CN105133299A - Method for preparing nanosilver from honey and finishing cotton linen bamboo fiber fabric - Google Patents
Method for preparing nanosilver from honey and finishing cotton linen bamboo fiber fabric Download PDFInfo
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- CN105133299A CN105133299A CN201510517519.1A CN201510517519A CN105133299A CN 105133299 A CN105133299 A CN 105133299A CN 201510517519 A CN201510517519 A CN 201510517519A CN 105133299 A CN105133299 A CN 105133299A
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Abstract
The invention relates to a method for preparing nanosilver from honey and finishing a cotton linen bamboo fiber fabric. The method comprises the steps: preparing a 0.01-100 g/L aqueous solutions with silver nitrate, then adding a certain amount of honey, under the condition of the temperature of 50 DEG C-90 DEG C, uniformly stirring for 30-600 min, to obtain a nanosilver colloidal solution, repeatedly washing with ethanol and deionized water respectively, centrifuging, carrying out drying treatment to obtain nanosilver particles, then dipping a cotton/linen/bamboo fiber blended fabric to the nanosilver solution with the concentration of 0.01-10 g/L, and dipping for two times and rolling for two times. The honey is used as a reducing agent and a stabilizer for nanosilver, and the method has the advantages of simple process, mild reaction, green environmental protection and the like. The prepared nanosilver is applied in the textile field, and the blended fabric having the bactericidal effect can be prepared, so as to greatly improve the added value of the textile.
Description
Technical field
The invention belongs to field of textiles, particularly a kind of honey is prepared Nano Silver and is arranged the method for cotton linen bamboo fiber.
Background technology
Textiles is acknowledged as the medium of cooperating microorganisms as bacterium, fungi.The microbiologic population of occurring in nature is present in the environment of surrounding widely, can grow rapidly once run into suitable humidity, nutrient and temperature.The microorganism grown on the textile not only affects textiles self serviceability, and has influence on the health of user.Therefore how suppressing or killing the microorganism being attached to textiles is especially textiles industry problem in the urgent need to address.
Antibacterial fabric can improve value-added content of product, meets the demand of people to health environment-friendly, and be therefore more and more subject to the attention of vast textile research person, market potential is very large.In the research field of antibacterial fabric, the application of nano silver antimicrobials is the important channel realizing antibacterial textile performance.Silver-series antibacterial agent has many good qualities: one is that antibacterial activity is high, and particularly in the environment of warm moist, it is active that silver-series antibacterial agent has stronger biological antibiotic, when the concentration of silver ion is 10
-6during level, just there is certain fungistatic effect, have in the metal ion of antibacterial action numerous, the ability of its sterilization and suppression pathogen has following rule: Ag>>Hg>CuGreat T.GreaT.GTCd>Cr>NiGreatT.Gre aT.GTPb>Co>Zn> Fe; Two is very high securities, and do not have the change of obvious cell aggregation, cytomorphosis, cytolysis and pH value etc. with the cell after the silver ion treatment that concentration is very low, silver ion a small amount of does not as seen have obvious injury effect to human body; Silver-series antibacterial agent also not easily develops immunity to drugs simultaneously, has good durability.Greatly, the particle of silver is less, and antimicrobial efficiency is higher, and therefore in silver-series antibacterial agent, nano silver antimicrobials especially receives and pays close attention to widely for the antimicrobial efficiency of silver-series antibacterial agent and its surface area relationship.Nano Silver refers to that particle diameter is less than 100nm, approximately containing 20-15, and the Argent grain of 000 silver atoms.Nano Silver, because having small-size effect, skin effect, quantum size effect and macro quanta tunnel effect etc., shows and is different from conventional physics, chemistry and biological property, comprises excellent anti-microbial property.
The preparation of traditional Nano Silver is divided into Physical and chemical method.Physical requires higher to instrument and equipment, and producing cost is expensive.Chemical method many employings hydrazine hydrate, formaldehyde, polyalcohol, organic amine etc. make reductant, although these reductants have high activity, to bad environmental, and obtained Nano Silver easily agglomeration occurs.
In recent years, green, environmental protection, efficient and cheap method is adopted to prepare the focus that Nano Silver becomes research gradually, compared to physics, chemical method advantageously, wide material sources, reaction condition is gentle, just can react at normal temperatures and pressures, the nano silver particles of synthesis has good biocompatibility.The green reducing agent adopted at present mainly comprises: vitamin, natrium citricum, pyrogallol, hydroquinones, Tea Polyphenols, glucose, fructose, sucrose, plant and pericarp extract, microorganism etc.
The honey of honey nectar brew in honeycomb that to be honeybee adopt from the spending of flowering plant.Honeybee takes moisture to be about nectar or the secretion of 80% from the spending of plant, stored in oneself second stomach, under the effect of multiple invertase in vivo, repeatedly ferment various vitamin, mineral matter and amino acid through about 15 days and enrich certain numerical value, simultaneously the polysaccharide in nectar is transformed into simple sugar glucose, the fructose that human body can directly absorb, moisture is less than 10% and is stored in nest hole, seals with beeswax.Honey is the supersaturated solution of sugar, can produce crystallization during low temperature, and what generate crystallization is glucose, does not produce the part mainly fructose of crystallization.Honey is because of the difference of honeybee kind, nectar source, environment, and its chemical composition has very big-difference.Its main component is fructose and glucose, both account for 70%, still containing a small amount of sucrose, maltose, dextrin, natural gum and nitrogen-containing compound, organic acid, volatile oil, pigment, wax, natural perfume material, vegetable debris (particularly pollen grain), yeast, enzyme, inorganic salts etc. at content total.Have no at present with honey is the report that Nano Silver prepared by reductant.
Summary of the invention
The present invention is directed to the deficiency that prior art exists, aim to provide a kind of method that honey is prepared Nano Silver and arranged cotton linen bamboo fiber.
The present invention is achieved by following technical proposals:
Described BLENDED FABRIC is formed by warp and weft interweaving, described warp thread is 50% cotton/30% flax/20% bamboo fibre, described weft yarn is 100% cotton, the described line density through weft yarn is 18.2*18.2tex, institutional framework 3/1 twill, fabric width 60cm, tightness 77.04%, thickness 0.5mm, Density 344*264/ (root (10cm)
-1).
Silver nitrate is configured to respectively the aqueous solution of 0.01-100g/L, then a certain amount of honey is added, wherein the mass ratio of honey and silver nitrate is 10:1-1:10, under the temperature conditions of 50 DEG C-90 DEG C, average rate stirs 30-600min, obtain nano-class silver colloidal solution, repeatedly clean with ethanol and deionized water, centrifugal, obtain nano-Ag particles after dry process; Then configure the Nano silver solution of 0.01-10g/L, then above-mentioned BLENDED FABRIC be immersed, dip time is 100min, and two leachings two are rolled, and pressure is 1kg/m
2, liquid carrying rate is preliminary drying 3 minutes at 90%, 120 DEG C, bakes 30 seconds at 180 DEG C, is washed to neutral rear 30 DEG C of low temperature dryings.
The present invention has following beneficial effect:
Honey main component is fructose and glucose, and both account for 70%, still containing a small amount of sucrose, maltose, dextrin, yeast, enzyme at content total.The present invention adopts honey as the reductant of Nano Silver and stabilizing agent, possess that technique is simple, reaction temperature and, the advantage such as environmental protection.The Nano Silver prepared is used for field of textiles, can prepare the fabric with biocidal efficacies, substantially increases the added value of textiles.
Detailed description of the invention
Below in conjunction with detailed description of the invention, set forth the present invention further.
Embodiment 1:
Described BLENDED FABRIC is formed by warp and weft interweaving, described warp thread is 50% cotton/30% flax/20% bamboo fibre, described weft yarn is 100% cotton, the described line density through weft yarn is 18.2*18.2tex, institutional framework 3/1 twill, fabric width 60cm, tightness 77.04%, thickness 0.5mm, Density 344*264/ (root (10cm)
-1).
Get 1g silver nitrate, be configured to the aqueous solution of 1g/L, then add the honey of 1g, under the temperature conditions of 50 DEG C, average rate stirs 600min, obtains nano-class silver colloidal solution, repeatedly cleans with ethanol and deionized water, centrifugal, obtains nano-Ag particles after dry process.
The Nano silver solution of configuration concentration 0.1g/L, is then immersed fabric, and dip time is 100min, and two leachings two are rolled, and pressure is 1kg/m
2, liquid carrying rate is preliminary drying 3 minutes at 90%, 120 DEG C, bakes 30 seconds at 180 DEG C, is washed to neutral rear 30 DEG C of low temperature dryings.
Embodiment 2:
Described BLENDED FABRIC is formed by warp and weft interweaving, described warp thread is 50% cotton/30% flax/20% bamboo fibre, described weft yarn is 100% cotton, the described line density through weft yarn is 18.2*18.2tex, institutional framework 3/1 twill, fabric width 60cm, tightness 77.04%, thickness 0.5mm, Density 344*264/ (root (10cm)
-1).
Get 1g silver nitrate, be configured to the aqueous solution of 10g/L, then add the honey of 5g, under the temperature conditions of 70 DEG C, average rate stirs 300min, obtains nano-class silver colloidal solution, repeatedly cleans with ethanol and deionized water, centrifugal, obtains nano-Ag particles after dry process.
The Nano silver solution of configuration concentration 1g/L, is then immersed fabric, and dip time is 100min, and two leachings two are rolled, and pressure is 1kg/m
2, liquid carrying rate is preliminary drying 3 minutes at 90%, 120 DEG C, bakes 30 seconds at 180 DEG C, is washed to neutral rear 30 DEG C of low temperature dryings.
Embodiment 3:
Described BLENDED FABRIC is formed by warp and weft interweaving, described warp thread is 50% cotton/30% flax/20% bamboo fibre, described weft yarn is 100% cotton, the described line density through weft yarn is 18.2*18.2tex, institutional framework 3/1 twill, fabric width 60cm, tightness 77.04%, thickness 0.5mm, Density 344*264/ (root (10cm)
-1).
Get 10g silver nitrate, be configured to the aqueous solution of 50g/L, then add the honey of 2g, under the temperature conditions of 90 DEG C, average rate stirs 60min, obtains nano-class silver colloidal solution, repeatedly cleans with ethanol and deionized water, centrifugal, obtains nano-Ag particles after dry process.
The Nano silver solution of configuration concentration 10g/L, is then immersed fabric, and dip time is 100min, and two leachings two are rolled, and pressure is 1kg/m
2, liquid carrying rate is preliminary drying 3 minutes at 90%, 120 DEG C, bakes 30 seconds at 180 DEG C, is washed to neutral rear 30 DEG C of low temperature dryings.
Obviously, the above embodiment of the present invention is only for example of the present invention is clearly described, and is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here cannot give exhaustive to all embodiments.Every belong to technical scheme of the present invention the apparent change of amplifying out or variation be still in the row of protection scope of the present invention.
Claims (5)
1. honey is prepared Nano Silver and is arranged a method for cotton linen bamboo fiber, it is characterized in that:
(1) described BLENDED FABRIC is formed by warp and weft interweaving, described warp thread is 50% cotton/30% flax/20% bamboo fibre, described weft yarn is 100% cotton, the described line density through weft yarn is 18.2*18.2tex, institutional framework 3/1 twill, fabric width 60cm, tightness 77.04%, thickness 0.5mm, Density 344*264/ (root (10cm)
-1);
(2) silver nitrate is configured to the certain density aqueous solution respectively, then adds a certain amount of honey, under the temperature conditions of 50 DEG C-90 DEG C, average rate stirs 30-600min, obtain nano-class silver colloidal solution, repeatedly clean with ethanol and deionized water, centrifugal, obtain nano-Ag particles after dry process;
(3) configure certain density Nano silver solution, then above-mentioned BLENDED FABRIC be immersed, dip time is 100min, and two leachings two are rolled, and pressure is 1kg/m
2, liquid carrying rate is preliminary drying 3 minutes at 90%, 120 DEG C, bakes 30 seconds at 180 DEG C, is washed to neutral rear 30 DEG C of low temperature dryings.
2. the method for nano silver antibacterial fabric prepared by a kind of instant coffee according to claim 1, it is characterized in that, the concentration of described liquor argenti nitratis ophthalmicus is 0.01-100g/L.
3. a kind of honey according to claim 1 is prepared Nano Silver and is arranged the method for cotton linen bamboo fiber, and it is characterized in that, the mass ratio of described honey and silver nitrate is 10:1-1:10.
4. a kind of honey according to claim 1 is prepared Nano Silver and is arranged the method for cotton linen bamboo fiber, and it is characterized in that, the particle size range of described Nano Silver is in 1-200 nanometer.
5. a kind of honey according to claim 1 is prepared Nano Silver and is arranged the method for cotton linen bamboo fiber, and it is characterized in that, the concentration of described Nano silver solution is 0.01-10g/L.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107538839A (en) * | 2017-08-24 | 2018-01-05 | 江苏格玛斯特种织物有限公司 | A kind of processing technology of the wear-resisting Western-style trousers fabric of water proof type |
| CN109023928A (en) * | 2018-06-21 | 2018-12-18 | 盐城工学院 | A kind of preparation method of antibacterial anti-UV fabric |
| CN109108277A (en) * | 2017-06-23 | 2019-01-01 | 保佳利实业有限公司 | Water hardware device with nano-silver material and manufacturing method thereof |
| CN109964957A (en) * | 2019-03-29 | 2019-07-05 | 江苏理工学院 | A kind of Cu2The environment-friendly preparation method thereof of O/Ag nano anti-biotic material |
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| CN1709618A (en) * | 2005-07-08 | 2005-12-21 | 昆明理工大学 | Method for preparing nano or submicron silver powder |
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| CN103464782A (en) * | 2013-09-16 | 2013-12-25 | 江苏大学 | Method utilizing shaddock ped extracting solution to synthesize silver nanoparticles in microwave |
| CN104562658A (en) * | 2015-01-21 | 2015-04-29 | 辽东学院 | Amino acid nano-silver modified finishing agent as well as preparation method of finishing agent and modified fishing shell fabric |
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Patent Citations (5)
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| CN1709618A (en) * | 2005-07-08 | 2005-12-21 | 昆明理工大学 | Method for preparing nano or submicron silver powder |
| CN101173432A (en) * | 2007-10-19 | 2008-05-07 | 无锡汇罗新材料科技有限公司 | Nano-silver antibiotic finish technique for facing material |
| CN102202815A (en) * | 2008-05-16 | 2011-09-28 | 维鲁泰克技术股份有限公司 | Green synthesis of nanometals using plant extracts and use thereof |
| CN103464782A (en) * | 2013-09-16 | 2013-12-25 | 江苏大学 | Method utilizing shaddock ped extracting solution to synthesize silver nanoparticles in microwave |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109108277A (en) * | 2017-06-23 | 2019-01-01 | 保佳利实业有限公司 | Water hardware device with nano-silver material and manufacturing method thereof |
| CN107538839A (en) * | 2017-08-24 | 2018-01-05 | 江苏格玛斯特种织物有限公司 | A kind of processing technology of the wear-resisting Western-style trousers fabric of water proof type |
| CN109023928A (en) * | 2018-06-21 | 2018-12-18 | 盐城工学院 | A kind of preparation method of antibacterial anti-UV fabric |
| CN109964957A (en) * | 2019-03-29 | 2019-07-05 | 江苏理工学院 | A kind of Cu2The environment-friendly preparation method thereof of O/Ag nano anti-biotic material |
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Application publication date: 20151209 |