CN105088211A - Aluminum profile environment-friendly composite chromate-free passivation conditioning fluid and preparing method thereof - Google Patents
Aluminum profile environment-friendly composite chromate-free passivation conditioning fluid and preparing method thereof Download PDFInfo
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- CN105088211A CN105088211A CN201510521776.2A CN201510521776A CN105088211A CN 105088211 A CN105088211 A CN 105088211A CN 201510521776 A CN201510521776 A CN 201510521776A CN 105088211 A CN105088211 A CN 105088211A
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Abstract
The invention discloses aluminum profile environment-friendly composite chromate-free passivation conditioning fluid. The aluminum profile environment-friendly composite chromate-free passivation conditioning fluid comprises, by weight, 9.6-10 parts of cerous nitrate, 2-2.2 parts of potassium permanganate, 0.2-0.3 part of glycerin, 0.1-0.2 part of benzisothiazolones, 1.2-1.3 parts of K2ZrF6, 0.6-0.8 part of styrene, 0.2-0.3 part of acrylamide, 0.4-0.5 part of crylic acid, 0.05-0.1 part of azodiisobutyronitrile, 0.5-0.6 part of sodium allylsulfonate, 0.02-0.03 part of lauryl sodium sulfate, 0.9-1 part of cetane, 0.3-0.4 part of nanosilicon dioxide, 0.3-0.4 part of nanometer titania and an appropriate amount of deionized water. By means of the conditioning fluid, an oxidation film can be rapidly formed evenly; the glycerin, the benzisothiazolones and the K2ZrF6 are used, so that film-forming property and the corrosion resistance are improved; the film is rough in surface; and the binding ability of the aluminum alloy and a macromolecule coating is better improved.
Description
Technical field
The present invention relates to chromium-free metal surface treatment agent technical field, particularly relate to a kind of aluminium section bar environmental protection compound non-chromium passivation treatment fluid and preparation method thereof.
Background technology
Spray-painted aluminum profile normal chromic salt chemistry deactivation method that adopts before application carries out pre-treatment, but hexavalent chromium has carcinogenesis to human body in chromic salt process, deal with improperly and can cause serious pollution to environment, therefore chromating technique receives great concern, and some country has limited it and used.Recent domestic has carried out large quantity research to non-chromium inactivating technique, develops the multiple passivating solution system for handling such as rare earth, cobalt salt, silicate, molybdic acid, titanium/zirconate, has certain corrosion resistance nature.At present, employing rare-earth cerium compound is that the research of the non-chromium inactivating technique of main component is more, but cerium salt and oxidant species various, adopt cerous nitrate and potassium permanganate composite treating agent to carry out Passivation Treatment to aluminium section bar, obtain good film-formation result and outward appearance, but still to there is passive film even not for the passivation effect of this treatment agent, compactness is inadequate, processing speed is slow, the imperfect shortcoming of corrosion resistance, needs to improve.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of aluminium section bar environmental protection compound non-chromium passivation treatment fluid and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of aluminium section bar environmental protection compound non-chromium passivation treatment fluid, is made up of the raw material of following weight part: cerous nitrate 9.6-10, potassium permanganate 2-2.2, glycerol 0.2-0.3, BIT 0.1-0.2, K
2zrF
61.2-1.3, vinylbenzene 0.6-0.8, acrylamide 0.2-0.3, vinylformic acid 0.4-0.5, Diisopropyl azodicarboxylate 0.05-0.1, sodium allylsulfonate 0.5-0.6, sodium lauryl sulphate 0.02-0.03, n-Hexadecane 0.9-1, silane coupling agent KH570 surface modified nano silicon 0.3-0.4, silane coupling agent KH570 surface-modified nano titanium dioxide 0.3-0.4, deionized water are appropriate.
The preparation method of described aluminium section bar environmental protection compound non-chromium passivation treatment fluid, comprises the following steps:
(1) sodium lauryl sulphate is dissolved in the deionized water of 7-7.5 weight part and forms the aqueous solution, n-Hexadecane is mixed with vinylbenzene, silane coupling agent KH570 surface modified nano silicon, silane coupling agent KH570 surface-modified nano titanium dioxide, BIT is added after being stirred to dissolving, then by above two kinds of liquid mixing, supersound process 3-4min under ultrasonic cell disruptor, obtains emulsion; Described emulsion and acrylamide, vinylformic acid, sodium allylsulfonate are mixed, stirs, pass into nitrogen 15-16min, regulate pH=8, be warming up to 60-62 DEG C, add Diisopropyl azodicarboxylate, continue stirring reaction 1-2h, obtain membrane-forming agent;
(2) cerous nitrate is mixed with the aqueous solution of 9.6-10g/L, add potassium permanganate by the concentration of 2-2.2g/L again and be mixed with solution, add membrane-forming agent and other remaining components that 0.9-1.1wt% (1) step obtains again, stir, supersound process 3-4min under ultrasonic cell disruptor, to obtain final product.
First aluminium section bar is carried out pre-treatment during use, then be immersed in treatment solution by aluminium section bar and carry out Passivation Treatment, temperature is 15-45 DEG C, and pH value is 1.8-4.5, and process 20-23min, takes out, and rinses with water, dries.
Advantage of the present invention is: treatment solution of the present invention, by using cerous nitrate, potassium permanganate, decreases environmental pollution; Film is made into by using nano silicon, nano titanium oxide and organic materials, make nanoparticle dispersed with system, can promote that passivation uniform composition is coated on aluminium shape surface fast, the uniform oxide film of quick formation, and nano silicon, nano titanium oxide have good antioxidant property, slowing down corrosion speed, improve paint application performance, reduce hole simultaneously, make the film of formation finer and close, even; By using glycerol, BIT, K2ZrF6, improve film-forming properties and erosion resistance, this film surface is coarse, is conducive to the bonding properties improving aluminium alloy and polymeric coating layer.
Embodiment
A kind of aluminium section bar environmental protection compound non-chromium passivation treatment fluid, is made up of the raw material of following weight part (kilogram): cerous nitrate 9.6, potassium permanganate 2, glycerol 0.2, BIT 0.1, K
2zrF
61.2, vinylbenzene 0.6, acrylamide 0.2, vinylformic acid 0.4, Diisopropyl azodicarboxylate 0.05, sodium allylsulfonate 0.5, sodium lauryl sulphate 0.02, n-Hexadecane 0.9, silane coupling agent KH570 surface modified nano silicon 0.3, silane coupling agent KH570 surface-modified nano titanium dioxide 0.3, deionized water are appropriate.
The preparation method of described aluminium section bar environmental protection compound non-chromium passivation treatment fluid, comprises the following steps:
(1) sodium lauryl sulphate is dissolved in the deionized water of 7 weight parts and forms the aqueous solution, n-Hexadecane is mixed with vinylbenzene, silane coupling agent KH570 surface modified nano silicon, silane coupling agent KH570 surface-modified nano titanium dioxide, BIT is added after being stirred to dissolving, then by above two kinds of liquid mixing, supersound process 3min under ultrasonic cell disruptor, obtains emulsion; Described emulsion and acrylamide, vinylformic acid, sodium allylsulfonate are mixed, stirs, pass into nitrogen 15min, regulate pH=8, be warming up to 60 DEG C, add Diisopropyl azodicarboxylate, continue stirring reaction 1h, obtain membrane-forming agent;
(2) cerous nitrate is mixed with the aqueous solution of 9.6g/L, add potassium permanganate by the concentration of 2g/L again and be mixed with solution, then add the membrane-forming agent and other remaining components that 0.9wt% (1) step obtains, stir, supersound process 3min under ultrasonic cell disruptor, to obtain final product.
First aluminium section bar is carried out pre-treatment during use, then be immersed in treatment solution by aluminium section bar and carry out Passivation Treatment, temperature is 15 DEG C, and pH value is 1.8, and process 20min, takes out, and rinses with water, dries.
Passive film surface is finer and close, and naked eyes this film visible is golden yellow, has good outward appearance; After the test of the acetic acid salt spray of 1000h, corrosion-free, without obscission.
Claims (2)
1. an aluminium section bar environmental protection compound non-chromium passivation treatment fluid, is characterized in that being made up of the raw material of following weight part: cerous nitrate 9.6-10, potassium permanganate 2-2.2, glycerol 0.2-0.3, BIT 0.1-0.2, K
2zrF
61.2-1.3, vinylbenzene 0.6-0.8, acrylamide 0.2-0.3, vinylformic acid 0.4-0.5, Diisopropyl azodicarboxylate 0.05-0.1, sodium allylsulfonate 0.5-0.6, sodium lauryl sulphate 0.02-0.03, n-Hexadecane 0.9-1, silane coupling agent KH570 surface modified nano silicon 0.3-0.4, silane coupling agent KH570 surface-modified nano titanium dioxide 0.3-0.4, deionized water are appropriate.
2. the preparation method of aluminium section bar environmental protection compound non-chromium passivation treatment fluid according to claim 1, is characterized in that comprising the following steps:
(1) sodium lauryl sulphate is dissolved in the deionized water of 7-7.5 weight part and forms the aqueous solution, n-Hexadecane is mixed with vinylbenzene, silane coupling agent KH570 surface modified nano silicon, silane coupling agent KH570 surface-modified nano titanium dioxide, BIT is added after being stirred to dissolving, then by above two kinds of liquid mixing, supersound process 3-4min under ultrasonic cell disruptor, obtains emulsion; Described emulsion and acrylamide, vinylformic acid, sodium allylsulfonate are mixed, stirs, pass into nitrogen 15-16min, regulate pH=8, be warming up to 60-62 DEG C, add Diisopropyl azodicarboxylate, continue stirring reaction 1-2h, obtain membrane-forming agent;
(2) cerous nitrate is mixed with the aqueous solution of 9.6-10g/L, add potassium permanganate by the concentration of 2-2.2g/L again and be mixed with solution, add membrane-forming agent and other remaining components that 0.9-1.1wt% (1) step obtains again, stir, supersound process 3-4min under ultrasonic cell disruptor, to obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510521776.2A CN105088211A (en) | 2015-08-24 | 2015-08-24 | Aluminum profile environment-friendly composite chromate-free passivation conditioning fluid and preparing method thereof |
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| CN201510521776.2A CN105088211A (en) | 2015-08-24 | 2015-08-24 | Aluminum profile environment-friendly composite chromate-free passivation conditioning fluid and preparing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018185133A (en) * | 2017-04-25 | 2018-11-22 | マーレ インターナショナル ゲゼルシャフト ミット ベシュレンクテル ハフツングＭＡＨＬＥ Ｉｎｔｅｒｎａｔｉｏｎａｌ ＧｍｂＨ | Manufacturing method of heat exchanger |
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2015
- 2015-08-24 CN CN201510521776.2A patent/CN105088211A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018185133A (en) * | 2017-04-25 | 2018-11-22 | マーレ インターナショナル ゲゼルシャフト ミット ベシュレンクテル ハフツングＭＡＨＬＥ Ｉｎｔｅｒｎａｔｉｏｎａｌ ＧｍｂＨ | Manufacturing method of heat exchanger |
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Application publication date: 20151125 |