CN105107367B - It is a kind of to use the method that carbide slag is raw material production desulfurizing agent - Google Patents
It is a kind of to use the method that carbide slag is raw material production desulfurizing agent Download PDFInfo
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- CN105107367B CN105107367B CN201510587846.4A CN201510587846A CN105107367B CN 105107367 B CN105107367 B CN 105107367B CN 201510587846 A CN201510587846 A CN 201510587846A CN 105107367 B CN105107367 B CN 105107367B
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Abstract
The invention discloses a kind of using the method that carbide slag is raw material production desulfurizing agent, mainly comprise the following steps：Drying is broken：The carbide slag addition hammer dryer structure of accumulation is carried out into drying to crush, obtains 15~60 μm of particulate matters；Gather dust, store in a warehouse, raw material tower mixing, the carbide slag for drying broken is uniformly mixed with calcium oxide and catalyst, obtains desulfurizing agent.Compared with prior art, the present invention has simple in construction, and drying crushing effect is good, the advantages such as fault rate is low.
Description
Technical field
The method that carbide slag is raw material production desulfurizing agent is used the present invention relates to a kind of.
Background technology
Carbide slag is that calcium carbide hydrolysis obtains the waste residue using calcium hydroxide as main component after acetylene gas.1t calcium carbides add water can
Kg acetylene gas more than 300 is generated, while generates the industrial wastes of 10t solid contents about 12%, the industrial wastes is commonly called as carbide slag slurries.μm
Before, carbide slag, which is turned waste into wealth, can replace lime cement made of stones, production quick lime to be used as carbide raw material, production chemical products, life
Produce construction material and for environmental improvement etc..With the raising of environmental requirement, thermal power plant needs to carry out desulfurization process to flue gas, by
Main component in carbide slag is calcium hydroxide, and hence it is also possible to the use of carbide slag slurries be that raw material produces what thermal power plant used
Desulfurizing agent.
Disclosed in Chinese patent CN102266715A, CN101822943A, CN101898083A and CN104437023A
Desulfurizing agent that carbide slag is produced, produce in the method and apparatus of desulfurizing agent, have the following disadvantages：
1st, desulfurizing agent working condition requires that temperature is too high, only can be used at the air inlet of chimney, has arrived chimney top, temperature
After degree reduces, the desulfurized effect of desulfurizing agent reduces, and influences desulfurized effect；2nd, desulfurizing agent and smoke reaction speed are slow, reaction speed
Slowly desulfurized effect can be influenceed, flue gas moves upwards, is not sufficiently mixed with the desulfurizing agent ejected also and realizes desulfurization, has been drained off cigarette
Chimney；3rd, particle is larger, and larger granularity is that particle is too big the main reason for influenceing desulfurized effect, and desulfurized effect reduces；The 4th, the weight such as
The desulfurizing agent diffusion area of amount is smaller, and because granularity is larger, therefore, the area that spreads apart of desulfurizing agent etc. weight is smaller, increases
Add the usage amount of desulfurizing agent；5th, usage amount is larger, and in order to realize environmental requirement, the desulfurized effect of meet the requirement of environmental protection is, it is necessary to increase
The usage amount of big desulfurizing agent, increases cost.
Therefore, it is a kind of to have that desulfurized effect is good, and desulfurization working reaction speed is fast, desulfurizing agent easy to use and to produce this de-
The method and special equipment of sulphur agent are suggested.
The content of the invention
The present invention is to provide that a kind of desulfurized effect is good, and desulfurization working reaction speed is fast, and reaching identical desulfurized effect and reducing makes
The desulfurizing agent of dosage, the desulfurizing agent include：The parts by weight of calcium oxide 3~5%, the parts by weight of catalyst 1~3%, its surplus are processing
Carbide slag finished product afterwards.
Above-mentioned calcium oxide is active calcium oxide, and the content of calcium oxide is more than 70%.
Above-mentioned catalyst is TiO2、Al(OH)3、V2O5、WO3、K2O、C58H26N16CoFe or CaSiO3At least one of or
The two or more mixtures mixed in any proportion.
Above-mentioned carbide slag finished product is to use following device to carry out the finished product obtained after drying is broken, the concrete structure of the device
It is as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), and the housing (6) is interior
Chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at the another of " V " shape
End, housing (6) is interior to be provided with crushing mechanism (4), and feeding distribution mechanism (7) is provided between charging aperture (8) and crushing mechanism (4), described
Feeding distribution mechanism (7) is the body of rod of crisscross distribution, and the concrete structure of the crushing mechanism (4) is as follows：It is rotatable comprising one
Body (4-1), be evenly equipped with that one end and body (4-1) are be hinged on body (4-1) surface, the other end is the pendulum (2) of free end.
Above-mentioned air inlet (10) connects boiling boiler, conveys heat to drying crusher structure by boiling boiler, makes drying
Temperature in breaker is maintained at more than 800 DEG C.
Above-mentioned discharging opening (11) is provided with cyclone dust collector, avoids dust pollution.
In order to avoid the heat in drying crusher structure outwards distributes, blower fan is closed preferably, being provided with charging aperture (8) place
Structure (9) carbide slag raw material enters housing (6) inner chamber by closing wind mechanism (9).
As an improvement, body (4-1) is hollow body, its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) is by entering
Liquid pipe (4-3) and drain pipe (4-4) connect outside with housing (6).
As an improvement, be provided with least two layers of screen layer between crushing mechanism (4) and discharging opening (11), i.e., wide-meshed screen (12) and
Fine screen mesh (14).
It is above-mentioned to be filtered by the broken obtained carbide slag finished product of drying breaker by fine screen mesh (14), obtain 15~70
μm particulate matter.
Above-mentioned wide-meshed screen (12) is provided with gap with housing (6) inwall, and wide-meshed screen (12) passes through dowel (13) and housing
(6) inwall is fixed, and can stop the carbide slag of a portion larger particles, continues have crushing mechanism to crush, when being fine-sieved net
(14) carbide slag under intercepting, can fall from the gap of wide-meshed screen (12) and housing (6) inwall, continue to be broken by crushing mechanism
It is broken.
Above-mentioned carbide slag finished product, calcium oxide and catalyst obtain desulfurizing agent finished product after being sufficiently mixed in raw material tower.
Desulfurizing agent finished product moisture content≤0.2% obtained after mixing；15~70 μm of fineness.
A kind of carbide slag that is exclusively used in prepares the hammer drying plant used in desulfurizing agent, comprising housing (6), on housing (6)
Provided with charging aperture (8), air inlet (10) and discharging opening (11), housing (6) inner chamber is in " V " shape, above-mentioned charging aperture (8) and is entered
Air port (10) is located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, crushing mechanism (4) is provided with housing (6),
Feeding distribution mechanism (7) is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is the bar of crisscross distribution
Body, the concrete structure of the crushing mechanism (4) are as follows：It is equal on body (4-1) surface comprising a rotatable body (4-1)
It is be hinged with body (4-1) to be furnished with one end, the other end is the pendulum (2) of free end.
Above-mentioned air inlet (10) connects boiling boiler, conveys heat to drying crusher structure by boiling boiler, makes drying
Temperature in breaker is maintained at more than 800 DEG C.
Above-mentioned discharging opening (11) is provided with cyclone dust collector, avoids dust pollution.
In order to avoid the heat in drying crusher structure outwards distributes, closed preferably, being provided with above-mentioned charging aperture (8) place
Wind mechanism (9).
As an improvement, body (4-1) is hollow body, its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) is by entering
Liquid pipe (4-3) and drain pipe (4-4) connect outside with housing (6).
As an improvement, be provided with least two layers of screen layer between crushing mechanism (4) and discharging opening (11), i.e., wide-meshed screen (12) and
Fine screen mesh (14).
Above-mentioned wide-meshed screen (12) is provided with gap with housing (6) inwall, and wide-meshed screen (12) passes through dowel (13) and housing
(6) inwall is fixed, and can stop the carbide slag of a portion larger particles, continues have crushing mechanism to crush, when being fine-sieved net
(14) carbide slag under intercepting, can fall from the gap of wide-meshed screen (12) and housing (6) inwall, continue to be broken by crushing mechanism
It is broken.
A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Will accumulation carbide slag weigh after add hammer dryer structure to carry out drying broken, obtain 15~
70 μm of carbide slag finished particle thing, resulting carbide slag finished product are discharged by discharging opening (11), the hammer dryer structure
Concrete structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product, obtain desulfurizing agent semi-finished product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is TiO2、Al(OH)3、V2O5、WO3、K2O、C58H26N16CoFe or CaSiO3At least one of or it is two or more according to appoint
The mixture of meaning ratio mixing, obtains finished product desulfurizing agent.
The specific composition of above-mentioned desulfurizing agent finished product is as follows：Calcium oxide is 3~5% parts by weight, and catalyst is 1~3% weight
Part, its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Desulfurizing agent finished product moisture content≤0.2% obtained after mixing；15~70 μm of fineness.
Selected calcium oxide is active calcium oxide in above-mentioned Step d, and the content of calcium oxide is more than 70%.
Above-mentioned body (4-1) is hollow body, and its chamber is cooling chamber (4-2), and the cooling chamber (4-2) passes through feed tube (4-3)
Connected outside with drain pipe (4-4) with housing (6).
At least two layers of screen layer, i.e. wide-meshed screen (12) and dusting cover are provided between above-mentioned crushing mechanism (4) and discharging opening (11)
Net (14).
Wide-meshed screen (12) described above and housing (6) inwall are provided with gap, and wide-meshed screen (12) by dowel (13) and
Housing (6) inwall is fixed.
Brief description of the drawings
Fig. 1 is main structure diagram of the present invention.
Fig. 2 is Figure 1A-A directions cross section structure diagram.
Fig. 3 is Figure 1B-B directions cross section structure diagram.
Fig. 4 is process chart.
Shown in figure：1 is transmission device, and 2 be pendulum, and 3 be jointed shaft, and 4 be crushing mechanism, and 4-1 is body, and 4-2 is cold
But chamber, 4-3 are feed tubes, and 4-4 is drain pipe, and 5 be rotating shaft, and 6 be housing, and 7 be feeding distribution mechanism, and 8 be charging aperture, and 9 be to close blower fan
Structure, 10 be air inlet, and 11 be discharging opening, and 12 be wide-meshed screen, and 13 be dowel, and 14 be fine screen mesh, and 15 be gap.
Embodiment
Embodiment 1：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 3%, the parts by weight of catalyst 1.8%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%, catalyst TiO2, after processing
Carbide slag finished product, calcium oxide and catalyst obtain desulfurizing agent finished product after being sufficiently mixed in raw material tower, above-mentioned carbide slag into
Product are to use following device to carry out the finished product obtained after drying is broken, and the concrete structure of the device is as follows：Include housing (6), shell
Body (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), and housing (6) inner chamber is in " V " shape, above-mentioned charging aperture
(8) and air inlet (10) is located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, is provided with housing (6) broken
Mechanism (4), is provided with feeding distribution mechanism (7) between charging aperture (8) and crushing mechanism (4), and the feeding distribution mechanism (7) is crisscross
The body of rod of distribution, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), in body (4-
1) surface is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closed
Wind mechanism (9) carbide slag raw material enters housing (6) inner chamber by closing wind mechanism (9), and body (4-1) is hollow body, its hollow cavity
For cooling chamber (4-2), the cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), disintegrating machine
At least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between structure (4) and discharging opening (11), it is broken by drying
The broken obtained carbide slag finished product of device filters by fine screen mesh (14), obtains 60 μm of particulate matter.
Embodiment 2：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 5%, the parts by weight of catalyst 2.4%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 75%, and catalyst is Al (OH)3, processing
Carbide slag finished product, calcium oxide and catalyst afterwards obtains desulfurizing agent finished product, above-mentioned carbide slag after being sufficiently mixed in raw material tower
Finished product is to use following device to carry out the finished product obtained after drying is broken, and the concrete structure of the device is as follows：Comprising housing (6),
Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), and housing (6) inner chamber is in " V " shape, above-mentioned charging
Mouth (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, is provided with housing (6) broken
Broken mechanism (4), is provided with feeding distribution mechanism (7) between charging aperture (8) and crushing mechanism (4), and the feeding distribution mechanism (7) is to hand in length and breadth
The body of rod of mistake distribution, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), in body
(4-1) surface is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is set
Close wind mechanism (9) carbide slag raw material and enter housing (6) inner chamber by closing wind mechanism (9), body (4-1) is hollow body, and it is empty
The chambers of the heart is cooling chamber (4-2), and the cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), is broken
At least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between broken mechanism (4) and discharging opening (11), by drying
The broken obtained carbide slag finished product of breaker filters by fine screen mesh (14), obtains 30 μm of particulate matter.
Embodiment 3：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 4%, the parts by weight of catalyst 2%, its surplus are processing
Carbide slag finished product afterwards, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 80%, catalyst V2O5, the electricity after processing
Rock ballast finished product, calcium oxide and catalyst obtain desulfurizing agent finished product after being sufficiently mixed in raw material tower, and above-mentioned carbide slag finished product is
The finished product for using following device obtain after drying is broken, the concrete structure of the device are as follows：Include housing (6), housing (6)
Be provided with charging aperture (8), air inlet (10) and discharging opening (11), housing (6) inner chamber is in " V " shape, above-mentioned charging aperture (8) and
Air inlet (10) is located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closes blower fan
Structure (9) carbide slag raw material enters housing (6) inner chamber by closing wind mechanism (9), and body (4-1) is hollow body, and its hollow cavity is cold
But chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) at least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between discharging opening (11), by drying broken dress
Put broken obtained carbide slag finished product to filter by fine screen mesh (14), obtain 15 μm of particulate matter.
Embodiment 4：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 3.5%, the parts by weight of catalyst 1%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 90%, catalyst WO3, after processing
Carbide slag finished product, calcium oxide and catalyst obtain desulfurizing agent finished product, above-mentioned carbide slag finished product after being sufficiently mixed in raw material tower
It is to use following device to carry out the finished product obtained after drying is broken, the concrete structure of the device is as follows：Include housing (6), housing
(6) charging aperture (8), air inlet (10) and discharging opening (11) are provided with, housing (6) inner chamber is in " V " shape, above-mentioned charging aperture
(8) and air inlet (10) is located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, is provided with housing (6) broken
Mechanism (4), is provided with feeding distribution mechanism (7) between charging aperture (8) and crushing mechanism (4), and the feeding distribution mechanism (7) is crisscross
The body of rod of distribution, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), in body (4-
1) surface is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closed
Wind mechanism (9) carbide slag raw material enters housing (6) inner chamber by closing wind mechanism (9), and body (4-1) is hollow body, its hollow cavity
For cooling chamber (4-2), the cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), disintegrating machine
At least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between structure (4) and discharging opening (11), it is broken by drying
The broken obtained carbide slag finished product of device filters by fine screen mesh (14), obtains 55 μm of particulate matter.
Embodiment 5：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 4.5%, the parts by weight of catalyst 1%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 75%, catalyst K2O, after processing
Carbide slag finished product, calcium oxide and catalyst obtain desulfurizing agent finished product, above-mentioned carbide slag finished product after being sufficiently mixed in raw material tower
It is to use following device to carry out the finished product obtained after drying is broken, the concrete structure of the device is as follows：Include housing (6), housing
(6) charging aperture (8), air inlet (10) and discharging opening (11) are provided with, housing (6) inner chamber is in " V " shape, above-mentioned charging aperture
(8) and air inlet (10) is located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, is provided with housing (6) broken
Mechanism (4), is provided with feeding distribution mechanism (7) between charging aperture (8) and crushing mechanism (4), and the feeding distribution mechanism (7) is crisscross
The body of rod of distribution, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), in body (4-
1) surface is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closed
Wind mechanism (9) carbide slag raw material enters housing (6) inner chamber by closing wind mechanism (9), and body (4-1) is hollow body, its hollow cavity
For cooling chamber (4-2), the cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), disintegrating machine
At least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between structure (4) and discharging opening (11), it is broken by drying
The broken obtained carbide slag finished product of device filters by fine screen mesh (14), obtains 70 μm of particulate matter.
Embodiment 6：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 3%, the parts by weight of catalyst 3%, its surplus are processing
Carbide slag finished product afterwards, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 85%, catalyst C58H26N16CoFe, place
Carbide slag finished product, calcium oxide and catalyst after reason obtain desulfurizing agent finished product, above-mentioned calcium carbide after being sufficiently mixed in raw material tower
Slag finished product is to use following device to carry out the finished product obtained after drying is broken, and the concrete structure of the device is as follows：Include housing
(6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), and housing (6) inner chamber is in " V " shape, above-mentioned
Charging aperture (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, set in housing (6)
There is crushing mechanism (4), feeding distribution mechanism (7) is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is vertical
The horizontal body of rod being interspersed, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), at this
Body (4-1) surface is evenly equipped with that one end and body (4-1) are be hinged, and the other end is the pendulum (2) of free end, above-mentioned charging aperture (8) place
Entering housing (6) inner chamber by closing wind mechanism (9) provided with wind mechanism (9) carbide slag raw material is closed, body (4-1) is hollow body, its
Hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6),
At least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between crushing mechanism (4) and discharging opening (11), by drying
The broken obtained carbide slag finished product of dry breaker filters by fine screen mesh (14), obtains 30 μm of particulate matter.
Embodiment 7：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 3.5%, the parts by weight of catalyst 2%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%, catalyst CaSiO3, processing
Carbide slag finished product, calcium oxide and catalyst afterwards obtains desulfurizing agent finished product, above-mentioned carbide slag after being sufficiently mixed in raw material tower
Finished product is to use following device to carry out the finished product obtained after drying is broken, and the concrete structure of the device is as follows：Comprising housing (6),
Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), and housing (6) inner chamber is in " V " shape, above-mentioned charging
Mouth (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, is provided with housing (6) broken
Broken mechanism (4), is provided with feeding distribution mechanism (7) between charging aperture (8) and crushing mechanism (4), and the feeding distribution mechanism (7) is to hand in length and breadth
The body of rod of mistake distribution, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), in body
(4-1) surface is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is set
Close wind mechanism (9) carbide slag raw material and enter housing (6) inner chamber by closing wind mechanism (9), body (4-1) is hollow body, and it is empty
The chambers of the heart is cooling chamber (4-2), and the cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), is broken
At least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between broken mechanism (4) and discharging opening (11), by drying
The broken obtained carbide slag finished product of breaker filters by fine screen mesh (14), obtains 65 μm of particulate matter.
Embodiment 8：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 5%, the parts by weight of catalyst 3%, its surplus are processing
Carbide slag finished product afterwards, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%, catalyst TiO2With Al (OH)3Press
The mixture of arbitrary proportion mixing, carbide slag finished product, calcium oxide and the catalyst after processing in raw material tower after being sufficiently mixed
Desulfurizing agent finished product is obtained, above-mentioned carbide slag finished product is to use following device to carry out the finished product obtained after drying is broken, the device
Concrete structure is as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), the shell
Body (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at " V " shape
The other end, is provided with crushing mechanism (4) in housing (6), feeding distribution mechanism is provided between charging aperture (8) and crushing mechanism (4)
(7), the feeding distribution mechanism (7) is the body of rod of crisscross distribution, and the concrete structure of the crushing mechanism (4) is as follows：Include one
Individual rotatable body (4-1), one end is evenly equipped with body (4-1) surface and is hinged with body (4-1), the other end is free end
Pendulum (2), above-mentioned charging aperture (8) place are interior into housing (6) by closing wind mechanism (9) provided with wind mechanism (9) carbide slag raw material is closed
Chamber, body (4-1) are hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) is by feed tube (4-3) and goes out liquid
Pipe (4-4) is connected outside with housing (6), and at least two layers of screen layer, i.e. wide-meshed screen are provided between crushing mechanism (4) and discharging opening (11)
(12) and fine screen mesh (14), by drying the broken obtained carbide slag finished product of breaker by fine screen mesh (14) filtering, obtain
35 μm of particulate matter.
Embodiment 9：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 4.5%, the parts by weight of catalyst 1%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%, catalyst TiO2And V2O5Press
The mixture of arbitrary proportion mixing, carbide slag finished product, calcium oxide and the catalyst after processing in raw material tower after being sufficiently mixed
Desulfurizing agent finished product is obtained, above-mentioned carbide slag finished product is to use following device to carry out the finished product obtained after drying is broken, the device
Concrete structure is as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), the shell
Body (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at " V " shape
The other end, is provided with crushing mechanism (4) in housing (6), feeding distribution mechanism is provided between charging aperture (8) and crushing mechanism (4)
(7), the feeding distribution mechanism (7) is the body of rod of crisscross distribution, and the concrete structure of the crushing mechanism (4) is as follows：Include one
Individual rotatable body (4-1), one end is evenly equipped with body (4-1) surface and is hinged with body (4-1), the other end is free end
Pendulum (2), above-mentioned charging aperture (8) place are interior into housing (6) by closing wind mechanism (9) provided with wind mechanism (9) carbide slag raw material is closed
Chamber, body (4-1) are hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) is by feed tube (4-3) and goes out liquid
Pipe (4-4) is connected outside with housing (6), and at least two layers of screen layer, i.e. wide-meshed screen are provided between crushing mechanism (4) and discharging opening (11)
(12) and fine screen mesh (14), by drying the broken obtained carbide slag finished product of breaker by fine screen mesh (14) filtering, obtain
45 μm of particulate matter.
Embodiment 10：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 3%, the parts by weight of catalyst 2%, its surplus are processing
Carbide slag finished product afterwards, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 75%, catalyst TiO2、Al(OH)3With
V2O5The mixture mixed in any proportion, carbide slag finished product, calcium oxide and the catalyst after processing are by fully mixed in raw material tower
Desulfurizing agent finished product is obtained after conjunction, above-mentioned carbide slag finished product is to use following device to carry out the finished product obtained after drying is broken, the dress
The concrete structure put is as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), institute
It is in " V " shape to state housing (6) inner chamber, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at
The other end of " V " shape, housing (6) is interior to be provided with crushing mechanism (4), and depiler is provided between charging aperture (8) and crushing mechanism (4)
Structure (7), the feeding distribution mechanism (7) are the body of rod of crisscross distribution, and the concrete structure of the crushing mechanism (4) is as follows：Comprising
One rotatable body (4-1), one end is evenly equipped with body (4-1) surface and is hinged with body (4-1), the other end is free end
Pendulum (2), above-mentioned charging aperture (8) place is provided with and closes wind mechanism (9) carbide slag raw material and enter housing (6) by closing wind mechanism (9)
Inner chamber, body (4-1) are hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) is by feed tube (4-3) and goes out
Liquid pipe (4-4) is connected outside with housing (6), and at least two layers of screen layer, i.e. scalping are provided between crushing mechanism (4) and discharging opening (11)
Net (12) and fine screen mesh (14), filter, obtain by fine screen mesh (14) by drying the broken obtained carbide slag finished product of breaker
To 55 μm of particulate matter.
Embodiment 11：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 5%, the parts by weight of catalyst 1.5%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%, and catalyst is Al (OH)3、V2O5、
WO3And K2The mixture that O is mixed in any proportion, carbide slag finished product, calcium oxide and the catalyst after processing in raw material tower by filling
Desulfurizing agent finished product is obtained after dividing mixing, above-mentioned carbide slag finished product is to use following device to carry out the finished product obtained after drying is broken,
The concrete structure of the device is as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, crushing mechanism (4) is provided with housing (6), is set between charging aperture (8) and crushing mechanism (4)
There is feeding distribution mechanism (7), the feeding distribution mechanism (7) is the body of rod of crisscross distribution, and the concrete structure of the crushing mechanism (4) is such as
Under：Comprising a rotatable body (4-1), one end is evenly equipped with body (4-1) surface and is hinged with body (4-1), the other end
For the pendulum (2) of free end, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9) carbide slag raw material by closing wind mechanism (9) entrance
Housing (6) inner chamber, body (4-1) are hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) passes through feed tube
(4-3) and drain pipe (4-4) are connected outside with housing (6), and at least two layers of screen cloth is provided between crushing mechanism (4) and discharging opening (11)
Layer, i.e. wide-meshed screen (12) and fine screen mesh (14), pass through fine screen mesh by drying the broken obtained carbide slag finished product of breaker
(14) filter, obtain 75 μm of particulate matter.
Embodiment 12：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 4%, the parts by weight of catalyst 2.5%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 90%, catalyst V2O5、WO3、K2O、
C58H26N16CoFe and CaSiO3The mixture mixed in any proportion, carbide slag finished product, calcium oxide and catalyst warp after processing
Cross in raw material tower after being sufficiently mixed and obtain desulfurizing agent finished product, above-mentioned carbide slag finished product be using following device carry out drying it is broken after
Obtained finished product, the concrete structure of the device are as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10)
With discharging opening (11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape,
Discharging opening (11) is located at the other end of " V " shape, crushing mechanism (4) is provided with housing (6), in charging aperture (8) and crushing mechanism (4)
Between be provided with feeding distribution mechanism (7), the feeding distribution mechanism (7) is the body of rod of crisscross distribution, the crushing mechanism (4) it is specific
Structure is as follows：Comprising a rotatable body (4-1), one end is evenly equipped with body (4-1) surface and is hinged with body (4-1),
The other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closes wind mechanism (9) carbide slag raw material by closing wind mechanism
(9) housing (6) inner chamber is entered, body (4-1) is hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) passes through
Feed tube (4-3) and drain pipe (4-4) are connected outside with housing (6), and at least two are provided between crushing mechanism (4) and discharging opening (11)
Layer screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), by drying the broken obtained carbide slag finished product of breaker through meticulous
Screen cloth (14) filters, and obtains 20 μm of particulate matter.
Embodiment 13：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 4.5%, the parts by weight of catalyst 2.1%, its surplus are
Carbide slag finished product after processing, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%, catalyst TiO2、Al
(OH)3、V2O5、WO3、K2O and C58H26N16The mixture that CoFe is mixed in any proportion, carbide slag finished product, calcium oxide after processing
Desulfurizing agent finished product is obtained after being sufficiently mixed in raw material tower with catalyst, above-mentioned carbide slag finished product is carried out using following device
The finished product obtained after drying is broken, the concrete structure of the device are as follows：Comprising housing (6), housing (6) be provided with charging aperture (8),
Air inlet (10) and discharging opening (11), housing (6) inner chamber are in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at
One end of " V " shape, discharging opening (11) are located at the other end of " V " shape, crushing mechanism (4) are provided with housing (6), in charging aperture (8)
Feeding distribution mechanism (7) is provided between crushing mechanism (4), the feeding distribution mechanism (7) is the body of rod of crisscross distribution, described broken
The concrete structure of mechanism (4) is as follows：Comprising a rotatable body (4-1), one end and this are evenly equipped with body (4-1) surface
Body (4-1) is be hinged, and the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closes wind mechanism (9) carbide slag raw material
Enter housing (6) inner chamber by closing wind mechanism (9), body (4-1) is hollow body, and its hollow cavity is cooling chamber (4-2), the cooling
Chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism (4) and discharging opening (11) it
Between be provided with least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), by drying the broken obtained calcium carbide of breaker
Slag finished product filters by fine screen mesh (14), obtains 50 μm of particulate matter.
Embodiment 14：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 3.5%, the parts by weight of catalyst 1.2%, its surplus are
Carbide slag finished product after processing, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 85%, catalyst TiO2、Al
(OH)3、WO3、K2O、C58H26N16CoFe and CaSiO3The mixture mixed in any proportion, carbide slag finished product, oxygen after processing
Change calcium and catalyst obtains desulfurizing agent finished product after being sufficiently mixed in raw material tower, above-mentioned carbide slag finished product is to use following device
The finished product obtained after drying is broken is carried out, the concrete structure of the device is as follows：Comprising housing (6), housing (6) is provided with charging aperture
(8), air inlet (10) and discharging opening (11), housing (6) inner chamber are in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are set
In one end of " V " shape, discharging opening (11) is located at the other end of " V " shape, crushing mechanism (4) is provided with housing (6), in charging aperture
(8) feeding distribution mechanism (7) is provided between crushing mechanism (4), the feeding distribution mechanism (7) is the body of rod of crisscross distribution, described
The concrete structure of crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), one end is evenly equipped with body (4-1) surface
Be hinged with body (4-1), the other end is the pendulum (2) of free end, and above-mentioned charging aperture (8) place is provided with and closes wind mechanism (9) carbide slag
Raw material enters housing (6) inner chamber by closing wind mechanism (9), and body (4-1) is hollow body, and its hollow cavity is cooling chamber (4-2), should
Cooling chamber (4-2) is connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism (4) and discharging opening
(11) at least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between, breaker is broken to be obtained by drying
Carbide slag finished product by fine screen mesh (14) filter, obtain 65 μm of particulate matter.
Embodiment 15：A kind of desulfurizing agent, comprising：The parts by weight of calcium oxide 5%, the parts by weight of catalyst 2.8%, its surplus are place
Carbide slag finished product after reason, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 80%, catalyst TiO2、V2O5、WO3
And K2The mixture that O is mixed in any proportion, carbide slag finished product, calcium oxide and the catalyst after processing are by abundant in raw material tower
Desulfurizing agent finished product is obtained after mixing, above-mentioned carbide slag finished product is to use following device to carry out the finished product obtained after drying is broken, should
The concrete structure of device is as follows：Comprising housing (6), housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11),
Housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is set
Crushing mechanism (4) is provided with the other end of " V " shape, housing (6), sub-material is provided between charging aperture (8) and crushing mechanism (4)
Mechanism (7), the feeding distribution mechanism (7) are the body of rod of crisscross distribution, and the concrete structure of the crushing mechanism (4) is as follows：Bag
Containing a rotatable body (4-1), one end is evenly equipped with body (4-1) surface and is hinged with body (4-1), the other end is freely
The pendulum (2) at end, above-mentioned charging aperture (8) place are provided with and close wind mechanism (9) carbide slag raw material and enter housing by closing wind mechanism (9)
(6) inner chamber, body (4-1) are hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) passes through feed tube (4-3)
Connected outside with drain pipe (4-4) with housing (6), at least two layers of screen layer is provided between crushing mechanism (4) and discharging opening (11), i.e.,
Wide-meshed screen (12) and fine screen mesh (14), pass through fine screen mesh (14) mistake by drying the broken obtained carbide slag finished product of breaker
Filter, obtains 30 μm of particulate matter.
Embodiment 16：A kind of carbide slag that is exclusively used in prepares the hammer drying plant used in desulfurizing agent, comprising housing (6),
Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening (11), and housing (6) inner chamber is in " V " shape, above-mentioned charging
Mouth (8) and air inlet (10) are located at one end of " V " shape, and discharging opening (11) is located at the other end of " V " shape, is provided with housing (6) broken
Broken mechanism (4), is provided with feeding distribution mechanism (7) between charging aperture (8) and crushing mechanism (4), and the feeding distribution mechanism (7) is to hand in length and breadth
The body of rod of mistake distribution, the concrete structure of the crushing mechanism (4) are as follows：Comprising a rotatable body (4-1), in body
(4-1) surface is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and air inlet (10) connection is seethed with excitement
Boiler, by boiling boiler to drying crusher structure convey heat, make the temperature in drying breaker be maintained at 800 DEG C with
On, discharging opening (11) is provided with cyclone dust collector, avoids the above-mentioned charging aperture of dust pollution (8) place from being provided with and closes wind mechanism (9), body
(4-1) is hollow body, and its hollow cavity is cooling chamber (4-2), and the cooling chamber (4-2) passes through feed tube (4-3) and drain pipe (4-4)
Connected outside with housing (6), two layers of screen layer, i.e. wide-meshed screen (12) and dusting cover are provided between crushing mechanism (4) and discharging opening (11)
Net (14), wide-meshed screen (12) is provided with gap with housing (6) inwall, and wide-meshed screen (12) passes through in dowel (13) and housing (6)
Wall is fixed, and can stop the carbide slag of a portion larger particles, continues have crushing mechanism to crush, and is blocked when being fine-sieved net (14)
The carbide slag cut down, it can be fallen from the gap of wide-meshed screen (12) and housing (6) inwall, continue to be crushed by crushing mechanism.
Embodiment 17：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 40 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 50 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is TiO2、Al(OH)3、V2O5、WO3、K2O、C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, is obtained
To finished product desulfurizing agent, calcium oxide is active calcium oxide, and the content of calcium oxide is more than 75%.Above-mentioned calcium oxide is 3% parts by weight, is urged
Agent is 1.1% parts by weight, and its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 18：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 35 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 25 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is Al (OH)3、V2O5And WO3, according to arbitrary proportion mix mixture, obtain finished product desulfurizing agent, calcium oxide is active oxygen
Change calcium, the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 5% parts by weight, and catalyst is 1.6% parts by weight, and its surplus is c
The stand-by desulfurizing agent semi-finished product of step storage.
Embodiment 19：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 15 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 55 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is TiO2、Al(OH)3And WO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, calcium oxide is active oxygen
Change calcium, the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 3.5% parts by weight, and catalyst is 2.4% parts by weight, its surplus
For the desulfurizing agent semi-finished product that step c storage is stand-by.
Embodiment 20：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 60 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 45 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is Al (OH)3、V2O5、WO3、K2O and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, aoxidizes
Calcium is active calcium oxide, and the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 4.5% parts by weight, and catalyst is 2.7% weight
Part, its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 21：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 35 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 25 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is TiO2、Al(OH)3、WO3、K2O and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, aoxidizes
Calcium is active calcium oxide, and the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 4% parts by weight, and catalyst is 1.7% weight
Part, its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 22：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 15 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 60 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is V2O5、K2O、C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, aoxidizes
Calcium is active calcium oxide, and the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 3% parts by weight, and catalyst is 1% parts by weight,
Its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 23：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 35 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 45 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is Al (OH)3、V2O5、K2O、C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurization
Agent, calcium oxide are active calcium oxide, and the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 5% parts by weight, catalyst 3%
Parts by weight, its surplus are the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 24：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 55 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 20 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is TiO2、V2O5、WO3And CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, and calcium oxide is activity
Calcium oxide, the content of calcium oxide are more than 70%.Above-mentioned calcium oxide is 4% parts by weight, and catalyst is 2% parts by weight, and its surplus is c
The stand-by desulfurizing agent semi-finished product of step storage.
Embodiment 25：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 40 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 50 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is K2O、C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, calcium oxide is
Active calcium oxide, the content of calcium oxide are more than 70%.Above-mentioned calcium oxide is 3.5% parts by weight, and catalyst is 2.5% parts by weight,
Its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 26：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 25 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 35 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is V2O5And CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, and calcium oxide is active calcium oxide,
The content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 5% parts by weight, and catalyst is 2.1% parts by weight, and its surplus is step c
The desulfurizing agent semi-finished product for storing in a warehouse stand-by.
Embodiment 27：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 40 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 15 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, and calcium oxide is activity
Calcium oxide, the content of calcium oxide are more than 70%.Above-mentioned calcium oxide is 4.5% parts by weight, and catalyst is 1.9% parts by weight, remaining
Measure stand-by desulfurizing agent semi-finished product of being stored in a warehouse for step c.
Embodiment 28：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 40 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 30 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is V2O5And WO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, and calcium oxide is active calcium oxide, oxidation
The content of calcium is more than 70%.Above-mentioned calcium oxide is 3.5% parts by weight, and catalyst is 2.3% parts by weight, and its surplus is step c storehouse
Store up stand-by desulfurizing agent semi-finished product.
Embodiment 29：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 20 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 15 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is Al (OH)3、V2O5、WO3And C58H26N16The mixture that CoFe mixes according to arbitrary proportion, obtain finished product desulfurizing agent, oxygen
Change calcium is active calcium oxide, and the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 4% parts by weight, and catalyst is 2.8% weight
Part, its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 30：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 60 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 20 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is Al (OH)3、V2O5、WO3And CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent, calcium oxide is
Active calcium oxide, the content of calcium oxide are more than 70%.Above-mentioned calcium oxide is 4.5% parts by weight, and catalyst is 1.6% parts by weight,
Its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Embodiment 31：A kind of method for being produced desulfurizing agent for raw material using carbide slag, is mainly comprised the following steps：
A, drying is broken：Addition hammer dryer structure dry and crushed after the carbide slag of accumulation is weighed, and obtains 30 μm
Carbide slag finished particle thing, resulting carbide slag finished product by discharging opening (11) discharge, the hammer dryer structure it is specific
Structure is as follows：Include housing (6), it is characterised in that：Housing (6) is provided with charging aperture (8), air inlet (10) and discharging opening
(11), housing (6) inner chamber is in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at one end of " V " shape, discharging opening
(11) other end of " V " shape is located at, above-mentioned charging aperture (8) place, which is provided with, closes wind mechanism (9), and crushing mechanism is provided with housing (6)
(4) feeding distribution mechanism (7), is provided between charging aperture (8) and crushing mechanism (4), the feeding distribution mechanism (7) is crisscross distribution
The body of rod, the concrete structure of the crushing mechanism (4) is as follows：Comprising a rotatable body (4-1), in body (4-1) table
Face is evenly equipped with one end and is hinged with body (4-1), and the other end is the pendulum (2) of free end, and body (4-1) is hollow body, and its chamber is
Cooling chamber (4-2), the cooling chamber (4-2) are connected outside by feed tube (4-3) and drain pipe (4-4) with housing (6), crushing mechanism
(4) two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14), wide-meshed screen (12) and housing are provided between discharging opening (11)
(6) inwall is provided with gap, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall, by drying breaker
Broken obtained carbide slag finished product filters by fine screen mesh (14), obtains 40 μm of particulate matter；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtain desulfurizing agent half into
Product；
C, store in a warehouse：The desulfurizing agent semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The desulfurizing agent semi-finished product that step c obtains are mixed with calcium oxide and catalyst, it is described to urge
Agent is TiO2、Al(OH)3、C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, obtains finished product desulfurizing agent,
Calcium oxide is active calcium oxide, and the content of calcium oxide is more than 70%.Above-mentioned calcium oxide is 5% parts by weight, and catalyst is 1.3% weight
Part is measured, its surplus is the stand-by desulfurizing agent semi-finished product of step c storage.
Claims (4)
1. a kind of use the method that carbide slag is raw material production desulfurizing agent, it is characterised in that comprises the following steps：
A, drying is broken：The carbide slag addition hammer dryer structure of accumulation is carried out into drying to crush, obtains 15~60 μm of particulate matters,
The concrete structure of the hammer dryer structure is as follows：Include housing (6), it is characterised in that：Housing (6) be provided with charging aperture (8),
Air inlet (10) and discharging opening (11), housing (6) inner chamber are in " V " shape, and above-mentioned charging aperture (8) and air inlet (10) are located at
One end of " V " shape, discharging opening (11) are located at the other end of " V " shape, and above-mentioned charging aperture (8) place is provided with and closes wind mechanism (9), housing
(6) crushing mechanism (4) is provided with, feeding distribution mechanism (7), the feeding distribution mechanism are provided between charging aperture (8) and crushing mechanism (4)
(7) it is as follows for the body of rod of crisscross distribution, the concrete structure of the crushing mechanism (4)：Include a rotatable body (4-
1), the body (4-1) is hollow body, and its chamber is cooling chamber (4-2), and the cooling chamber (4-2) is by feed tube (4-3) and goes out liquid
Pipe (4-4) is connected outside with housing (6), and one end is evenly equipped with body (4-1) surface and is hinged with body (4-1), the other end is freely
The pendulum (2) at end；
B, gather dust：Cloth bag machine is sent into the discharging of a steps discharging opening (11) and carries out cyclone dust collection, obtains desulfurizing agent semi-finished product；
C, store in a warehouse：The semi-finished product obtained after b step is handled store in a warehouse stand-by；
D, raw material tower mixes：The semi-finished product that step c obtains are mixed with calcium hydroxide, calcium oxide and catalyst, it is described to urge
Agent is TiO2、Al(OH)3、V2O5、WO3、K2O、C58H26N16CoFe and CaSiO3The mixture mixed according to arbitrary proportion, is obtained
To finished product desulfurizing agent；The specific composition of finished product desulfurizing agent obtained above is as follows：Calcium oxide is 3~6% parts by weight, catalyst 1
~3% parts by weight, its surplus are the carbide slag finished product prepared by a steps.
2. according to claim 1 use the method that carbide slag is raw material production desulfurizing agent, it is characterised in that：Crushing mechanism
(4) at least two layers of screen layer, i.e. wide-meshed screen (12) and fine screen mesh (14) are provided between discharging opening (11).
3. according to claim 2 use the method that carbide slag is raw material production desulfurizing agent, it is characterised in that：The scalping
Net (12) is provided with gap with housing (6) inwall, and wide-meshed screen (12) is fixed by dowel (13) and housing (6) inwall.
4. use the method that carbide slag is raw material production desulfurizing agent according to claim 1,2 or 3, it is characterised in that：D is walked
Selected calcium oxide is active calcium oxide in rapid, and the content of calcium oxide is more than 70%.
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| CN1353004A (en) * | 2000-11-06 | 2002-06-12 | 浙江大学 | Process for desulfurizing fume of coalpowder boiler |
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| CN101642674B (en) * | 2009-09-03 | 2012-04-04 | 浙江天蓝环保技术股份有限公司 | Wet flue gas desulphurization process for carbide slag slurry pretreatment |
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Denomination of invention: A method for producing desulfurizer using carbide slag as raw material Effective date of registration: 20220328 Granted publication date: 20171222 Pledgee: Bank of China, Limited by Share Ltd, Shihezi branch Pledgor: SHIHEZI LAIMENG CALCIUM INDUSTRY Co.,Ltd. Registration number: Y2022980003425 |
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