic agent, in units of weight portion, including following raw material: Nocard's bacillus 120 parts, 15 parts of Linesless charcoal, humic acids 15 parts, biological growth stimulant 10 parts, biological nutritive agent 8 parts, flocculation aid 6 parts, demulsifier 6 parts, antibacterial 4 parts, oxygen scavenger 4 parts, enzyme agent 3 parts, flotation agent 2 parts, foaming agent 2 parts.
Described biological growth stimulant is in units of weight portion, including following raw material: cerous sulfate 2 parts, 8 parts of aluminum sulfate.
Described biological nutritive agent is in units of weight portion, including following raw material: sodium gluconate 3 parts, 3 parts of ethanedioic acid potassium, sodium phosphate 2 parts.
Described flocculation aid is in units of weight portion, including following raw material: polyacrylamide 3 parts, activated silicic acid 2 parts, potassium alginate 1 part.
Described demulsifier is in units of weight portion, including following raw material: 3 parts of polyethylene polyamine polyoxyethylene polyoxypropylene ether, secondary octyl phenol polyethenoxy ether 1 part, expoxy propane 1 part, 0.5 part of oxirane, sodium hydroxide 0.5 part.
Described antibacterial is in units of weight portion, including following raw material: butanediol 2 parts, glycerol 1 part, hydroquinone 0.5 part, three octyl tertiary amine 0.5 part.
Described oxygen scavenger is in units of weight portion, including following raw material: ammonium bisulfite 2 parts, sulfur dioxide 1 part, hydrazine 0.5 part, sodium sulfite 0.5 part.
Described enzyme agent is in units of weight portion, including following raw material: lipase 2 parts, Triacylglycerol acylhydrolase 0.5 part, cellulase 0.5 part.
Described flotation agent is in units of weight portion, including following raw material: 1 part of alkyl dithiocarbonic acids sodium, thioamides 1 part.
Described foaming agent is in units of weight portion, including following raw material: isomery hexanol or pungent liquor-saturated 1 part, phenolic acid mixed fatty alcohol 1 part.
The preparation method of described organic sewage biofermentation inorganic agent, comprises the following steps:
S1: vinegar factory waste liquid is stood clarification, obtain supernatant, then described supernatant being heated to 72 DEG C be evaporated concentrating, being concentrated into pH value is 2.4, stops heating, left at room temperature activation 12h, be subsequently adding ammonium carbonate regulation pH value to 6.2, it is thus achieved that humic acid solution, humic acid solution is dried at 85 DEG C to water content be 6%, cross 100 mesh sieve after pulverizing, prepare humic acids;
S2: mixed homogeneously with Nocard's bacillus, biological growth stimulant, biological nutritive agent, water by the humic acids that step S1 prepares, cultivates 8h at temperature is 30 DEG C, prepares culture fluid;
S3: culture fluid akaline liquid regulation pH step S2 prepared is 6.7, stirs, prepare organic sewage biofermentation inorganic agent after adding Linesless charcoal, flocculation aid, demulsifier, antibacterial, oxygen scavenger, enzyme agent, flotation agent, foaming agent mixing.
Embodiment 2
A kind of organic sewage biofermentation inorganic agent, in units of weight portion, including following raw material: Nocard's bacillus 220 parts, 30 parts of Linesless charcoal, humic acids 20 parts, biological growth stimulant 15 parts, biological nutritive agent 12 parts, flocculation aid 10 parts, demulsifier 10 parts, antibacterial 8 parts, oxygen scavenger 8 parts, enzyme agent 6 parts, flotation agent 4 parts, foaming agent 4 parts.
Described biological growth stimulant is in units of weight portion, including following raw material: cerous sulfate 2-5 part, aluminum sulfate 8-10 part.
Described biological nutritive agent is in units of weight portion, including following raw material: sodium gluconate 5 parts, 4 parts of ethanedioic acid potassium, sodium phosphate 3 parts.
Described flocculation aid is in units of weight portion, including following raw material: polyacrylamide 4 parts, activated silicic acid 3 parts, potassium alginate 3 parts.
Described demulsifier is in units of weight portion, including following raw material: 4 parts of polyethylene polyamine polyoxyethylene polyoxypropylene ether, secondary octyl phenol polyethenoxy ether 2 parts, expoxy propane 2 parts, 1 part of oxirane, sodium hydroxide 1 part.
Described antibacterial is in units of weight portion, including following raw material: butanediol 4 parts, glycerol 2 parts, hydroquinone 1 part, three octyl tertiary amine 1 part.
Described oxygen scavenger is in units of weight portion, including following raw material: ammonium bisulfite 4 parts, sulfur dioxide 2 parts, hydrazine 1 part, sodium sulfite 1 part.
Described enzyme agent is in units of weight portion, including following raw material: lipase 4 parts, Triacylglycerol acylhydrolase 1 part, cellulase 1 part.
Described flotation agent is in units of weight portion, including following raw material: 2 parts of alkyl dithiocarbonic acids sodium, thioamides 2 parts.
Described foaming agent is in units of weight portion, including following raw material: isomery hexanol or pungent liquor-saturated 2 parts, phenolic acid mixed fatty alcohol 2 parts.
The preparation method of described organic sewage biofermentation inorganic agent, comprises the following steps:
S1: vinegar factory waste liquid is stood clarification, obtain supernatant, then described supernatant being heated to 82 DEG C be evaporated concentrating, being concentrated into pH value is 3.6, stops heating, left at room temperature activation 16h, be subsequently adding ammonium carbonate regulation pH value to 7.6, it is thus achieved that humic acid solution, humic acid solution is dried at 105 DEG C to water content be 3%, cross 300 mesh sieve after pulverizing, prepare humic acids;
S2: mixed homogeneously with Nocard's bacillus, biological growth stimulant, biological nutritive agent, water by the humic acids that step S1 prepares, cultivates 4h at temperature is 30 DEG C, prepares culture fluid;
S3: culture fluid akaline liquid regulation pH step S2 prepared is 6.9, stirs, prepare organic sewage biofermentation inorganic agent after adding Linesless charcoal, flocculation aid, demulsifier, antibacterial, oxygen scavenger, enzyme agent, flotation agent, foaming agent mixing.
Embodiment 3
A kind of organic sewage biofermentation inorganic agent, in units of weight portion, including following raw material: Nocard's bacillus 170 parts, 25 parts of Linesless charcoal, humic acids 18 parts, biological growth stimulant 12 parts, biological nutritive agent 10 parts, flocculation aid 9 parts, demulsifier 9 parts, antibacterial 6 parts, oxygen scavenger 6 parts, enzyme agent 5 parts, flotation agent 3 parts, foaming agent 3 parts.
Described biological growth stimulant is in units of weight portion, including following raw material: cerous sulfate 3 parts, 9 parts of aluminum sulfate.
Described biological nutritive agent is in units of weight portion, including following raw material: sodium gluconate 4 parts, 4 parts of ethanedioic acid potassium, sodium phosphate 2 parts.
Described flocculation aid is in units of weight portion, including following raw material: polyacrylamide 4 parts, activated silicic acid 2 parts, potassium alginate 3 parts.
Described demulsifier is in units of weight portion, including following raw material: 3 parts of polyethylene polyamine polyoxyethylene polyoxypropylene ether, secondary octyl phenol polyethenoxy ether 2 parts, expoxy propane 2 parts, 1 part of oxirane, sodium hydroxide 1 part.
Described antibacterial is in units of weight portion, including following raw material: butanediol 3 parts, glycerol 2 parts, hydroquinone 0.5 part, three octyl tertiary amine 0.5 part.
Described oxygen scavenger is in units of weight portion, including following raw material: ammonium bisulfite 3 parts, sulfur dioxide 1 part, hydrazine 1 part, sodium sulfite 1 part.
Described enzyme agent is in units of weight portion, including following raw material: lipase 3 parts, Triacylglycerol acylhydrolase 1 part, cellulase 1 part.
Described flotation agent is in units of weight portion, including following raw material: 2 parts of alkyl dithiocarbonic acids sodium, thioamides 1 part.
Described foaming agent is in units of weight portion, including following raw material: isomery hexanol or pungent liquor-saturated 2 parts, phenolic acid mixed fatty alcohol 1 part.
The preparation method of described organic sewage biofermentation inorganic agent, comprises the following steps:
S1: vinegar factory waste liquid is stood clarification, obtain supernatant, then described supernatant being heated to 75 DEG C be evaporated concentrating, being concentrated into pH value is 3, stops heating, left at room temperature activation 14h, be subsequently adding ammonium carbonate regulation pH value to 6.4, it is thus achieved that humic acid solution, humic acid solution is dried at 95 DEG C to water content be 6%, cross 200 mesh sieve after pulverizing, prepare humic acids;
S2: mixed homogeneously with Nocard's bacillus, biological growth stimulant, biological nutritive agent, water by the humic acids that step S1 prepares, cultivates 6h at temperature is 33 DEG C, prepares culture fluid;
S3: culture fluid akaline liquid regulation pH step S2 prepared is 6.8, stirs, prepare organic sewage biofermentation inorganic agent after adding Linesless charcoal, flocculation aid, demulsifier, antibacterial, oxygen scavenger, enzyme agent, flotation agent, foaming agent mixing.
The organic sewage biofermentation inorganic agent using the present invention manufactures waste water to oils chemical products to carry out processing test, and result is as shown in the table.
Project PH value SS(mg/L) COD(mg/L) Oil (mg/L)
Former water sample 8.2 168 914 372
Water sample after embodiment 1 process 7.3 1.56 8.91 3.53
Water sample after embodiment 2 process 7 1.52 8.82 3.52
Water sample after embodiment 3 process 7.2 1.54 8.66 3.48
As seen from the above table, after sewage being processed with organic sewage biofermentation inorganic agent of the present invention, pH value basically reaches neutrality, and SS value is reduced to 1.52-1.56mg/L, reaches 99.1%-99.11% except SS leads, COD value is reduced to 8.66-8.91mg/L, reaching 99.04-99.05% except COD leads, oil content is reduced to 3.48-3.53mg/L, and oil removal rate reaches 99.05%-99.06%, illustrating to use the organic sewage biofermentation inorganic agent of the present invention to process sewage effective, effluent quality is excellent.
Above content is it cannot be assumed that the present invention is embodied as being confined to these explanations; for general technical staff of the technical field of the invention; without departing under present inventive concept premise; some simple deduction or replace can also be made, all should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.

Claims (10)

1. the preparation method of an organic sewage biofermentation inorganic agent, it is characterised in that comprise the following steps:
S1: vinegar factory waste liquid is stood clarification, obtain supernatant, then described supernatant being heated to 72-82 DEG C be evaporated concentrating, being concentrated into pH value is 2.4-3.6, stops heating, left at room temperature activation 12-16h, it is subsequently adding ammonium carbonate regulation pH value to 6.2-7.6, it is thus achieved that humic acid solution, humic acid solution is dried to water content≤6% at 85-105 DEG C, cross 100-300 mesh sieve after pulverizing, prepare humic acids;
S2: mixed homogeneously with Nocard's bacillus, biological growth stimulant, biological nutritive agent, water by the humic acids that step S1 prepares, cultivates 4-8h at temperature is 30-35 DEG C, prepares culture fluid;
S3: culture fluid akaline liquid regulation pH step S2 prepared is 6.7-6.9, stirs, prepare organic sewage biofermentation inorganic agent after adding Linesless charcoal, flocculation aid, demulsifier, antibacterial, oxygen scavenger, enzyme agent, flotation agent, foaming agent mixing.
The preparation method of organic sewage biofermentation inorganic agent the most according to claim 1, it is characterised in that biological growth stimulant described in step S2 is in units of weight portion, including following raw material: cerous sulfate 2-5 part, aluminum sulfate 8-10 part.
The most according to claim 1, the preparation method of organic sewage biofermentation inorganic agent, it is characterised in that described in step S2, biological nutritive agent is in units of weight portion, including following raw material: sodium gluconate 3-5 part, ethanedioic acid potassium 3-4 part, sodium phosphate 2-3 part.
The most according to claim 1, the preparation method of organic sewage biofermentation inorganic agent, it is characterised in that described in step S3, flocculation aid is in units of weight portion, including following raw material: polyacrylamide 3-4 part, activated silicic acid 2-3 part, potassium alginate 1-3 part.
The preparation method of organic sewage biofermentation inorganic agent the most according to claim 1, it is characterized in that, described in step S3, demulsifier is in units of weight portion, including following raw material: polyethylene polyamine polyoxyethylene polyoxypropylene ether 3-4 part, secondary octyl phenol polyethenoxy ether 1-2 part, expoxy propane 1-2 part, oxirane 0.5-1 part, sodium hydroxide 0.5-1 part.
The preparation method of organic sewage biofermentation inorganic agent the most according to claim 1, it is characterized in that, described in step S3, antibacterial is in units of weight portion, including following raw material: butanediol 2-4 part, glycerol 1-2 part, hydroquinone 0.5-1 part, three octyl tertiary amine 0.5-1 parts.
The preparation method of organic sewage biofermentation inorganic agent the most according to claim 1, it is characterized in that, described in step S3, oxygen scavenger is in units of weight portion, including following raw material: ammonium bisulfite 2-4 part, sulfur dioxide 1-2 part, hydrazine 0.5-1 part, sodium sulfite 0.5-1 part.
The preparation method of organic sewage biofermentation inorganic agent the most according to claim 1; it is characterized in that; enzyme agent described in step S3 is in units of weight portion, including following raw material: lipase 2-4 part, Triacylglycerol acylhydrolase 0.5-1 part, cellulase 0.5-1 part.
The most according to claim 1, the preparation method of organic sewage biofermentation inorganic agent, it is characterised in that described in step S3, flotation agent is in units of weight portion, including following raw material: alkyl dithiocarbonic acids sodium 1-2 part, thioamides 1-2 part.
The most according to claim 1, the preparation method of organic sewage biofermentation inorganic agent, it is characterised in that described in step S3, foaming agent is in units of weight portion, including following raw material: isomery hexanol or pungent liquor-saturated 1-2 part, phenolic acid mixed fatty alcohol 1-2 part.
CN201610468559.6A 2016-06-25 2016-06-25 Preparation method of organic biological fermentation treating agent for wastewater Pending CN105884044A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610468559.6A CN105884044A (en) 2016-06-25 2016-06-25 Preparation method of organic biological fermentation treating agent for wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610468559.6A CN105884044A (en) 2016-06-25 2016-06-25 Preparation method of organic biological fermentation treating agent for wastewater

Publications (1)

Publication Number Publication Date
CN105884044A true CN105884044A (en) 2016-08-24

Family

ID=56718147

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610468559.6A Pending CN105884044A (en) 2016-06-25 2016-06-25 Preparation method of organic biological fermentation treating agent for wastewater

Country Status (1)

Country Link
CN (1) CN105884044A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106315863A (en) * 2016-09-29 2017-01-11 梁忠顺 Organic sewage biological fermentation treatment agent
CN106477730A (en) * 2016-09-29 2017-03-08 梁忠顺 A kind of preparation method of organic sewage biofermentation inorganic agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101654298A (en) * 2009-09-14 2010-02-24 江苏省环境科学研究院 Primer for improving biochemical and purifying efficacy of sewage and preparation method and application method thereof
CN105174489A (en) * 2015-09-10 2015-12-23 石东秀 Grease sewage treatment agent
CN105295934A (en) * 2015-10-26 2016-02-03 富川富兴果蔬有限责任公司 Novel water-retaining agent using vinegar factory liquid waste and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101654298A (en) * 2009-09-14 2010-02-24 江苏省环境科学研究院 Primer for improving biochemical and purifying efficacy of sewage and preparation method and application method thereof
CN105174489A (en) * 2015-09-10 2015-12-23 石东秀 Grease sewage treatment agent
CN105295934A (en) * 2015-10-26 2016-02-03 富川富兴果蔬有限责任公司 Novel water-retaining agent using vinegar factory liquid waste and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106315863A (en) * 2016-09-29 2017-01-11 梁忠顺 Organic sewage biological fermentation treatment agent
CN106477730A (en) * 2016-09-29 2017-03-08 梁忠顺 A kind of preparation method of organic sewage biofermentation inorganic agent

Similar Documents

Publication Publication Date Title
CN103771650B (en) A kind for the treatment of process of coal gasification waste water
CN106587197B (en) Nano biological circulating water treatment agent
CN103304107A (en) Method for treating canned citrus petal pectin wastewater
CN103772532B (en) Method for processing skim rubber
CN105884043A (en) Method for preparing biological fermentation treatment agents for sewage
CN105884045A (en) Preparation method of oily sewage biological fermentation treatment agent
CN105884044A (en) Preparation method of organic biological fermentation treating agent for wastewater
CN105948403A (en) Preparation method of oil recovery plant sewage biofermentation treating agent
CN108017197B (en) Hydrodynamic cavitation coupling H2O2Process for recycling mineral processing wastewater of purified lead-zinc sulfide ore
CN102126763B (en) Deformer special for treating landfill leachate
CN103896457B (en) A kind of Fine Chemistry Wastewater treatment process
CN106865782A (en) It is a kind of to be added with sewage-treating agent of butyl titanate and preparation method thereof
CN104743723A (en) Photocatalytic treatment process for fracturing flow-back fluid
CN106430622A (en) Biological fermentation treating agent for wastewater containing oily fouling
CN105936548A (en) Domestic sewage biological fermentation treatment agent
CN106315863A (en) Organic sewage biological fermentation treatment agent
CN109205941B (en) Resourceful treatment method for high-salt high-ammonia nitrogen wastewater
CN108017196B (en) A kind of wastewater deep treatment process of acid out oxidizing, flocculating precipitating
CN106316690A (en) Method for produce liquid organic fertilizer with starch wastewater to improve saline and alkaline land
CN105967345A (en) Biological fermentation treating agent for medical waste water
CN105174488A (en) Organic sewage treatment agent
CN106315712A (en) Grease type sewage biological fermentation treatment agent
CN106477730A (en) A kind of preparation method of organic sewage biofermentation inorganic agent
CN109665605A (en) A kind of decolorization flocculation agent and preparation method thereof
CN106315865A (en) Biological fermentation sewage treatment agent

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160824

RJ01 Rejection of invention patent application after publication