CN105152215A - Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure - Google Patents
Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure Download PDFInfo
- Publication number
- CN105152215A CN105152215A CN201510418712.XA CN201510418712A CN105152215A CN 105152215 A CN105152215 A CN 105152215A CN 201510418712 A CN201510418712 A CN 201510418712A CN 105152215 A CN105152215 A CN 105152215A
- Authority
- CN
- China
- Prior art keywords
- hierarchical structure
- molybdenum disulfide
- solution
- dimensional hierarchical
- ball
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention provides a preparation method for an Au-modified flower-ball-shaped molybdenum disulfide microsphere with a three-dimensional hierarchical structure, belonging to the technical field of preparation technology of inorganic advanced nanometer materials. The Au-modified flower-ball-shaped molybdenum disulfide with the three-dimensional hierarchical structure is synthesized by reaction at room temperature with chloroauric acid, sodium borohydride, L-lysine and prepared molybdenum disulfide as raw materials. A preparation method concretely comprises the following steps: dispersing the prepared molybdenum disulfide into a certain volume of deionized water, then adding the chloroauric acid and L-lysine in a certain molar ratio, carrying out full mixing, then adding a certain amount of a sodium borohydride solution, and carrying out full mixing under stirring; and after a certain time of reaction at room temperature, carrying out centrifugal separation, washing and drying, then placing an obtained dried sample in a muffle furnace, and carrying out calcining at a certain temperature for a certain time so as to obtain the Au-modified flower-ball-shaped molybdenum disulfide microsphere with the three-dimensional hierarchical structure. The method provided by the invention has the advantages of low cost, simple production process, high yield, no environmental pollution and facilitation to large-scale industrial production. The obtained Au-modified flower-ball-shaped molybdenum disulfide microsphere with the three-dimensional hierarchical structure has regular morphology and can be applied in the fields of chemical catalysis, photocatalyst gas sensors, etc.
Description
Technical field
The invention belongs to inorganic advanced technical field of nano-composite material preparation technology, particularly relate to the preparation method that Au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Background technology
Class Graphene molybdenumdisulphide (MoS
2) compound with " sandwich " laminate structure that is made up of the single or multiple lift molybdenumdisulphide of hexagonal system, the three layers of S-Mo-S covalent linkage separated by Van der Waals space are tightly packed to be formed, the Van der Waals space of its interlayer can allow that external reactant carries out insertion reaction, material of main part expands along C crystallographic direction, causes the volume change of material.Class Graphene MoS
2because of microtexture and reason, the voltinism matter of its uniqueness, still there is in the shortcoming overcoming zero band gap Graphene the lot of advantages of Graphene simultaneously, thus gather around in various fields such as secondary cell, field-effect transistor, sensor, electroluminescent, electricity storages and have broad application prospects.Different from the Graphene with two-dimensional layered structure, MoS
2more stable in the air atmosphere of certain temperature range, therefore, molybdenumdisulphide based composites will have more practical significance in fields such as photocatalysis technology, gas sensing techniques and devices.
Jin Yixiang is acknowledged as chemically inert, and it is very weak to the chemical adsorption capacity of oxygen and other gases.From thermodynamics, its oxide compound Au
2o
3unstable.Secondly, the electronegativity of gold is greater than every other metal, only than sulphur and iodine element slightly more just.And due to the Standard Electrode Potentials of Au+/Au0 be+1.691V, it is in fact also large than oxygen element to the affinity of electronics, and therefore it is difficult to oxidizing reaction occurs.Finally, due on periodictable/lanthanide contraction 0 effect, the atomic radius being positioned at the gold of the 3rd transition system is less than the silver atoms of the second transition system, and its fusing point and enthalpy of sublimation are all than the height of silver, and the interaction force between the atom of explanation own is stronger.These characteristics above-mentioned cause chemical reaction ability and the low major cause of catalytic activity of gold.But along with metallics particle diameter reduces, surface atom number increases, and the electronic property of itself will change, thus cause its chemistry and physical properties to occur sudden change, catalytic activity also increases to some extent.In recent years, researchers found that golden loaded catalyst can to photochemical catalysis, and there is excellent performance in the fields such as air-sensitive, (Xu Jiaqiang, Han Jianjun, Xie Bing, the Liu Yun .Au-In such as Xu Jiaqiang
2o
3the performance of CO gas sensor and study mechanism. sensing technology journal, 2007,20 (3)) synthesize In by chemical precipitation method
2o
3nano particle, better, average particle size particle size is at 20 ~ 40nm for its size uniform, dispersiveness.300 DEG C time, 2% gold medal doping has good sensitization to Indium sesquioxide base CO sensor, and to H
2there is no obvious sensitization.The catalysis detection etc. of gold has been studied into a compelling new direction in the world, and relevant new discovery continues to bring out, and Yang Jianjun etc. (Yang Jianjun, He Panke, Zhang Min, Wang Xiaohui, Yang Dongmei, Jin Zhensheng. the Au/TiO of Ozone Photocatalytic
2catalyzer [P]. Chinese patent: CN200510107365.5,2005-12-30) prepare Au/TiO
2matrix material, is suitable for the elimination of ozone in indoor air-purification device.Load type gold catalyst all demonstrates good catalytic activity to many important reactions such as Oxidation of Carbon Monoxide, hydrocarbon catalytic burning, epoxidation of propylene, liquid-phase selective oxidation, catalytic hydrogenation reactions, imply that Au catalyst has broad application prospects.
Research about class graphene-structured molybdenumdisulphide/gold nano grain matrix material is all at home and abroad ground zero, (the Wang Xinhuan such as Wang Xinhuan, Han Qiusen, Yang Rong, Wang Chen. a kind of molybdenumdisulphide/gold nanorods matrix material, Preparation method and use [P]. Chinese patent: CN201410815045.4,2014-12-23) prepared molybdenumdisulphide/gold nanorods matrix material, gold nanorods at about 30nm, and is pointed out for photo-thermal therapy.But other relevant research reports seldom.Therefore, gold grain load-type composite material and the application thereof of exploring smaller szie are directions being worth making great efforts research.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of molybdenumdisulphide/gold nano grain, present method production technique is simple, and productive rate is high, non-environmental-pollution, has good scientific research prospect and using value.Gained molybdenumdisulphide/gold nano grain regular appearance, can be used for the fields such as chemical industry catalysis, photochemical catalysis, gas sensor.
Technical scheme of the present invention is: be distributed in the deionized water of certain volume by a certain amount of molybdenum disulfide powder, add the chlorauric acid solution of certain mol proportion, 1B solution and sodium borohydride solution fully mix, normal-temperature reaction certain hour, centrifugation, washing, dry, under being placed in retort furnace certain temperature in air, thermal treatment can obtain Au modification three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Concrete synthesis step is as follows:
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.01-0.1g is in 10-50ml deionized water;
(3) in the solution in step (2), add 1-5ml chlorauric acid solution and 1-5mlL-lysine solution, wherein, it is 1:1, magnetic agitation 10-30min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 0.1-1.0ml sodium borohydride solution, magnetic agitation 10-30min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dry 5-10 hour, are then placed in retort furnace, thermal treatment 30min-120min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
After the present invention adopts technique scheme, mainly contain following effect:
(1) the present invention's each step in preparation process does not produce hazardous and noxious substances, and be conducive to environment protection, and the hydro-thermal reaction time is short, efficiency is high;
(2) the inventive method is simple, and easy to operate, the plant-scale equipment is simple and easy, is easy to industrialization scale operation;
(3) Au that prepared by the present invention modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere regular appearance, and specific surface area is large and gold grain particle diameter is little, is uniformly dispersed, can be used for the field such as chemical industry catalysis, photocatalyst gas sensor.
Accompanying drawing explanation
Fig. 1 is the X ray diffracting spectrum of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere in embodiment 1
Fig. 2 is the FESEM figure of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere in embodiment 1
Fig. 3 is the X ray diffracting spectrum that in embodiment 1, Au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Fig. 4 is the FESEM figure that in embodiment 1, Au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Fig. 5 is the EDS energy spectrogram that in embodiment 1, Au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Fig. 6 is the FESEM figure that in embodiment 2, Au modifies three-dimensional hierarchical structure flower ball-shaped mos2 microsphere
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
Embodiment
Embodiment 1
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.05g is in 15ml deionized water;
(3) in the solution in step (2), add 1.5ml chlorauric acid solution and 1.5mlL-lysine solution, wherein, it is 1:1, magnetic agitation 20min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 0.2ml sodium borohydride solution, magnetic agitation 20min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dryings 8 hours, are then placed in retort furnace, thermal treatment 30min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
The X-ray diffractogram collection of illustrative plates of three-dimensional hierarchical structure flower ball-shaped mos2 microsphere used in embodiment 1 as shown in Figure 1, the position of all diffraction peaks of the XRD figure spectrum of sample is consistent with international standard card PDF#65-0160, shows that sample used is exactly molybdenumdisulphide.Through the FESEM picture of field emission scanning electron microscope shooting gained, as shown in Figure 2, can find out that the pattern of molybdenumdisulphide is the flower ball-shaped of three-dimensional hierarchical structure, regular appearance.
The X-ray diffractogram collection of illustrative plates of molybdenumdisulphide/gold nano grain three-dimensional hierarchical structure microballoon that embodiment 1 is prepared as shown in Figure 3, the position of all diffraction peaks of the XRD figure of the sample prepared by the present invention spectrum is adopted to be consistent with the diffraction peak of molybdenumdisulphide and gold, without other assorted peaks, show that prepared sample is composite molybdenum disulfide/gold nano grain.Through the FESEM picture of field emission scanning electron microscope shooting gained, as shown in Figure 4, can find out molybdenumdisulphide/gold nano grain three-dimensional hierarchical structure regular appearance, gold grain is of a size of below 10nm and is uniformly dispersed.Through EDS energy-spectrum scanning gained result as shown in Figure 5, the existence of gold (Au), molybdenum (Mo), sulphur (S) three kinds of elements can be found out, and the strength of signal of gold is very high, comprehensive XRD, SEM, EDS result illustrates that gold grain successfully loads on molybdenum disulfide nano sheet.
Embodiment 2
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.01g is in 10ml deionized water;
(3) in the solution in step (2), add 1ml chlorauric acid solution and 1mlL-lysine solution, wherein, it is 1:1, magnetic agitation 10min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 0.1ml sodium borohydride solution, magnetic agitation 10min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dryings 5 hours, are then placed in retort furnace, thermal treatment 30min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Molybdenumdisulphide/gold nano grain prepared by embodiment 2 as shown in Figure 6, can find out that obtained molybdenumdisulphide/gold nano grain three-dimensional hierarchical structure compound is good.
Embodiment 3
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.03g is in 20ml deionized water;
(3) in the solution in step (2), add 2ml chlorauric acid solution and 2mlL-lysine solution, wherein, it is 1:1, magnetic agitation 20min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 0.2ml sodium borohydride solution, magnetic agitation 20min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dryings 6 hours, are then placed in retort furnace, thermal treatment 60min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Embodiment 4
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.08g is in 30ml deionized water;
(3) in the solution in step (2), add 3ml chlorauric acid solution and 3mlL-lysine solution, wherein, it is 1:1, magnetic agitation 30min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 5.0ml sodium borohydride solution, magnetic agitation 30min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dryings 8 hours, are then placed in retort furnace, thermal treatment 30min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Embodiment 5
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.1g is in 50ml deionized water;
(3) in the solution in step (2), add 5ml chlorauric acid solution and 5mlL-lysine solution, wherein, it is 1:1, magnetic agitation 30min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 1.0ml sodium borohydride solution, magnetic agitation 30min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dryings 10 hours, are then placed in retort furnace, thermal treatment 120min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Claims (1)
1. Au modifies a preparation method for three-dimensional hierarchical structure flower ball-shaped mos2 microsphere, and concrete synthesis step is as follows:
(1) 0.01M chlorauric acid solution is prepared, the 1B solution of 0.01M and 0.1M sodium borohydride solution;
(2) the molybdenum disulfide powder ultrasonic disperse prepared by 0.01-0.1g is in 10-50ml deionized water;
(3) in the solution in step (2), add 1-5ml chlorauric acid solution and 1-5mlL-lysine solution, wherein, it is 1:1, magnetic agitation 10-30min that hydrochloro-auric acid and sodium borohydride solution obtain mol ratio; Dropwise add 0.1-1.0ml sodium borohydride solution, magnetic agitation 10-30min;
(4) reacted product whizzer is carried out solid-liquid separation, and with deionized water and ethanol, gained solid product is repeatedly washed;
(5) be positioned in loft drier by step (4) gained solid product, 60 DEG C of dry 5-10 hour, are then placed in retort furnace, thermal treatment 30min-120min at 300 DEG C, obtain Au and modify three-dimensional hierarchical structure flower ball-shaped mos2 microsphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510418712.XA CN105152215B (en) | 2015-07-17 | 2015-07-17 | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510418712.XA CN105152215B (en) | 2015-07-17 | 2015-07-17 | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105152215A true CN105152215A (en) | 2015-12-16 |
| CN105152215B CN105152215B (en) | 2017-01-18 |
Family
ID=54793343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510418712.XA Expired - Fee Related CN105152215B (en) | 2015-07-17 | 2015-07-17 | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105152215B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106442672A (en) * | 2016-09-19 | 2017-02-22 | 盐城工学院 | Sulfate ion inhibition type electrochemical biosensor and preparation method thereof |
| CN107008458A (en) * | 2017-05-10 | 2017-08-04 | 南昌航空大学 | A kind of petal-shaped MoS2Load the preparation method of Au photochemical catalysts |
| CN107102036A (en) * | 2017-06-02 | 2017-08-29 | 东北大学 | Vanadium oxide particles of gold load and preparation method thereof |
| CN107598182A (en) * | 2017-07-24 | 2018-01-19 | 西北工业大学 | Gold nano grain molybdenum disulfide gold hypersensitive SERS base materials and preparation method |
| CN108654648A (en) * | 2018-05-03 | 2018-10-16 | 东北林业大学 | A kind of photocatalytic water efficiently produces the preparation method and applications of the photochemical catalyst of hydrogen peroxide |
| CN110394174A (en) * | 2019-08-07 | 2019-11-01 | 山东师范大学 | The catalyst and preparation method of a kind of rodlike CeO 2 supporting gold and application |
| CN111979518A (en) * | 2020-08-20 | 2020-11-24 | 中国科学院兰州化学物理研究所 | Composite lubricating film loaded with metal-based nanoparticles and preparation method thereof |
| CN113125385A (en) * | 2021-04-13 | 2021-07-16 | 湘潭大学 | Based on Au @ MoS2Localized surface plasmon enhanced NO2Gas sensor and preparation method thereof |
| CN114772643A (en) * | 2022-04-27 | 2022-07-22 | 广东省科学院生物与医学工程研究所 | Composite nano material and preparation method and application thereof |
| CN115121260A (en) * | 2022-06-17 | 2022-09-30 | 武汉理工大学 | Nano gold-cuprous oxide heterojunction and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2621859B1 (en) * | 2010-10-01 | 2015-02-25 | Universita' Degli Studi di Salerno | "one-pot" synthesis of 2d, 1d, e 0d nano crystals of tungsten and molybdenum chalcogenides (ws2,mos2) functionalized with long chain amine and/or carboxylic acid and/or thiol |
| CN104525938A (en) * | 2014-12-23 | 2015-04-22 | 国家纳米科学中心 | Molybdenum disulfide/gold nanorod composite, preparation method and application |
-
2015
- 2015-07-17 CN CN201510418712.XA patent/CN105152215B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2621859B1 (en) * | 2010-10-01 | 2015-02-25 | Universita' Degli Studi di Salerno | "one-pot" synthesis of 2d, 1d, e 0d nano crystals of tungsten and molybdenum chalcogenides (ws2,mos2) functionalized with long chain amine and/or carboxylic acid and/or thiol |
| CN104525938A (en) * | 2014-12-23 | 2015-04-22 | 国家纳米科学中心 | Molybdenum disulfide/gold nanorod composite, preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| ZONGYOU YIN ET AL.: ""Au Nanoparticle-Modifi ed MoS2 Nanosheet-Based Photoelectrochemical Cells for Water Splitting"", 《SMALL》 * |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106442672B (en) * | 2016-09-19 | 2018-10-26 | 盐城工学院 | A kind of sulfate ion suppressive electrochemica biological sensor and preparation method thereof |
| CN106442672A (en) * | 2016-09-19 | 2017-02-22 | 盐城工学院 | Sulfate ion inhibition type electrochemical biosensor and preparation method thereof |
| CN107008458A (en) * | 2017-05-10 | 2017-08-04 | 南昌航空大学 | A kind of petal-shaped MoS2Load the preparation method of Au photochemical catalysts |
| CN107102036A (en) * | 2017-06-02 | 2017-08-29 | 东北大学 | Vanadium oxide particles of gold load and preparation method thereof |
| CN107102036B (en) * | 2017-06-02 | 2019-10-01 | 东北大学 | The preparation method of the vanadium oxide particles of gold load |
| CN107598182A (en) * | 2017-07-24 | 2018-01-19 | 西北工业大学 | Gold nano grain molybdenum disulfide gold hypersensitive SERS base materials and preparation method |
| CN108654648A (en) * | 2018-05-03 | 2018-10-16 | 东北林业大学 | A kind of photocatalytic water efficiently produces the preparation method and applications of the photochemical catalyst of hydrogen peroxide |
| CN108654648B (en) * | 2018-05-03 | 2020-04-24 | 东北林业大学 | Preparation method and application of photocatalyst for efficiently preparing hydrogen peroxide by photolyzing water |
| CN110394174A (en) * | 2019-08-07 | 2019-11-01 | 山东师范大学 | The catalyst and preparation method of a kind of rodlike CeO 2 supporting gold and application |
| CN111979518A (en) * | 2020-08-20 | 2020-11-24 | 中国科学院兰州化学物理研究所 | Composite lubricating film loaded with metal-based nanoparticles and preparation method thereof |
| CN113125385A (en) * | 2021-04-13 | 2021-07-16 | 湘潭大学 | Based on Au @ MoS2Localized surface plasmon enhanced NO2Gas sensor and preparation method thereof |
| CN113125385B (en) * | 2021-04-13 | 2022-12-02 | 湘潭大学 | Based on Au @ MoS 2 Localized surface plasmon enhanced NO 2 Gas sensor and preparation method |
| CN114772643A (en) * | 2022-04-27 | 2022-07-22 | 广东省科学院生物与医学工程研究所 | Composite nano material and preparation method and application thereof |
| CN114772643B (en) * | 2022-04-27 | 2024-03-29 | 广东省科学院生物与医学工程研究所 | Composite nano material and preparation method and application thereof |
| CN115121260A (en) * | 2022-06-17 | 2022-09-30 | 武汉理工大学 | Nano gold-cuprous oxide heterojunction and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105152215B (en) | 2017-01-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105152215A (en) | Preparation method for Au nanometer particle modified flower-ball-shaped molybdenum disulfide with three-dimensional hierarchical structure | |
| Tahir et al. | Enhanced photocatalytic performance of visible-light active graphene-WO3 nanostructures for hydrogen production | |
| Cui et al. | Fabrication of dual Z-scheme MIL-53 (Fe)/α-Bi2O3/g-C3N4 ternary composite with enhanced visible light photocatalytic performance | |
| CN105148910B (en) | A kind of preparation method of hexagonal flake molybdenum oxide load gold nano grain | |
| Wang et al. | Facile synthesis of porous α-Fe2O3 nanorods and their application in ethanol sensors | |
| Duan et al. | Effects of hierarchical structure on the performance of tin oxide-supported platinum catalyst for room-temperature formaldehyde oxidation | |
| CN104649324B (en) | A kind of preparation method of molybdenumdisulphide/zinc oxide nanometer composite material | |
| CN102489284B (en) | Graphene composite titanium dioxide photocatalyst capable of magnetic separation and recovery, and preparation method thereof | |
| Wang et al. | Construction of NiO/g-C3N4 pn heterojunctions for enhanced photocatalytic CO2 reduction | |
| George et al. | CO Oxidation on Colloidal Au0. 80Pd0. 20–Fe x O y Dumbbell Nanocrystals | |
| Liu et al. | Versatile bifunctional nitrogen-doped porous carbon derived from biomass in catalytic reduction of 4-nitrophenol and oxidation of styrene | |
| Fu et al. | Oxygen-vacancy generation in MgFe2O4 by high temperature calcination and its improved photocatalytic activity for CO2 reduction | |
| Peng et al. | MoS2 nanosheets supported on carbon hybridized montmorillonite as an efficient heterogeneous catalyst in aqueous phase | |
| CN103011129A (en) | Method for preparing high-specific-surface-area porous graphitic nanocarbon plate with coconut shells serving as raw materials | |
| Zhuang et al. | Branched In2O3 mesocrystal of ordered architecture derived from the oriented alignment of a metal–organic framework for accelerated hydrogen evolution over In2O3–ZnIn2S4 | |
| Hou et al. | Atomic-level insights in tuning defective structures for nitrogen photofixation over amorphous SmOCl nanosheets | |
| Zhang et al. | Co-Ag alloy protected by nitrogen doped carbon as highly efficient and chemoselective catalysts for the hydrogenation of halogenated nitrobenzenes | |
| Valian et al. | Sol-gel synthesis of DyFeO3/CuO nanocomposite using Capsicum Annuum extract: Fabrication, structural analysis, and assessing the impacts of g-C3N4 on electrochemical hydrogen storage behavior | |
| Chen et al. | Solvent-free synthesis of N-doped carbon-based catalyst for high-efficient reduction of 4-nitrophenol | |
| CN107601557A (en) | One kind prepares 1T@2H MoS2/ black TiO2Method | |
| Mahzoon et al. | Sonoprecipitation fabrication of enhanced electron transfer Cu (OH) 2/g-C3N4 nanophotocatalyst with promoted H2-Production activity under visible light irradiation | |
| Li et al. | Effect of hydrogen spillover on the surface of tungsten oxide on hydrogenation of cyclohexene and N-propylcarbazole | |
| Zhang et al. | Synergistic enhancement of hydrogen production by ZIF-67 (Co) derived Mo–Co–S modified gC 3 N 4/rGO photocatalyst | |
| CN104941636A (en) | Method for preparing silver-modified cerium dioxide/graphene photocatalyst by electron beam irradiation | |
| CN102274737A (en) | Method for preparing macroporous material loaded with silver nanometer particles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170118 Termination date: 20190717 |