CN105153595B - A kind of imitation wood line moulding and preparation method thereof - Google Patents
A kind of imitation wood line moulding and preparation method thereof Download PDFInfo
- Publication number
- CN105153595B CN105153595B CN201510648602.2A CN201510648602A CN105153595B CN 105153595 B CN105153595 B CN 105153595B CN 201510648602 A CN201510648602 A CN 201510648602A CN 105153595 B CN105153595 B CN 105153595B
- Authority
- CN
- China
- Prior art keywords
- parts
- mah
- imitation wood
- line moulding
- wood line
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002023 wood Substances 0.000 title claims abstract description 27
- 238000000465 moulding Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 20
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000012745 toughening agent Substances 0.000 claims abstract description 13
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 10
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 33
- 239000000463 material Substances 0.000 description 21
- 229920003023 plastic Polymers 0.000 description 15
- 239000004033 plastic Substances 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 150000003573 thiols Chemical class 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009415 formwork Methods 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- -1 insulation Substances 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- QRCJOCOSPZMDJY-UHFFFAOYSA-N valnoctamide Chemical compound CCC(C)C(CC)C(N)=O QRCJOCOSPZMDJY-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Abstract
The invention discloses a kind of imitation wood line moulding and preparation method thereof, the imitation wood line moulding is prepared by the raw material of following weight parts：80 120 parts of polyvinyl chloride resin, 2.5 7.5 parts of heat stabilizer, 12 parts of stearic acid, 12 parts of Tissuemat E, 10 30 parts of talcum powder, 48 parts of toughener.The heat endurance for the imitation wood line moulding that the present invention obtains is good, and mechanical performance is excellent, wood grain svelteness, wood grain effect are true to nature.
Description
Technical field
The present invention relates to polyvinyl-chloride plate material technical field, and in particular to a kind of imitation wood line moulding extremely prepares method.
Background technology
With the rapid development of construction industry, the status of form work engineering becomes increasingly conspicuous, and mould plate technique directly affects engineering construction
Quality, cost and benefit, while the theory such as green, low-carbon, sustainable is also increasingly becoming focus in all kinds of engineer applieds.Pass
The building template of the system such as needs such as plank sheathing, bamboo plywood, wood plywood largely use timber, not only cause the broken of the forest reserves
It is bad, and discarded object can not be realized and reused, it is most of to be thrown aside or burned, easily cause environmental pollution.Modern steel form
Production power consumption, Master Cost, mounting cost it is all higher, be relatively specific for the use of large form, tool-typed formwork.In addition plastics
The advantages of continuous development of industry, therefore, wood plastics composite template are arisen at the historic moment, and it combines timber and plastics, such as it is weather-proof, can
Lean on, be environmentally friendly, be convenient, be recyclable etc..
One of PVC material kind maximum as yield, dosage in synthetic material, has very excellent combination property,
It is such as fire-retardant, insulation, acid and alkali-resistance, wear-resistant, and cost is cheap, raw material are sufficient, the most of recoverable of waste product,
It is widely used in fields such as commodity, outer packing, building trade, agricultural, electronics.
Although the combination property of PVC material is fine, defect is it is also obvious that main following points：
(1) resistance to ag(e)ing is poor：Light, oxygen comprehensive function under will slowly decompose, begun at 80 DEG C or so discharge HCl
Gas, the temperature are far below the machine-shaping temperature of material, while also produce considerable influence to the routine use of molded material.
Just because of this, the ageing resistace for studying PVC material is constantly in critical positions in the development of the material.
(2) poor heat resistance：Polyvinyl chloride resin easily decomposes in high temperature, when temperature is higher than 100 DEG C, starts to decompose and discharges
HCl, its decomposition rate are accelerated with the raising of temperature, meanwhile, it can soften during the material stress, mobility occur, therefore adding
Man-hour need to fill heat stabilizer.
(3) shock resistance is poor：Hard PVC impact resistance is poor, and brittle failure easily occurs, and PVC board typically selects soft material
Material, with extrusion process shaping of foaming.
The temperature that it is plastified during PVC composite plastic machine-shapings and the temperature close decomposed, but because the heat of its own is steady
Qualitative and fragility etc. is poor, so must fill heat stabilizer, filler, impact property modifying agent, plasticizer, filler etc. during processing
Additive, and carry out reasonably combined.
Corvic is adding man-hour requirement to carry out toughening modifying, typically uses elastic body toughening and rigid particles at present
Two methods of toughness reinforcing.
The structure of polyvinyl chloride resin particle has a major impact to processing characteristics.Generally the particle diameter of resin mainly divides
For cloth at 100~150 μm, processing characteristics is preferable.
The apparent density of resin has direct relation with production and processing speed, and in extrusion process, the speed of extrusion is with PVC
The increase of resin apparent density and accordingly improve.
The porosity of material is directly proportional to the speed that it absorbs rate accelerating material, and the addition of plasticizer helps to reduce processing temperature
And improve physical property, therefore in the conceived case, the porosity of resin material should be improved to increase the uptake of plasticizer.
The viscosity and melt strength of polyvinyl chloride resin material are also the important indicator for examining material processing characteristics good and bad, with melting
Factor F is weighed.
PVC heat endurances and fragility etc. are poor, are restricted its application.Therefore invent that a kind of stability is good, good toughness
PVC composite plastics demand be present.
The content of the invention
For above shortcomings in the prior art, the technical problems to be solved by the invention are to provide a kind of imitation wood line
Moulding and preparation method thereof.
The present invention seeks to what is be achieved through the following technical solutions：
A kind of imitation wood line moulding, is prepared by the raw material of following weight parts：
Polyvinyl chloride resin 80-120 parts, heat stabilizer 2.5-7.5 parts, stearic acid 1-2 parts, Tissuemat E 1-2 parts, talcum powder 10-
30 parts, toughener 4-8 parts.
Preferably, described toughener is selected from maleic anhydride grafting polymer elastomer, preferably POE-g-MAH, PP-g-
One or more mixing in MAH, HDPE-g-MAH, PE-g-MAH, EVA-g-MAH, SEBS-g-MAH, EPDM-g-MAH
Thing.
It is highly preferred that described toughener is mixed by PP-g-MAH, EPDM-g-MAH and HDPE-g-MAH, it is described
PP-g-MAH, EPDM-g-MAH, HDPE-g-MAH mass ratio are (1-3)：(1-3)：(1-3).
Preferably, described heat stabilizer be lead sulfate tribasic, it is dibasic lead phosphite, dibasic lead stearate, hard
One or more mixtures in resin acid zinc, calcium stearate, thiol methyl tin, dibutyl tin dilaurate.
It is furthermore preferred that described heat stabilizer is thiol methyl tin.
Present invention also offers the preparation method of above-mentioned imitation wood line moulding, comprise the following steps：
(1) raw material mixes；
(2) raw material is sent into hot press；
(3) cooling and shaping.
Preferably,
120-130 DEG C of the temperature of hot press, pressure 8Mpa-10Mpa in the step (2).
Shaped in the step (3) with water cooling down.
The heat endurance for the imitation wood line moulding that the present invention obtains is good, and mechanical performance is excellent, wood grain svelteness, wood grain
Effect is true to nature.
Embodiment
Each raw material introduction in embodiment：
Polyvinyl chloride resin, use polyvinyl chloride resin of the trade mark that Qilu Petrochemical Company produces for S-700.
Heat stabilizer, using the thiol methyl tin heat stabilizer of Chuan Baoqi Chemical Co., Ltd.s of Shenzhen, model：SC-
688。
Talcum powder, using the mesh talcum powder of Chuzhou Anhui thin,tough silk board 400 of Chuzhou City Zhu Longguangwei sericites in powder factory.
Stearic acid, using the stearic acid of the model 200 of Wujiang Quan Cheng Chemical Co., Ltd.s.
Tissuemat E, using the model PE-WAX of RAKUTEN of South Korea production Tissuemat E.
PP-g-MAH, using the PP-g-MAH from the sub- match plasticizing Co., Ltd production in Suzhou.
EPDM-g-MAH, the EPDM-g-MAH produced using Fa Bang trade Co., Ltds of Shunde District.
HDPE-g-MAH, using the HDPE-g-MAH of the sub- match plasticizing Co., Ltd production in Suzhou.
Hot press, using the model RY-100 of Community of Jin Tan County blue star machinery plant production heat pressing forming machines.
Embodiment 1
Weigh each raw material (parts by weight)：100 parts of polyvinyl chloride resin, 5 parts of heat stabilizer, 1.5 parts of stearic acid, Tissuemat E 1.5
Part, 20 parts of talcum powder, 6 parts of toughener.
Described toughener is mixed by PP-g-MAH, EPDM-g-MAH and HDPE-g-MAH, the PP-g-MAH,
EPDM-g-MAH, HDPE-g-MAH mass ratio are 1：1：1.
(1) above-mentioned raw materials are mixed；
(2) raw material is sent into hot press, 125 DEG C of temperature, pressure 9Mpa；
(3) cooling and shaping, room temperature is cooled to water.
Embodiment 2
Imitation wood line moulding is prepared by the raw material proportioning and method of embodiment 1, is differed only in：Toughener is replaced with
PP-g-MAH is 1 with EPDM-g-MAH mass ratioes：1 mixture.
Embodiment 3
Imitation wood line moulding is prepared by the raw material proportioning and method of embodiment 1, is differed only in：Toughener is replaced with
PP-g-MAH is 1 with HDPE-g-MAH mass ratioes：1 mixture.
Embodiment 4
Imitation wood line moulding is prepared by the raw material proportioning and method of embodiment 1, is differed only in：Toughener is replaced with
EPDM-g-MAH is 1 with HDPE-g-MAH mass ratioes：1 mixture.
Test case 1：Tensile property is tested
The imitation wood line moulding that embodiment 1-4 is prepared carries out tensile property test.Due to no existing wood moulding
Board test standard, this experiment use ASTM D638-2003 plastic tensile performance standard method of testings.
Test sample uses II class dumbbell shape sample.For soft thermoplastic and sheet material, test sample is typically adopted
With II type, injection, molding or machining can, and previous experiences think that the optimal test thickness of sample is 2mm, and new
Type PVC compound plastic board application times are shorter, and related plastic testing specification had not provided specific thickness requirement, ASTM
Itd is proposed in D638-2003, when determining the mechanical property of plastics, the thickness maximum of sample can reach 14mm, and examination is tackled when excessive
Sample is handled, and its thickness is ensured within 14mm.More researchs show that the thickness of sample is for plastics Mechanics Performance Testing
Influence is that the density of each layer of material is it will be apparent that the raw material of this test are the materials of fretting map inside two-sided skinning
It is differentiated, if handling the thickness of raw material, it will produce considerable influence to the test result of material mechanical performance.Root
According to the standard recommendation of ASTM International Association for Testing materials, the specific appearance and size of this sample is overall length 185.0mm, gauge length 50.0mm,
Width 12.0mm, thickness, 12.0mm.
The tension test of PVC composite plastic template materials uses UTM-1422 universal testing machines, and sample is by sheet-punching machine
It is made, carries out examination to that may have an impact the sample of result of the test defect before experiment, randomly select 5 samples and carry out stretching examination
Test.Due to no existing wood-plastic board testing standard, this experiment is tested using ASTM D638-2003 plastic tensiles performance standard
Method.
In tension test, the environment temperature, the speed etc. of stretching when the previous stressing conditions of sample, experiment are to the experiment
Influence be critically important, therefore in this experiment.In order to reduce the influence of these factors on test results as far as possible, to sample
Relevant treatment is carried out.After sample is made, prestretching loading is carried out in the small deformation elastic range of prediction, in temperature after unloading
24h is placed in (25 ± 2) DEG C, relative humidity (65 ± 5) % standard environment.Each embodiment is random in obtained sample
Choose five to be tested, and the outward appearance of check test sample is so as not to influence the accuracy of result of the test.According to plastics
Tension test standard recommendation, the speed of this tension test select 2mm/min.23 DEG C of environment temperature, relative humidity during experiment
64%.Specific test result is shown in Table 1.
The tensile test data of the imitation wood line moulding sample of table 1
| Tensile strength/MPa | |
| Embodiment 1 | 22.2 |
| Embodiment 2 | 17.9 |
| Embodiment 3 | 18.4 |
| Embodiment 4 | 18.1 |
By the test result of table 1, embodiment 1 has used the toughness reinforcing that PP-g-MAH, EPDM-g-MAH, HDPE-g-MAH are compounded
Agent, compared with embodiment 2-4 omits any of which, in the case of toughener adds total amount identical, obtained imitation wood line
Moulding tensile strength is higher.
Test case 2：Crooked test
With reference to《The measure of plastics bending property》(GB/T9341-2008) and《Plywood for concrete form》
Relevant regulations in (GBT17656-2008) are tested.
The bend test of this material uses UTM-1422 universal testing machines.With sample support into simply supported beam,
Span centre is at the uniform velocity bent with 2mm/min, until stress is not further added by or reached to stop experiment during 5% strain, sample is protected when loading
It is vertical with the long axis centerline of sample to demonstrate,prove loading roll axis.Sample is rectangular slab, is made by sampling machine, the specific size of sample
For overall length 240.0mm, across footpath 200.0mm, width 20.0mm, thickness, 12.0mm.
Sample be made after, temperature (25 ± 2) DEG C, relative humidity (65 ± 5) % standard environment in placed 24h.
Each embodiment randomly selects five and tested in obtained sample, and the outward appearance of check test sample is so as not to influence
The accuracy of result of the test.During sample fracture, result of the test of the fracture position beyond simply supported beam span centre 1/3 is cancelled, again with
Machine is chosen sample and tested.23 DEG C of environment temperature during experiment, relative humidity 63%.Anti-bending strength data are shown in Table 2.
The experiment on flexural behavior data of the imitation wood line moulding of table 2
| Modulus of elasticity/MPa | |
| Embodiment 1 | 2865 |
| Embodiment 2 | 2638 |
| Embodiment 3 | 2688 |
| Embodiment 4 | 2662 |
By the test result of table 2, embodiment 1 has used the toughness reinforcing that PP-g-MAH, EPDM-g-MAH, HDPE-g-MAH are compounded
Agent, compared with embodiment 2-4 omits any of which, in the case of toughener adds total amount identical, obtained imitation wood line
Moulding modulus of elasticity is higher.
Claims (2)
1. a kind of imitation wood line moulding, it is characterised in that be prepared by the raw material of following weight parts：Polyvinyl chloride resin 80-120
Part, heat stabilizer 2.5-7.5 parts, stearic acid 1-2 parts, Tissuemat E 1-2 parts, talcum powder 10-30 parts, toughener 4-8 parts；
Described toughener is mixed by PP-g-MAH, EPDM-g-MAH and HDPE-g-MAH, described PP-g-MAH, EPDM-
G-MAH, HDPE-g-MAH mass ratio are (1-3)：(1-3)：(1-3).
2. the preparation method of imitation wood line moulding as claimed in claim 1, it is characterised in that comprise the following steps：
(1) raw material mixes；
(2) raw material is sent into hot press；
(3) cooling and shaping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510648602.2A CN105153595B (en) | 2015-10-09 | 2015-10-09 | A kind of imitation wood line moulding and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510648602.2A CN105153595B (en) | 2015-10-09 | 2015-10-09 | A kind of imitation wood line moulding and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105153595A CN105153595A (en) | 2015-12-16 |
| CN105153595B true CN105153595B (en) | 2017-12-12 |
Family
ID=54794664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510648602.2A Expired - Fee Related CN105153595B (en) | 2015-10-09 | 2015-10-09 | A kind of imitation wood line moulding and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105153595B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108559222A (en) * | 2018-04-09 | 2018-09-21 | 合肥博之泰电子科技有限公司 | A kind of ageing-resistant resin material of imitation wood line for skirting manufacture |
| CN111410800A (en) * | 2020-02-24 | 2020-07-14 | 苏州绿萃筑新材料科技有限公司 | Wood-grain-like decorative line and preparation method thereof |
| CN112457607A (en) * | 2020-11-30 | 2021-03-09 | 颍上县方圆新材料有限公司 | PVC moulding and setting device for production thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417678A (en) * | 2011-11-23 | 2012-04-18 | 濮阳市东宝科技发展有限公司 | Wood plastic plate strip |
| CN102898710A (en) * | 2011-07-28 | 2013-01-30 | 合肥杰事杰新材料股份有限公司 | Wood plastic material and preparation method thereof |
-
2015
- 2015-10-09 CN CN201510648602.2A patent/CN105153595B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898710A (en) * | 2011-07-28 | 2013-01-30 | 合肥杰事杰新材料股份有限公司 | Wood plastic material and preparation method thereof |
| CN102417678A (en) * | 2011-11-23 | 2012-04-18 | 濮阳市东宝科技发展有限公司 | Wood plastic plate strip |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105153595A (en) | 2015-12-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ayrilmis et al. | Effect of printing layer thickness on water absorption and mechanical properties of 3D-printed wood/PLA composite materials | |
| CN105153595B (en) | A kind of imitation wood line moulding and preparation method thereof | |
| Tajvidi et al. | Long‐term water uptake behavior of natural fiber/polypropylene composites | |
| CN101260230B (en) | Hot-pressing forming artificial stone material and preparation method thereof | |
| CN101942207B (en) | Wood powder-polyvinyl chloride compound material and preparation method thereof | |
| CN103601976B (en) | Fiber glass reinforced polypropylene material of a kind of ladder of swimming pool pedal and preparation method thereof | |
| CN101522402B (en) | Wood composite material and method for making same | |
| CN107722448A (en) | Utilize the automotive interior material complex composition of natural fiber | |
| CN103881258A (en) | PVC (Polyvinyl Chloride) building plastic template and manufacturing method thereof | |
| CN102504497A (en) | Modified PBT material and preparation method thereof | |
| CN110229417A (en) | A kind of plastic products and preparation method based on artificial marble waste residue filler | |
| CN104761820A (en) | Method for preparing polypropylene-based wood-plastic composite material by using rice husk powder | |
| CN105153596A (en) | PVC mouldings and preparation method thereof | |
| CN106867214A (en) | It is a kind of for the low-temperature thermoplastic 3 D-printing material of BUILDINGS MODELS product and preparation | |
| CN104774407A (en) | Method for preparing PVC (polyvinyl chloride)-based wood-plastic composite material by using peanut shell powder | |
| JP2017052919A (en) | Glass fiber reinforced polypropylene resin composition | |
| CN104629220A (en) | PVC modified material and preparation method thereof | |
| CN105153661B (en) | Anion environmental protection moulding and preparation method thereof | |
| TabkhPaz et al. | Procedure effect on the physical and mechanical properties of the extruded wood plastic composites | |
| Nadir et al. | Effect of printing layer thickness on water absorption and mechanical properties of 3D-printed wood/PLA composite materials | |
| CN103910927B (en) | A kind of plastic building template polymeric composition and preparation method thereof | |
| CN104774408A (en) | Method for preparing PVC (polyvinyl chloride)-based wood-plastic composite material by using rice hull powder | |
| CN104788855A (en) | Method for preparing PVC-based wood-plastic composite by using bagasse | |
| CN109467799A (en) | A kind of composite material prepared using solid waste as matrix and preparation method | |
| CN101722558A (en) | Process for producing regenerated plates |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170724 Address after: 510640 Guangdong City, Tianhe District Province, No. five, road, public education building, unit 371-1, unit 2401 Applicant after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Applicant before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| CB03 | Change of inventor or designer information |
Inventor after: Guo Tao Inventor before: Chen Longdi |
|
| CB03 | Change of inventor or designer information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20171020 Address after: 221400 north side of Mount Huangshan Road, Wuxi Industrial Zone, Xinyi, Xuzhou, Jiangsu, Xinyi Applicant after: Jiangsu tin Yi High-tech Zone Technology Development Co.,Ltd. Address before: 510640 Guangdong City, Tianhe District Province, No. five, road, public education building, unit 371-1, unit 2401 Applicant before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180611 Address after: 221400 8 Taishan Road, Xiyi high tech Zone, Xinyi, Xuzhou, Jiangsu Patentee after: JIANGSU KANG CHENG NEW MATERIAL TECHNOLOGY Ltd. Address before: 221400 Wuxi, Xinyi Industrial Park, Wuxi Town, Xinyi, Xuzhou, Jiangsu Patentee before: Jiangsu tin Yi High-tech Zone Technology Development Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171212 Termination date: 20211009 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |