CN105155839A - High-strength formwork free of layer separation and method for manufacturing high-strength formwork - Google Patents

High-strength formwork free of layer separation and method for manufacturing high-strength formwork Download PDF

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CN105155839A
CN105155839A CN201510513732.5A CN201510513732A CN105155839A CN 105155839 A CN105155839 A CN 105155839A CN 201510513732 A CN201510513732 A CN 201510513732A CN 105155839 A CN105155839 A CN 105155839A
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lath
delamination
high strength
continuous lod
continuous
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CN105155839B (en
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陈大华
范欣愉
孙雅杰
黄有平
孟姗姗
刘玲
汪丽
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Guangdong Jinfa Composite Materials Co ltd
Guangzhou Kingfa Carbon Fiber New Material Development Co ltd
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GUANGZHOU KINGFA CARBON FIBER NEW MATERIAL DEVELOPMENT Co Ltd
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Abstract

The invention discloses a high-strength formwork free of layer separation and a method for manufacturing the high-strength formwork. The high-strength formwork and the method have the advantages that the length directions of battens a are consistent with the growth direction of wood, the height directions of battens b are consistent with the growth direction of the wood, accordingly, sufficient adhesive steeping and mechanical bracing effects can be realized, a core is extremely high in mechanical property in the vertical direction and the horizontal direction and is low in deformation, layer separation phenomena inside the machined core can be prevented, the high-strength formwork is high in modulus, and buckling deformation of the formed formwork can be prevented; the mechanical properties of the formwork can be improved by the aid of continuous fiber reinforcement composite surface layers, the high-strength formwork is light, waterproof and anticorrosion, is high in strength and recycling frequency, and can be easily released from forms, the recycling frequency of the high-strength formwork can reach a hundred at least, accordingly, the service life of the building formwork can be greatly prolonged, and the single-service cost can be reduced.

Description

A kind of high strength not delamination template and preparation method thereof
Technical field
The present invention relates to construction formwork field, particularly continuous lod construction formwork field.
Background technology
The template adopted in building operations is punching block, wooden model, bamboo mould, plastic formwork etc., wherein, although punching block is firm, and recycle often, but it is expensive, not corrosion-resistant easy get rusty, simultaneously, punching block weight is large, not only transports inconvenience, in work progress, also there is larger potential safety hazard; At present, using maximum in building operations is wooden form or Bamboo Formwork, and this class template is lightweight, is convenient to transport, and its low price, but this kind of template strength is low, not corrosion-resistant, infiltration is rear easy to crack, and the demoulding is difficult, recycles number of times little, be less than 5 times, in addition, this class template is large to Wood demand, causes very big destruction to environment.In recent years, for the defect solving above-mentioned punching block, wooden model, bamboo mould exist as template, a lot of novel plastic template has been there is in industry, as Wood-plastic formwork, GMT template, hollow plastic formwork, foaming PVC template etc., but these templates is expensive, improve building operations cost, and all there is the shortcomings such as intensity is low, poor rigidity, yielding, weatherability is poor, recycle number of times low, about 10 times can only be used.
For solving the defect that above-mentioned template is brought, patent 201110000869.2 discloses a kind of building template reinforced by composite of continuous fiber plastic coated belt material and preparation method thereof, which employs wooden oriented wood chipboard as plate core, solar absorber surface and the enhancing surface layer be made up of 2 ~ 4 layers of continuous fiber plastic coated belt material are together with double-side hot-melt adhesive film heat pressure adhesive, thus make enhancing construction formwork, the hot melt adhesive film one side used is acrylic resin, another side resin is maleic anhydride modified acrylic resin, rely on hot melt adhesive film adhesive sheet core and strengthen surface layer and there is two problems: 1, hot melt adhesive film is expensive, considerably increase building operations cost, 2, the viscose glue preparing wooden oriented wood chipboard is generally thermosetting glue, with PUR bonding and insecure, can there is the phenomenon of foaming, bulge in Long-Time Service, cause the rapid drawdown of template performance.In addition, because shaving board is a kind of flakeboard, although cover fiber reinforcement surface layer on its surface, but still can there is the problem of rigidity deficiency, stratification can occur in its shaving board, cause template strength to be deteriorated, application life shortens.
Another patent 201310422446.9 discloses a kind of construction formwork laminate and manufacture method thereof, described plate core is common fast growing wood veneer, wooden flake board or density fiber board, described enhancing surface layer is the fiber reinforced thermolplastic plate that one side is covered with non-woven fabrics, by glue, the non-woven fabrics and plate core that strengthen facing surface are bonded together, described fiber reinforced thermolplastic plate is that continuous fiber reinforced thermoplastic prepreg and short fiber strengthen thermoplasticity prepreg feed back and lay and form, if the plate core used is fast growing wood veneer, then need the veneer of larger fabric width, just can be processed into the template of high rigidity, processed complex, cost is high, if use shaving board or density fiber board as plate core, then its mechanical strength is inadequate, easily there is stratification in plate in-core.
Summary of the invention
The present invention aims to provide a kind ofly has high structural rigidity, waterproof anticorrosion, the easily demoulding, not delamination and anti-ly fall high strength not delamination template of falling destructive characteristics and preparation method thereof, and that significantly improves template recycles number of times, extends the application life of template.
A kind of high strength not delamination template of the present invention, comprise plate core, and the continuous lod composite cover of one is bonded as respectively with plate core upper and lower surface, the lath that described plate core is formed by many wood materials forms by matrix shape is bonding, lath is rectangular-shaped, described lath is divided into lath a and lath b, and the length direction of lath a is consistent with wood grows direction, and the short transverse of lath b is consistent with wood grows direction; The adhesive layer that described continuous lod composite cover is arranged on the surface by one or more layers continuous lod preliminary-dip piece and the continuous lod preliminary-dip piece wherein outside forms, and by bonding adhesive, by the adhesive layer on continuous lod composite cover, upper and lower two surfaces are bonded as one with plate core respectively.
The preparation method of a kind of high strength not delamination template of the present invention, the steps include:
1) plate core is prepared: wood materials is made into rectangular-shaped lath, described lath is divided into lath a and lath b, the length direction of lath a is consistent with wood grows direction, the short transverse of lath b is consistent with wood grows direction, lath a and lath b is formed by a cuboid batten respectively, or lath a and lath b is spliced to form along stave lengths direction in the mode of mitered or docking by bonding adhesive by many battens respectively, its docking angle is θ=90 °, miter angles is θ <90 °, to reach plate core (1) length dimension requirement; Along width of sheet direction: be bonded as one with the form of docking by bonding adhesive between adjacent slat, docking angle is θ=90 °, to reach the requirement of plate core width dimensions, the plate core that final formation is consistent with lath height;
2) prepare continuous lod composite cover: by continuous fiber goods through in resin melt, fully after dipping, through cooling, trimming, cutting rolling, form continuous lod preliminary-dip piece; Together with successively the continuous lod preliminary-dip piece be made up of unidirectional fibre goods or multidirectional fibre being laid in adhesive layer order, put it in hot blast constant temperature drying tunnel through 120 DEG C ~ 260 DEG C, 30s ~ 180s heating, with after through pressurization, cooling, cutting edge and deburring, obtain continuous lod composite cover;
3) template is prepared: at two coating adhesives on the surface up and down of plate core, scribble bonding adhesive plate core two be covered with continuous lod composite cover respectively on the surface up and down, adhesive layer on continuous lod composite cover is contacted with plate core, be placed in press hot pressing, hot pressing temperature is 110 DEG C ~ 160 DEG C, pressure 10MPa ~ 20MPa, hot pressing time is 10min ~ 20min, forms template.
A kind of high strength not delamination template of the present invention and preparation method thereof, template by plate core and be bonded as with plate core upper and lower surface respectively one continuous lod composite cover form, wherein, plate core is made up of the length direction lath a consistent with wood grows direction and short transverse and the consistent lath b in wood grows direction, therefore, can make plate core along the short transverse in vertical slats length and width face and the length direction of lath consistent with the tube axial cell in wood grows direction respectively, not only can play the effect of abundant impregnated resin stick and mechanical support simultaneously, plate core can also be made on vertical direction and horizontal direction, all to have high mechanical property and be out of shape little, the plate core inner machined is made to there will not be stratification, there is high-modulus, the template formed can not buckling deformation, in addition, the plate core of this kind of template, its size to material, material are less demanding, and without the need to the veneer of larger wide cut, the natural defect of material, processing familiar lacunas are on the performance of final finished without impact, and therefore, processing cost is low, the mechanical property of template can be improved by this kind of continuous lod composite cover, make template have lightweight, intensity is high, the performance of waterproof anticorrosion, the easily demoulding, recycle often, more than hundred times can be reached, substantially increase the application life of construction formwork, reduce single use cost, and can be recycled often due to this kind of template, therefore, decrease the destruction to forest, significantly reduce resource loss rate.
Accompanying drawing explanation
Fig. 1 is the trunk tangent plane schematic diagram of timber of the present invention.
Fig. 2 is lath a structural representation of the present invention (length direction is consistent with wood grows direction, and L is for long, and H is high, and W is wide).
Fig. 3 is lath b structural representation of the present invention (short transverse is consistent with wood grows direction, and L is for long, and H is high, and W is wide).
Fig. 4 is formwork structure schematic diagram of the present invention (continuous lod composite cover and plate core are peeled off).
Fig. 5 is template cross section structure schematic diagram of the present invention.
Detailed description of the invention
A kind of high strength not delamination template, as shown in Figures 1 to 5, comprise plate core 1, and the continuous lod composite cover 2 of one is bonded as respectively with plate core 1 upper and lower surface, the lath that described plate core 1 is formed by many wood materials forms by matrix shape is bonding, and lath is rectangular-shaped, and described lath is divided into lath a6 and lath b3, the length direction of lath a6 is consistent with wood grows direction, and the short transverse of lath b3 is consistent with wood grows direction; The adhesive layer that described continuous lod composite cover 2 is arranged on the surface by one or more layers continuous lod preliminary-dip piece and the continuous lod preliminary-dip piece wherein outside forms, and is bonded as one respectively by the adhesive layer on continuous lod composite cover 2 by bonding adhesive with plate core about 1 two surface.
Along vertical slats by growing the direction with the wide length and width face 5 formed, described plate core 1 is highly 1mm ~ 300mm, can give full play to the mechanical property of plate core 1.
The width of described lath a6 and lath b3 is respectively 0.2 ~ 20mm, preferably 1 ~ 3mm, effectively can ensure that the plate core 1 made has excellent mechanical property.
The number of described lath b3 and the number proportion of lath a6 are 0.1 ~ 2, preferably 0.75 ~ 1.3; Ensure that the plate core 1 be spliced to form by lath has excellent mechanical property.
Along width of sheet direction, the same level of the correspondence of adjacent slat adopts the mode of docking to be bonded as one by bonding adhesive, and its docking angle is θ=90 °, is easy to processing.
Lath a6 and lath b3 is formed by a cuboid batten respectively; Or lath a6 and lath b3 is spliced to form along stave lengths direction in the mode of mitered or docking by bonding adhesive by many battens respectively, miter angles is θ <90 °, docking angle is θ=90 °, thus ensure that bond area is large, when bearing shearing force, stress distribution is even, and supporting capacity is high, and the stress that mitered mode can effectively avoid fault in seam to cause is concentrated.
Described continuous lod composite cover 2 is made up of 1 ~ 4 layer of continuous lod preliminary-dip piece and the adhesive layer on continuous lod preliminary-dip piece surface that overlays on wherein outside one, preferably 2 ~ 4 layers of continuous lod preliminary-dip piece, described continuous lod composite cover 2 thickness is 0.2mm ~ 4mm, and surface density is 200g/m 2~ 3200g/m 2, based on the gross weight of continuous lod composite cover, the percentage by weight of continuous fiber is 20wt% ~ 80wt%, preferred 45wt% ~ 80wt%, on the basis saving materials, effectively can improve the mechanical strength of template.
Described continuous lod preliminary-dip piece is made up of continuous fiber goods and thermoplastic resin composition, described continuous fiber goods are unidirectional fibre goods or multidirectional fibre, the continuous lod preliminary-dip piece be made up of unidirectional fibre goods and thermoplastic resin composition is angularly laid in one, and its ply stacking angle is 90 ° or 0 °, [90 °/0 °] tor [0 °/90 °] t, [90 °/0 °/90 °] tor [0 °/90 °/0 °] t, [90 °/0 °] 2Tor [0 °/90 °] 2T, [90 °/0 °] 2sor [0 °/90 °] 2s, effectively can strengthen the mechanical property of continuous lod composite cover 2.Described continuous fiber goods material is one or more combinations of alkali-free glass fibre, medium-alkali glass fibre or high alkali glass fibre, carbon fiber, aramid fiber, basalt fibre, silicon carbide fibre, continuous fiber diameter is 5 ~ 20 μm, preferred alkali-free glass fibre goods, described unidirectional fibre goods are continuous fiber yarn, unidirectional cloth etc., and described multidirectional fibre is continuous fiber felt, continuous fiber grid cloth, plain cloth, twills, satin fabric, braid, blended fabric, multi-axial fabric, three dimensional fabric etc.Described thermoplastic resin composition is made up of vistanex, auxiliary agent and filler, based on the gross weight of thermoplastic resin composition, the percentage by weight of vistanex is 70wt% ~ 100wt%, the percentage by weight of auxiliary agent is 0 ~ 20wt%, the percentage by weight of filler is 0 ~ 10wt%, wherein the melt index scope of vistanex is 10 ~ 1000g/10min, contributes to resin fully flood fibre in this melting means scope, improves the interface performance of composite material; Described vistanex be in polyethylene, polypropylene and polyethylene reclaimed materials, polypropylene reclaimed material one or more with arbitrarily than combination, this kind of resin system is nonpolar or low polar resin, waterproof and the easily demoulding.Described auxiliary agent comprises one or more combinations in the functional additives such as compatilizer, antioxidant, sliding agent, uvioresistant stabilizing agent, anti-dripping agent, plasticizing agent, coupling agent, fire retardant.Described compatilizer is selected from one or more combinations of maleic anhydride grafted PP, NCO graft modification polypropylene or acrylic ester grafted modified polypropene.Described antioxidant is selected from 2; 6-tri-grades of butyl-4-methylphenols, N; N '-bis--(3-(3; 5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine, four (β-(3; 5-di-tert-butyl-hydroxy phenyl) propionic acid) one or more in pentaerythritol ester, three (2.4-di-tert-butyl-phenyl) phosphite ester, two (3,5-, tri-grades of butyl-4-hydroxy phenyls) thioether or thio-2 acid dibasic acid esters.Described sliding agent be selected from saturated hydrocarbons (atoleine, solid paraffin, microlite cerate low molecular weight polyethylene (molecular weight 1000 ~ 10000), chlorinated paraffin wax, OPE etc.), metal soap (calcium stearate, lead stearate etc.), aliphatic amide (ethyl two hard acid amides, N, N ethylenebis ricinoleic acid amide etc.), fatty acid (stearic acid etc.), fatty acid ester (butyl stearate, glycerin monostearate etc.) and aliphatic alcohols one or more.Described ultraviolet light stabilizing agent be selected from benzotriazole light stabilizer, salicylate class ultraviolet light stabilizing agent, benzophenone ultraviolet light stabilizing agent or hindered amine light stabilizer one or more.Described anti-dripping agent be selected from pure powder type or cladded type fluorine class anti-dripping agent one or more.Described plasticizing agent is selected from phthalic acid ester, phosphate, fatty group dibasic acid, polyol ester, epoxide etc.Described coupling agent be selected from the coupling agent etc. of silane coupler, titanate coupling agent, aluminate coupling agent, bimetallic coupling agent, phosphate coupling agent, boric acid ester coupler, chromium complex and other higher fatty acids, alcohol, ester one or more.Described fire retardant is selected from bromide fire retardant (bromination imines, brominated polycarbonate, brominated Polystyrene, brominated polystyrene, brominated epoxy, brominated triazine, tetrabromobisphenol A, eight bromo ether, eight bromine S ethers, deca-BDE, TDE etc.), antimony based flame retardant (stibate, the antimonides such as antimony oxide) high purity alumina-magnesia fire retardant (magnesium hydroxide, aluminium hydroxide etc.), phosphorus flame retardant (red phosphorus, hypophosphites, phosphate etc.), nitrogenated flame retardant (melamine polyphosphate, Quadrafos, melamine cyanurate etc.), Firebrake ZB, sulfonate, one or more in silicon system flame-retardant system.Described filler comprises one or more combinations in the fillers such as titanium dioxide, calcium carbonate, mica powder, toner.
The one side that described continuous lod composite cover 2 does not bond with plate core 1 is provided with surperficial embossing or without surperficial embossing, if without surperficial embossing, then mainly as the structure mold of concreting, low and the ganoid concrete products of porosity is obtained after the demoulding, without the need to post processing, easy form removal, easy construction; If there is surperficial embossing, then be mainly used in concreting body of wall, embossing depth bounds is 0.01mm ~ 0.4mm, and this embossing degree of depth can to accelerate in concrete moisture fast transferring to top layer, form coarse pitted skin surface after form removal, contribute to carrying out mortar or processing of plastering to body of wall.
Described adhesive layer is textile fabrics, textile fabrics is woven fabric, knitted fabric, woven cloth, multi-axial fabric, non-woven fabrics, the main component of adhesive layer is natural fiber (as plant, animal, mineral fibers), chemical fibre (comprising synthetic fibers, as terylene, polyamide fibre, acrylic fibers), regenerated fiber (as viscose rayon), inorfil (as glass fiber), blend fibre linen-cotton, polyester-cotton blend, wash sticky, wash in brocade one or more combination.The fusing point of described adhesive layer or heat decomposition temperature are greater than the fusing point of vistanex in continuous lod preliminary-dip piece, prevent in template hot pressing, adhesive layer melted by heating or decomposition.
Described bonding adhesive is one or more in polyurethane, epoxy resin, phenolic resins, Lauxite or melamine, and wherein resin solid content is 15% ~ 65%, because the pH value of timber is in 4 ~ 7 scopes, therefore, and preferred phenolic resin glue or melamine glue.
A preparation method for high strength not delamination template, the steps include:
(1) plate core is prepared: wood materials is made into rectangular-shaped lath, described lath is divided into lath a6 and lath b3, the length direction of lath a6 is consistent with wood grows direction, the short transverse of lath b3 is consistent with wood grows direction, lath a6 and lath b3 is formed by a cuboid batten respectively, or lath a6 and lath b3 is spliced to form along stave lengths direction in the mode of mitered or docking by bonding adhesive by many battens respectively, its docking angle is θ=90 °, miter angles is θ <90 °, to reach the requirement of plate core 1 length dimension; Along width of sheet direction: be bonded as one with the form of docking by bonding adhesive between adjacent slat, docking angle is θ=90 °, to reach the requirement of plate core 1 width dimensions, the plate core 1 that final formation is consistent with lath height; During splicing, two seams in the horizontal at least stagger 200mm, hole sawdusts all on sheets thus obtained core 1 and polyurethane glue adjust mixed after fill up, carry out drying after hole repairing, obtain dried plate core 1, dried plate core 1 is placed on sander and carries out two-sided fixed thick sanding;
(2) prepare continuous lod composite cover: by continuous fiber goods through in resin melt, fully after dipping, through cooling, trimming, cutting rolling, form continuous lod preliminary-dip piece; Together with successively the continuous lod preliminary-dip piece be made up of unidirectional fibre goods or multidirectional fibre being laid in adhesive layer order, put it in hot blast constant temperature drying tunnel through 120 DEG C ~ 260 DEG C, 30s ~ 180s heating, with after through pressurization, cooling, cutting edge and deburring, obtain continuous lod composite cover 2, wherein, if continuous fiber goods are unidirectional fibre goods, then making by it the continuous lod preliminary-dip piece that formed can according to machine direction angularly 90 ° or 0 °, [90 °/0 °] tor [0 °/90 °] t, [90 °/0 °/90 °] tor [0 °/90 °/0 °] t, [90 °/0 °] 2Tor [0 °/90 °] 2T, [90 °/0 °] 2sor [0 °/90 °] 2slay;
(3) template is prepared: at two coating adhesives on the surface up and down of plate core 1, scribble bonding adhesive plate core 1 two be covered with continuous lod composite cover 2 respectively on the surface up and down, adhesive layer on continuous lod composite cover 2 is contacted with plate core 1, be placed in press hot pressing, hot pressing temperature is 110 DEG C ~ 160 DEG C, pressure 10MPa ~ 20MPa, and hot pressing time is 10min ~ 20min, form template, the template that hot pressing completes also will through operations such as supercooling, clipping edge, bound edges.
Described bonding adhesive is one or more in polyurethane, epoxy resin, phenolic resins, Lauxite or melamine, and wherein resin solid content is 15% ~ 65%.
Embodiment 1:
In the present embodiment, along vertical slats by growing and the wide direction, length and width face 5 formed, described plate core 1 is highly 10mm, wherein, the width of lath a6 and lath b3 is all 2mm, the number of lath b3 and the number ratio of lath a6 are 2, lath a6 and lath b3 is spliced to form along stave lengths direction in the mode of docking by adhesive phenolic resin by many battens respectively, docking angle is θ=90 °, along width of sheet direction, the same level of the correspondence of adjacent slat adopts the mode of docking to be bonded as one by adhesive phenolic resin, its docking angle is θ=90 °, the thickness of continuous lod composite cover 2 is 0.5mm, based on the gross weight of continuous fiber composite strengthening surface layer, the percentage by weight of continuous fiber is 20wt%, the surface density of continuous lod composite cover 2 is 300g/m 2, it is made up of one deck continuous lod preliminary-dip piece and the non-woven fabrics overlaying on continuous lod preliminary-dip piece surface, the ply stacking angle of one deck continuous lod preliminary-dip piece is 90 °, the continuous fiber yarn that continuous lod preliminary-dip piece is made up of alkali-free glass fibre and thermoplastic resin composition form, the diameter of continuous fiber is 10 μm, based on the gross weight of thermoplastic resin composition, the percentage by weight of vistanex is 90wt%, the percentage by weight of auxiliary agent is 5wt%, the percentage by weight of filler is 5wt%, wherein the melt index of vistanex is 80g/10min, described vistanex is polypropylene, auxiliary agent is antioxidant, filler is calcium carbonate, be melamine glue for bonding continuous lod composite cover 2 with the bonding adhesive of plate core 1, by the template that the material of above-mentioned parameter is made through processing technology, through Mechanics Performance Testing: longitudinal MOR is 35MPa, longitudinal modulus of elasticity is 2500MPa, and bending strength is 19MPa, and transverse modulus of elasticity is 3000MPa, test through water resistance I class stripping performance: unchanged, through 6 meters of vertical fall-down tests in high-altitude: flawless.
Embodiment 2:
In the present embodiment, the number of lath b3 and the number ratio of lath a6 are 0.75, and all the other contents are identical with embodiment 1, through Mechanics Performance Testing: longitudinal MOR is 37MPa, longitudinal modulus of elasticity is 2800MPa, and bending strength is 22MPa, and transverse modulus of elasticity is 3100MPa; Test through water resistance I class stripping performance: unchanged; Through 6 meters of vertical fall-down tests in high-altitude: flawless.
Embodiment 3:
In the present embodiment, the number of lath b3 and the number ratio of lath a6 are 0.75, continuous lod composite cover 2 is made up of one deck continuous lod preliminary-dip piece and the non-woven fabrics overlaying on continuous lod preliminary-dip piece surface, the thickness of continuous lod composite cover 2 is 0.5mm, based on the gross weight of continuous fiber composite strengthening surface layer, the percentage by weight of continuous fiber is 45wt%, and the surface density of continuous lod composite cover 2 is 400g/m 2, all the other contents are identical with embodiment 1, through Mechanics Performance Testing: longitudinal MOR is 38MPa, and longitudinal modulus of elasticity is 4000MPa, and bending strength is 23MPa, and transverse modulus of elasticity is 3500MPa; Test through water resistance I class stripping performance: unchanged; Through 6 meters of vertical fall-down tests in high-altitude: flawless.
Embodiment 4:
In the present embodiment, the number of lath b3 and the number ratio of lath a6 are 0.75, continuous lod composite cover 2 is made up of two-layer continuous lod preliminary-dip piece and the non-woven fabrics on continuous lod preliminary-dip piece surface that overlays on wherein outside one, according to machine direction, the ply stacking angle of two-layer continuous lod preliminary-dip piece is [90 °/0 °] tor [0 °/90 °] t, the thickness of continuous lod composite cover 2 is 0.8mm, and based on the gross weight of continuous fiber composite strengthening surface layer, the percentage by weight of continuous fiber is 45wt%, and the surface density of continuous lod composite cover 2 is 800g/m 2, all the other contents are identical with embodiment 1, through Mechanics Performance Testing: longitudinal MOR is 48MPa, and longitudinal modulus of elasticity is 5100MPa, and bending strength is 35MPa, and transverse modulus of elasticity is 4000MPa; Test through water resistance I class stripping performance: unchanged; Through 6 meters of vertical fall-down tests in high-altitude: flawless.
Embodiment 5:
In the present embodiment, the number of lath b3 and the number ratio of lath a6 are 1, continuous lod composite cover 2 is made up of two-layer continuous lod preliminary-dip piece and the non-woven fabrics on continuous lod preliminary-dip piece surface that overlays on wherein outside one, according to machine direction, the ply stacking angle of two-layer continuous lod preliminary-dip piece is [90 °/0 °] tor [0 °/90 °] t, the thickness of continuous lod composite cover 2 is 0.8mm, and based on the gross weight of continuous fiber composite strengthening surface layer, the percentage by weight of continuous fiber is 60wt%, and the surface density of continuous lod composite cover 2 is 1000g/m 2, all the other contents are identical with embodiment 1, through Mechanics Performance Testing: longitudinal MOR is 55MPa, and longitudinal modulus of elasticity is 6400MPa, and bending strength is 37MPa, and transverse modulus of elasticity is 5100MPa; Test through water resistance I class stripping performance: unchanged; Through 6 meters of vertical fall-down tests in high-altitude: flawless.
Embodiment 6:
In the present embodiment, the number of lath b3 and the number ratio of lath a6 are 1.3, continuous lod composite cover 2 is made up of three layers of continuous lod preliminary-dip piece and the non-woven fabrics on continuous lod preliminary-dip piece surface that overlays on wherein outside one, according to machine direction, the ply stacking angle of three layers of continuous lod preliminary-dip piece is [90 °/0 °/90 °] tor [0 °/90 °/0 °] t, the thickness of continuous lod composite cover 2 is 1.2mm, and based on the gross weight of continuous fiber composite strengthening surface layer, the percentage by weight of continuous fiber is 70wt%, and the surface density of continuous lod composite cover 2 is 1600g/m 2, all the other contents are identical with embodiment 1, through Mechanics Performance Testing: longitudinal MOR is 82MPa, and longitudinal modulus of elasticity is 7200MPa, and bending strength is 48MPa, and transverse modulus of elasticity is 5700MPa; Test through water resistance I class stripping performance: unchanged; Through 6 meters of vertical fall-down tests in high-altitude: flawless.
Embodiment 7:
In the present embodiment, the number of lath b3 and the number ratio of lath a6 are 1.3, continuous lod composite cover 2 is made up of four layers of continuous lod preliminary-dip piece and the non-woven fabrics on continuous lod preliminary-dip piece surface that overlays on wherein outside one, according to machine direction, the ply stacking angle of four layers of continuous lod preliminary-dip piece is [90 °/0 °] 2Tor [0 °/90 °] 2Tor [90 °/0 °] 2sor [0 °/90 °] 2s, the thickness of continuous lod composite cover 2 is 1.6mm, and based on the gross weight of continuous fiber composite strengthening surface layer, the percentage by weight of continuous fiber is 80wt%, and the surface density of continuous lod composite cover 2 is 2600g/m 2, all the other contents are identical with embodiment 1, through Mechanics Performance Testing: longitudinal MOR is 87MPa, and longitudinal modulus of elasticity is 7600MPa, and bending strength is 53MPa, and transverse modulus of elasticity is 6400MPa; Test through water resistance I class stripping performance: unchanged; Through 6 meters of vertical fall-down tests in high-altitude: flawless.

Claims (25)

1. a high strength not delamination template, comprise plate core (1), and the continuous lod composite cover (2) of one is bonded as respectively with plate core (1) upper and lower surface, it is characterized in that: the lath that described plate core (1) is formed by many wood materials forms by matrix shape is bonding, lath is rectangular-shaped, described lath is divided into lath a(6) and lath b(3), lath a(6) length direction consistent with wood grows direction, lath b(3) short transverse consistent with wood grows direction; The adhesive layer that described continuous lod composite cover (2) is arranged on the surface by one or more layers continuous lod preliminary-dip piece and the continuous lod preliminary-dip piece wherein outside forms, and is bonded as one respectively by the adhesive layer on continuous lod composite cover (2) by bonding adhesive with upper and lower two surfaces of plate core (1).
2. a kind of high strength not delamination template according to claim 1, is characterized in that: along vertical slats by growing the direction with the wide length and width face (5) formed, described plate core (1) is highly 1mm ~ 300mm.
3. a kind of high strength not delamination template according to claim 1, is characterized in that: described lath a(6) and lath b(3) width be respectively 0.2mm ~ 20mm, preferred 1mm ~ 3mm.
4. a kind of high strength not delamination template according to claim 1 or 3, is characterized in that: described lath b(3) number and lath a(6) number proportion be 0.1 ~ 2, preferably 0.75 ~ 1.3.
5. a kind of high strength not delamination template according to claim 1 or 3, is characterized in that: lath a(6) and lath b(3) formed by a cuboid batten respectively; Or lath a(6) and lath b(3) be spliced to form along stave lengths direction in the mode of mitered or docking by bonding adhesive by many battens respectively, miter angles is θ <90 °, and docking angle is θ=90 °.
6. a kind of high strength not delamination template according to claim 1-2 any one, is characterized in that: along width of sheet direction, and same level corresponding to adjacent slat adopts the mode of docking to be bonded as one by bonding adhesive, and its docking angle is θ=90 °.
7. a kind of high strength not delamination template according to claim 1, it is characterized in that: described continuous lod composite cover (2) is made up of 1 ~ 4 layer of continuous lod preliminary-dip piece and the adhesive layer on continuous lod preliminary-dip piece surface that overlays on wherein outside one, preferably 2 ~ 4 layers of continuous lod preliminary-dip piece, described continuous lod composite cover (2) thickness is 0.2mm ~ 4mm, and surface density is 200g/m 2~ 3200g/m 2, based on the gross weight of continuous lod composite cover (2), the percentage by weight of continuous fiber is 20wt% ~ 80wt%, preferred 45wt% ~ 80wt%.
8. a kind of high strength not delamination template according to claim 7, it is characterized in that: described continuous lod preliminary-dip piece is made up of continuous fiber goods and thermoplastic resin composition, described continuous fiber goods are unidirectional fibre goods or multidirectional fibre.
9. a kind of high strength not delamination template according to claim 8, it is characterized in that: the continuous lod preliminary-dip piece be made up of unidirectional fibre goods and thermoplastic resin composition is angularly laid in one, its ply stacking angle is 90 ° or 0 °, [90 °/0 °] tor [0 °/90 °] t, [90 °/0 °/90 °] tor [0 °/90 °/0 °] t, [90 °/0 °] 2Tor [0 °/90 °] 2T, [90 °/0 °] 2sor [0 °/90 °] 2s.
10. a kind of high strength not delamination template according to claim 8 or claim 9, it is characterized in that: the material of described continuous fiber goods is one or more combinations of alkali-free glass fibre, medium-alkali glass fibre or high alkali glass fibre, carbon fiber, aramid fiber, basalt fibre, silicon carbide fibre, and continuous fiber diameter is 5 ~ 20 μm.
11. a kind of high strength not delamination templates according to claim 8 or claim 9, is characterized in that: described unidirectional fibre goods are continuous fiber yarn, unidirectional cloth.
12. a kind of high strength not delamination templates according to claim 8, is characterized in that: described multidirectional fibre is continuous fiber felt, continuous fiber grid cloth, plain cloth, twills, satin fabric, braid, blended fabric, multi-axial fabric, three dimensional fabric.
13. a kind of high strength not delamination templates according to claim 8 or claim 9, it is characterized in that: described thermoplastic resin composition is made up of vistanex, auxiliary agent and filler, based on the gross weight of thermoplastic resin composition, the percentage by weight of vistanex is 70wt% ~ 100wt%, the percentage by weight of auxiliary agent is 0 ~ 20wt%, the percentage by weight of filler is 0 ~ 10wt%, and wherein the melt index scope of vistanex is 10g/10min ~ 1000g/10min.
14. a kind of high strength not delamination templates according to claim 13, is characterized in that: described vistanex be in polyethylene, polypropylene and polyethylene reclaimed materials, polypropylene reclaimed material one or more with arbitrarily than combination.
15. a kind of high strength not delamination templates according to claim 13, is characterized in that: described auxiliary agent comprises one or more combinations in compatilizer, antioxidant, sliding agent, uvioresistant stabilizing agent, anti-dripping agent, plasticizing agent, coupling agent, fire retardant.
16. a kind of high strength not delamination templates according to claim 13, is characterized in that: described filler comprises one or more combinations in titanium dioxide, calcium carbonate, mica powder, toner.
17. a kind of high strength not delamination templates according to claim 1 or 7, is characterized in that: the one side that described continuous lod composite cover (2) does not bond with plate core (1) is provided with surperficial embossing or without surperficial embossing.
18. a kind of high strength not delamination templates according to claim 17, is characterized in that: the one side that described continuous lod composite cover (2) does not bond with plate core (1) is provided with surperficial embossing, and embossing depth bounds is 0.01mm ~ 0.4mm.
19. a kind of high strength not delamination templates according to claim 5 or 6, it is characterized in that: described bonding adhesive is one or more in polyurethane, epoxy resin, phenolic resins, Lauxite or melamine, and wherein resin solid content is 15% ~ 65%.
20. a kind of high strength not delamination templates according to claim 1 or 7, it is characterized in that: described adhesive layer is textile fabrics, textile fabrics is woven fabric, knitted fabric, woven cloth, multi-axial fabric, non-woven fabrics.
21. a kind of high strength not delamination templates according to claim 20, is characterized in that: the main component of described adhesive layer is natural fiber, chemical fibre, regenerated fiber, inorfil, blend fibre linen-cotton, polyester-cotton blend, wash sticky, wash in brocade one or more combination.
22. a kind of high strength not delamination templates according to claim 7 or 21, is characterized in that: the fusing point of described adhesive layer or heat decomposition temperature are greater than the fusing point of vistanex in continuous lod preliminary-dip piece.
The preparation method of 23. 1 kinds of high strength not delamination templates, is characterized in that, the steps include:
1) plate core is prepared: wood materials is made into rectangular-shaped lath, described lath is divided into lath a(6) and lath b(3), lath a(6) length direction consistent with wood grows direction, lath b(3) short transverse consistent with wood grows direction, lath a(6) and lath b(3) formed by a cuboid batten respectively, or lath a(6) and lath b(3) be spliced to form along stave lengths direction in the mode of mitered or docking by bonding adhesive by many battens respectively, its docking angle is θ=90 °, miter angles is θ <90 °, to reach plate core (1) length dimension requirement, along width of sheet direction: be bonded as one with the form of docking by bonding adhesive between adjacent slat, docking angle is θ=90 °, to reach plate core (1) width dimensions requirement, the plate core (1) that final formation is consistent with lath height,
2) prepare continuous lod composite cover: by continuous fiber goods through in resin melt, fully after dipping, through cooling, trimming, cutting rolling, form continuous lod preliminary-dip piece; Together with successively the continuous lod preliminary-dip piece be made up of unidirectional fibre goods or multidirectional fibre being laid in adhesive layer order, put it in hot blast constant temperature drying tunnel through 120 DEG C ~ 260 DEG C, 30s ~ 180s heating, with after through pressurization, cooling, cutting edge and deburring, obtain continuous lod composite cover (2);
3) template is prepared: at two coating adhesives on the surface up and down of plate core (1), scribble bonding adhesive plate core (1) two be covered with continuous lod composite cover (2) on the surface respectively up and down, adhesive layer on continuous lod composite cover (2) is contacted with plate core (1), be placed in press hot pressing, hot pressing temperature is 110 DEG C ~ 160 DEG C, pressure 10MPa ~ 20MPa, hot pressing time is 10min ~ 20min, forms template.
The preparation method of 24. a kind of high strength not delamination templates according to claim 23, is characterized in that: its laying angle of the continuous lod preliminary-dip piece be made up of unidirectional fibre goods in step 2 can be 90 ° or 0 °, [90 °/0 °] tor [0 °/90 °] t, [90 °/0 °/90 °] tor [0 °/90 °/0 °] t, [90 °/0 °] 2Tor [0 °/90 °] 2T, [90 °/0 °] 2sor [0 °/90 °] 2s.
The preparation method of 25. a kind of high strength not delamination templates according to claim 23, it is characterized in that: described bonding adhesive is one or more in polyurethane, epoxy resin, phenolic resins, Lauxite or melamine, and wherein resin solid content is 15% ~ 65%.
CN201510513732.5A 2015-08-20 2015-08-20 A kind of high intensity not delamination template and preparation method thereof Active CN105155839B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105604312A (en) * 2016-02-25 2016-05-25 广州金发碳纤维新材料发展有限公司 Fiber-reinforced building formwork and preparation method thereof
CN110922903A (en) * 2019-12-06 2020-03-27 常州华岳微创医疗器械有限公司 Easy-to-tear gasket and processing technology thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105604312A (en) * 2016-02-25 2016-05-25 广州金发碳纤维新材料发展有限公司 Fiber-reinforced building formwork and preparation method thereof
CN110922903A (en) * 2019-12-06 2020-03-27 常州华岳微创医疗器械有限公司 Easy-to-tear gasket and processing technology thereof

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