CN105152215B - Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure - Google Patents
Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure Download PDFInfo
- Publication number
- CN105152215B CN105152215B CN201510418712.XA CN201510418712A CN105152215B CN 105152215 B CN105152215 B CN 105152215B CN 201510418712 A CN201510418712 A CN 201510418712A CN 105152215 B CN105152215 B CN 105152215B
- Authority
- CN
- China
- Prior art keywords
- hierarchical structure
- molybdenum disulfide
- dimensional hierarchical
- solution
- ball
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Powder Metallurgy (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
The invention provides a preparation method for an Au-modified flower-ball-shaped molybdenum disulfide microsphere with a three-dimensional hierarchical structure, belonging to the technical field of preparation technology of inorganic advanced nanometer materials. The Au-modified flower-ball-shaped molybdenum disulfide with the three-dimensional hierarchical structure is synthesized by reaction at room temperature with chloroauric acid, sodium borohydride, L-lysine and prepared molybdenum disulfide as raw materials. A preparation method concretely comprises the following steps: dispersing the prepared molybdenum disulfide into a certain volume of deionized water, then adding the chloroauric acid and L-lysine in a certain molar ratio, carrying out full mixing, then adding a certain amount of a sodium borohydride solution, and carrying out full mixing under stirring; and after a certain time of reaction at room temperature, carrying out centrifugal separation, washing and drying, then placing an obtained dried sample in a muffle furnace, and carrying out calcining at a certain temperature for a certain time so as to obtain the Au-modified flower-ball-shaped molybdenum disulfide microsphere with the three-dimensional hierarchical structure. The method provided by the invention has the advantages of low cost, simple production process, high yield, no environmental pollution and facilitation to large-scale industrial production. The obtained Au-modified flower-ball-shaped molybdenum disulfide microsphere with the three-dimensional hierarchical structure has regular morphology and can be applied in the fields of chemical catalysis, photocatalyst gas sensors, etc.
Description
Technical field
The invention belongs to inorganic advanced technical field of nano-composite material preparation technology, more particularly, to au modification three-dimensional hierarchical structure
The preparation method of flower ball-shaped mos2 microsphere.
Background technology
Class Graphene molybdenum bisuphide (mos2) by what the single or multiple lift molybdenum bisuphide of hexagonal crystal system formed, there is " Sanming City
Control sandwich " compound of layer structure, the three layers of s-mo-s covalent bond being separated by Van der Waals space are tightly packed to be formed, its layer
Between Van der Waals space can allow that external reactant carries out insertion reaction, material of main part expands along c crystallographic direction,
Cause the change in volume of material.Class Graphene mos2Because of its unique microstructure and reason, change property, overcome zero band gap graphite
The shortcoming of alkene still has the lot of advantages of Graphene simultaneously, thus in secondary cell, field-effect transistor, sensor, electroluminescent
The various fields such as luminous, electricity storage are gathered around and are had broad application prospects.Different from the Graphene with two-dimensional layered structure, mos2?
More stable in the air atmosphere of certain temperature range, therefore, molybdenum bisuphide based composites are in photocatalysis technology, gas sensing
Technology will be more of practical significance with fields such as devices.
Jin Yixiang is acknowledged as chemically inert, and it is very weak to the chemical adsorption capacity of oxygen and other gases.From heat
From the point of view of amechanical angle, its oxide au2o3It is unstable.Secondly, the electronegativity of gold is more than every other metal, only than sulfur
With I slightly more just.And because the standard electrode EMF of au+/au0 is+1.691 v, its affinity to electronics
Actually also big than oxygen element, therefore it is to be difficult to oxidation reaction.Finally, due on periodic chart/lanthanide contraction 0
Effect, is less than the silver atoms of the second transition system, its fusing point and enthalpy of sublimation are all than silver positioned at the atomic radius of the gold of the 3rd transition system
Height, the interaction force between explanation atom itself is stronger.These characteristics above-mentioned be cause gold chemical reaction ability and
The low main cause of catalysis activity.However, reducing with metallic particle diameter, surface atom number increases, the electronics of itself
Property will change, thus leading to its chemical and physical features mutation, catalysis activity also increased.In recent years, ground
Study carefully scholars and find that golden loaded catalyst can be to photocatalysis, there is excellent performance in the field such as air-sensitive, Xu Jia waits by force (Xu Jia
By force, Han Jianjun, Xie Bing, Liu Yun. au-in2o3The performance of co gas sensor and study mechanism. sensing technology journal,
2007,20 (3)) synthesized in chemical precipitation method2o3Nano-particle, its size uniform, dispersibility are preferable, average particle size particle size
In 20 ~ 40 nm.When 300 DEG C, 2% gold medal doping has preferable sensitization to oxidation indio co sensor, and to h2Not bright
Aobvious sensitization.Catalysis detection of gold etc. has been studied in the world compelling new direction, and relevant new discovery is not
Break and emerge in large numbers, and Yang Jianjun etc. (Yang Jianjun, He Panke, Zhang Min, Wang Xiaohui, Yang Dongmei, Jin Zhensheng. Ozone Photocatalytic
Au/tio2Catalyst [p]. Chinese patent: cn200510107365.5,2005-12-30) it is prepared for au/tio2Composite wood
Material, is suitable for the elimination of ozone in indoor air-purification device.Load type gold catalyst fires to Oxidation of Carbon Monoxide, hydrocarbon catalytic
Many important reactions such as burning, epoxidation of propylene, liquid-phase selective oxidation, catalytic hydrogenation reaction all show good catalysis activity,
Imply that Au catalyst has broad application prospects.
Research with regard to class graphene-structured molybdenum bisuphide/gold nano grain composite is all at home and abroad just to have risen
Step, and Wang Xinhuan etc. (Wang Xinhuan, Han Qiusen, Yang Rong, Wang Chen. a kind of molybdenum bisuphide/gold nanorods composite, preparation side
Method and purposes [p]. Chinese patent: cn201410815045.4,2014-12-23) prepare molybdenum bisuphide/gold nanorods
Composite, gold nanorods are in 30 nm, and point out for photo-thermal therapy.However, the research report of other correlations is seldom.
Therefore, explore smaller size of gold grain load-type composite material and its application is one and is worth making great efforts the direction of research.
Content of the invention
It is an object of the invention to provide a kind of preparation method of molybdenum bisuphide/gold nano grain, this method production technology
Simply, yield is high, and non-environmental-pollution has good scientific research prospect and using value.Gained molybdenum bisuphide/gold nano grain shape
Looks are regular, can be used for the fields such as chemical industry catalysis, photocatalysis, gas sensor.
The technical scheme is that and a certain amount of molybdenum disulfide powder is distributed in the deionized water of certain volume,
The chlorauric acid solution of certain mol proportion, l- lysine solution and sodium borohydride solution is added to be sufficiently mixed, normal-temperature reaction one timing
Between, centrifugation, washing, it is dried, in the air is placed in heat treatment under uniform temperature in Muffle furnace and can get three-dimensional point of au modification
Level structure flower ball-shaped mos2 microsphere.
Concrete synthesis step is as follows:
(1) 0.01 m chlorauric acid solution, the l- lysine solution of 0.01 m and 0.1 m sodium borohydride solution are prepared；
(2) the molybdenum disulfide powder ultrasonic disperse preparing 0.01-0.1 g is in 10-50 ml deionized water；
(3) 1-5 ml chlorauric acid solution and 1-5 ml l- lysine solution are added in the solution in step (2), wherein,
Gold chloride and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 10-30 min；It is added dropwise over 0.1-1.0 ml hydroboration
Sodium solution, magnetic agitation 10-30 min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol produce to gained solid
Thing is repeatedly washed；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C are dried 5-10 hour, are subsequently placed in Muffle
In stove, heat treatment 30 min-120 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
After the present invention adopts technique scheme, mainly have the following effects:
(1) present invention each step in preparation process does not produce poisonous and harmful substance, is conducive to environmental conservation, and
The hydro-thermal reaction time is short, efficiency high；
(2) the inventive method is simple, easy to operate, the plant-scale equipment simple it is easy to industrialization large-scale production；
(3) au of present invention preparation modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere regular appearance, specific surface area
Big and gold grain particle diameter is little, it is uniformly dispersed, can be used for the fields such as chemical industry catalysis, photocatalyst gas sensor.
Brief description
Fig. 1 is the x-ray diffraction collection of illustrative plates of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere in embodiment 1
Fig. 2 is the fesem figure of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere in embodiment 1
Fig. 3 is the x-ray diffraction collection of illustrative plates that in embodiment 1, au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Fig. 4 is the fesem figure that in embodiment 1, au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Fig. 5 is the eds energy spectrum diagram that in embodiment 1, au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Fig. 6 is the fesem figure that in embodiment 2, au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
With specific embodiment, the present invention is described in further detail below in conjunction with the accompanying drawings.
Specific embodiment
Embodiment 1
(1) 0.01 m chlorauric acid solution, the l- lysine solution of 0.01 m and 0.1 m sodium borohydride solution are prepared；
(2) the molybdenum disulfide powder ultrasonic disperse preparing 0.05 g is in 15 ml deionized waters；
(3) 1.5 ml chlorauric acid solutions and 1.5 ml l- lysine solutions are added in the solution in step (2), wherein,
Gold chloride and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 20 min；It is added dropwise over 0.2 ml sodium borohydride solution,
Magnetic agitation 20 min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol produce to gained solid
Thing is repeatedly washed；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C of dryings 8 hours, is subsequently placed in Muffle furnace
In, heat treatment 30 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
X-ray diffraction pattern collection of illustrative plates such as Fig. 1 institute of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere used in embodiment 1
Show, the position of all diffraction maximums of the xrd collection of illustrative plates of sample is consistent with international standard card pdf#65-0160, show used
Sample is exactly molybdenum bisuphide.Shoot the fesem picture of gained through field emission scanning electron microscope, as shown in Figure 2 it can be seen that
The pattern of molybdenum bisuphide is the flower ball-shaped of three-dimensional hierarchical structure, regular appearance.
The X-ray diffraction pattern collection of illustrative plates of the molybdenum bisuphide that embodiment 1 is prepared/gold nano grain three-dimensional hierarchical structure microsphere is such as
Shown in Fig. 3, using the position of all diffraction maximums of the xrd collection of illustrative plates of the sample prepared by the present invention and the diffraction of molybdenum bisuphide and gold
Peak is consistent, no other miscellaneous peaks, shows that prepared sample is composite molybdenum disulfide/gold nano grain.Scan electricity through Flied emission
The fesem picture of sub- microscope photographing gained, as shown in Figure 4 it can be seen that molybdenum bisuphide/gold nano grain three-dimensional hierarchical structure
Regular appearance, gold grain a size of 10 below nm and being uniformly dispersed.Result through eds energy-spectrum scanning gained is as shown in figure 5, can
To find out the presence of golden (au), molybdenum (mo), three kinds of elements of sulfur (s), and the signal intensity of gold is very high, comprehensive xrd, sem, eds knot
Fruit explanation gold grain successfully loads on molybdenum disulfide nano sheet.
Embodiment 2
(1) 0.01 m chlorauric acid solution, the l- lysine solution of 0.01 m and 0.1 m sodium borohydride solution are prepared；
(2) the molybdenum disulfide powder ultrasonic disperse preparing 0.01 g is in 10 ml deionized waters；
(3) 1 ml chlorauric acid solution and 1 ml l- lysine solution are added in the solution in step (2), wherein, chlorine gold
Acid and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 10 min；It is added dropwise over 0.1 ml sodium borohydride solution, magnetic force
Stir 10 min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol produce to gained solid
Thing is repeatedly washed；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C of dryings 5 hours, is subsequently placed in Muffle furnace
In, heat treatment 30 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Molybdenum bisuphide/the gold nano grain of embodiment 2 preparation is as shown in Figure 6 it can be seen that obtained molybdenum bisuphide/gold
Nanoparticle three-dimensional hierarchy is combined good.
Embodiment 3
(1) 0.01 m chlorauric acid solution, the l- lysine solution of 0.01 m and 0.1 m sodium borohydride solution are prepared；
(2) the molybdenum disulfide powder ultrasonic disperse preparing 0.03 g is in 20 ml deionized waters；
(3) 2 ml chlorauric acid solutions and 2 ml l- lysine solutions are added in the solution in step (2), wherein, chlorine gold
Acid and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 20 min；It is added dropwise over 0.2 ml sodium borohydride solution, magnetic force
Stir 20 min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol produce to gained solid
Thing is repeatedly washed；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C of dryings 6 hours, is subsequently placed in Muffle furnace
In, heat treatment 60 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Embodiment 4
(1) 0.01 m chlorauric acid solution, the l- lysine solution of 0.01 m and 0.1 m sodium borohydride solution are prepared；
(2) the molybdenum disulfide powder ultrasonic disperse preparing 0.08 g is in 30 ml deionized waters；
(3) 3 ml chlorauric acid solutions and 3 ml l- lysine solutions are added in the solution in step (2), wherein, chlorine gold
Acid and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 30 min；It is added dropwise over 5.0 ml sodium borohydride solutions, magnetic force
Stirring 30min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol produce to gained solid
Thing is repeatedly washed；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C of dryings 8 hours, is subsequently placed in Muffle furnace
In, heat treatment 30 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Embodiment 5
(1) 0.01 m chlorauric acid solution, the l- lysine solution of 0.01 m and 0.1 m sodium borohydride solution are prepared；
(2) the molybdenum disulfide powder ultrasonic disperse preparing 0.1 g is in 50 ml deionized waters；
(3) 5 ml chlorauric acid solutions and 5 ml l- lysine solutions are added in the solution in step (2), wherein, chlorine gold
Acid and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 30 min；It is added dropwise over 1.0 ml sodium borohydride solutions, magnetic force
Stir 30 min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol produce to gained solid
Thing is repeatedly washed；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C of dryings 10 hours, is subsequently placed in Muffle furnace
In, heat treatment 120 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Claims (1)
1. a kind of au modifies the preparation method of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere, and concrete synthesis step is as follows:
(1) 0.01m chlorauric acid solution, the l- lysine solution of 0.01m and 0.1m sodium borohydride solution are prepared；
(2) the three-dimensional hierarchical structure flower ball-shaped molybdenum disulfide powder ultrasonic disperse that 0.01-0.1g prepares is gone to 10-50 ml
In ionized water；
(3) 1-5ml chlorauric acid solution and 1-5 ml l- lysine solution, wherein, chlorine gold are added in the solution in step (2)
Acid and sodium borohydride solution obtain mol ratio for 1:1, magnetic agitation 10-30 min；It is added dropwise over 0.1-1.0 ml sodium borohydride molten
Liquid, magnetic agitation 10-30 min；
(4) reacted product is carried out solid-liquid separation with centrifuge, and deionized water and ethanol enter to gained solid product
Row repeatedly washs；
(5) step (4) gained solid product is positioned in drying baker, 60 DEG C are dried 5-10 hour, are subsequently placed in Muffle furnace
In, heat treatment 30 min-120 min at 300 DEG C, obtain au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510418712.XA CN105152215B (en) | 2015-07-17 | 2015-07-17 | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510418712.XA CN105152215B (en) | 2015-07-17 | 2015-07-17 | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105152215A CN105152215A (en) | 2015-12-16 |
| CN105152215B true CN105152215B (en) | 2017-01-18 |
Family
ID=54793343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510418712.XA Expired - Fee Related CN105152215B (en) | 2015-07-17 | 2015-07-17 | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105152215B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106442672B (en) * | 2016-09-19 | 2018-10-26 | 盐城工学院 | A kind of sulfate ion suppressive electrochemica biological sensor and preparation method thereof |
| CN107008458A (en) * | 2017-05-10 | 2017-08-04 | 南昌航空大学 | A kind of petal-shaped MoS2Load the preparation method of Au photochemical catalysts |
| CN107102036B (en) * | 2017-06-02 | 2019-10-01 | 东北大学 | The preparation method of the vanadium oxide particles of gold load |
| CN107598182B (en) * | 2017-07-24 | 2019-05-10 | 西北工业大学 | Gold nano grain-molybdenum disulfide-gold hypersensitive SERS base material and preparation method |
| CN108654648B (en) * | 2018-05-03 | 2020-04-24 | 东北林业大学 | Preparation method and application of photocatalyst for efficiently preparing hydrogen peroxide by photolyzing water |
| CN110394174A (en) * | 2019-08-07 | 2019-11-01 | 山东师范大学 | The catalyst and preparation method of a kind of rodlike CeO 2 supporting gold and application |
| CN111979518B (en) * | 2020-08-20 | 2021-12-31 | 中国科学院兰州化学物理研究所 | Composite lubricating film loaded with metal-based nanoparticles and preparation method thereof |
| CN113125385B (en) * | 2021-04-13 | 2022-12-02 | 湘潭大学 | Based on Au @ MoS 2 Localized surface plasmon enhanced NO 2 Gas sensor and preparation method |
| CN114772643B (en) * | 2022-04-27 | 2024-03-29 | 广东省科学院生物与医学工程研究所 | Composite nano material and preparation method and application thereof |
| CN115121260A (en) * | 2022-06-17 | 2022-09-30 | 武汉理工大学 | Nano gold-cuprous oxide heterojunction and preparation method and application thereof |
| CN116328763A (en) * | 2023-02-28 | 2023-06-27 | 西南交通大学 | Gold-loaded silicon microsphere composite material with three-layer hierarchical structure and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1402163B1 (en) * | 2010-10-01 | 2013-08-28 | Univ Degli Studi Salerno | "ONE-POT" SYNTHESIS OF NANO CRISTALLI 1D, 2D, AND 0D OF TUNGSTEN AND MOLYBDENUM CALCOGENURES (WS2, MOS2) FUNCTIONALIZED WITH LONG-CHAIN AND / OR TIOL-AMMINE ACIDS AND / OR TIOLS |
| CN104525938B (en) * | 2014-12-23 | 2017-02-22 | 国家纳米科学中心 | Molybdenum disulfide/gold nanorod composite, preparation method and application |
-
2015
- 2015-07-17 CN CN201510418712.XA patent/CN105152215B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105152215A (en) | 2015-12-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105152215B (en) | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure | |
| Tahir et al. | Enhanced photocatalytic performance of visible-light active graphene-WO3 nanostructures for hydrogen production | |
| Zhou et al. | Semiconductor/boron nitride composites: synthesis, properties, and photocatalysis applications | |
| Cui et al. | Fabrication of dual Z-scheme MIL-53 (Fe)/α-Bi2O3/g-C3N4 ternary composite with enhanced visible light photocatalytic performance | |
| Yang et al. | Highly efficient photocatalytic hydrogen evolution and simultaneous formaldehyde degradation over Z-scheme ZnIn2S4-NiO/BiVO4 hierarchical heterojunction under visible light irradiation | |
| Wu et al. | Sequential two-step hydrothermal growth of MoS2/CdS core-shell heterojunctions for efficient visible light-driven photocatalytic H2 evolution | |
| Wang et al. | Function of NiSe2 over CdS nanorods for enhancement of photocatalytic hydrogen production—from preparation to mechanism | |
| Fu et al. | Oxygen-vacancy generation in MgFe2O4 by high temperature calcination and its improved photocatalytic activity for CO2 reduction | |
| Zhou et al. | Hydrothermal synthesis of novel ternary hierarchical MoS2/TiO2/clinoptilolite nanocomposites with remarkably enhanced visible light response towards xanthates | |
| Wang et al. | Controlled synthesis of α-Fe2O3 nanostructures for efficient photocatalysis | |
| CN105148910B (en) | A kind of preparation method of hexagonal flake molybdenum oxide load gold nano grain | |
| Hassanzadeh-Tabrizi et al. | Synthesis of Fe2O3/Pt/Au nanocomposite immobilized on g-C3N4 for localized plasmon photocatalytic hydrogen evolution | |
| Wang et al. | Construction of NiO/g-C3N4 pn heterojunctions for enhanced photocatalytic CO2 reduction | |
| Xiong et al. | Thermally stable hematite hollow nanowires | |
| Yang et al. | Petal-biotemplated synthesis of two-dimensional Co3O4 nanosheets as photocatalyst with enhanced photocatalytic activity | |
| Yang et al. | Synthesis of ZnO–SnO2 composite oxides by CTAB-assisted co-precipitation and photocatalytic properties | |
| Li et al. | Integrating CoOx cocatalyst on hexagonal α-Fe2O3 for effective photocatalytic oxygen evolution | |
| Li et al. | Mesoporous yolk-shell structure Bi2MoO6 microspheres with enhanced visible light photocatalytic activity | |
| Ren et al. | 3D hollow MXene@ ZnIn2S4 heterojunction with rich zinc vacancies for highly efficient visible-light photocatalytic reduction | |
| Chen et al. | Noble metal-free NiSe2 nanosheets decorated MIL-53 (Fe) microrods with highly efficient visible-light driven photocatalytic H2 generation | |
| Su et al. | Metal organic framework-derived Co3O4/NiCo2O4 hollow double-shell polyhedrons for effective photocatalytic hydrogen generation | |
| Dang et al. | Hydrothermal preparation and characterization of nanostructured CNTs/ZnFe2O4 composites for solar water splitting application | |
| Mahzoon et al. | Sonoprecipitation fabrication of enhanced electron transfer Cu (OH) 2/g-C3N4 nanophotocatalyst with promoted H2-Production activity under visible light irradiation | |
| CN107601557A (en) | One kind prepares 1T@2H MoS2/ black TiO2Method | |
| Chen et al. | Fabrication of a novel carbon quantum Dots-Modified 2D heterojunction for highly efficient sunlight photocatalysis |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170118 Termination date: 20190717 |