CN105152310B - In-situ excitation method of biological aerated filter aged biological film - Google Patents

In-situ excitation method of biological aerated filter aged biological film Download PDF

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CN105152310B
CN105152310B CN201510609240.6A CN201510609240A CN105152310B CN 105152310 B CN105152310 B CN 105152310B CN 201510609240 A CN201510609240 A CN 201510609240A CN 105152310 B CN105152310 B CN 105152310B
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backwash
eluent
flushing
air
time
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CN105152310A (en
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黄辉
任洪强
俞启生
丁丽丽
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Nanjing University
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YIXING ENVIRONMENTAL PROTECTION RESEARCH INSTITUTE NANJING UNIVERSITY
Nanjing University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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Abstract

The invention discloses an in-situ excitation method of a biological aerated filter aged biological film and belongs to the technical field of biofilm process sewage treatment. The method comprises the following steps: 1, stopping running of a biological aerated filter, opening a back-flushing air-inlet valve, starting a back-flushing draught fan, and conducting air back flushing; 2, preparing eluant I, starting a back-flushing water pump, and conducting eluant-air united back flushing; 3, powering off the back-flushing draught fan, closing the back-flushing air-inlet valve, preparing eluant II, and conducting rinsing; 4, pumping in clear water, conducting water rinsing, and completing in-situ excitation. According to the in-situ excitation method of the biological aerated filter aged biological film, solubilization and dispersion of the aged biological film are achieved through surfactant which is easy to biodegrade, the back flushing efficiency is improved, the difficult problem of in-situ updating and activation of a biological aerated filter aged biological film is effectively solved, the operation is simple and convenient, and the environment-friendliness is achieved.

Description

A kind of aging biomembranous in-situ activation method of BAF
Technical field
The present invention relates to biomembrance process technical field of sewage, more particularly, it relates to a kind of BAF is old Change biomembranous in-situ activation method.
Background technology
BAF is one kind of biomembrance process, with particulate filler in filter tank (such as haydite, zeolite, quartz sand, expansion Alumino-silicate etc.) it is carrier, aeration is carried out inside filter tank, make filter material surface grow a large amount of biomembranes.When sewage is flowed through, Appended biofilm microorganisms carry out absorption degradation or metabolic conversion to pollutant on filtrate, and cooperate with the Physical entrapment of filtrate to act on And aerobic, anaerobic environment in filter tank, realize along water (flow) direction food chain classification predation and to dirty organic pollutants, nitrogen and Remove while phosphorus, obtain in fields such as advanced treatment of wastewater, slightly-polluted raw water process, organic wastewater with difficult degradation thereby process and extensively should With.
When BAF runs, As time goes on, there is aging, sewage treating efficiency in filter material surface biomembrane Reduce, also result in filtering layer blocking, threaten system operation, need to clear up in time.It is general to remove filtrate table by the way of backwash The aging biomembrane in face, but the aging biomembrane of conventional backwash removing filter material surface is applied, its frequency is higher, such as city is given birth to Sewage living, general operation 24-48 hours are backwashed once, are made troubles to operational management, and development is efficiently and easily to operate Demoulding activation method in situ, it appears very necessary.
Additionally, acid, alkali and oxidant are used as remover used in traditional handicraft, although cost is relatively low, effect is preferable, but its Contaminant degradation related microorganisms in biomembrane can be produced inactivation, or even produce dissolving to filler in filter tank and be made by non-selectivity With using less in Practical Project.Ferment treatment can optionally degradation characteristic composition (protein, polysaccharide etc.), the aging life of promotion Thing film is peeled off, but it is compared with easy in inactivation and relatively costly by water quality impact (temperature, pH, toxicant etc.).
Jing is retrieved, Chinese Patent Application No. 201310404605.2, and the applying date is September in 2013 3, invention and created name For:A kind of novel biological filter medium cleaning;This application case adopts surfactant sodium sulfate of polyethenoxy ether of fatty alcohol With reagent oxalic acid as remover filter material for biological filter cleaning program, its technical process is:By the 8- of the volume of pool inner water 12% amount adds surfactant sodium sulfate of polyethenoxy ether of fatty alcohol and reagent oxalic acid, and filtrate in biofilter is carried out clearly Wash, being passed through air carries out aeration agitation 20-40 minute, 18-30 hours are soaked after stopping the supple of gas or steam.Carry out atm number backwash aeration 1-3 little When, stop aeration static 20-40 minutes, rapid pollution discharging 3-5 minutes, carrying out combined water and air backwash 1-3 hours, stop air purge, Clear water backwash 20-40 minutes.Sewage in net pond is put, combined water and air backwash 1-3 hours, clear water backwash 20- are carried out again 40 minutes, until the content of surfactant sodium sulfate of polyethenoxy ether of fatty alcohol is less than 5mg/L in water.Above-mentioned surfactant Can effective solubilization biomembrane, promote it from the stripping on filler surface, but its biological degradability is poor, easily remains in and produce in filter tank two Secondary pollution;To avoid this situation from occurring, the program limits remaining surface by long-time combined water and air backwash and clear water backwash Active agent content is less than 5mg/L, and power consumption is larger, relatively costly, and wants AEO in dynamic detection water outlet The content of sodium sulphate, it is relatively complicated.
The content of the invention
1. the invention technical problem to be solved
It is of the invention that for BAF, routinely the aging biomembrane of backwash removing filter material surface is less efficient, run pipe The present situation of reason inconvenience, and the secondary pollution that brought using chemical surfactant and cost are the problems such as raise, there is provided it is a kind of The aging biomembranous in-situ activation method of BAF, the present invention is realized to aging life using new bio surfactant The solubilising dispersion of thing film;For filter material surface activating agent residue problem after process, using safely and effectively type of elution, remaining trace Amount surfactant can be biodegradable in filter tank, less to system disturbance.Meanwhile, the present invention can improve backwash efficiency, shorten Aging biomembrane updates the time of activation, easy to operate, environmental friendliness, with wide application prospect.
2. technical scheme
To reach above-mentioned purpose, the technical scheme that the present invention is provided is:
A kind of aging biomembranous in-situ activation method of BAF of the present invention, its step is:
Step one, BAF are out of service, open backwash air intake valve, start backwash blower fan, carry out sky Gas is backwashed;
Step 2, preparation eluent I, start backwash pump, carry out eluent-air joint backwash;
Step 3, closing backwash blower fan and backwash air intake valve, pump into eluent II, are rinsed;
Step 4, clear water is pumped into, enter water-filling rinsing, complete in-situ activation.
Further improve as the present invention, air purge intensity is 10-15L/m in step one2S, the time is 3-5min, with Filter material layer is loosened, filter material layer is expanded.
Further improve as the present invention, the eluent I in step 2 is mass percent concentration 0.1%-1.0% Rhamnolipid or APG solution in one kind, the back washing strength of eluent I be 4-6L/m2S, the time is 5-10min, with The aging biomembrane of solubilising dispersion simultaneously takes it out.
Further improve as the present invention, the eluent II in step 3 is the ethanol solution of volume fraction 30%, The back washing strength of eluent II is 3-5L/m2S, the time is 5-10min, and back washing strength is not higher than, washing time is not less than Eluent I, it is therefore an objective to elute the eluent I of filter material surface residual.Jing after this step process, filter material surface residue trace surface is lived Property agent can produce certain COD (COD), after 1.5-2.5 days can in filter tank complete biodegradable, to system disturbance It is less.
Further improve as the present invention, backwash washing intensity is 4-6L/m in step 42S, the time is 3- 5min, it is therefore an objective to clean eluent II, and further rinse the aging biomembrane of filter material surface and suspension.
3. beneficial effect
The technical scheme provided using the present invention, compared with existing known technology, with following remarkable result:
(1) a kind of aging biomembranous in-situ activation method of BAF of the invention, using biodegradable, ring Border friendly biosurfactant, biomembrane is promoted from filler table by solubilization of the reinforcing to microorganism extracellular polymeric Face is peeled off, and the loss of contaminant degradation related microorganisms in biomembrane is mitigated to greatest extent;And action time is shorter, backwash effect Rate is higher;
(2) a kind of aging biomembranous in-situ activation method of BAF of the invention, easily biological-degradable surface is lived Property agent application avoid secondary pollution, processing procedure micro- life related to contaminant degradation in biomembrane is alleviated to greatest extent The impact of thing activity, shortens the time that biomembrane updates activation;Safety is carried out to the activating agent of filter material surface residual after process Wash-out, remaining trace amount of surfactant can be biodegradable in filter tank, less to system disturbance;
(3) a kind of aging biomembranous in-situ activation method of BAF of the invention, be based on original backwash System and its method for operation, reduce the cost of technological transformation, and in situ renewal of the aging biomembrane of effectively solving BAF is lived Change a difficult problem, easy to operate, environmental friendliness extends the normal continuous operating time in filter tank, reduces operating cost.
Specific embodiment
To further appreciate that present disclosure, with reference to embodiment, the invention will be further described.
Embodiment 1
A kind of aging biomembranous in-situ activation method of BAF of the present embodiment, carries out processing urban life dirt The aging biomembranous in-situ activation of water BAF.Filler is quartz sand in filter tank.Influent quality is:COD 330- 420mg/L, BOD5130-200mg/L, SS 210-290mg/L, NH3- N 20-40mg/L, TN 55-80mg/L, TP 3.2- 4.6mg/L, volumetric loading is 3kg BOD5/(m3·d).Aging biomembranous in-situ activation is concretely comprised the following steps:
Step one, BAF are out of service, open backwash air intake valve, start backwash blower fan, carry out sky Gas is backwashed, and air purge intensity is 10L/m2S, the time is 4min, expands filter material layer.
Step 2, preparation eluent I:Use quality percent concentration is 0.1% rhamnolipid solution, starts backwash Water pump, carries out eluent-air joint backwash, and eluent back washing strength is 5L/m2S, the time is 5min, with solubilising dispersion Aging biomembrane simultaneously takes it out.
Step 3, closing backwash blower fan and backwash air intake valve, dose volume fraction is that 30% ethanol solution (is washed De- liquid II), rinsed, back washing strength is 3L/m2S, the time is 8min, fully to elute the eluent of filter material surface residual Ⅰ。
Step 4, backwashing water water pump suction pipe is switched to into clear water reserviors, enter water-filling rinsing, backwash washing intensity is 5L/ m2S, the time is 3min, it is therefore an objective to cleans eluent II, and further rinses the aging biomembrane of filter material surface and suspension, completes In-situ activation.After normal water inlet 1 day, the clearance of Wastewater Pollutant with activate before be closer to, show that biomembrane is tentatively completed Growth is updated, and after activation, the more conventional backwash of the normal continuous operating time in filter tank extends 3 times (4.5 days or so).
Inventor points out that filler surface biological film is mainly made up of microorganism and its extracellular polymeric in filter tank, with many Mutually heterogeneous the characteristics of, and typical spatial distribution characteristic is presented.For aging biomembranous activation, biomembrane should be strengthened from filling out Material surface stripping, while to greatest extent mitigate biomembrane in contaminant degradation related microorganisms loss or inactivation, with shorten The follow-up time for updating activation.Based on this, the present embodiment is taken off based on original backwashing system and its method for operation using preferred Film, realizes, to aging biomembranous solubilising dispersion, improve backwash efficiency, reduces the cost of technological transformation, defines The aging biomembrane in-situ activation scheme of economical and efficient, convenient management.
Embodiment 2
A kind of aging biomembranous in-situ activation method of BAF of the present embodiment, carries out fermentation waste water depth The aging biomembranous in-situ activation of reason BAF.Filler is haydite in filter tank.Influent quality is:COD 360-510mg/ L, BOD5120-210mg/L, SS 220-285mg/L, NH3- N 25-40mg/L, TN 60-85mg/L, TP 5.4-8.5mg/L, Volumetric loading is 6kg BOD5/(m3·d).Aging biomembranous in-situ activation is concretely comprised the following steps:
Step one, BAF are out of service, open backwash air intake valve, start backwash blower fan, carry out sky Gas is backwashed, and air purge intensity is 15L/m2S, the time is 5min, expands filter material layer.
Step 2, preparation eluent I:The APG solution of mass concentration 0.5%, starts backwash pump, is washed De- liquid-air joint backwash, eluent back washing strength is 4L/m2S, the time is 8min, with the aging biomembrane of solubilising dispersion And take it out.
Step 3, closing backwash blower fan and backwash air intake valve, the ethanol solution (wash-out of dose volume fraction 30% Liquid II), rinsed, back washing strength is 5L/m2S, the time is 10min, fully to elute the eluent of filter material surface residual Ⅰ。
Step 4, backwashing water water pump suction pipe is switched to into clear water reserviors, enter water-filling rinsing, backwash washing intensity is 4L/ m2S, the time is 4min, it is therefore an objective to cleans eluent II, and further rinses the aging biomembrane of filter material surface and suspension, completes In-situ activation.After normal water inlet 2 days, the clearance of Wastewater Pollutant with activate before be closer to, show that biomembrane is tentatively completed Growth is updated, and after activation, the more conventional backwash of the normal continuous operating time in filter tank extends 2.3 times (3.5 days or so).
Embodiment 3
A kind of aging biomembranous in-situ activation method of BAF of the present embodiment, carries out livestock breeding wastewater depth Degree processes the aging biomembranous in-situ activation of BAF.Filler is zeolite in filter tank.Influent quality is:COD 460- 620mg/L, BOD5135-186mg/L, SS 270-315mg/L, NH3- N 45-65mg/L, TN 83-116mg/L, TP 8.2- 14.3mg/L, volumetric loading is 6kg BOD5/(m3·d).Aging biomembranous in-situ activation is concretely comprised the following steps:
Step one, BAF are out of service, open backwash air intake valve, start backwash blower fan, carry out sky Gas is backwashed, and air purge intensity is 14L/m2S, the time is 3min, expands filter material layer.
Step 2, preparation eluent I:The rhamnolipid solution of mass concentration 1%, starts backwash pump, is eluted Liquid-air joint backwash, eluent back washing strength is 6L/m2S, the time is 10min, with the aging biomembrane of solubilising dispersion simultaneously Take it out.
Step 3, closing backwash blower fan and backwash air intake valve, the ethanol solution (wash-out of dose volume fraction 30% Liquid II), rinsed, back washing strength is 4L/m2S, the time is 5min, fully to elute the eluent I of filter material surface residual.
Step 4, backwashing water water pump suction pipe is switched to into clear water reserviors, enter water-filling rinsing, backwash washing intensity is 6L/ m2S, the time is 5min, it is therefore an objective to cleans eluent II, and further rinses the aging biomembrane of filter material surface and suspension, completes In-situ activation.After normal water inlet 2.5 days, the clearance of Wastewater Pollutant with activate before be closer to, show that biomembrane is tentatively complete Grow into updating, and after activation, the more conventional backwash of the normal continuous operating time in filter tank extends 4 times (5 days or so).
What deserves to be explained is, to those skilled in the art, under present inventive concept and specific embodiment enlightenment, energy Enough some deformations directly derived from the disclosure of invention and general knowledge or associate, it will be recognized by those of ordinary skill in the art that May also be employed commonly using the replacement of known technology in additive method, or prior art, and the mutually different combination between feature etc. Unsubstantiality change, equally can be employed, can realize the present invention description function and effect, no longer one by one citing launch Describe in detail, belong to the scope of the present invention.

Claims (3)

1. a kind of aging biomembranous in-situ activation method of BAF, its step is:
Step one, BAF are out of service, open backwash air intake valve, start backwash blower fan, carry out air anti- Rinse;
Step 2, preparation eluent I, eluent I is that mass percent concentration is sugared for the rhamnolipid or alkyl of 0.1%-1.0% One kind in glycosides solution, starts backwash pump, carries out eluent-air joint backwash, and the back washing strength of eluent I is 4- 6L/m2S, the time is 5-10min;
Step 3, closing backwash blower fan and backwash air intake valve, pump into eluent II, and eluent II is for volume fraction 30% ethanol solution, is rinsed, and the back washing strength of eluent II is 3-5L/m2S, the time is 5-10min, and is backwashed strong Degree is not higher than, washing time is not less than eluent I;
Step 4, clear water is pumped into, enter water-filling rinsing, complete in-situ activation.
2. the aging biomembranous in-situ activation method of a kind of BAF according to claim 1, it is characterised in that: Air purge intensity is 10-15L/m in step one2S, the time is 3-5min.
3. the aging biomembranous in-situ activation method of a kind of BAF according to claim 2, it is characterised in that: Backwash washing intensity is 4-6L/m in step 42S, the time is 3-5min.
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CN105600921B (en) * 2015-12-18 2018-10-30 南京大学 A kind of in-situ activation method of filler aging biomembrane
CN105753142B (en) * 2016-04-18 2019-03-26 南京大学 A kind of the in-situ activation agent and in-situ activation method of aerating biological filter pool filler biomembrane
CN106554077B (en) * 2016-10-12 2017-11-07 南京大学 It is a kind of to alleviate device and its operation method that denitrification deep-bed filter top layer is blocked
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CN111099742A (en) * 2018-10-26 2020-05-05 中国石油化工股份有限公司 Composition for improving resistance of denitrification system and denitrification method thereof
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