CN105108374B - Nuclear power station main steam line automatic welding special welding wire - Google Patents

Nuclear power station main steam line automatic welding special welding wire Download PDF

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Publication number
CN105108374B
CN105108374B CN201510313717.6A CN201510313717A CN105108374B CN 105108374 B CN105108374 B CN 105108374B CN 201510313717 A CN201510313717 A CN 201510313717A CN 105108374 B CN105108374 B CN 105108374B
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China
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content
main steam
nuclear power
welding wire
steam line
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CN105108374A (en
Inventor
朱德才
刘以亮
王东
李予卫
梁健
贾军辉
彭杰
谭文良
谢静
康泽坛
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China General Nuclear Power Corp
China Nuclear Power Engineering Co Ltd
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China General Nuclear Power Corp
China Nuclear Power Engineering Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3026Mn as the principal constituent

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)

Abstract

The invention discloses a kind of nuclear power station main steam line automatic welding special welding wire, it includes following chemical composition:0.05~0.1wt% of C content, 0.7~1.0wt% of Si contents, 1~1.5wt% of Mn contents, P content≤0.02wt%, S content≤0.02wt%, Ni content≤1.29~1.50wt% of 0.15wt%, Cr content, Mo content < 0.15wt%, Cu content≤0.4wt%.Compared with prior art, the chemical composition and SA335 P11 main steam lines of nuclear power station main steam line automatic welding special welding wire deposited metal of the present invention are relatively, mechanical property is also superior to existing CHW 40CNH welding wires or suitable with existing CHW 40CNH welding wires, therefore it is significantly increased using the anti-FAC performances of its SA335 P11 main steam line weld seam completed, quality of the nuclear power station main steam line weld seam during operation is ensure that, the safe operation to nuclear power generating sets is significant.

Description

Nuclear power station main steam line automatic welding special welding wire
Technical field
The present invention relates to nuclear power station main steam line automatic welding special welding material, especially one kind can be reduced substantially The special welding wire of FAC corrosion rates.
Background technology
Medium temperature is high in the secondary circuit main steam delivery pipe of nuclear island of nuclear power station, flow velocity is fast, big flow (is about thermoelectricity 1.7~1.9 times), it can produce because " Flow accelerated corrosion (FAC) " is existing caused by the flowing velocity of conveying steam and water is higher As, i.e. carbon steel pipe internal surface is in the case where substantial amounts of, swiftly flowing carbonated drink is washed away, inwall have defencive function oxide layer deterioration, It is thinning, make steel matrix variation, the increased phenomenon of annual corrosion rate.Flow accelerated corrosion phenomenon is likely to result in pipe explosion accident when serious, Therefore the anti-carbonated drink erosion property of raising delivery pipe is needed.
According to existing research data, FAC corrosion rate depends on medium temperature, flow velocity, pH value, electrode electricity in carbon steel The factor such as position, tubing alloying element, thermodynamics, wherein tubing alloying element can be by select steel grades to solve. Research has shown that, FAC corrosion rate can be substantially reduced after the Cr contents that particular range is added in carbon steel, " is thinned relatively Cr% relations in rate-steel " result of the test shows that, as the Cr content > 0.04% in carbon steel, FAC speed declines rapidly:Pipeline Corrosion rate of the material Cr contents at≤0.04% is higher, and corrosion rate is substantially suitable, it is assumed that be 1, with the increasing of Cr contents Plus, corrosion rate is gradually reduced;When Cr contents reach 0.2%, the relative velocity of corrosion is 0.2;When Cr contents reach 1% When, the relative velocity of corrosion is 0.045.SA335P11 main steam lines are exactly to develop in this context with higher anti-FAC The new steel grade of performance, its chemical composition and mechanical property is as shown in table 1, table 2.
Table 1, SA335P11 steel chemical compositions table/wt%
Table 2, SA335P11 steel mechanical property tables
The anti-FAC purposes of SA335P11 steel, it is desirable to which also there is certain content in matched welding material deposited metal Cr elemental compositions, so as to also have the Cr of certain content in weld metal, the weld metal part of such pipeline also has anti- FAC abilities.Due to chemistry can only be selected there is presently no the welding material special matched with SA335P11 steel, therefore in Construction of Nuclear Electricity Composition, mechanical property and the close CHW-40CNH welding wires of SA335P11 steel carry out the welding of SA335P11 steel.
CHW-40CNH welding wires are to the addition of Ni, Cr, Cu element in a kind of weathering steel welding wire, its chemical composition, for corruption Corrosion atmospheric environment.Chemical composition, the mechanical property of CHW-40CNH welding wires are as shown in table 3, though from table 3 it can be seen that its composition It is so close with SA335P11 steel, but still have bigger difference., it was also found that using CHW-40CNH welding wires in actual welding construction When welding SA335P11 steel, molten bath poor fluidity, similar to stainless steel welding stick, operates level requirement higher welder, is unfavorable for Welding quality is applied and improved to automatic welding technique.
Table 3, CHW-40CNH welding wires chemical composition (wt%), mechanical property table
In view of this, it is special it is necessory to provide that a kind of chemical composition and mechanical property and SA335P11 steel match completely Welding wire.
The content of the invention
It is an object of the invention to:A kind of chemical composition and mechanical property is provided and the welding of SA335P11 steel automatic welding is complete The special welding wire of matching, to ensure the demand of the engineering construction of nuclear power projects mass and follow-up operation maintenance.
In order to realize foregoing invention purpose, present inventor is through concentrating on studies and testing, it was found that a kind of chemistry into Divide and be best suitable for the material as SA335P11 steel automatic welding special welding wires, there is provided a kind of nuclear power SA335P11 steel is automatic accordingly Special welding wire is welded, it is to include the steel wire of following chemical composition:0.05~0.1wt% of C content, 0.7~1.0wt% of Si contents, 1~1.5wt% of Mn contents, P content≤0.02wt%, S content≤0.02wt%, Ni content≤0.15wt%, Cr content 1.29 ~1.50wt%, Mo content < 0.15wt%, Cu content≤0.4wt%.
Improved as one kind of nuclear power main steam automatic welding of pipelines special welding wire of the present invention, the deposited metal of the welding wire Including following chemical composition:C content 0.05wt%, Si content 0.82wt%, Mn content 1.26wt%, P content 0.013wt%, S Content 0.006wt%, Ni content 0.018wt%, Cr content 1.29wt%, Mo content 0.011wt%, Cu content 0.188wt%.
Improved as one kind of nuclear power main steam automatic welding of pipelines automatic welding special welding wire of the present invention, the rule of the welding wire Lattice are Φ 0.8mm.
Present invention also offers a kind of nuclear power main steam automatic welding of pipelines special welding wire, the deposited metal bag of the welding wire Include following chemical composition:C content 0.03wt%, Si content 0.90wt%, Mn content 1.19wt%, P content 0.013wt%, S contain Measure 0.006wt%, Ni content 0.016wt%, Cr content 1.32wt%, Mo content 0.011wt%, Cu content 0.242wt%.
Improved as one kind of nuclear power main steam automatic welding of pipelines special welding wire of the present invention, the specification of the welding wire is Φ 1.0mm。
Compared with prior art, the chemical composition of nuclear power main steam automatic welding of pipelines special welding wire deposited metal of the present invention With SA335P11 main steam lines relatively, mechanical property also superior to existing CHW-40CNH welding wires or with existing CHW- 40CNH welding wires quite, therefore are significantly increased using its anti-FAC performance for completing main steam line weld seam, it is ensured that nuclear power station Quality of the main steam line weld seam during operation, the safe operation to nuclear power generating sets is significant.It can be seen that, core of the present invention Electric main steam line automatic welding special welding wire is efficiently solved currently without the welding matched with SA335P11 main steam lines Problem of materials.
Embodiment
In order that goal of the invention, technical scheme and its advantageous effects of the present invention become apparent from, below in conjunction with accompanying drawing And embodiment, the present invention will be described in further detail.It should be appreciated that the specific reality described in this specification Apply mode to explain the present invention, be not intended to limit the present invention.
In order to coordinate with SA335P11 main steam lines steel, inventor has drawn nuclear power of the present invention through many experiments Chemical composition, the chemical composition of welding wire deposited metal and the mechanical property of SA335P11 main steam line steel automatic welding special welding wires Energy design load, as shown in Table 4-6.
Table 4, nuclear power station main steam line automatic welding special welding wire Design of Chemical Composition value/wt%
Table 5, nuclear power station main steam line automatic welding special welding wire deposited metal composition design load/wt%
Table 6, nuclear power station main steam line automatic welding special welding wire deposited metal mechanical property design load
When production is smelted, because of the limitation scope of silicone content in nuclear power station main steam line automatic welding special welding wire of the present invention Relative narrower, so, the smelting of steel ingot acquires a certain degree of difficulty, after by selecting high quality silicon iron material, then add the silicon of proper content Iron, has reached the purpose of increase alloy.
For copper-plating technique, because of nuclear power main steam pipeline automatic welding special welding wire element containing Cr of the present invention, with common Electroless copper replacement result it is poor, welding wire surface copper facing is bad, uneven, by experiment, uses electroplating technology instead and has reached reason Think effect.
After tested, according to two kinds of nuclear power main steam line automatic welding special welding wire deposited metals of the design production of the present invention Chemical composition and mechanical property are as shown in table 7-8.
Table 7, each embodiment welding wire deposited metal composition test result/wt%
Embodiment C Si Mn P S Ni Cr Mo Cu
Φ0.8mm 0.05 0.82 1.26 0.013 0.006 0.018 1.29 0.011 0.188
Φ1.0mm 0.03 0.90 1.19 0.013 0.006 0.016 1.32 0.011 0.242
Table 8, each embodiment welding wire deposited metal mechanical experimental results
Compared with prior art, nuclear power station main steam line automatic welding special welding wire deposited metal of the present invention chemistry into Divide with SA335P11 steel relatively, mechanical property is welded also superior to existing CHW-40CNH welding wires or with existing CHW-40CNH Silk quite, therefore is significantly increased using the anti-FAC performances of its SA335P11 main steam line weld seam completed, it is ensured that nuclear power Quality of station owner's jet chimney weld seam during operation, the safe operation to nuclear power generating sets is significant.It can be seen that, the present invention Nuclear power main steam pipeline automatic welding special welding wire is efficiently solved asks currently without the welding material matched with SA335P11 steel Topic.
The announcement and teaching of book according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula carries out appropriate change and modification.Therefore, the invention is not limited in embodiment disclosed and described above, to this Some modifications and changes of invention should also be as falling into the scope of the claims of the present invention.Although in addition, this specification In used some specific terms, but these terms are merely for convenience of description, do not constitute any limitation to the present invention.

Claims (5)

1. a kind of nuclear power station main steam line automatic welding special welding wire, it is characterised in that:The welding wire include it is following chemistry into Point:0.05~0.1wt% of C content, 0.7~1.0wt% of Si contents, 1~1.5wt% of Mn contents, P content≤0.02wt%, S contain Amount≤0.02wt%, Ni content≤1.29~1.50wt% of 0.15wt%, Cr content, Mo content < 0.15wt%, Cu content≤ 0.4wt%.
2. nuclear power station main steam line automatic welding special welding wire according to claim 1, it is characterised in that:The welding wire Deposited metal include following chemical composition:C content 0.05wt%, Si content 0.82wt%, Mn content 1.26wt%, P content 0.013wt%, S content 0.006wt%, Ni content 0.018wt%, Cr content 1.29wt%, Mo content 0.011wt%, Cu contain Measure 0.188wt%.
3. nuclear power station main steam line automatic welding special welding wire according to claim 2, it is characterised in that:The welding wire Specification be Φ 0.8mm.
4. a kind of nuclear power station main steam line automatic welding special welding wire, it is characterised in that:The deposited metal of the welding wire includes Following chemical composition:C content 0.03wt%, Si content 0.90wt%, Mn content 1.19wt%, P content 0.013wt%, S content 0.006wt%, Ni content 0.016wt%, Cr content 1.32wt%, Mo content 0.011wt%, Cu content 0.242wt%.
5. nuclear power station main steam line automatic welding special welding wire according to claim 4, it is characterised in that:The welding wire Specification be Φ 1.0mm.
CN201510313717.6A 2015-06-09 2015-06-09 Nuclear power station main steam line automatic welding special welding wire Active CN105108374B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106271205B (en) * 2016-08-31 2019-10-22 北京国电富通科技发展有限责任公司 A kind of alloy welding wire
CN109719418A (en) * 2018-12-31 2019-05-07 苏州新普新材料科技有限公司 Nuclear power 20 controls chromium steel special welding wire

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4273838A (en) * 1976-03-08 1981-06-16 Combustion Engineering, Inc. Weld metal resistant to neutron-bombardment embrittlement
JP2002336989A (en) * 2001-05-16 2002-11-26 Sumikin Welding Ind Ltd Welding material for seashore weather resistant steel
CN101664863A (en) * 2009-09-24 2010-03-10 湖北猴王焊材有限公司 Seawater corrosion resistant submerged arc welding wire
CN101670477A (en) * 2009-09-17 2010-03-17 胜利油田孚瑞特石油装备有限责任公司 Welding method of sulfureted hydrogen resistant underground heat-insulated oil pipe
CN103600178A (en) * 2013-11-27 2014-02-26 南车眉山车辆有限公司 High-strength solid wire made of weathering resistant steel through gas shielded welding

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4273838A (en) * 1976-03-08 1981-06-16 Combustion Engineering, Inc. Weld metal resistant to neutron-bombardment embrittlement
JP2002336989A (en) * 2001-05-16 2002-11-26 Sumikin Welding Ind Ltd Welding material for seashore weather resistant steel
CN101670477A (en) * 2009-09-17 2010-03-17 胜利油田孚瑞特石油装备有限责任公司 Welding method of sulfureted hydrogen resistant underground heat-insulated oil pipe
CN101664863A (en) * 2009-09-24 2010-03-10 湖北猴王焊材有限公司 Seawater corrosion resistant submerged arc welding wire
CN103600178A (en) * 2013-11-27 2014-02-26 南车眉山车辆有限公司 High-strength solid wire made of weathering resistant steel through gas shielded welding

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