CN105155035B - The fiber garment material and its preparation technology of a kind of antimicrobial health care function - Google Patents
The fiber garment material and its preparation technology of a kind of antimicrobial health care function Download PDFInfo
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- CN105155035B CN105155035B CN201510682866.XA CN201510682866A CN105155035B CN 105155035 B CN105155035 B CN 105155035B CN 201510682866 A CN201510682866 A CN 201510682866A CN 105155035 B CN105155035 B CN 105155035B
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Abstract
The present invention relates to the fiber garment material and its preparation technology of a kind of antimicrobial health care function.The present invention makes most embedding distributions of nanometer silver metal particles only be attached to fiber surface with sub-fraction nanometer silver metal particles within the hole of fiber surface by the function fiber type in hole of the preparation with high distribution density；Even if washing is not easy to come off repeatedly during making the long-term use of dress materials, and also inhibits the oxidation of silver, the efficient of precious metal raw material is reached and has fully used.
Description
Technical field
The present invention relates to textile garment Material Field, and in particular to a kind of fiber garment material of antimicrobial health care function and its
Preparation technology.
Background technology
Functional form dress materials refer to having health care, treatment, magnetic concurrently on the basis of the general utility functions of ordinary garment materials
Property, the dress materials of the specific function such as luminous, heating.Wherein, the functional form dress materials of antibiotic health care can obtain prevention disease
Infection, it is mould proof de-taste, sanatory effect, the personal clothing that is particularly suitable for use in, footgear, mouth mask etc. directly contact human body skin and
The dress-goods of organ.
The functional form dress materials of antibiotic health care be added in ordinary garment materials with bactericidal bacteriostasis into
Point, in wearing process, these are slowly released into branch's continuation.Nano level silver metal particles (the general 25- of particle diameter
50nm) it is a kind of disinfecting antipathogenic composition for attracting attention very much in recent years, is also obtained among functional form dress materials
More and more extensive application.Nano-Ag particles have advantages below：First, there is the bactericidal and bacteriostatic effect of broad spectrum activity, to drenching ball
Hundreds of bacterium such as bacterium, Chlamydia, Escherichia coli works, and sterilizing ability is notable；Next to that drug resistance is not produced, to alleviating
The present situation of antiseptic abuse is significant；3rd is that totally nontoxic is tasteless non-stimulated, will not trigger allergic, is not had to human body
There is side effect；4th is also to have the function that to strengthen Cell growth ability, improve microcirculation, and is permeable to subcutaneously, therefore
Be advantageous to anti-inflammatory, wound healing and damaged skin reparation.
In the prior art, among the manufacture craft of functional form dress materials, simplest is directly to spray functional component
Apply or compress is on dress materials surface；Or dress materials are impregnated among the solution containing functional component so that function
Composition is attached to the surface of dress materials fiber.But the compatibility of nanometer silver metal particles itself and dress materials fiber compared with
Difference, absorption affinity each other is very weak, though and nanometer silver metal particles are nanoscale, than molecule particles again it is obvious more
Greatly, when therefore using with upper type, nanometer silver metal particles easily come off from dress materials；Particularly personal clothes want frequent water
Wash, more exacerbate the loss of nanometer silver metal particles.Another factor is that the silver metal for being directly exposed to surface is easy to aoxidize,
Once the beneficial effects such as oxidation antibacterial will disappear.The reason for the two aspects, to use the Nano Silver work(produced with upper type
Energy type dress materials are quickly invalidated.
It is existing it is another make functional form dress materials method be：Function fiber type is made first, then again with work(
Energy fiber type textile garment material, or utilize function fiber type and other fiber blend dress materials.Function fiber type be
Dissolving either adds dissolved state or graininess among the spinning solution such as the cellulose of molten form, silk-fibroin, high polymer
Functional ingredients, then carry out throwing and sizing with spinning process.But nanometer silver metal particles must be with bacterium or skin
Directly contacting competence exertion, it is acted on；Because the charge adsorption that bacterium is carried by silver metal particles when directly contacting, and then by
Its silver ion discharged kills；The silver ion of nanometer silver metal particles release in the state of direct skin contact with that could permeate
Its effect for promoting cell growth is played in skin.And added according to the preparation technology of above-mentioned function fiber type, the overwhelming majority
The organic principle that can be spun into liquid of silver metal particles firmly coat and be sealed in fibrous inside, without directly contact bacterium and
The chance of skin.Therefore, the Nano Silver functional form dress materials DeGrain of above method production, noble metal raw materials consumption
Also meaningless increase.
Chinese patent application CN102392347A discloses a kind of Intelligent silver-contained antibacterial fiber, using doughnut as shell,
In the sandwich layer that the empty intra-bladder instillation argentiferous hydrogel of doughnut is formed；Simple substance containing 0.1%-10% among argentiferous hydrogel
Silver.Because argentiferous hydrogel is covered by inside hollow fibre, it is not easy to aoxidize, elemental silver will not also depart among fiber；
When meeting water in use, the water swelling of argentiferous hydrogel and from the open end expansion of doughnut, so as to realize pair
The elemental silver release of surrounding environment.But the functional component used in above patent is argentiferous hydrogel, rather than effect is more excellent
Silver metal particles；Moreover, quite a few elemental silver is closed in inside hollow fibre all the time and can not discharged, release efficiency is inclined
Low, the effect of bactericidal is restricted.
It can be seen that still lack a kind of functional component using nanometer silver metal particles as bactericidal in the prior art, and
And realize that nanometer silver metal particles are combined with fibre compact and be not easily disconnected from, be advantageous to the high efficiency use of Argent grain and fully release
Put and the antibacterial functions type dress materials of silver metal particles Quick Oxidation can be prevented.
The content of the invention
Based on above-mentioned the problem of being previously mentioned, the invention provides the fiber garment material and its system of a kind of antimicrobial health care function
Standby technique.The present invention prepare with high distribution density hole function fiber type, nanometer silver metal particles by coupling-point
Dissipate-reduction, within main chimeric and fiber surface hole, there is good anti-detachment, do not influence silver metal particles with
External influence and discharge bactericidal action.
The present invention provides the fiber garment material preparation process of antimicrobial health care function, it is characterised in that comprises the following steps：
Prepare the blend spinning liquid comprising heteropolymerization thing and volatile solvent；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action, is had
The fibrous material intermediate in hole；
Coupling agent, dispersant are added into the mixed solution that silver ion saline solution is formed；By obtained fibrous material
Intermediate is totally submerged into mixed solution；Taken out after standing enough durations, add in reducing agent aqueous solution and reduce instead
Should, generate the function fiber type that the hole is fitted together to silver metal particles；
By the function fiber type successively be soaked in absolute ethyl alcohol and deionized water, remove be not reduced silver from
Son and the unrealized chimeric silver metal particles attached with surface and other reactants；
Vacuum drying.
Preferably, PLA (PLLA), makrolon (PC) and PVK are taken
(Polyvinylcarbazole), it is dissolved at room temperature in dichloromethane, obtains blend spinning liquid；Also, in the mixing
In spinning solution, PLLA mass concentration is 3-5wt%, and PC mass concentration is 12-15wt%, and PVK concentration is 6-
8wt%.
Preferably, coupling agent, dispersant are added among the mixed solution that silver ion saline solution is formed, and coupling agent is
Trimethyl silane (MTS), dispersant are polyvinylpyrrolidone (PVP), and silver ion salt is silver nitrate；Wherein, silver nitrate water
The initial concentration of solution is 0.15-0.3mol/L, and silver nitrate and dispersant PVP mol ratio are 1: 1.5, silver nitrate and coupling agent
MTS mol ratio is 1: 0.3.
The invention provides the fiber garment material preparation process of another antimicrobial health care function, it is characterised in that bag
Include following steps：
Prepare the blend spinning liquid comprising heteropolymerization thing and volatile solvent；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action, is had
The fibrous material intermediate in hole；
Sodium cellulose glycolate and polyvinylpyrrolidone (PVP) are added in deionized water, generation deionized water mixing
Solution；The fibrous material intermediate is immersed among deionized water mixed solution, and added to the deionized water mixed solution
Enter silver nitrate and coupling agent aqueous solution, generate the function fiber type that the hole is fitted together to silver metal particles；
By the function fiber type successively be soaked in absolute ethyl alcohol and deionized water, remove be not reduced silver from
Son and the unrealized chimeric silver metal particles attached with surface and other reactants；
Vacuum drying.
Preferably, polyvinylpyrrolidone (PVP), Kynoar (PVDF) input dimethylformamide (DMF) are taken
Mixed solution is prepared, as the blend spinning liquid；Mass volume ratio example of the above three in mixed solution be respectively：PVP
10g PVP and 20g PVDF are added in 10g: PVDF 20g: DMF 100mL, the i.e. DMF per 100mL.
Preferably, after sodium cellulose glycolate and polyvinylpyrrolidone (PVP) being added into deionized water, in 55-60
Stirred under degrees celsius, alkali lye, which is added dropwise, makes pH value be 8.0；Added among wherein per 100mL deionized waters
0.06g-0.08g sodium cellulose glycolates and 0.1-0.2g PVP；It is molten that fibrous material intermediate is immersed into deionized water mixing
After among liquid, the coupling agent added to the deionized water mixed solution uses trimethyl silane (MTS)；Per 100mL deionizations
1-1.5mL silver nitrates are added in water mixed solution and coupling agent mixed aqueous solution, the molar concentration of wherein silver nitrate aqueous solution are
2mol/L, and silver nitrate and coupling agent MTS mol ratio are 1: 0.25；Add during silver nitrate and coupling agent mixed aqueous solution
Kept for 55-60 degrees Celsius and be sufficiently stirred, react 3-5 hours.
The invention provides the fiber garment material preparation process of another antimicrobial health care function, it is characterised in that bag
Include following steps：
Prepare the blend spinning liquid comprising nv polymer and volatility polymer；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action；Wire drawing is obtained
The fiber obtained enters water-bath in high temperature deionized water, promotes the volatility polymer in fiber to volatilize, and obtains and has cuniculate fibre
Tie up material intermediate；
By ammoniacal liquor and Ag2Silver ammino solution is made in O dry powder, and reducing agent, dispersant and coupling agent are added to the silver ammino solution
Mixed solution, be put into fibrous material intermediate, then with ultraviolet light, generate the function that the hole is fitted together to silver metal particles
Fiber type；
By the function fiber type successively be soaked in absolute ethyl alcohol and deionized water, remove be not reduced silver from
Son and the unrealized chimeric silver metal particles attached with surface and other reactants；
Vacuum drying.
Preferably, take polyacrylonitrile (PAN) and PEO (PEO) to put into dimethylformamide (DMF), taken the photograph 80
Mixed solution is prepared under family name's degree constant temperature, as the blend spinning liquid；Mass concentrations of the wherein PAN in mixed solution be
4wt%-7wt%；Mass concentrations of the PEO in mixed solution is 1.2wt%-4.0wt%；PAN and both PEO are in mixed solution
In total mass concentration keep 8wt%.
Preferably, polyvinylpyrrolidone (PVP) is added in the silver ammino solution and coupling agent MTS mixing is molten
Liquid；Wherein, silver-colored ammonium ion and dispersant PVP mol ratio are 1: 1.5, and the mol ratio of silver-colored ammonium ion and coupling agent MTS is 1:
0.3；With wave-length coverage 254-365nm ultraviolet light, irradiation power 40W, irradiation time -2.5 hours 2 hours.
Present invention also offers the fiber garment material prepared with a kind of method of any of the above.
By preparing the function fiber type in the hole with high distribution density, make the most embedding of nanometer silver metal particles
Enter to be distributed within the hole of fiber surface, be only attached to fiber surface with sub-fraction nanometer silver metal particles；Add
Appropriate coupling agent contributes to the combination of silver metal particles and hole inwall and fiber surface in preparation process, while does not interfere with silver
The Spontaneous release of metallic particles in use；Silver metal particles are not united, and are disperseed with individual particle；Due to embedded hole with
It is interior, even if washing is not easy to come off most nanometer silver metal particles repeatedly during the long-term use of dress materials, and
And it also inhibits the oxidation of silver；The silver metal particles overwhelming majority is in the hole of fiber surface, thus can with fiber with
Outer fully contact has reached the efficient of precious metal raw material and fully used so as to the effect for playing sterilization and promoting cell growth.
Brief description of the drawings
Accompanying drawing 1 is the microstructure of fibrous material intermediate.
Embodiment
Below by embodiment, and with reference to accompanying drawing, technical scheme is described in further detail.
Embodiment I
PLA (PLLA), makrolon (PC) and PVK (Polyvinylcarbazole) are taken, in room temperature
Under be dissolved in dichloromethane, obtain blend spinning liquid；Wherein, PLLA mass concentration is 3- in the blend spinning liquid
5wt%, PC mass concentration are 12-15wt%, and PVK concentration is 6-8wt%；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action, obtains fiber
Material intermediate；Drawing speed is 2-5 meter per seconds, 20-25 degrees Celsius of drawing process environment temperature, electric-field intensity 10KV.In electrostatic
In spinning process, electric field force overcomes the surface tension of the fine droplet of spinning solution, forms the droplet morphology suitable for spinning, dichloromethane
Alkane quickly volatilizees, and PLLA, PC and Polyvinylcarbazole reciprocal compatibility are poor, after out-phase fast enriching and solidification
The supporting and shaping structure of fiber is formed, the hole that the solvent vapored away is formed between supporting and shaping structure, undulation degree as shown in Figure 1
Expect the microstructure of intermediate, it is seen that the hole being wherein largely distributed, the diameter in hole is about between 1 hundred to two hundred nanometer, greatly
It is small to be suitable to embedded some nanometers of silver metal particles；Void structure as formation depend primarily on PLLA, PC with
Polyvinylcarbazole special component is formed in the crystallinity that crystallization 30%-40% is can reach under above spinning condition,
Less than the crystallinity of generally spinning fibre more than 60%.After the solidification of fibrous material intermediate is stable, it can be heated to
50-60 degrees Celsius, dichloromethane remaining in hole is promoted quickly to volatilize.
Obtained fibrous material intermediate is totally submerged to by coupling agent, dispersant and adds silver nitrate aqueous solution and is formed
Mixed solution in, wherein coupling agent is trimethyl silane (MTS), and dispersant is polyvinylpyrrolidone (PVP).Wherein, nitre
The initial concentration of sour silver be 0.15-0.3mol/L, and silver nitrate and dispersant PVP mol ratio are 1: 1.5, silver nitrate and coupling agent
MTS mol ratio is 1: 0.3.
Fibrous material intermediate stood Immersion time no less than 30 minutes in above-mentioned mixed solution, after then taking out without
Reducing agent sodium borohydride aqueous solution (NaBH is immersed in washing4) among place；NaBH4Mol ratio with silver nitrate is 1: 4.It is heated up to
45 degrees Celsius of reaction temperature, carry out ultrasonic vibration, more than 1 hour reaction time；So that the silver adhered on fibrous material intermediate
It is nanometer silver metal particles, the particle diameter 30nm of silver metal particles made from reduction or so that ion, which is reduced agent reduction reaction,.
In being reacted more than, the effect of dispersant is to avoid silver metal particles that agglomeration occurs after being reduced out；It is even
Join outer surface and hole inwall of the agent one side chemical bonded refractory together in fibrous material intermediate, on the other hand have with silver ion compared with
Strong combination, it is chimeric in fibrous material hole so as to strengthen silver metal particles after reduction reaction, lead to simultaneously
The release for keeping the low dosage of coupling agent to avoid to nano-Ag particles is crossed to cause to hinder.
Through above-mentioned reduction reaction, generation hole is fitted together to the function fiber type of silver metal particles；By the function fiber type successively
It is soaked in absolute ethyl alcohol and deionized water, removes the silver ion not being reduced and be not implemented chimeric and surface attaching
Silver metal particles and other reactants, immersion process can repeat 3-5 times；It should try one's best and avoid by the way of rinsing to function
Fiber type is washed；And then be fully dried in vacuo in 50-80 degrees Celsius of environment, duration 20-24 hours are dried, are obtained with anti-
The fiber garment material of bacterium healthcare function.The fiber garment material can be apparel textile with other fiber blends.
Embodiment II
Take polyvinylpyrrolidone (PVP), Kynoar (PVDF) input dimethylformamide (DMF) preparation mixing molten
Liquid is as spinning solution；Mass volume ratio example of the above three in mixed solution be respectively：PVP10g∶PVDF 20g∶DMF
10g PVP and 20g PVDF are added in 100mL, the i.e. DMF per 100mL.
Spinning solution is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action, is obtained among fibrous material
Thing；Drawing speed is 2-5 meter per seconds, and drawing process environment temperature keeps room temperature, electric-field intensity 15KV.After electrospinning wire drawing,
It is put into vacuum environment to be dried, promotes solvent volatilization, form the fibrous material intermediate with high density hole.Electrospinning wire drawing
During, due to PVP and PVDF objectionable interminglings, the enrichment of the two split-phase, the DMF as solvent fully volatilizees, so that hole
Distribution density it is higher, and fiber surface is relatively rough.
Sodium cellulose glycolate and polyvinylpyrrolidone (PVP) are added in deionized water, in 55-60 degrees celsius
Under stir, be added dropwise alkali lye make pH value be 8.0；0.06g-0.08g hydroxyl first is added among wherein per 100mL deionized waters
Base sodium cellulosate and 0.1-0.2g PVP.
By with high density hole fibrous material intermediate immerse deionized water mixed solution among, and to this go from
Sub- water mixed solution adds silver nitrate and coupling agent aqueous solution, coupling agent use trimethyl silane (MTS)；Per 100mL deionizations
1-1.5mL silver nitrates and coupling agent aqueous solution are added in water mixed solution, the wherein molar concentration of silver nitrate aqueous solution is 2mol/
L, and silver nitrate and coupling agent MTS mol ratio are 1: 0.25.55-60 is kept during addition silver nitrate and coupling agent aqueous solution
Degree Celsius and be sufficiently stirred, react 3-5 hours.The colloidal solution of the silver metal particles containing nanometer is generated in above-mentioned course of reaction,
Silver metal particles therein enter the hole of fibrous material intermediate with colloid or are adsorbed in fiber surface, form functional form
Fiber.
The function fiber type is successively soaked in absolute ethyl alcohol and deionized water, removes the silver ion not being reduced
And the unrealized chimeric silver metal particles attached with surface and other reactants, immersion process can repeat 3-5 times；It should use up
Amount avoids washing function fiber type by the way of rinsing；And then fully dried in 50-80 degrees Celsius of environment, when drying
Long 20-24 hours, obtain the fiber garment material with antimicrobial health care function.The fiber garment material can be with other fiber blends
For apparel textile.
Embodiment III
Polyacrylonitrile (PAN) and PEO (PEO) is taken to put into dimethylformamide (DMF), in 80 degrees Celsius of constant temperature
Under the conditions of prepare mixed solution；Mass concentrations of the wherein PAN in mixed solution is 4wt%-7wt%, preferably 6.8wt%；PEO
Mass concentration in mixed solution is 1.2wt%-4.0wt%；PAN and total mass concentrations of both PEO in mixed solution
Keep 8wt%；The mixed solution is as spinning solution.
Spinning solution is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action；Temperature keeps room temperature,
The fiber vacuum obtained in drawing process after electric-field intensity 8KV wire drawings is placed 24 hours, so as to DMF solvent remaining on fiber
Volatilization；And then fiber is immersed in water-bath 10 minutes in 70 degrees Celsius of deionized water, remove the PEO among fiber.In fiber
Originally hole is formed by the position of PEO institutes occupy-place.Fiber is dried -6 hours 4 hours under 70 degrees Celsius and vacuum environment, obtained
Must have cuniculate fiber intermediate.
By mass concentration 2wt% ammoniacal liquor and Ag2Silver ammino solution is made according to 4: 1 mixed in molar ratio in O dry powder；To the silver-colored ammonia
Polyvinylpyrrolidone (PVP) and coupling agent MTS mixed solution are added in solution, and fiber intermediate is entered into the solution
Among.PVP is as dispersant and reducing agent；Wherein, silver-colored ammonium ion and dispersant PVP mol ratio are 1: 1.5, silver-colored ammonium ion with
Coupling agent MTS mol ratio is 1: 0.3.With wave-length coverage 254-365nm ultraviolet light, irradiation power 40W, irradiation time
- 2.5 hours 2 hours, obtain the scattered nanometer silver metal particles within 20 nanometers of particle diameter, the insertion of trickle nanometer silver metal particles
To the hole of fiber.
The function fiber type is successively soaked in absolute ethyl alcohol and deionized water, removes the silver ion not being reduced
And the unrealized chimeric silver metal particles attached with surface and other reactants, immersion process can repeat 3-5 times；It should use up
Amount avoids washing function fiber type by the way of rinsing；And then fully dried in 50-80 degrees Celsius of environment, when drying
Long 20-24 hours, obtain the fiber garment material with antimicrobial health care function.The fiber garment material can be with other fiber blends
For apparel textile.
In the embodiment above, by preparing the function fiber type in the hole with high distribution density, the Nano Silver gold made
Most embedding distributions of metal particles are only attached within the hole of fiber surface with sub-fraction nanometer silver metal particles
In fiber surface；The appropriate coupling agent added contributes to silver metal particles and hole inwall and the knot of fiber surface in preparation process
Close, while do not interfere with the Spontaneous release of silver metal particles in use；Silver metal particles are not united, with individual particle point
Dissipate；Within embedded hole, even if most nanometer silver metal particles during the long-term use of dress materials repeatedly
Washing is not easy to come off, and also inhibits the oxidation of silver；The silver metal particles overwhelming majority is in the hole of fiber surface,
Therefore precious metal raw material can have been reached with fully being contacted beyond fiber so as to play sterilization and promote the effect of cell growth
Efficiently fully use.
Above example is merely to illustrate the present invention, and not limitation of the present invention, the common skill about technical field
Art personnel, without departing from the spirit and scope of the present invention, it can also make a variety of changes and modification, thus it is all etc.
Same technical scheme falls within scope of the invention, and scope of patent protection of the invention should be defined by the claims.
Claims (10)
1. the fiber garment material preparation process of a kind of antimicrobial health care function, it is characterised in that comprise the following steps：
Prepare the blend spinning liquid comprising heteropolymerization thing and volatile solvent；The heteropolymerization thing is PLA
(PLLA), makrolon (PC) and PVK (Polyvinylcarbazole)；The volatile solvent is dichloromethane
Alkane；The heteropolymerization thing is dissolved in dichloromethane at room temperature forms the blend spinning liquid；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action so that the dichloro
Methane quickly volatilizees, the PLA (PLLA), makrolon (PC) and PVK (Polyvinylcarbazole)
By out-phase fast enriching and solidify, reach 30%-40% crystallinity, form the supporting and shaping structure of fiber, vapor away
The hole that dichloromethane is formed between supporting and shaping structure, so as to obtain the cuniculate fibrous material intermediate of tool；
Coupling agent, dispersant are added into the mixed solution that silver ion saline solution is formed；Among obtained fibrous material
Thing is totally submerged into mixed solution；Taken out after standing enough durations, add in reducing agent aqueous solution and carry out reduction reaction, make
It is nanometer silver metal particles to obtain the silver ion adhered on fibrous material intermediate and be reduced agent reduction reaction, and it is embedding to generate the hole
Close the function fiber type of silver metal particles；
The function fiber type is successively soaked in absolute ethyl alcohol and deionized water, remove the silver ion that is not reduced with
And the chimeric silver metal particles attached with surface and other reactants is not implemented；
Vacuum drying.
2. fiber garment material preparation process according to claim 1, it is characterised in that in the blend spinning liquid,
The mass concentration of PLA (PLLA) is 3-5wt%, and the mass concentration of makrolon (PC) is 12-15wt%, polyvinyl click
Azoles (Polyvinylcarbazole) concentration is 6-8wt%.
3. fiber garment material preparation process according to claim 2, it is characterised in that coupling agent, dispersant, which add, to be contained
Among the mixed solution that silver ion saline solution is formed, coupling agent is trimethyl silane (MTS), and dispersant is polyvinyl pyrrole
Alkanone (PVP), silver ion salt are silver nitrate；Wherein, the initial concentration of silver nitrate aqueous solution is 0.15-0.3mol/L, nitric acid
Silver and dispersant PVP mol ratio are 1:1.5, silver nitrate and coupling agent MTS mol ratio are 1:0.3.
4. the fiber garment material preparation process of a kind of antimicrobial health care function, it is characterised in that comprise the following steps：
Prepare the blend spinning liquid comprising heteropolymerization thing and volatile solvent；The heteropolymerization thing is polyvinylpyrrolidine
Ketone (PVP) and Kynoar (PVDF)；The volatile solvent is dimethylformamide (DMF)；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action, makes dimethyl formyl
Amine (DMF) volatilizees, and forms hole, mutual exclusive polyvinylpyrrolidone (PVP) and the enrichment of Kynoar (PVDF) split-phase,
So as to obtain the cuniculate fibrous material intermediate of tool；
Sodium cellulose glycolate and polyvinylpyrrolidone (PVP) are added in deionized water, generate deionized water mixed solution；
The fibrous material intermediate is immersed among deionized water mixed solution, and nitric acid is added to the deionized water mixed solution
Silver and coupling agent aqueous solution, the colloidal solution of reaction generation silver metal particles containing nanometer, silver metal particles therein are with colloid
Into the hole of fibrous material intermediate or fiber surface is adsorbed in, generates the functional form that the hole is fitted together to silver metal particles
Fiber；
The function fiber type is successively soaked in absolute ethyl alcohol and deionized water, remove the silver ion that is not reduced with
And the chimeric silver metal particles attached with surface and other reactants is not implemented；
Vacuum drying.
5. fiber garment material preparation process according to claim 4, it is characterised in that polyvinylpyrrolidone (PVP),
The mass volume ratio example of Kynoar (PVDF), dimethylformamide (DMF) in mixed solution is respectively:Polyvinyl pyrrole
Alkanone (PVP) 10g:Kynoar (PVDF) 20g:Dimethylformamide (DMF) 100mL, i.e. the dimethyl formyl per 100mL
10g polyvinylpyrrolidones (PVP) and 20g Kynoar (PVDF) are added in amine (DMF).
6. fiber garment material preparation process according to claim 5, it is characterised in that by sodium cellulose glycolate with gathering
After vinylpyrrolidone (PVP) adds deionized water, stirred under 55-60 degrees celsius, alkali lye, which is added dropwise, makes pH
It is worth for 8.0；0.06g-0.08g sodium cellulose glycolates and the poly- second of 0.1-0.2g are added among wherein per 100mL deionized waters
Alkene pyrrolidone (PVP)；After fibrous material intermediate is immersed among deionized water mixed solution, mixed to the deionized water
The coupling agent that solution adds uses trimethyl silane (MTS)；1-1.5mL nitric acid is added in per 100mL deionized water mixed solutions
Silver and coupling agent mixed aqueous solution, the wherein molar concentration of silver nitrate aqueous solution are 2mol/L, and silver nitrate is with coupling agent MTS's
Mol ratio is 1:0.25；55-60 degrees Celsius is kept during addition silver nitrate and coupling agent mixed aqueous solution and is sufficiently stirred,
React 3-5 hours.
7. the fiber garment material preparation process of a kind of antimicrobial health care function, it is characterised in that comprise the following steps：
Prepare the blend spinning liquid for including polyacrylonitrile (PAN), PEO (PEO) and dimethylformamide (DMF)；
The blend spinning liquid is inserted in electrostatic spinning machine, injection wire drawing is carried out under forceful electric power field action, vacuum is put after wire drawing
Put, dimethylformamide (DMF) is volatilized；Water-bath in high temperature deionized water is entered to the fiber that wire drawing obtains, fiber is removed and works as
In PEO (PEO) so that originally by the occupy-place of PEO (PEO) institute position formed hole, so as to be had
Cuniculate fibrous material intermediate；
By ammoniacal liquor and Ag2Silver ammino solution is made in O dry powder, and the mixing of reducing agent, dispersant and coupling agent is added to the silver ammino solution
Solution, fibrous material intermediate is put into, then with ultraviolet light, obtains the scattered nanometer silver metal within 20 nanometers of particle diameter
Grain, nanometer silver metal particles are embedded in inside the hole of fiber, generate the function fiber type that the hole is fitted together to silver metal particles；
The function fiber type is successively soaked in absolute ethyl alcohol and deionized water, removes the silver ion not being reduced
And the chimeric silver metal particles attached with surface and other reactants is not implemented；
Vacuum drying.
8. fiber garment material preparation process according to claim 7, it is characterised in that polyacrylonitrile in blend spinning liquid
(PAN) mass concentration is 4wt%-7wt%；The mass concentration of PEO (PEO) is 1.2wt%-4.0wt%；Poly- third
Total mass concentration of the alkene nitrile (PAN) with both PEOs (PEO) in mixed solution keeps 8wt%.
9. fiber garment material preparation process according to claim 8, it is characterised in that added in the silver ammino solution
The mixed solution of polyvinylpyrrolidone (PVP) and coupling agent MTS；Wherein, silver-colored ammonium ion and polyethylene of dispersing agent pyrrolidones
(PVP) mol ratio is 1:1.5, silver-colored ammonium ion and coupling agent MTS mol ratio are 1:0.3；With wave-length coverage 254-365nm's
Ultraviolet light, irradiation power 40W, irradiation time -2.5 hours 2 hours.
10. fiber garment material made of the preparation technology described in any one in above claim.
Priority Applications (1)
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