CN105088084B - Alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used - Google Patents
Alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used Download PDFInfo
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- CN105088084B CN105088084B CN201510585731.1A CN201510585731A CN105088084B CN 105088084 B CN105088084 B CN 105088084B CN 201510585731 A CN201510585731 A CN 201510585731A CN 105088084 B CN105088084 B CN 105088084B
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 18
- 239000000956 alloy Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910001563 bainite Inorganic materials 0.000 claims abstract description 19
- 238000001816 cooling Methods 0.000 claims abstract description 15
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 14
- 238000005266 casting Methods 0.000 claims abstract description 13
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 238000005516 engineering process Methods 0.000 claims abstract description 10
- 230000000717 retained effect Effects 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 7
- 229910000831 Steel Inorganic materials 0.000 claims description 23
- 239000010959 steel Substances 0.000 claims description 23
- 238000010791 quenching Methods 0.000 claims description 12
- 230000000171 quenching effect Effects 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 238000010079 rubber tapping Methods 0.000 claims description 9
- 238000002791 soaking Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000005496 tempering Methods 0.000 claims description 5
- 238000005275 alloying Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052729 chemical element Inorganic materials 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims 1
- 229910000617 Mangalloy Inorganic materials 0.000 abstract description 5
- 239000012535 impurity Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 abstract description 2
- 239000011651 chromium Substances 0.000 description 9
- 230000009466 transformation Effects 0.000 description 9
- 229910052796 boron Inorganic materials 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000010955 niobium Substances 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 229910052758 niobium Inorganic materials 0.000 description 6
- 229910052761 rare earth metal Inorganic materials 0.000 description 6
- 150000002910 rare earth metals Chemical class 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- 230000008520 organization Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 229910000859 α-Fe Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- ZLHLYESIHSHXGM-UHFFFAOYSA-N 4,6-dimethyl-1h-imidazo[1,2-a]purin-9-one Chemical compound N=1C(C)=CN(C2=O)C=1N(C)C1=C2NC=N1 ZLHLYESIHSHXGM-UHFFFAOYSA-N 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001339 C alloy Inorganic materials 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
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- Heat Treatment Of Articles (AREA)
Abstract
The present invention discloses alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used, and the percentage by weight of liner plate chemical composition is:C0.25%~0.45%;Si1.0%~1.5%;Cr0.5%~1.6%;Mn1.8%~2.2%;Mo0.3%~0.5%;B0.002%~0.004%;Nb0.03%~0.05%;Ti0.01%~0.03%;RE≤0.4%;Surplus is Fe and inevitable impurity, and the percent by volume of liner plate tissue is 50% ~ 55% lower bainite, 40% ~ 45% lath martensite and less than 5% retained austenite.Preparation method includes melting, casting, separation, heat treatment, and its case hardness of lining board of crusher of the present invention can reach 50~51HRC, and hardness is evenly distributed, and impact flexibility is in 100J/cm2~300J/cm2, tensile strength reaches more than 1500MPa, reaches the requirement of unimach.Production technology is easy to operate, and uniform lower bainite and martensite heterogeneous structure are obtained in the range of larger cooling rate, it is ensured that have higher wearability, breaks through high manganese steel lining plate tradition, and cost has some superiority.
Description
Technical field
The invention belongs to preparation equipment technical field, alloy ultra-high strength and toughness liner plate and system during especially a kind of disintegrating machine is used
Preparation Method.
Background technology
The liner plate of gyratory crusher, it is general to use potassium steel and modified high manganese steel, carbon alloy steel and chromium cast iron contained, strong
Impact load under, form hardening and wear-resisting toughness on its surface.But in the thin broken stage because shock loading is smaller,
Under weak impact loading, potassium steel is not wear-resisting.
The use industrial and mineral inclement condition of mine lining plate of cone crusher, had not only been hit but also frayed.Justify in recent years both at home and abroad
It is now undesirable with various material liner plate using effects in conic crusher, it is mainly shown as that the life-span is shorter.Conventional liner material quality is high
Manganese steel and ultra-high manganese steel toughness are had a surplus, and hardness, wear-resisting, corrosion resistance is not enough;Low-alloy steel toughness and corrosion resistance are inadequate;Gao Ge
Cast iron wearability is good, but toughness is not enough;So that the service life of liner plate is very short.Current grade of ore reduction, its hardness increase is needed
Want liner plate to have enough hardness and toughness, just can guarantee that the life-span;It is generally acknowledged that the hardness of preferable material need to reach HRC50, it is tough
Property also reaches 50J/cm-2More than.
The content of the invention
Alloy ultra-high strength and toughness liner plate and preparation method in being used it is an object of the invention to provide a kind of disintegrating machine, by closing
The composition design and Design of Heat Treatment Process of reason provide a kind of with low cost, excellent performance, the simple lining board of crusher of technique.
Disintegrating machine of the present invention percentage by weight of alloy ultra-high strength and toughness liner plate chemical composition in is:C 0.25%~
0.45%, Si 1.0% ~ 1.5%, Cr 0.5% ~ 1.6%, Mn 1.8% ~ 2.2%, Mo 0.3% ~ 0.5%, B 0.002% ~ 0.004%, Nb
0.03% ~ 0.05%, Ti 0.01% ~ 0.03%, RE≤0.4%, surplus is iron and inevitable impurity.
Alloy ultra-high strength and toughness liner plate chemical composition act as during disintegrating machine of the present invention is used:
C:Carbon is that bainitic steel obtains good obdurability matching and the most important element of comprehensive mechanical property.Carbon in steel with
The carbide of other alloying elements formation, which is solid-solution in ferrite, strengthens matrix, the intensity and hardness of steel is all increased substantially,
So as to improve the wearability of steel.Carbon content is too high, and hardness, the wearability of material can be improved accordingly, but is easily formed during heat treatment
Crackle, material fragility is big;Carbon content is too low, and hardness is low, wearability is not good after casting quenching.
Si:Silicon is solution strengthening element, can prevent Austenite Grain Growth, moves to right bainite transformation C curve, makes bayesian
Body transformation occurs in lower temperature.Silicon has good deoxidizing capacity, improves intensity, wearability and the yield strength of steel.Together
When silicon can hinder in drawing process the formation of carbide nucleus and grow up, suppress temper brittleness, carbon do not separated out in ferrite forward position
Compound, adds the stability of retained austenite, improves the temper resistance of martensite.But block iron element excessively occurs in silicon
Body, reduces toughness, and the silicon of moderate content is for ensureing that toughness is most suitable.
Cr:Chromium can improve the quenching degree and temper resistance of steel in steel, make F-P transition curves and bainite transformation curve
Separation.Chromium can be solid-solution in ferrite, can form a variety of carbide with the carbon in steel again, improved the antioxygenic property of steel, carried
Gao Gang wearability.When chromium content is less than 2%, the plasticity of steel can be improved, too high chromium can increase temper brittleness.
Mn:Manganese largely dissolves in ferrite, strengthens matrix, improves intensity, quenching degree and wearability, moreover it is possible to slow down pearlite
The forming core of alloyed cementite can effectively improve the stability of austenite with growing up during transformation, so as to improve the toughness of material.Necessarily
The manganese of content coordinates with boron, can protrude bainite transformation area, bainite is obtained in the range of larger cooling rate.While the price phase of manganese
To cheap, molybdenum amount can be reduced by improving manganese content.
Mo:Molybdenum can significantly improve the quenching degree of material, solution strengthening matrix, crystal grain thinning, energy when being used in mixed way with Cr, Mn
Reduce temper brittleness, the toughness and anti-fatigue ability of reinforcing material.After conditioned or normalizing and tempering heat treatment, it can obtain excellent
Good mechanical property.But in order to control alloy to add excessively, typically 1% or so.
B:Minimal amount of boron is postponed and Bainite Region is become flat significantly with regard to Neng Shi high temperature transformations area.Into bainitic steel
Quenching degree can be significantly improved and improve toughness by adding micro B element, and B and Mo compound actions make overcooling austenite to ferritic etc.
Warm transition curve is further moved to right, and bainite transformation initial is substantially protruded.But, B is that a chemical property is more active
Element, easily form boride segregation in crystal boundary, reduce the toughness of steel.When B content is more than 0.006%, easily separate out thick
Fe23 (CB) 6, will cause boron crisp.
Nb、Ti:Niobium can improve bainite matrix strength, be mutually promoted between boron so that the compound ratio that adds is individually added into
Niobium or boron can more be played a role, the addition of trace niobium, and the carbonitride Nb of the indissoluble of a large amount of Dispersed precipitates is produced in the base
(CN), the pinning dislocation in drawing process so that dislocation is not easy to recover and disappeared, it is ensured that the intensity of matrix;Nb and B etc. is combined
Add, reduce the transition temperature of bainite, further thinning microstructure improves matrix middle position dislocation density;Titanium is that strong carbide is formed
Element, grain refinement effect clearly, can eliminate the primary crystallization and crystal boundary element segregation that is typically heat-treated and can not eliminate,
Steel belt roof bolt fragility is reduced, quenching degree can be also improved, instead of part noble element.But too high niobium, titanium can cause thick be mingled with
Thing is formed.
RE:RE can improve as cast condition crystalline structure, crystal grain thinning, increase the consistency of steel, improve field trash property, form and
Distribution, reduction objectionable impurities elements are improved the toughness of steel, the corrosion resistance to steel also has necessarily in the degree of segregation of crystal boundary
Influence.The Adding Way and addition of rare earth have a great impact to Steel Properties, and adding excessively may deteriorate the performance of steel.Become
The matter agent rare earth alterative that 10min will be preheated before tapping(≤ 0.4% molten steel weight)Add the addition of ladle bottom rare earth
The general ratio and rare earth yield according to [RE]/[S] of amount determines that the rate of recovery is between 10%~30%.By empirical equation [RE]/
[S]=2.0 ~ 2.5, calculate rare earth adding quantity=0.4%.
The preparation method of alloy ultra-high strength and toughness liner plate during disintegrating machine of the present invention is used.
Pure iron is melted in vaccum sensitive stove, in 1500 ~ 1550 DEG C of tappings, alloy is added into vaccum sensitive stove before tapping
Alloying is carried out, while carrying out desulfurization, deoxidation, detecting and adjust chemical element component content, taps preceding ten minutes and adds Y base weights
Rare earth alterative carries out Metamorphism treatment;When temperature drops to 1450 ~ 1470 DEG C in vaccum sensitive stove, sand mold mould type is poured into
In chamber;Casting terminates rear natural cooling 1.5h ~ 2h, is unpacked after cooling and casting is cleared up.With 80 ~ 100 DEG C/h speed
Casting is heated to 550 ~ 650 DEG C from normal temperature, soaking time is determined with the maximum thickness of liner plate, 1 ~ 2h is incubated, then with 150 ~
200 DEG C/h speed is heated to 900 ~ 950 DEG C, and soaking time is determined with the maximum thickness of liner plate, is incubated 2 ~ 5h, afterwards air cooling
Or oil quenching, temperature is 300 ~ 350 DEG C, determines soaking time with the maximum thickness of liner plate, is incubated 3 ~ 6h, is taken out after tempering
Casting air cooling.
The percent by volume of the liner plate tissue be 50% ~ 55% lower bainite, 40% ~ 45% lath martensite and 5% with
Under retained austenite.
Beneficial effects of the present invention, its case hardness of lining board of crusher can reach 50~51HRC, and hardness is evenly distributed,
Impact flexibility is in 100J/cm2~300J/cm2Between, tensile strength reaches more than 1500MPa, reaches wanting for unimach
Ask.Production technology is easy to operate, uniform lower bainite and martensite heterogeneous structure is obtained in the range of larger cooling rate, it is ensured that have
Higher wearability, breaks through high manganese steel lining plate tradition, and cost has some superiority.
Brief description of the drawings
Fig. 1 is the embodiment of the present invention 1, the Technology for Heating Processing route map of embodiment 2;
Fig. 2 is the embodiment of the present invention 3, the Technology for Heating Processing route map of embodiment 4;
Fig. 3 is the organization chart of the embodiment of the present invention 1(52% lower bainite, 43% lath martensite, 5% retained austenite);
Fig. 4 is the organization chart of the embodiment of the present invention 2(50% lower bainite, 45% lath martensite, 5% retained austenite);
Fig. 5 is the organization chart of the embodiment of the present invention 3(55% lower bainite, 43% lath martensite, 2% retained austenite);
Fig. 6 is the organization chart of the embodiment of the present invention 4(52% lower bainite, 45% lath martensite, 3% retained austenite).
Embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings.
Fig. 1 shows Example 1 and Example 2 of the present invention Technology for Heating Processing route map, and Fig. 2 shows embodiment 3 and real
Apply the Technology for Heating Processing route map of example 4;The alloy ultra-high strength and toughness liner plate chemical component weight percentage such as institute of table 1 during disintegrating machine is used
Show, altogether using 4 embodiments.
Alloy ultra-high strength and toughness liner plate Technology for Heating Processing is as shown in table 2 during disintegrating machine is used.First, constitute former as described in table 1
The percentage by weight of material weighs each element, in the fusing of intermediate frequency furnace iron, in 1500 DEG C ~ 1550 DEG C tappings, to melting before tapping
Alloy is added in stove and carries out alloying, at the same carry out desulfurization, deoxidation, using refining agent, detect and adjust chemical element component and contain
Amount, taps preceding ten minutes and adds Y based heavy rare earths alterant progress Metamorphism treatment.1450 are dropped in vaccum sensitive stove when temperature ~
At 1470 DEG C, it is poured into sand mold mould die cavity;Casting terminates rear natural cooling 1.5h ~ 2h, is unpacked after cooling and casting is entered
Row cleaning.For embodiment 1, embodiment 2,550 DEG C are heated to from normal temperature with 90 DEG C/h speed, 1.5h is incubated(Liner plate is most
General goal thickness is 75mm), then with 180 DEG C/h speed it is heated to 950 DEG C, after insulation 3h, air quenching or oil quenching, temperature is
350 DEG C, 5h is incubated, liner plate air cooling is taken out after tempering;For embodiment 3, embodiment 4, heated with 90 DEG C/h speed from normal temperature
To 600 DEG C, 2h is incubated(The maximum thickness of liner plate is 100mm), then with 180 DEG C/h speed it is heated to 900 DEG C, it is incubated 4h
Afterwards, air quenching or oil quenching, temperature are 300 DEG C, are incubated 6h, and liner plate air cooling is taken out after tempering.
The liner plate chemical composition (Wt%) of table 1
Embodiment | C | Si | Cr | Mn | Mo | B | Nb | Ti | RE |
1、2 | 0.4 | 1.29 | 0.51 | 1.88 | 0.42 | 0.0022 | 0.033 | 0.01 | |
3、4 | 0.35 | 1.35 | 1.46 | 1.82 | 0.44 | 0.0031 | 0.049 | 0.028 | 0.011 |
The liner plate preparation technology parameter of table 2
The liner plate mechanical performance of table 3
Alloy ultra-high strength and toughness liner plate mechanical performance is as shown in table 3 during disintegrating machine is used, with reference to accompanying drawing 3, accompanying drawing 4, the and of accompanying drawing 5
Tissue understands that the even tissue of embodiment 1 is tiny in accompanying drawing 6, and main phase composition is bainite, can be provided for liner plate well
Toughness;The main phase composition of embodiment 2 is martensite, and martensite possesses high intensity, excellent hardness is provided for liner plate;Embodiment
3rd, a small amount of retained austenite can be substantially observed in embodiment 4, retained austenite can produce phase transformation in the course of the work, to tool
There are martensite and the bainite transformation of premium properties, a small amount of austenite can also organize the extension of crackle, further improve
The toughness of liner plate.
Claims (4)
- Alloy ultra-high strength and toughness liner plate during 1. a kind of disintegrating machine is used, it is characterised in that:The weight percent of the liner plate chemical composition Than for:The percent by volume of the liner plate tissue be 50%~55% lower bainite, 40%~45% lath martensite and Less than 5% retained austenite, impact flexibility is in 100J/cm2~300J/cm2Between;Preparation method comprises the following steps:(1) pure iron is melted in vaccum sensitive stove, in 1500~1550 DEG C of tappings, alloy is added into vaccum sensitive stove before tapping Alloying is carried out, while carrying out desulfurization, deoxidation, detecting and adjust chemical element component content;(2) when temperature drops to 1450~1470 DEG C in vaccum sensitive stove, it is poured into sand mold mould die cavity;After casting terminates Natural cooling 1.5h~2h, unpacks after cooling and casting is cleared up;(3) Technology for Heating Processing:Casting is heated to 550~650 DEG C from normal temperature with 80~100 DEG C/h speed, with liner plate most General goal thickness determines soaking time, is incubated 1~2h, then is heated to 900~950 DEG C with 150~200 DEG C/h speed, with liner plate Maximum thickness determine soaking time, be incubated 2~5h, air cooling or oil quenching afterwards, temperature are 300~350 DEG C, with liner plate Maximum thickness determine soaking time, be incubated 3~6h, after tempering take out casting air cooling.
- Alloy ultra-high strength and toughness liner plate during 2. disintegrating machine according to claim 1 is used, it is characterised in that:The step (1) Add alterant within ten minutes before middle tapping and carry out Metamorphism treatment, alterant is Y based heavy rare earths alterants, and particle diameter size is less than 11mm, the gained after 150~180 DEG C of temperature baking carries out Metamorphism treatment using method is poured in bag to molten steel.
- Alloy ultra-high strength and toughness liner plate during 3. disintegrating machine according to claim 1 is used, it is characterised in that:The tapping temperature For 1550 DEG C, pouring temperature is 1455 DEG C.
- Alloy ultra-high strength and toughness liner plate during 4. disintegrating machine according to claim 1 is used, it is characterised in that:The liner plate thickness For 75~100mm, casting is heated to 550~600 DEG C by heat treatment with 90~100 DEG C/h speed from normal temperature, and insulation 1.5~ 2h, then 930~950 DEG C are heated to 180~200 DEG C/h speed, 3~3.5h is incubated, temperature is 300~340 DEG C, is protected 4~6h of temperature.
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CN101956140A (en) * | 2010-09-28 | 2011-01-26 | 河南科技大学 | Lining plate for large ball mill and casting method thereof |
CN104532130A (en) * | 2015-01-21 | 2015-04-22 | 北京科技大学 | High-strength and toughness anticorrosive lining plate for wet ball mill and preparation method |
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CN101956140A (en) * | 2010-09-28 | 2011-01-26 | 河南科技大学 | Lining plate for large ball mill and casting method thereof |
CN104532130A (en) * | 2015-01-21 | 2015-04-22 | 北京科技大学 | High-strength and toughness anticorrosive lining plate for wet ball mill and preparation method |
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