CN105131732A - Long-acting led heat-dissipating coating material and preparation method thereof - Google Patents

Abstract

The present invention discloses a long-acting led heat-dissipating coating material, which comprises the following raw materials: 0.1-0.13 part of divinylbenzene, 1-2 parts of o-phthalic anhydride, 3-5 parts of acrylic ester, 12-15 parts of a styrene-maleic anhydride copolymer, 6-10 parts of propargyl alcohol, 90-100 parts of tetrahydrofuran, 4-7 parts of graphene, 16-20 parts of nanometer silica, 0.2-0.3 part of a silane coupling agent KH560, 700-800 parts of dimethylformamide, 4-5 parts of sodium nitride, 0.04-0.05 part of aluminum trichloride, 1.6-2 parts of a 2-3%sodium ascorbate solution, 1.8-2 parts of a 2-3% copper sulfate solution, 120-130 parts of high-density polyethylene, 0.7-1 part of polyvinyl alcohol, 3-4 parts of trioctyl trimellitate, 2-4 parts of borax, and 0.6-1 part of ethyl cellulose. According to the present invention, the coating material can form the uniform and stable coating film on the substrate surface, and the formed coating film has characteristics of high temperature resistance, low temperature resistance, strong corrosion resistance, good storage stability, and lasting protection effect.

Description

A kind of long-acting led heat radiation coating and preparation method thereof

Technical field

The present invention relates to heat radiation coating technical field, particularly relate to a kind of long-acting led heat radiation coating and preparation method thereof.

Background technology

Along with the fast development of modern science and technology, intensive and the miniaturization of the high frequency of electron device, high speed and unicircuit, the overall power density of unit volume electron device and thermal value are increased by a wide margin, thus makes the cooling problem of electron device become more and more outstanding.And the cooling power that the cooling system of routine can reach is subject to great challenge, especially in fields such as the energy, automobile, air-conditioning, agricultural, chemical industry, heating, aerospace, microelectronics, information, the technology such as enhancement of heat transfer, raising radiating efficiency are had higher requirement.And heat radiation coating is a kind of body surface radiating efficiency that improves, reduce the speciality coating of system temperature, heat radiation coating is coated with the radiating efficiency that can improve electron device on the electronic devices;

Nano silicon is because having in tridimensional network, and stability, reinforcing and thickening property is superior, low price, the feature such as easily to produce, is widely used in corrosion protection coating, to improve carrying and the antiseptic power of coating.The specific surface area of nano silicon is large, and specific surface energy is high, and easily occur in the coating reunite and form offspring, cause the performance of activeness and quietness to reduce, the hydroxyl on its surface also enhances this kind of phenomenon simultaneously.Therefore, improving the dispersiveness of nanosized SiO_2 in organic coating is problem demanding prompt solution.

Summary of the invention

The object of the invention is exactly the defect in order to make up prior art, provides a kind of long-acting led heat radiation coating and preparation method thereof.

The present invention is achieved by the following technical solutions:

A kind of long-acting led heat radiation coating, it is made up of the raw material of following weight parts:

Vinylstyrene 0.1-0.13, Tetra hydro Phthalic anhydride 1-2, acrylate 3-5, styrene-maleic anhydride copolymer 12-15, propiolic alcohol 6-10, tetrahydrofuran (THF) 90-100, Graphene 4-7, nano silicon 16-20, silane coupling agent KH5600.2-0.3, dimethyl formamide 700-800, sodium nitride 4-5, aluminum chloride 0.04-0.05, 2-3% sodium ascorbate solution 1.6-2, 2-3% copper-bath 1.8-2, high density polyethylene(HDPE) 120-130, polyvinyl alcohol 0.7-1, trioctyl trimellitate 3-4, borax 2-4, ethyl cellulose 0.6-1.

A preparation method for described long-acting led heat radiation coating, comprises the following steps:

(1) by Tetra hydro Phthalic anhydride, crylic acid ester mixture, join in the ethanolic soln of compound weight 40-50 times 30-40%, raised temperature is 70-80 DEG C, adds Vinylstyrene, insulation reaction 2-3 hour, and cooling, obtains crosslinked Preblend;

(2) by above-mentioned styrene-maleic anhydride copolymer, propiolic alcohol, tetrahydrofuran (THF) mixing, insulated and stirred 10-16 hour at 50-60 DEG C, underpressure distillation, removing liquid, vacuum-drying, obtains alkynyl multipolymer;

(3) above-mentioned polyvinyl alcohol is joined in 10-15 dimethyl formamide doubly, stir, add ethyl cellulose, raised temperature is 50-60 DEG C, adds Graphene, insulated and stirred 30-40 minute, suction filtration, by filter cake vacuum-drying, mix with nano silicon, borax, ball milling 30-40 minute;

(4) get above-mentioned ball milling particle, join in 20-30 toluene doubly, ultrasonic disperse 2-3 hour, adds silane coupling agent KH560, and raised temperature is 86-90 DEG C, insulated and stirred 10-12 hour, cooling, suction filtration, and vacuum-drying, obtains silanization nanoparticle;

(5) get the 46-50% of residue dimethyl formamide weight, add silanization nanoparticle, ultrasonic disperse 2-3 hour, add sodium nitride, aluminum chloride, stir 24-25 hour, suction filtration at 30-35 DEG C, washing, vacuum-drying, obtains Sodium Azide rice corpuscles;

(6) by above-mentioned Sodium Azide rice corpuscles, alkynyl multipolymer mixes, join in remaining dimethyl formamide, nitrogen bubble 30-40 minute, add 2-3% sodium ascorbate solution successively, 2-3% copper-bath, 20-24 hour is reacted at being placed in 76-80 DEG C, add above-mentioned trioctyl trimellitate, continue insulated and stirred 20-30 minute, add crosslinked Preblend, the 10-20% of above-specified high density polyethylene weight, 60-100 rev/min is stirred 7-10 minute, suction filtration, filter cake is used distilled water successively, dimethyl formamide, acetone respectively washs 2-3 time, after vacuum-drying, obtain engrafted nanometer particle,

(7) mixed with each raw material of residue by above-mentioned engrafted nanometer particle, stir, be sent to twin screw extruder, melt extrude, cooling, pulverizes and sieves, to obtain final product.

Advantage of the present invention is:

(1) coating of the present invention has good shock resistance:

Graphene, nano silicon all have larger specific surface area, can strengthen Graphene, reactive force between nano silicon and polyvinyl resin, put forward heavily stressed transfer efficiency, and then improve its shock resistance;

(2) coating of the present invention has good erosion resistance;

Graphene, nano silicon in the medium-altitude dispersion of resin, can form fine and close film, corrosive medium is more difficult to be penetrated in coating by this interface, well improves corrosion resistance;

(3) coating of the present invention has good heat conduction and heat radiation:

First the present invention prepares the styrene-maleic anhydride copolymer containing multiple alkynyl on molecular chain, then modified Nano particle, its surface is made to introduce multiple azido-, finally utilize " click " chemical method at particle surface graftomer, polymer molecular chain has multiple point to be grafted to particle surface, molecular chain " is crouched down " at particle surface, thus it is coated what do not need to realize under the condition introducing number of polymers chain to particle, obtain grafting density high, the nanoparticle of good dispersity, strengthen its dispersiveness in resin matrix, the two-dimension plane structure of Graphene that is scattered here and there in resin and the tridimensional network of nano silicon can form stable heat conduction network, greatly improve the transmission of heat, play good heat conduction and heat radiation effect.

Coating of the present invention can form uniform and stable film at substrate surface, and resistant of high or low temperature, erosion resistance are strong, and excellent storage stability, protected effect is lasting.

Embodiment

A kind of long-acting led heat radiation coating, it is made up of the raw material of following weight parts:

Vinylstyrene 0.1, Tetra hydro Phthalic anhydride 1, acrylate 3, Zelan 338 12, propiolic alcohol 6, tetrahydrofuran (THF) 90, Graphene 4, nano silicon 16, silane coupling agent KH5600.2, dimethyl formamide 700, sodium nitride 4, aluminum chloride 0.04,2% sodium ascorbate solution 1.6,2% copper-bath 1.8, high density polyethylene(HDPE) 120, polyvinyl alcohol 0.7, trioctyl trimellitate 3, borax 2, ethyl cellulose 0.6.

A preparation method for described long-acting led heat radiation coating, comprises the following steps:

(1) by Tetra hydro Phthalic anhydride, crylic acid ester mixture, join in the ethanolic soln of compound weight 40 times 30%, raised temperature is 70 DEG C, adds Vinylstyrene, insulation reaction 2 hours, and cooling, obtains crosslinked Preblend;

(2) by above-mentioned Zelan 338, propiolic alcohol, tetrahydrofuran (THF) mixing, insulated and stirred 10 hours at 50 DEG C, underpressure distillation, removing liquid, vacuum-drying, obtains alkynyl multipolymer;

(3) joined in the dimethyl formamide of 10 times by above-mentioned polyvinyl alcohol, stir, add ethyl cellulose, raised temperature is 50 DEG C, add Graphene, insulated and stirred 30 minutes, suction filtration, by filter cake vacuum-drying, mix with nano silicon, borax, ball milling 30 minutes;

(4) get above-mentioned ball milling particle, join in the toluene of 20 times, ultrasonic disperse 2 hours, adds silane coupling agent KH560, and raised temperature is 86 DEG C, insulated and stirred 10 hours, cooling, suction filtration, and vacuum-drying, obtains silanization nanoparticle;

(5) get 46% of residue dimethyl formamide weight, add silanization nanoparticle, ultrasonic disperse 2 hours, adds sodium nitride, aluminum chloride, stirs 24 hours, suction filtration at 30 DEG C, washing, and vacuum-drying, obtains Sodium Azide rice corpuscles;

(6) by above-mentioned Sodium Azide rice corpuscles, the mixing of alkynyl multipolymer, join in remaining dimethyl formamide, nitrogen bubble 30 minutes, add 2% sodium ascorbate solution, 2% copper-bath successively, react 20 hours at being placed in 76 DEG C, add above-mentioned trioctyl trimellitate, continue insulated and stirred 20 minutes, add crosslinked Preblend, above-specified high density polyethylene weight 10%, 60 revs/min are stirred 7 minutes, and suction filtration, respectively washs 2 times with distilled water, dimethyl formamide, acetone successively by filter cake, after vacuum-drying, obtain engrafted nanometer particle;

(7) mixed with each raw material of residue by above-mentioned engrafted nanometer particle, stir, be sent to twin screw extruder, melt extrude, cooling, pulverizes and sieves, to obtain final product.

Performance test:

Appearance of film: flat smooth, without shrinkage cavity, free of pinholes;

Just recoiling test: pass through;

Pencil hardness test: 2H is without scuffing;

Sticking power and resistance to Neutral Salt Spray Corrosion grade are 2 grades;

Thermal conductivity is 0.481W/mK.

Claims (2)

1. a long-acting led heat radiation coating, is characterized in that what it was made up of the raw material of following weight parts:

Vinylstyrene 0.1-0.13, Tetra hydro Phthalic anhydride 1-2, acrylate 3-5, styrene-maleic anhydride copolymer 12-15, propiolic alcohol 6-10, tetrahydrofuran (THF) 90-100, Graphene 4-7, nano silicon 16-20, silane coupling agent KH5600.2-0.3, dimethyl formamide 700-800, sodium nitride 4-5, aluminum chloride 0.04-0.05, 2-3% sodium ascorbate solution 1.6-2, 2-3% copper-bath 1.8-2, high density polyethylene(HDPE) 120-130, polyvinyl alcohol 0.7-1, trioctyl trimellitate 3-4, borax 2-4, ethyl cellulose 0.6-1.

2. a preparation method for long-acting led heat radiation coating as claimed in claim 1, is characterized in that comprising the following steps:

(1) by Tetra hydro Phthalic anhydride, crylic acid ester mixture, join in the ethanolic soln of compound weight 40-50 times 30-40%, raised temperature is 70-80 DEG C, adds Vinylstyrene, insulation reaction 2-3 hour, and cooling, obtains crosslinked Preblend;

(2) by above-mentioned styrene-maleic anhydride copolymer, propiolic alcohol, tetrahydrofuran (THF) mixing, insulated and stirred 10-16 hour at 50-60 DEG C, underpressure distillation, removing liquid, vacuum-drying, obtains alkynyl multipolymer;

(3) above-mentioned polyvinyl alcohol is joined in 10-15 dimethyl formamide doubly, stir, add ethyl cellulose, raised temperature is 50-60 DEG C, adds Graphene, insulated and stirred 30-40 minute, suction filtration, by filter cake vacuum-drying, mix with nano silicon, borax, ball milling 30-40 minute;

(4) get above-mentioned ball milling particle, join in 20-30 toluene doubly, ultrasonic disperse 2-3 hour, adds silane coupling agent KH560, and raised temperature is 86-90 DEG C, insulated and stirred 10-12 hour, cooling, suction filtration, and vacuum-drying, obtains silanization nanoparticle;

(5) get the 46-50% of residue dimethyl formamide weight, add silanization nanoparticle, ultrasonic disperse 2-3 hour, add sodium nitride, aluminum chloride, stir 24-25 hour, suction filtration at 30-35 DEG C, washing, vacuum-drying, obtains Sodium Azide rice corpuscles;

(6) by above-mentioned Sodium Azide rice corpuscles, alkynyl multipolymer mixes, join in remaining dimethyl formamide, nitrogen bubble 30-40 minute, add 2-3% sodium ascorbate solution successively, 2-3% copper-bath, 20-24 hour is reacted at being placed in 76-80 DEG C, add above-mentioned trioctyl trimellitate, continue insulated and stirred 20-30 minute, add crosslinked Preblend, the 10-20% of above-specified high density polyethylene weight, 60-100 rev/min is stirred 7-10 minute, suction filtration, filter cake is used distilled water successively, dimethyl formamide, acetone respectively washs 2-3 time, after vacuum-drying, obtain engrafted nanometer particle,

(7) mixed with each raw material of residue by above-mentioned engrafted nanometer particle, stir, be sent to twin screw extruder, melt extrude, cooling, pulverizes and sieves, to obtain final product.