CN105116699A - Developing agent and preparation method thereof - Google Patents
Developing agent and preparation method thereof Download PDFInfo
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- CN105116699A CN105116699A CN201510562486.2A CN201510562486A CN105116699A CN 105116699 A CN105116699 A CN 105116699A CN 201510562486 A CN201510562486 A CN 201510562486A CN 105116699 A CN105116699 A CN 105116699A
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Abstract
The invention provides a developing agent and a preparation method thereof. The developing agent is used for CMYK four-color laser developing equipment and comprises the following components in parts by weight: 86-92 parts of bonding resin, 5-6 parts of a bronze red pigment and 0.1-1.5 parts of a magenta pigment. The preparation method of the developing agent mainly comprises a mixing step, a melting step, a cooling step, a crushing grading, post-mixing and sieving step. The main concept of the invention is that the bronze red pigment is used as a main pigment and the magenta pigment is used as an auxiliary color mixing pigment, and the pigments are mixed through a reasonable weight ratio; and finally, the developing agent with the developing effect which is consistent to the developing effect of a standard official document is obtained.
Description
Technical field
The invention belongs to the developer field used in laser development equipment, specifically, relate to a kind of developer for M box in CMYK tetra-look laser development equipment.
Background technology
" official document " generally refers to the file that administration is sent out for not specific citizen and tissue system, the rights and duties that this class file is binding to the public, relate to them, the administrative regulation namely alleged by legal language, other with general binding force regulatory documents beyond regulations.
Have employed this official document in a lot of situation of official document of governments at all levels of China, and the color display effect of word in official document and bright red seal all has regulation, the color developing effect of its color is not identical with the color of common red writing.At present, the manufacture method of the official document of standard is mainly or by the spot color printing of printing house, but this spot color printing needs plate-making and printing will reach a certain amount of, and needs to change once file, the file then printed off will cancel, and this just causes the huge wasting of resources.
Electrophotographic image forming comprises laser development equipment as laser printer, copy and all-in-one multifunctional machine etc., and its groundwork process can be divided into charging, exposure, development, transfer printing, fix steps etc.
CMYK tetra-look laser printer is the product of a laser development equipment wherein type, CMYK refers to green grass or young crops, fuchsin (magenta), Huang, black four kinds of colors usually respectively, the color of the official document that common CMYK tetra-look laser printer types goes out and the misalignment of standard official document are very large, and that is common CMYK tetra-look laser printer cannot print official document.OKI Electrics Industry Co., Ltd. of Japan (OKI) is for the demand in this market domestic, and produce a kind of two-color printing of special printing official document, it is the printer that one can only print redness (R) and black (B).Although the color of its official document printed can obtain the accreditation of departments of government, there are some problems in this dedicated printer, and on the one hand, its price is very expensive, generally more than 50,000 yuan; On the other hand, the printer of this type also can only be used for printing official document, and general purposes cannot meet.
Summary of the invention
Fundamental purpose of the present invention is to provide a kind of developer that may be used for the M box of common CMYK tetra-look laser development equipment.
Another object of the present invention is to provide the manufacture method of above-mentioned developer.
Developer for CMYK tetra-look laser development equipment provided by the invention, comprises the binding resin of 86 to 92 parts, the bronze red pigment of 5 to 6 parts and the magenta pigment of 0.1 to 1.5 part by weight.
From such scheme, central scope of the present invention is with bronze red pigment for mass-tone material, with magenta pigment for auxiliary toning colorant, and by rational weight proportion, finally obtains the developer that color developing effect is consistent with standard official document color developing effect.Wherein, the model of bronze red pigment is PR53:1, and magenta pigment does not then specifically limit, and its model can select PR122, PR269 etc., when practical application, and can also the corresponding increase or reduce its proportioning weight according to the form and aspect of magenta pigment chosen.In the application testing of reality, this developer is put in laser printer corresponding to model, such as Ricoh's commercial production type laser printer, after this developer is encased in the M toner cartridge in CMYK tetra-look printer, the official document printed can get the nod.In addition, developer provided by the invention also has a very outstanding advantage, and namely this developer is after being encased in laser printer corresponding to model, and it can also be used for common office picture and text process, this adds increased the versatility of developer, use convenient.
A preferred scheme is, by weight, developer also comprises the release agent of 1 to 5 part.
From such scheme, the major function of release agent plays demoulding effect to developer when fixing, avoids the developer of melting to be bonded on fixing roller.Particularly, release agent can select one or more in Tissuemat E, polypropylene wax, paraffin, Fischer-Tropsch wax, oxidized polyethlene wax, montanic acid ester type waxes, palm wax, microcrystalline wax, rice wax or fatty acid wax.Find after test, when release agent is at 1 to 5 part, stripping result is better.
A preferred scheme is, by weight, developer also comprises the charge adjusting agent of 0.5 to 2 part, and the color of charge adjusting agent is white or colourless.
From such scheme, charge adjusting agent generally with electronegativity or electropositivity, electrically consistent in order to the machine foresees with corresponding model, actual when using, electrically should carry out certain selection to charge adjusting agent.Particularly, electronegativity charge control agent can for containing the azo dyes of chromium, Monoazo metal complex or chelate compound, metallic salicylic acid compound, metal-organic complex containing aromatic hydroxy-carboxylic or aromatic dicarboxylic acid; Positive charge control agent can be fatty acid metal salts, salt, tributyl benzyl ammonium-1-hydroxyl-4-naphthol sulfonate or TBuA tetrafluoroborate containing quaternary amine.In addition, find after experiment, when the consumption of charge control agent controls when 0.5 to 2 weight portion, the effect of charge control agent is better.In addition, because the most basic improvement place of the present invention applies bronze red pigment and magenta pigment, and its color developing effect is for particularly crucial goal of the invention, find after experiment test, when the color of charge control agent is white or colourless, it is minimum on the impact of developer, avoiding problems the impact of other factors on developer color developing effect, adds the stability of developer color developing effect.
A preferred scheme is, binding resin is styrene-acrylic resin and/or alkyd resin.
From such scheme, the binding resin in developer can be various thermoplastic resin, and cardinal rule is that binding resin should match with the fixing temperature of corresponding printer, and not easily produces bottom ash.This programme is preferably styrene-acrylic resin and alkyd resin, wherein, vibrin can select the vibrin of linear polyester resin or low crosslinking degree, vibrin is the polyester that dicarboxylic acids and dibasic alcohol or dihydric phenol are obtained by reacting, wherein dicarboxylic acids is phthalic acid, m-phthalic acid, terephthalic acid (TPA), hexane diacid or succinic acid, dibasic alcohol is ethylene glycol, propylene glycol, butylene glycol, hexylene glycol or cyclohexanediol, and dihydric phenol is p-dihydroxy-benzene, catechol, resorcinol or bisnaphthol.In addition, because the market price of styrene-acrylic resin is lower, the scheme being therefore used alone styrene-acrylic resin significantly can reduce the cost of developer.
A preferred scheme is that developer also comprises small particle diameter aerosil, and the mean grain size of small particle diameter aerosil is 7 nanometer to 14 nanometers, and small particle diameter aerosil is hydrophobicity aerosil.
From such scheme, silicon dioxide can improve the mobility of developer, and hydrophobicity can promote the flowing property of developer further, the better effects if of print quality.
A preferred scheme is, developer also comprises middle particle diameter aerosil, and the mean grain size of middle particle diameter aerosil is 20 nanometer to 50 nanometers, and middle particle diameter aerosil is hydrophobicity aerosil.
From such scheme, small particle diameter aerosil and middle particle diameter aerosil can be used alone or merge use.Small particle diameter silica flour (aerosil) and middle particle diameter silica flour with the use of being to make the printer of the carried charge of developer and mobility and specific model more adapt to, such as Ricoh's commercial production type printer C5110S.Meanwhile, such scheme can increase persistence and the stability of developer.
A preferred scheme is, binding resin is styrene-acrylic resin, styrene-acrylic resin is 90.2 parts, magenta pigment is 0.8 part, bronze red pigment is 5 parts, and developer also comprises 3 parts of polypropylene waxes, 1 part of charge control agent, 0.4 part of small particle diameter aerosil, particle diameter aerosil, 0.6 part of titania and 0.2 part of zinc stearate in 1.0 parts.
From such scheme, after the test repeatedly to the proportioning of developer component on Ricoh commercial production type printer C5110S, the color developing effect of aforementioned proportion is very good, reaches the accreditation of client.Zinc stearate has lubrication, can reduce developer and glue bulging phenomenon, and adding of titania has been the effect of stable electricity, make powder under various circumstances carried charge stablize.It should be noted that, zinc stearate and titania need to consider according to different printers, the need of the ratio of adding and add, to achieve good effect after adopting this scheme in the printer of above-mentioned model.
The preparation method of developer provided by the invention comprises the following steps: blend step: by weight, 86 to 92 parts of binding resins, 5 to 6 parts of bronze red pigment, 0.1 to 1.5 part of magenta pigment, remover, charge adjusting agents are mixed in mixer, obtains developer master batch blend; Melting mixing: the developer master batch blend obtained melting mixing at the temperature of double screw extrusion machine at 110 to 140 degrees Celsius is become mixing thing; Cooling step: mixing thing is cooled to room temperature; Crushing and classification: cooled mixing thing is pulverized also classification through airslide disintegrating mill and obtained the developer precursor granule of 7 microns to 15 microns; Mix afterwards and sieve: in above-mentioned developer precursor granule, adding adjuvant, mixed at high speed in a in a henschel mixer, then by ultrasound wave vibrosieve, obtaining finished product developer.
From such scheme, preparation process is easy, reasonable, is suitable for large-scale commercial production.
A preferred scheme is, binding resin is styrene-acrylic resin and/or alkyd resin; Charge adjusting agent is 0.5 to 2 part, and the color of charge adjusting agent is white or colourless; Release agent is 1 to 5 part.
A preferred scheme is, in crushing and classification step, adjuvant comprises hydrophobic aerosil, zinc stearate and titania; Aerosil comprises small particle diameter aerosil and/or middle particle diameter aerosil, wherein, the mean grain size of small particle diameter aerosil is between 7 nanometer to 14 nanometers, and the mean grain size of middle particle diameter aerosil is between 20 nanometer to 50 nanometers.
Embodiment
Developer of the present invention is mainly used in CMYK tetra-look laser development equipment, and by weight, developer of the present invention is red developer, and it comprises the binding resin of 86 to 92 parts, the bronze red pigment of 5 to 6 parts, the magenta pigment of 0.1 to 1.5 part.Preferably, developer also comprises the release agent of 1 to 5 part, also comprises the charge adjusting agent of 0.5 to 2 part in another preferred version, and the color of charge adjusting agent is white or colourless.Binding resin is styrene-acrylic resin and/or alkyd resin.Preferably, developer also comprises small particle diameter aerosil and middle particle diameter aerosil, wherein, the mean grain size of small particle diameter aerosil is 7 nanometer to 14 nanometers, the mean grain size of middle particle diameter aerosil is 20 nanometer to 50 nanometers, and small particle diameter aerosil and middle particle diameter aerosil are hydrophobicity aerosil.
The preparation method of developer provided by the invention comprises the following steps.
First perform blend step: by weight, 86 to 92 parts of binding resins, 5 to 6 parts of bronze red pigment, 0.1 to 1.5 part of magenta pigment, 1 to 5 part of remover, 0.5 to 2 part of charge adjusting agent are mixed in mixer, obtains developer master batch blend.
Then melting mixing is performed: the developer master batch blend obtained melting mixing at the temperature of double screw extrusion machine at 110 to 140 degrees Celsius is become mixing thing.
Then cooling step is performed: mixing thing is cooled to room temperature.
Then crushing and classification step is performed: cooled mixing thing is pulverized also classification through airslide disintegrating mill and obtained the developer precursor granule of 7 microns to 15 microns.
Mixed and sifting step after finally performing: add adjuvant in above-mentioned developer precursor granule, mixed at high speed in a in a henschel mixer, then by ultrasound wave vibrosieve, obtain finished product developer.Adjuvant can be titania and zinc stearate.
According to the manufacture method of developer above, obtain 4 groups of specific embodiments, all give the proportional quantity (by weight) of styrene-acrylic resin, magenta pigment, bronze red pigment, polypropylene (PP) wax, charge control agent, small particle diameter aerosil (silica flour), middle particle diameter aerosil, titania and zinc stearate in each example.Form is below obtained after these data are gathered.
The sample of the developer obtained according to above-mentioned four embodiment proportioning situations is through Ricoh commercial production type printer C5110S printing test.Result shows, embodiment 3 is completely the same with government standard official document color, and although embodiment 1, embodiment 2 and embodiment 4 also can be satisfied the demand, but compared to the color developing effect of embodiment 3, the color developing effect of embodiment 1 and embodiment 2 is partially yellow and the color developing effect of embodiment 4 is partially red partially dark.Visible, on the basis of protection domain provided by the invention, according to the printer of concrete different model, can adjust the optimum proportioning embodiment of developer, to obtain best color developing effect.
Finally it should be noted that; the invention is not restricted to above-mentioned embodiment; such as choose the release agent that other is applicable to, add the aerosil of other average particle size range, choose the design of the adjuvant of other type etc. also within claims of the present invention.
Claims (10)
1. developer, for CMYK tetra-look laser development equipment, by weight, comprising:
The binding resin of 86 to 92 parts;
The bronze red pigment of 5 to 6 parts;
The magenta pigment of 0.1 to 1.5 part.
2. developer according to claim 1, is characterized in that:
By weight, described developer also comprises the release agent of 1 to 5 part.
3. developer according to claim 1, is characterized in that:
By weight, described developer also comprises the charge adjusting agent of 0.5 to 2 part, and the color of described charge adjusting agent is white or colourless.
4. developer according to claim 1, is characterized in that:
Described binding resin is styrene-acrylic resin and/or alkyd resin.
5. the developer according to any one of Claims 1-4, is characterized in that:
Described developer also comprises small particle diameter aerosil, and the mean grain size of described small particle diameter aerosil is 7 nanometer to 14 nanometers, and described small particle diameter aerosil is hydrophobicity aerosil.
6. the developer according to any one of Claims 1-4, is characterized in that:
Described developer also comprises middle particle diameter aerosil, and the mean grain size of described middle particle diameter aerosil is 20 nanometer to 50 nanometers, and described middle particle diameter aerosil is hydrophobicity aerosil.
7. developer according to claim 1, is characterized in that:
Described binding resin is styrene-acrylic resin, described styrene-acrylic resin is 90.2 parts, described magenta pigment is 0.8 part, described bronze red pigment is 5 parts, and described developer also comprises 3 parts of polypropylene waxes, 1 part of charge control agent, 0.4 part of small particle diameter aerosil, particle diameter aerosil, 0.6 part of titania and 0.2 part of zinc stearate in 1.0 parts.
8. the preparation method of developer, comprises the following steps:
Blend step: by weight, mixes 86 to 92 parts of binding resins, 5 to 6 parts of bronze red pigment, 0.1 to 1.5 part of magenta pigment, remover, charge adjusting agents, obtains developer master batch blend in mixer;
Melting mixing: the developer master batch blend obtained melting mixing at the temperature of double screw extrusion machine at 110 to 140 degrees Celsius is become mixing thing;
Cooling step: mixing thing is cooled to room temperature;
Crushing and classification: cooled mixing thing is pulverized also classification through airslide disintegrating mill and obtained the developer precursor granule of 7 microns to 15 microns;
Mix afterwards and sieve: in above-mentioned developer precursor granule, adding adjuvant, mixed at high speed in a in a henschel mixer, then by ultrasound wave vibrosieve, obtaining finished product developer.
9. the preparation method of developer according to claim 8, is characterized in that:
Described binding resin is styrene-acrylic resin and/or alkyd resin;
Described charge adjusting agent is 0.5 to 2 part, and the color of described charge adjusting agent is white or colourless;
Described release agent is 1 to 5 part.
10. the preparation method of developer according to claim 8, is characterized in that:
In described crushing and classification step, described adjuvant comprises hydrophobic aerosil, zinc stearate and titania;
Described aerosil comprises small particle diameter aerosil and/or middle particle diameter aerosil, wherein, the mean grain size of small particle diameter aerosil is between 7 nanometer to 14 nanometers, and the mean grain size of middle particle diameter aerosil is between 20 nanometer to 50 nanometers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510562486.2A CN105116699A (en) | 2015-09-07 | 2015-09-07 | Developing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510562486.2A CN105116699A (en) | 2015-09-07 | 2015-09-07 | Developing agent and preparation method thereof |
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| CN105116699A true CN105116699A (en) | 2015-12-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510562486.2A Pending CN105116699A (en) | 2015-09-07 | 2015-09-07 | Developing agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109141288A (en) * | 2018-11-06 | 2019-01-04 | 中国航空工业集团公司沈阳空气动力研究所 | A kind of developer and preparation method thereof for aircraft icing ice shape 3-D scanning |
| CN110083023A (en) * | 2019-05-13 | 2019-08-02 | 邯郸汉光办公自动化耗材有限公司 | A kind of bronze red ink powder and preparation method thereof being exclusively used in official document printing |
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| CN1841217A (en) * | 2005-03-31 | 2006-10-04 | 施乐公司 | Particle external surface additive compositions |
| CN101051194A (en) * | 2006-04-05 | 2007-10-10 | 施乐公司 | Developer |
| CN101196699A (en) * | 2006-12-06 | 2008-06-11 | 北京国信防伪技术有限公司 | Carbon powder especially for credit bill and certificate and its manufacturing process |
| CN101788774A (en) * | 2009-11-13 | 2010-07-28 | 无锡佳腾磁性粉有限公司 | Red durability anti-counterfeit developer of colored laser printer and preparation method thereof |
| CN102819200A (en) * | 2012-07-10 | 2012-12-12 | 珠海思美亚碳粉有限公司 | Toner for biobased electron photography |
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2015
- 2015-09-07 CN CN201510562486.2A patent/CN105116699A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1841217A (en) * | 2005-03-31 | 2006-10-04 | 施乐公司 | Particle external surface additive compositions |
| CN101051194A (en) * | 2006-04-05 | 2007-10-10 | 施乐公司 | Developer |
| CN101196699A (en) * | 2006-12-06 | 2008-06-11 | 北京国信防伪技术有限公司 | Carbon powder especially for credit bill and certificate and its manufacturing process |
| CN101788774A (en) * | 2009-11-13 | 2010-07-28 | 无锡佳腾磁性粉有限公司 | Red durability anti-counterfeit developer of colored laser printer and preparation method thereof |
| CN102819200A (en) * | 2012-07-10 | 2012-12-12 | 珠海思美亚碳粉有限公司 | Toner for biobased electron photography |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109141288A (en) * | 2018-11-06 | 2019-01-04 | 中国航空工业集团公司沈阳空气动力研究所 | A kind of developer and preparation method thereof for aircraft icing ice shape 3-D scanning |
| CN110083023A (en) * | 2019-05-13 | 2019-08-02 | 邯郸汉光办公自动化耗材有限公司 | A kind of bronze red ink powder and preparation method thereof being exclusively used in official document printing |
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Application publication date: 20151202 |
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