CN105113288B - A kind of method for carrying out natural dyeing to fiber using carotenoid - Google Patents
A kind of method for carrying out natural dyeing to fiber using carotenoid Download PDFInfo
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- CN105113288B CN105113288B CN201510564618.5A CN201510564618A CN105113288B CN 105113288 B CN105113288 B CN 105113288B CN 201510564618 A CN201510564618 A CN 201510564618A CN 105113288 B CN105113288 B CN 105113288B
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- 235000021466 carotenoid Nutrition 0.000 title claims abstract description 96
- 150000001747 carotenoids Chemical class 0.000 title claims abstract description 96
- 239000000835 fiber Substances 0.000 title claims abstract description 48
- 238000004043 dyeing Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000000243 solution Substances 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims abstract description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011259 mixed solution Substances 0.000 claims abstract description 19
- 244000000626 Daucus carota Species 0.000 claims abstract description 17
- 235000002767 Daucus carota Nutrition 0.000 claims abstract description 17
- 244000111489 Gardenia augusta Species 0.000 claims abstract description 17
- 235000018958 Gardenia augusta Nutrition 0.000 claims abstract description 17
- 238000000605 extraction Methods 0.000 claims abstract description 17
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims abstract description 16
- 240000003768 Solanum lycopersicum Species 0.000 claims abstract description 16
- 230000000694 effects Effects 0.000 claims abstract description 16
- 238000010186 staining Methods 0.000 claims abstract description 13
- 238000005406 washing Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 102000004190 Enzymes Human genes 0.000 claims abstract description 10
- 108090000790 Enzymes Proteins 0.000 claims abstract description 10
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 10
- 230000002401 inhibitory effect Effects 0.000 claims abstract description 10
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 9
- 206010033546 Pallor Diseases 0.000 claims abstract description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 18
- 229910001415 sodium ion Inorganic materials 0.000 claims description 18
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 15
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 15
- 230000033228 biological regulation Effects 0.000 claims description 8
- 102000004169 proteins and genes Human genes 0.000 claims description 7
- 108090000623 proteins and genes Proteins 0.000 claims description 7
- 229920003043 Cellulose fiber Polymers 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 238000004040 coloring Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 25
- 235000013311 vegetables Nutrition 0.000 description 12
- 235000005979 Citrus limon Nutrition 0.000 description 7
- 244000131522 Citrus pyriformis Species 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 229930002875 chlorophyll Natural products 0.000 description 3
- 235000019804 chlorophyll Nutrition 0.000 description 3
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N Indigo Chemical compound N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- 244000088415 Raphanus sativus Species 0.000 description 2
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- JMEVHYCNAPFOAB-UHFFFAOYSA-N 2-(3-hydroxy-5-sulfo-1H-indol-2-yl)-3-oxoindole-5-sulfonic acid Chemical compound Oc1c([nH]c2ccc(cc12)S(O)(=O)=O)C1=Nc2ccc(cc2C1=O)S(O)(=O)=O JMEVHYCNAPFOAB-UHFFFAOYSA-N 0.000 description 1
- 240000002900 Arthrospira platensis Species 0.000 description 1
- 235000016425 Arthrospira platensis Nutrition 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 244000170916 Paeonia officinalis Species 0.000 description 1
- 235000006484 Paeonia officinalis Nutrition 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 229930003935 flavonoid Chemical class 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000023597 hemostasis Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003053 immunization Effects 0.000 description 1
- 238000002649 immunization Methods 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000001656 lutein Substances 0.000 description 1
- 235000012680 lutein Nutrition 0.000 description 1
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 description 1
- 229960005375 lutein Drugs 0.000 description 1
- ORAKUVXRZWMARG-WZLJTJAWSA-N lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C ORAKUVXRZWMARG-WZLJTJAWSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940082787 spirulina Drugs 0.000 description 1
- 238000003815 supercritical carbon dioxide extraction Methods 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 150000003505 terpenes Chemical group 0.000 description 1
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Coloring (AREA)
- Cosmetics (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The present invention provides a kind of method for carrying out natural dyeing to fiber using carotenoid, comprises the following steps：(1) fresh carrot, tomato and cape jasmine are cleaned up, in 95 100 DEG C of water the activity of blanching 30s inhibitory enzymes, taking-up dry, stripping and slicing is smashed to pieces, gunk is formed, gunk is placed in supercritical carbon dioxide equipment, it is extracted to obtain Extraction of carotenoid pigment liquid；(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in metal ion solution, stirs to form mixed solution, the pH value for adjusting mixed solution with citric acid solution obtains the carotenoid dye liquor of color protection to 10 11；(3) with bath raio 1:50, the fiber of activity pretreatment is immersed in the carotenoid dye liquor of color protection prepared by step (2), taken out after direct staining, fixation washing and drying, obtains the fiber dyed using carotenoid.This colouring method cost is low, dyeability and good color fastness, green.
Description
Technical field：
The invention belongs to textile material technical field, and in particular to one kind is naturally contaminated fiber using carotenoid
The method of color.
Background technology：
21 century is one and advocates green, the safe and environment-friendly new century, ecological textile more and more welcomed by the people
With like, therefore increasing consumer shows special preference to the textile using green processing technologies production.Vegetable colour is
Principal item in natural dye, refer to the dyestuff extracted in the flower from noon, stem, leaf, fruit or core, due to this kind of dye
Material is derived from naturally, in production, processing and using causing environmental pollution, and the work to human body to health care, medication in the middle part of process
With.
The material that dyeing can be used in nature has in 3000-5000, and wherein vegetable colour chromatogram is more complete, can obtain purple
Color, red, yellow, green, brown, blueness, black etc., it can be used for the dyeing of the protein fibres such as silk, wool.Plant contaminates
Material can be divided into indoles, flavonoid class, quinones, tannin, carotenoid, chlorophyll and alkaloid according to its chemical composition.Thus
It can be seen that because the structure of natural plant dye is relative complex, different vegetable colours has different dyeing mechanisms, many dyestuffs
Dyeing mechanism still need exploration, and vegetable colour exist dyestuff content it is low, recovery rate is low, dyeing is complicated, dyeing is heavy
It is existing that property is poor, the problem such as low with colorfastness to rubbing of soaping.
Dyeing of a kind of chlorophyll to modified fabric disclosed in Chinese patent CN 103485196A (publication date 2014.1.1)
Technique, cation-modified polyester/cotton fabric is impregnated in the dye liquor containing chlorophyll and sodium sulphate and dyed, obtain tinting strength, tinting power and
The excellent product of color fastness, it is a kind of environmental type dyeing.Chinese patent CN 103080413B (publication date
2013.5.1) the disclosed method for carrying out natural dyeing to fiber using indigo plant, by the water containing liquid pigment, pulverized limestone and
Air concentrates the insoluble pigment to be formed and soluble pigment is decomposed into after microbial fermentation, and fiber then is immersed into soluble indigo
Fiber is dyed in blue vegetable colour solution, it is dyed after fiber and air contact after indigo blue,soluble plant is become again
Into insoluble pigment, product is finally given.The dyeing rate of the product is fast, good color fastness, and color is not easy washed colour fading, can prevent
Sealing pollutes or the generation of dermatitis., can be according to vegetable colour in order to improve the purity of dyestuff from above-mentioned prior art
Chemical composition concentrate dyeing arrangement is carried out to fabric, and aid in other means improve vegetable colour rate of dyeing and color jail
Degree, obtains Green Textiles best in quality.
Carotenoid falls within a kind of branch in vegetable colour, and it is the more natural colour of generally existing in nature
Element, raw material sources are extensive, material cost relative moderate, many natural plants for example spirulina, green vegetables, carrot, cape jasmine, kind
Carotenoid all be present in eggplant etc..Carotenoid be the hydrocarbon that is made up of 8 isoprenoid units and its they
Oxidized derivatives, i.e. carrotene and lutein general designation.The micro- liposoluble substance of carotenoid, being dissolved in acetone, chloroform etc. has
Solvent, pure product are in peony or kermesinus, glossiness rhombohedron or crystalline powder, but to oxygen,
Heat and photo-labile, therefore food coloring is also used primarily as at present, it is less in the application of dyeing and weaving industry.
The content of the invention：
The technical problem to be solved in the present invention is to provide a kind of side for carrying out natural dyeing to fiber using carotenoid
Method, using fresh carrot, tomato and cape jasmine as raw material, class is obtained recklessly through supercritical carbon dioxide extraction method and color protection technology
Radish element extract solution, then the fiber of activity pretreatment is obtained into the fiber dyed using carotenoid through direct staining technique.This
The natural dyeing method of invention can be rapidly and efficiently by stock-dye, color fastness is high, and the washing that will not be cleaned is faded, and green
Environmental protection, there is health-care efficacy.
In order to solve the above technical problems, the technical scheme is that：
A kind of method for carrying out natural dyeing to fiber using carotenoid, it is characterised in that：Comprise the following steps：
(1) fresh carrot, tomato and cape jasmine are cleaned up, the work of blanching 30s inhibitory enzymes in 95-100 DEG C of water
Property, taking-up dried, and stripping and slicing is smashed to pieces, forms gunk, and gunk is placed in supercritical carbon dioxide equipment, extracted
To Extraction of carotenoid pigment liquid；
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in metal ion solution, stirs to form mixing
Solution, the pH value for adjusting mixed solution with citric acid solution obtain the carotenoid dye liquor of color protection to 10-11；
(3) with bath raio 1:50, the fiber of activity pretreatment is immersed to the carotenoid dye liquor of color protection prepared by step (2)
In, taken out after direct staining, fixation washing and drying, obtain the fiber dyed using carotenoid.
As the preferred of above-mentioned technical proposal, in the step (1), the weight ratio of carrot, tomato and cape jasmine is 1:0.5-
1:0.3-0.7。
As the preferred of above-mentioned technical proposal, in the step (1), extraction process is pressure 250-300kg/cm2, extraction
Temperature is 50-55 DEG C, recovery rate 96-98%.
As the preferred of above-mentioned technical proposal, in the step (2), metal ion solution is monovalence sodium ion and divalent magnesium
The solution of ion, monovalence sodium ion and divalent magnesium from mol ratio be 1:1.
As the preferred of above-mentioned technical proposal, in the step (2), the concentration of metal ions of metal ion solution is 0.1-
0.3mol/L。
As the preferred of above-mentioned technical proposal, in the step (2), carotenoid in the carotenoid dye liquor of color protection
Content is 75-80%.
As the preferred of above-mentioned technical proposal, in the step (3), fiber is in cellulose fiber peacekeeping protein fibre
It is a kind of.
As the preferred of above-mentioned technical proposal, in the step (3), the fiber of activity pretreatment makes through plasma technique
The fiber of pretreatment.
As the preferred of above-mentioned technical proposal, in the step (3), the technique of direct staining is 25-35 DEG C of temperature, the time
For 80-100min.
Compared with prior art, the invention has the advantages that：
(1) fresh carrot, tomato and cape jasmine are used in the present invention, and as primary raw material, carrot and tomato are all more
Extensive vegetables and fruits, material source is extensive, and cost is cheap, can reduce the cost of vegetable colour, and carrot, tomato and cape jasmine contain
Carotenoids stability it is good, inoxidizability is high, and can be contacted by the long-time with skin, penetrates into skin surface,
The immunization of infiltration is improved, and the uranidin contained in cape jasmine has the physiological actions such as calm, hemostasis, anti-inflammatory,
(2) present invention is extracted using critical abstraction technique to the carotenoid in raw material, and extraction efficiency is high, will not
Active ingredient is caused damage, and organic solvent-free remains, and prevents from damaging the Green performance of product in processing technology is extracted.
(3) present invention using a small amount of metal ion to carotenoid carry out color protection, prevent process and use or in
The failure of carotenoid is caused, improves the dyeability and color fastness of product.
(4) present invention carries out dyeing processing using the carotenoid of wide material sources to fiber, is contaminated with traditional vegetable colour
Form and aspect ratio, cost is low, cheap, and passes through the pretreatment to carotenoid and fiber, the dyeability of the product of raising
And color fastness, meet production and the requirement used, and final products are green, it is free of a burden to environment.
Embodiment：
The present invention is described in detail below in conjunction with specific embodiment, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1：
(1) it is 1 by weight ratio:0.5:0.3 fresh carrot, tomato and cape jasmine cleans up, and is floated in 95 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 250kg/cm2Pressure and 50 DEG C at a temperature of, it is extracted to 96% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.1mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 10, the content for obtaining carotenoid is the carotenoid dye liquor of 75% color protection.
(3) with bath raio 1:50, the protein fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 80min at 25 DEG C, take out, fixation washing and drying, obtain using carotenoids uniformly dyeing
The fiber of color.
Embodiment 2：
(1) it is 1 by weight ratio:1:0.7 fresh carrot, tomato and cape jasmine cleans up, and is floated in 100 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 300kg/cm2Pressure and 55 DEG C at a temperature of, it is extracted to 98% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.3mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 11, the content for obtaining carotenoid is the carotenoid dye liquor of 80% color protection.
(3) with bath raio 1:50, the protein fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 100min at 35 DEG C, take out, fixation washing and drying, obtain using carotenoid
The fiber of dyeing.
Embodiment 3：
(1) it is 1 by weight ratio:0.6:0.5 fresh carrot, tomato and cape jasmine cleans up, and is floated in 95 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 280kg/cm2Pressure and 52 DEG C at a temperature of, it is extracted to 97% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.2mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 10.5, the content for obtaining carotenoid is the carotenoids uniformly dyeing of 77% color protection
Liquid.
(3) with bath raio 1:50, the cellulose fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 90min at 30 DEG C, take out, fixation washing and drying, obtain using carotenoids uniformly dyeing
The fiber of color.
Embodiment 4：
(1) it is 1 by weight ratio:0.8:0.4 fresh carrot, tomato and cape jasmine cleans up, and is floated in 99 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 290kg/cm2Pressure and 54 DEG C at a temperature of, it is extracted to 96% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.2mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 10.3, the content for obtaining carotenoid is the carotenoid of 75-80% color protection
Dye liquor.
(3) with bath raio 1:50, the protein fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 85min at 29 DEG C, take out, fixation washing and drying, obtain using carotenoids uniformly dyeing
The fiber of color.
Embodiment 5：
(1) it is 1 by weight ratio:0.6:0.6 fresh carrot, tomato and cape jasmine cleans up, and is floated in 97 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 270kg/cm2Pressure and 52 DEG C at a temperature of, it is extracted to 98% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.1mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 10, the content for obtaining carotenoid is the carotenoid dye liquor of 77% color protection.
(3) with bath raio 1:50, the cellulose fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 95min at 25 DEG C, take out, fixation washing and drying, obtain using carotenoids uniformly dyeing
The fiber of color.
Embodiment 6：
(1) it is 1 by weight ratio:0.8:0.6 fresh carrot, tomato and cape jasmine cleans up, and is floated in 95 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 300kg/cm2Pressure and 50 DEG C at a temperature of, it is extracted to 97% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.1mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 10, the content for obtaining carotenoid is the carotenoid dye liquor of 75% color protection.
(3) with bath raio 1:50, the cellulose fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 80-100min at 25-35 DEG C, take out, fixation washing and drying, obtain using class recklessly
The fiber of radish uniformly dyeing color.Embodiment 7：
(1) it is 1 by weight ratio:0.8:0.7 fresh carrot, tomato and cape jasmine cleans up, and is floated in 95 DEG C of water
The activity of 30s inhibitory enzymes is scalded, taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in into supercritical carbon dioxide
In equipment, in 300kg/cm2Pressure and 55 DEG C at a temperature of, it is extracted to 98% carotenoid, obtain carotenoid and carry
Take liquid.
(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in 0.2mol/L monovalence sodium ion and divalence magnesium ion
Solution in, wherein the mol ratio of monovalence sodium ion and divalence magnesium ion be 1:1, stir to form mixed solution, use lemon
For the pH value of acid solution regulation mixed solution to 10, the content for obtaining carotenoid is the carotenoid dye liquor of 77% color protection.
(3) with bath raio 1:50, the protein fibre of plasma technique pretreatment is immersed to the color protection of step (2) preparation
In carotenoid dye liquor, through direct staining 95min at 32 DEG C, take out, fixation washing and drying, obtain using carotenoids uniformly dyeing
The fiber of color.
After testing, the absorbance of the carotenoid dye liquor of color protection prepared by embodiment 1-6 and use carotenoids uniformly dyeing
The dye-uptake of the fiber of color and the result of color fastness are as follows：
As seen from the above table, the absorbance of carotenoid dye liquor prepared by the present invention is good, and is dyed using carotenoid
Fiber dye-uptake it is high, good color fastness.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause
This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (7)
- A kind of 1. method for carrying out natural dyeing to fiber using carotenoid, it is characterised in that：Comprise the following steps：(1) fresh carrot, tomato and cape jasmine are cleaned up, the activity of blanching 30s inhibitory enzymes in 95-100 DEG C of water, Taking-up is dried, and stripping and slicing is smashed to pieces, forms gunk, gunk is placed in supercritical carbon dioxide equipment, extracted to obtain Extraction of carotenoid pigment liquid；(2) Extraction of carotenoid pigment liquid prepared by step (1) is placed in metal ion solution, stirs to form mixed solution, With the pH value of citric acid solution regulation mixed solution to 10-11, the carotenoid dye liquor of color protection is obtained；(3) with bath raio 1:50, the fiber of activity pretreatment is immersed in the carotenoid dye liquor of color protection prepared by step (2), warp Taken out after direct staining, fixation washing and drying, obtain the fiber dyed using carotenoid；Wherein, in the step (2), metal ion solution is the solution of monovalence sodium ion and divalence magnesium ion, monovalence sodium ion With divalent magnesium from mol ratio be 1:1, in the step (3), the fiber of activity pretreatment is pre-processed through plasma technique Fiber.
- 2. a kind of method for being carried out natural dyeing to fiber using carotenoid according to claim 1, its feature are existed In：In the step (1), the weight ratio of carrot, tomato and cape jasmine is 1:0.5-1:0.3-0.7.
- 3. a kind of method for being carried out natural dyeing to fiber using carotenoid according to claim 1, its feature are existed In：In the step (1), extraction process is pressure 250-300kg/cm2, Extracting temperature is 50-55 DEG C, recovery rate 96- 98%.
- 4. a kind of method for being carried out natural dyeing to fiber using carotenoid according to claim 1, its feature are existed In：In the step (2), the concentration of metal ions of metal ion solution is 0.1-0.3mol/L.
- 5. a kind of method for being carried out natural dyeing to fiber using carotenoid according to claim 1, its feature are existed In：In the step (2), the content of carotenoid is 75-80% in the carotenoid dye liquor of color protection.
- 6. a kind of method for being carried out natural dyeing to fiber using carotenoid according to claim 1, its feature are existed In：In the step (3), fiber is one kind in cellulose fiber peacekeeping protein fibre.
- 7. a kind of method for being carried out natural dyeing to fiber using carotenoid according to claim 1, its feature are existed In：In the step (3), the technique of direct staining is 25-35 DEG C of temperature, time 80-100min.
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| CN110004739B (en) * | 2019-04-22 | 2021-08-27 | 中原工学院 | Method for dyeing specific fibers by using leather vegetable tanning material |
| CN113756111B (en) * | 2021-10-08 | 2023-11-21 | 芽米科技(广州)有限公司 | Yellow lyocell fabric prepared by dyeing Blakeslea trispora fermentation extract and preparation method thereof |
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