CN105131468A - Moisture-resistant waterproof polyvinyl chloride cable sheath material - Google Patents

Moisture-resistant waterproof polyvinyl chloride cable sheath material Download PDF

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Publication number
CN105131468A
CN105131468A CN201510611656.1A CN201510611656A CN105131468A CN 105131468 A CN105131468 A CN 105131468A CN 201510611656 A CN201510611656 A CN 201510611656A CN 105131468 A CN105131468 A CN 105131468A
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parts
polyvinyl chloride
water
moisture
compound
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程晓松
于德宝
孙玉萍
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Suzhou Hengli Communications Material Co Ltd
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Suzhou Hengli Communications Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a moisture-resistant waterproof polyvinyl chloride cable sheath material. The moisture-resistant waterproof polyvinyl chloride cable sheath material is composed of the following components in parts by weight: 55 parts of polyvinyl chloride of which the polymerization degree is 590 to 720, 36 parts of polyvinyl chloride of which the polymerization degree is 1,110 to 1,340, 29 parts of trioctyl trimellitate (TOTM), 25 parts of diisodecyl phthalate, 9 parts of an environmentally-friendly calcium-zinc compound stabilizer, 10 parts of a compound rare-earth stabilizer, 4 parts of antimonous oxide, 0.5 part of a lubricating agent, 0.1 part of an antioxidant, 3.8 parts of nano barium sulfate, 2.8 parts of calcined kaolin, 5 parts of nano silicon dioxide and 0.2 part of a silane coupling agent. According to the moisture-resistant waterproof polyvinyl chloride cable sheath material, the water absorption of a cable sheath layer is greatly reduced, the product is used under a wet or soaking environment, the electric performance stability is further improved, the compactness of the product is improved, and material micro-pores are eliminated.

Description

Moisture-resistant is water-fast polyvinyl chloride cable sheathing compound
Technical field
The present invention relates to a kind of vinylchlorid cable jacket material, particularly relate to the water-fast polyvinyl chloride cable sheathing compound of a kind of moisture-resistant.
Background technology
PVC cable insulating material is one of general synthetic plastics, is to be only second to poly second largest plastics variety in the world at present.Polyvinyl chloride cable material is owing to having good mechanical and physical performance, electric property, and complete processing is simple, and processing characteristics is excellent, and price is lower, occupy prostatitis always, be widely used in CABLE MATERIALS industry total amount.PVC cable material is generally applied to the product such as mesolow, data corresponding class cable, and general purpose electric wire product, PVC cable material can meet insulation, sheath demand substantially.But along with the expansion of electric wire application scenario, improving constantly the requirement of PVC cable material, on the water-fast electrical insulation capability of PVC, is a difficult point always, be difficult to for a long time solve.
Polyvinyl chloride resin itself has excellent water resistance, but due to CABLE MATERIALS produce must add all kinds of softening agent, stablizer, all kinds of weighting agent (potter's clay, calcium carbonate etc.), inevitably reduce the immersion electrical property of product.Prior art is difficult to find from document, but general employing high-quality softening agent, minimizing or the mode without weighting agent, product index performance is still difficult to meet the demands, and easily causes the indexs such as thermal distortion defective, the problems such as cost increase simultaneously.
Summary of the invention
The object of this invention is to provide the water-fast polyvinyl chloride cable sheathing compound of a kind of moisture-resistant, it greatly reduces the water-absorbent of the coat layer of power cable, and product uses under moist or water-immerged environment, further increases electric property and stablizes, substantially do not change, improve the tightness of product, get rid of material micropore.
To achieve the above object of the invention, the technical solution used in the present invention is: a kind of moisture-resistant is water-fast polyvinyl chloride cable sheathing compound, described waterproof flame retardant PVC cable material is made up of the component of following weight part: the polymerization degree is 590 ~ 720 polyvinyl chloride 55 parts, the polymerization degree is 1110 ~ 1340 polyvinyl chloride 36 parts, trioctyl trimellitate (TOTM) 29 parts, phthalic acid isodecyl ester 25 parts, environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor, nano barium sulfate 3.8 parts, calcined kaolin 2.8 parts, nano silicon 5 parts, silane coupling agent 0.2 part,
Described waterproof flame retardant PVC cable material is obtained by following steps:
Step one, be 590 ~ 720 polyvinyl chloride 55 parts by the polymerization degree, to be 1110 ~ 1340 polyvinyl chloride be 36 parts to the polymerization degree under high-speed stirring state, is mixed to form mixture through high-speed mixer; Start stirring at low speed, rotating speed 500rpm, add trioctyl trimellitate 29 parts and phthalic acid isodecyl ester 25 parts, it is in dry powdered form that stirring adds environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor and water-proofing agent 10 ~ 20 parts, continuation stirring is warming up to material, opens baiting valve blowing;
Step 2, the compound of step one put to carry out extrusion molding to twin screw mixing, then the granulation of singe screw extruding machine is entered, adopt die face fervent granulation process, the particle made enters first step whirlwind cooling separator by blower fan transport pipe, second stage whirlwind cooling separator, air-cooled vibratory screening apparatus, third stage whirlwind cooling separator obtain described waterproof flame retardant PVC cable material;
Described resistance to water improver obtains through following technique:
Step one, described nano barium sulfate 3.8 parts, calcined kaolin 2.8 parts, nano silicon 5 parts are carried out Surface coating process;
Step 2, dropped in high-speed mixer by the powder of said components, high-speed mixing carries out dehydration 3 ~ 5min to temperature 90 ~ 100 DEG C;
Step 3, silane coupling agent 0.2 part is carried out coated process to powder in vaporific spraying in high-speed mixer, continue high-speed mixing and carry out the coated processing reaction 3 ~ 5min of material surface;
Described resistance to water improver is obtained after step 4, cooling.
The technical scheme improved further in above-mentioned fabricating technology scheme is as follows:
1., in such scheme, described silane coupling agent is vinyl three ('beta '-methoxy oxyethyl group) silane or vinyltrimethoxy silane.
2., in such scheme, described silane coupling agent is γ-glycidyl ether oxygen propyl trimethoxy silicane.
3., in such scheme, described silane coupling agent is that vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltrimethoxy silane and γ-glycidyl ether oxygen propyl trimethoxy silicane mix by 10:5:3 weight ratio.
4., in such scheme, described lubricant is polyethylene wax or stearic acid.
5. in such scheme, high-speed stirring is started in described step one, rotating speed 1000rpm, treats that material temperature rises to that 80 DEG C add environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor and water-proofing agent 10 ~ 20 parts, to continue to be stirred to temperature 110 DEG C of materials in dry powdered form.
Due to the utilization of technique scheme, the present invention compared with prior art has following advantages:
Moisture-resistant of the present invention is water-fast polyvinyl chloride cable sheathing compound, overcome the water-absorbent that the softening agent of currently available products formula and weighting agent all have, thus easily there is the technological deficiency of product performance decline phenomenon in wet condition, contemplated by the invention all formula materials all with the problem of the consistency of water, select specific hydrophobic material and content.Carry out Surface coating process to after pulvis predrainage, improve the hydrophobic performance of product; Product uses under moist or water-immerged environment, and electric property is stablized, and does not substantially change; Water-proofing agent material selection nano level raw material, improves the tightness of product, and get rid of material micropore, steam cannot invade and cause degradation.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment: a kind of moisture-resistant is water-fast polyvinyl chloride cable sheathing compound, described polyvinyl chloride cable sheathing compound is made up of the component of following weight part: the polymerization degree is 590 ~ 720 polyvinyl chloride 55 parts, the polymerization degree is 1110 ~ 1340 polyvinyl chloride 36 parts, trioctyl trimellitate (TOTM) 29 parts, phthalic acid isodecyl ester 25 parts, environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor, nano barium sulfate 3.8 parts, calcined kaolin 2.8 parts, nano silicon 5 parts, silane coupling agent 0.2 part,
Described waterproof flame retardant PVC cable material is obtained by following steps:
Step one, be 590 ~ 720 polyvinyl chloride 55 parts by the polymerization degree, to be 1110 ~ 1340 polyvinyl chloride be 36 parts to the polymerization degree under high-speed stirring state, is mixed to form mixture through high-speed mixer; Start stirring at low speed, rotating speed 500rpm, add trioctyl trimellitate 29 parts and phthalic acid isodecyl ester 25 parts, it is in dry powdered form that stirring adds environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor and water-proofing agent 10 ~ 20 parts, continuation stirring is warming up to material, opens baiting valve blowing;
Step 2, the compound of step one put to carry out extrusion molding to twin screw mixing, then the granulation of singe screw extruding machine is entered, adopt die face fervent granulation process, the particle made enters first step whirlwind cooling separator by blower fan transport pipe, second stage whirlwind cooling separator, air-cooled vibratory screening apparatus, third stage whirlwind cooling separator obtain described waterproof flame retardant PVC cable material;
Described resistance to water improver obtains through following technique:
Step one, described nano barium sulfate 3.8 parts, calcined kaolin 2.8 parts, nano silicon 5 parts are carried out Surface coating process;
Step 2, dropped in high-speed mixer by the powder of said components, high-speed mixing carries out dehydration 3 ~ 5min to temperature 90 ~ 100 DEG C;
Step 3, silane coupling agent 0.2 part is carried out coated process to powder in vaporific spraying in high-speed mixer, continue high-speed mixing and carry out the coated processing reaction 3 ~ 5min of material surface;
Described resistance to water improver is obtained after step 4, cooling.
Above-mentioned silane coupling agent is vinyl three ('beta '-methoxy oxyethyl group) silane or vinyltrimethoxy silane; Or γ-glycidyl ether oxygen propyl trimethoxy silicane; Or silane coupling agent is that vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltrimethoxy silane and γ-glycidyl ether oxygen propyl trimethoxy silicane mix by 10:5:3 weight ratio.
Above-mentioned lubricant is polyethylene wax or stearic acid.
High-speed stirring is started in above-mentioned steps one, rotating speed 1000rpm, treats that material temperature rises to that 80 DEG C add environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor and water-proofing agent 10 ~ 20 parts, to continue to be stirred to temperature 110 DEG C of materials in dry powdered form.
Water resistance test adopts " ASTMD2219-02 electric wire and cable pvc material specification " 5.5 test conditionss (electric current 60Hz frequency, immersion temperature: 50 ± 1 DEG C).
Test result analysis: product is through accelerating water absorption test, and change in dielectric constant rate is much smaller than standard (1 ~ 14d, 10%; 7 ~ 14d, 5%) requirement, product has good water resistance.
To sum up, moisture-resistant of the present invention is water-fast polyvinyl chloride cable sheathing compound, overcomes the water-absorbent that the softening agent of currently available products formula and weighting agent all have, thus easily occurs the technological deficiency of product performance decline phenomenon in wet condition; Contemplated by the invention all formula materials all with the consistency of water, select hydrophobic material.Carry out Surface coating process to after pulvis predrainage, improve the hydrophobic performance of product; Product uses under moist or water-immerged environment, and electric property is stablized, and does not substantially change; Water-proofing agent material selection nano level raw material, improves the tightness of product, and get rid of material micropore, steam cannot invade and cause degradation.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (6)

1. the water-fast polyvinyl chloride cable sheathing compound of moisture-resistant, it is characterized in that: described polyvinyl chloride cable sheathing compound is made up of the component of following weight part: the polymerization degree is 590 ~ 720 polyvinyl chloride 55 parts, the polymerization degree is 1110 ~ 1340 polyvinyl chloride 36 parts, trioctyl trimellitate (TOTM) 29 parts, phthalic acid isodecyl ester 25 parts, environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor, nano barium sulfate 3.8 parts, calcined kaolin 2.8 parts, nano silicon 5 parts, silane coupling agent 0.2 part,
Described waterproof flame retardant PVC cable material is obtained by following steps:
Step one, be 590 ~ 720 polyvinyl chloride 55 parts by the polymerization degree, to be 1110 ~ 1340 polyvinyl chloride be 36 parts to the polymerization degree under high-speed stirring state, is mixed to form mixture through high-speed mixer; Start stirring at low speed, rotating speed 500rpm, add trioctyl trimellitate 29 parts and phthalic acid isodecyl ester 25 parts, it is in dry powdered form that stirring adds environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor and water-proofing agent 10 ~ 20 parts, continuation stirring is warming up to material, opens baiting valve blowing;
Step 2, the compound of step one put to carry out extrusion molding to twin screw mixing, then the granulation of singe screw extruding machine is entered, adopt die face fervent granulation process, the particle made enters first step whirlwind cooling separator by blower fan transport pipe, second stage whirlwind cooling separator, air-cooled vibratory screening apparatus, third stage whirlwind cooling separator obtain described waterproof flame retardant PVC cable material;
Described resistance to water improver obtains through following technique:
Step one, described nano barium sulfate 3.8 parts, calcined kaolin 2.8 parts, nano silicon 5 parts are carried out Surface coating process;
Step 2, dropped in high-speed mixer by the powder of said components, high-speed mixing carries out dehydration 3 ~ 5min to temperature 90 ~ 100 DEG C;
Step 3, silane coupling agent 0.2 part is carried out coated process to powder in vaporific spraying in high-speed mixer, continue high-speed mixing and carry out the coated processing reaction 3 ~ 5min of material surface;
Described resistance to water improver is obtained after step 4, cooling.
2. the water-fast polyvinyl chloride cable sheathing compound of moisture-resistant according to claim 1, is characterized in that: described silane coupling agent is vinyl three ('beta '-methoxy oxyethyl group) silane or vinyltrimethoxy silane.
3. the water-fast polyvinyl chloride cable sheathing compound of moisture-resistant according to claim 1, is characterized in that: described silane coupling agent is γ-glycidyl ether oxygen propyl trimethoxy silicane.
4. the water-fast polyvinyl chloride cable sheathing compound of moisture-resistant according to claim 1, is characterized in that: described silane coupling agent is that vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltrimethoxy silane and γ-glycidyl ether oxygen propyl trimethoxy silicane mix by 10:5:3 weight ratio.
5. the water-fast polyvinyl chloride cable sheathing compound of moisture-resistant according to claim 1, is characterized in that: described lubricant is polyethylene wax or stearic acid.
6. the water-fast polyvinyl chloride cable sheathing compound of moisture-resistant according to claim 1, it is characterized in that: in described step one, start high-speed stirring, rotating speed 1000rpm, treats that material temperature rises to that 80 DEG C add environmental protection calcium-zinc composite stabilizing agent 9 parts, compound rare-earth stablizer 10 parts, antimonous oxide 4 parts, lubricant 0.5 part, 0.1 part, oxidation inhibitor and water-proofing agent 10 ~ 20 parts, to continue to be stirred to temperature 110 DEG C of materials in dry powdered form.
CN201510611656.1A 2012-12-04 2012-12-04 Moisture-resistant waterproof polyvinyl chloride cable sheath material Pending CN105131468A (en)

Applications Claiming Priority (1)

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CN201210510995.7A CN103044802B (en) 2012-12-04 2012-12-04 Waterproof flame retardant PVC cable material and preparation technology thereof

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CN201510611656.1A Pending CN105131468A (en) 2012-12-04 2012-12-04 Moisture-resistant waterproof polyvinyl chloride cable sheath material
CN201510611657.6A Pending CN105131469A (en) 2012-12-04 2012-12-04 Preparation process for hydrophobic PVC cable material
CN201510391788.8A Pending CN104945779A (en) 2012-12-04 2012-12-04 High-insulating cable sheath material
CN201510391573.6A Pending CN104945778A (en) 2012-12-04 2012-12-04 Water-vapor-resisting inflaming retarding PVC protecting sleeve material
CN201210510995.7A Active CN103044802B (en) 2012-12-04 2012-12-04 Waterproof flame retardant PVC cable material and preparation technology thereof
CN201510391582.5A Active CN105017684B (en) 2012-12-04 2012-12-04 The preparation method of flame retardant type high reliability CABLE MATERIALS
CN201510612073.0A Pending CN105153590A (en) 2012-12-04 2012-12-04 High-water-resistance compact compound PVC cable material

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CN201510611657.6A Pending CN105131469A (en) 2012-12-04 2012-12-04 Preparation process for hydrophobic PVC cable material
CN201510391788.8A Pending CN104945779A (en) 2012-12-04 2012-12-04 High-insulating cable sheath material
CN201510391573.6A Pending CN104945778A (en) 2012-12-04 2012-12-04 Water-vapor-resisting inflaming retarding PVC protecting sleeve material
CN201210510995.7A Active CN103044802B (en) 2012-12-04 2012-12-04 Waterproof flame retardant PVC cable material and preparation technology thereof
CN201510391582.5A Active CN105017684B (en) 2012-12-04 2012-12-04 The preparation method of flame retardant type high reliability CABLE MATERIALS
CN201510612073.0A Pending CN105153590A (en) 2012-12-04 2012-12-04 High-water-resistance compact compound PVC cable material

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CN108831598A (en) * 2018-06-20 2018-11-16 江苏汉兴电缆有限公司 A kind of novel cable insulation sleeve
CN109776999A (en) * 2018-12-29 2019-05-21 安徽天康(集团)股份有限公司 A kind of high temperature resistance control cable
CN112795111A (en) * 2020-12-28 2021-05-14 宜宾天亿新材料科技有限公司 High-fluidity low-cost PVC (polyvinyl chloride) cable material and preparation method thereof

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CN103509294B (en) * 2013-10-12 2016-03-02 绿宝电缆(集团)有限公司 A kind of cold-resistant fire-retardant PVC CABLE MATERIALS
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CN107739485A (en) * 2017-11-29 2018-02-27 王秀云 A kind of high-temp resisting high-humidity resisting sensor modified PVC CABLE MATERIALS and preparation method thereof
CN109486053A (en) * 2018-09-18 2019-03-19 百通赫思曼工业(苏州)有限公司 A kind of PVC cable material of low-k
CN109593290B (en) * 2018-10-19 2021-04-30 中广核三角洲(中山)高聚物有限公司 Silane crosslinked flame-retardant polyvinyl chloride cable material and preparation method thereof
CN113754965B (en) * 2021-08-20 2022-09-16 湖南联塑科技实业有限公司 High-compression-resistance PVC (polyvinyl chloride) water leading and draining pipe material and preparation method and application thereof
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CN115322497B (en) * 2022-09-14 2023-12-19 江苏中天科技股份有限公司 Moisture-proof heat-resistant polyvinyl chloride cable sheath material, preparation method and application thereof, cable sheath, electric wire and cable

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CN104945778A (en) 2015-09-30
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CN103044802B (en) 2016-01-20
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CN105131469A (en) 2015-12-09
CN105153590A (en) 2015-12-16

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