CN105088084B - Alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used - Google Patents

Alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used Download PDF

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CN105088084B
CN105088084B CN201510585731.1A CN201510585731A CN105088084B CN 105088084 B CN105088084 B CN 105088084B CN 201510585731 A CN201510585731 A CN 201510585731A CN 105088084 B CN105088084 B CN 105088084B
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liner plate
toughness
temperature
high strength
disintegrating machine
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CN105088084A (en
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王汝杰
李东
孙伟锐
张�浩
于代林
费启鸥
苏耀明
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Angang Group Mining Co Ltd
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Angang Group Mining Co Ltd
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Abstract

The present invention discloses alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used, and the percentage by weight of liner plate chemical composition is:C0.25%~0.45%;Si1.0%~1.5%;Cr0.5%~1.6%;Mn1.8%~2.2%;Mo0.3%~0.5%;B0.002%~0.004%;Nb0.03%~0.05%;Ti0.01%~0.03%;RE≤0.4%;Surplus is Fe and inevitable impurity, and the percent by volume of liner plate tissue is 50% ~ 55% lower bainite, 40% ~ 45% lath martensite and less than 5% retained austenite.Preparation method includes melting, casting, separation, heat treatment, and its case hardness of lining board of crusher of the present invention can reach 50~51HRC, and hardness is evenly distributed, and impact flexibility is in 100J/cm2~300J/cm2, tensile strength reaches more than 1500MPa, reaches the requirement of unimach.Production technology is easy to operate, and uniform lower bainite and martensite heterogeneous structure are obtained in the range of larger cooling rate, it is ensured that have higher wearability, breaks through high manganese steel lining plate tradition, and cost has some superiority.

Description

Alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used
Technical field
The invention belongs to preparation equipment technical field, alloy ultra-high strength and toughness liner plate and system during especially a kind of disintegrating machine is used Preparation Method.
Background technology
The liner plate of gyratory crusher, it is general to use potassium steel and modified high manganese steel, carbon alloy steel and chromium cast iron contained, strong Impact load under, form hardening and wear-resisting toughness on its surface.But in the thin broken stage because shock loading is smaller, Under weak impact loading, potassium steel is not wear-resisting.
The use industrial and mineral inclement condition of mine lining plate of cone crusher, had not only been hit but also frayed.Justify in recent years both at home and abroad It is now undesirable with various material liner plate using effects in conic crusher, it is mainly shown as that the life-span is shorter.Conventional liner material quality is high Manganese steel and ultra-high manganese steel toughness are had a surplus, and hardness, wear-resisting, corrosion resistance is not enough;Low-alloy steel toughness and corrosion resistance are inadequate;Gao Ge Cast iron wearability is good, but toughness is not enough;So that the service life of liner plate is very short.Current grade of ore reduction, its hardness increase is needed Want liner plate to have enough hardness and toughness, just can guarantee that the life-span;It is generally acknowledged that the hardness of preferable material need to reach HRC50, it is tough Property also reaches 50J/cm-2More than.
The content of the invention
Alloy ultra-high strength and toughness liner plate and preparation method in being used it is an object of the invention to provide a kind of disintegrating machine, by closing The composition design and Design of Heat Treatment Process of reason provide a kind of with low cost, excellent performance, the simple lining board of crusher of technique.
Disintegrating machine of the present invention percentage by weight of alloy ultra-high strength and toughness liner plate chemical composition in is:C 0.25%~ 0.45%, Si 1.0% ~ 1.5%, Cr 0.5% ~ 1.6%, Mn 1.8% ~ 2.2%, Mo 0.3% ~ 0.5%, B 0.002% ~ 0.004%, Nb 0.03% ~ 0.05%, Ti 0.01% ~ 0.03%, RE≤0.4%, surplus is iron and inevitable impurity.
Alloy ultra-high strength and toughness liner plate chemical composition act as during disintegrating machine of the present invention is used:
C:Carbon is that bainitic steel obtains good obdurability matching and the most important element of comprehensive mechanical property.Carbon in steel with The carbide of other alloying elements formation, which is solid-solution in ferrite, strengthens matrix, the intensity and hardness of steel is all increased substantially, So as to improve the wearability of steel.Carbon content is too high, and hardness, the wearability of material can be improved accordingly, but is easily formed during heat treatment Crackle, material fragility is big;Carbon content is too low, and hardness is low, wearability is not good after casting quenching.
Si:Silicon is solution strengthening element, can prevent Austenite Grain Growth, moves to right bainite transformation C curve, makes bayesian Body transformation occurs in lower temperature.Silicon has good deoxidizing capacity, improves intensity, wearability and the yield strength of steel.Together When silicon can hinder in drawing process the formation of carbide nucleus and grow up, suppress temper brittleness, carbon do not separated out in ferrite forward position Compound, adds the stability of retained austenite, improves the temper resistance of martensite.But block iron element excessively occurs in silicon Body, reduces toughness, and the silicon of moderate content is for ensureing that toughness is most suitable.
Cr:Chromium can improve the quenching degree and temper resistance of steel in steel, make F-P transition curves and bainite transformation curve Separation.Chromium can be solid-solution in ferrite, can form a variety of carbide with the carbon in steel again, improved the antioxygenic property of steel, carried Gao Gang wearability.When chromium content is less than 2%, the plasticity of steel can be improved, too high chromium can increase temper brittleness.
Mn:Manganese largely dissolves in ferrite, strengthens matrix, improves intensity, quenching degree and wearability, moreover it is possible to slow down pearlite The forming core of alloyed cementite can effectively improve the stability of austenite with growing up during transformation, so as to improve the toughness of material.Necessarily The manganese of content coordinates with boron, can protrude bainite transformation area, bainite is obtained in the range of larger cooling rate.While the price phase of manganese To cheap, molybdenum amount can be reduced by improving manganese content.
Mo:Molybdenum can significantly improve the quenching degree of material, solution strengthening matrix, crystal grain thinning, energy when being used in mixed way with Cr, Mn Reduce temper brittleness, the toughness and anti-fatigue ability of reinforcing material.After conditioned or normalizing and tempering heat treatment, it can obtain excellent Good mechanical property.But in order to control alloy to add excessively, typically 1% or so.
B:Minimal amount of boron is postponed and Bainite Region is become flat significantly with regard to Neng Shi high temperature transformations area.Into bainitic steel Quenching degree can be significantly improved and improve toughness by adding micro B element, and B and Mo compound actions make overcooling austenite to ferritic etc. Warm transition curve is further moved to right, and bainite transformation initial is substantially protruded.But, B is that a chemical property is more active Element, easily form boride segregation in crystal boundary, reduce the toughness of steel.When B content is more than 0.006%, easily separate out thick Fe23 (CB) 6, will cause boron crisp.
Nb、Ti:Niobium can improve bainite matrix strength, be mutually promoted between boron so that the compound ratio that adds is individually added into Niobium or boron can more be played a role, the addition of trace niobium, and the carbonitride Nb of the indissoluble of a large amount of Dispersed precipitates is produced in the base (CN), the pinning dislocation in drawing process so that dislocation is not easy to recover and disappeared, it is ensured that the intensity of matrix;Nb and B etc. is combined Add, reduce the transition temperature of bainite, further thinning microstructure improves matrix middle position dislocation density;Titanium is that strong carbide is formed Element, grain refinement effect clearly, can eliminate the primary crystallization and crystal boundary element segregation that is typically heat-treated and can not eliminate, Steel belt roof bolt fragility is reduced, quenching degree can be also improved, instead of part noble element.But too high niobium, titanium can cause thick be mingled with Thing is formed.
RE:RE can improve as cast condition crystalline structure, crystal grain thinning, increase the consistency of steel, improve field trash property, form and Distribution, reduction objectionable impurities elements are improved the toughness of steel, the corrosion resistance to steel also has necessarily in the degree of segregation of crystal boundary Influence.The Adding Way and addition of rare earth have a great impact to Steel Properties, and adding excessively may deteriorate the performance of steel.Become The matter agent rare earth alterative that 10min will be preheated before tapping(≤ 0.4% molten steel weight)Add the addition of ladle bottom rare earth The general ratio and rare earth yield according to [RE]/[S] of amount determines that the rate of recovery is between 10%~30%.By empirical equation [RE]/ [S]=2.0 ~ 2.5, calculate rare earth adding quantity=0.4%.
The preparation method of alloy ultra-high strength and toughness liner plate during disintegrating machine of the present invention is used.
Pure iron is melted in vaccum sensitive stove, in 1500 ~ 1550 DEG C of tappings, alloy is added into vaccum sensitive stove before tapping Alloying is carried out, while carrying out desulfurization, deoxidation, detecting and adjust chemical element component content, taps preceding ten minutes and adds Y base weights Rare earth alterative carries out Metamorphism treatment;When temperature drops to 1450 ~ 1470 DEG C in vaccum sensitive stove, sand mold mould type is poured into In chamber;Casting terminates rear natural cooling 1.5h ~ 2h, is unpacked after cooling and casting is cleared up.With 80 ~ 100 DEG C/h speed Casting is heated to 550 ~ 650 DEG C from normal temperature, soaking time is determined with the maximum thickness of liner plate, 1 ~ 2h is incubated, then with 150 ~ 200 DEG C/h speed is heated to 900 ~ 950 DEG C, and soaking time is determined with the maximum thickness of liner plate, is incubated 2 ~ 5h, afterwards air cooling Or oil quenching, temperature is 300 ~ 350 DEG C, determines soaking time with the maximum thickness of liner plate, is incubated 3 ~ 6h, is taken out after tempering Casting air cooling.
The percent by volume of the liner plate tissue be 50% ~ 55% lower bainite, 40% ~ 45% lath martensite and 5% with Under retained austenite.
Beneficial effects of the present invention, its case hardness of lining board of crusher can reach 50~51HRC, and hardness is evenly distributed, Impact flexibility is in 100J/cm2~300J/cm2Between, tensile strength reaches more than 1500MPa, reaches wanting for unimach Ask.Production technology is easy to operate, uniform lower bainite and martensite heterogeneous structure is obtained in the range of larger cooling rate, it is ensured that have Higher wearability, breaks through high manganese steel lining plate tradition, and cost has some superiority.
Brief description of the drawings
Fig. 1 is the embodiment of the present invention 1, the Technology for Heating Processing route map of embodiment 2;
Fig. 2 is the embodiment of the present invention 3, the Technology for Heating Processing route map of embodiment 4;
Fig. 3 is the organization chart of the embodiment of the present invention 1(52% lower bainite, 43% lath martensite, 5% retained austenite);
Fig. 4 is the organization chart of the embodiment of the present invention 2(50% lower bainite, 45% lath martensite, 5% retained austenite);
Fig. 5 is the organization chart of the embodiment of the present invention 3(55% lower bainite, 43% lath martensite, 2% retained austenite);
Fig. 6 is the organization chart of the embodiment of the present invention 4(52% lower bainite, 45% lath martensite, 3% retained austenite).
Embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings.
Fig. 1 shows Example 1 and Example 2 of the present invention Technology for Heating Processing route map, and Fig. 2 shows embodiment 3 and real Apply the Technology for Heating Processing route map of example 4;The alloy ultra-high strength and toughness liner plate chemical component weight percentage such as institute of table 1 during disintegrating machine is used Show, altogether using 4 embodiments.
Alloy ultra-high strength and toughness liner plate Technology for Heating Processing is as shown in table 2 during disintegrating machine is used.First, constitute former as described in table 1 The percentage by weight of material weighs each element, in the fusing of intermediate frequency furnace iron, in 1500 DEG C ~ 1550 DEG C tappings, to melting before tapping Alloy is added in stove and carries out alloying, at the same carry out desulfurization, deoxidation, using refining agent, detect and adjust chemical element component and contain Amount, taps preceding ten minutes and adds Y based heavy rare earths alterant progress Metamorphism treatment.1450 are dropped in vaccum sensitive stove when temperature ~ At 1470 DEG C, it is poured into sand mold mould die cavity;Casting terminates rear natural cooling 1.5h ~ 2h, is unpacked after cooling and casting is entered Row cleaning.For embodiment 1, embodiment 2,550 DEG C are heated to from normal temperature with 90 DEG C/h speed, 1.5h is incubated(Liner plate is most General goal thickness is 75mm), then with 180 DEG C/h speed it is heated to 950 DEG C, after insulation 3h, air quenching or oil quenching, temperature is 350 DEG C, 5h is incubated, liner plate air cooling is taken out after tempering;For embodiment 3, embodiment 4, heated with 90 DEG C/h speed from normal temperature To 600 DEG C, 2h is incubated(The maximum thickness of liner plate is 100mm), then with 180 DEG C/h speed it is heated to 900 DEG C, it is incubated 4h Afterwards, air quenching or oil quenching, temperature are 300 DEG C, are incubated 6h, and liner plate air cooling is taken out after tempering.
The liner plate chemical composition (Wt%) of table 1
Embodiment C Si Cr Mn Mo B Nb Ti RE
1、2 0.4 1.29 0.51 1.88 0.42 0.0022 0.033 0.01
3、4 0.35 1.35 1.46 1.82 0.44 0.0031 0.049 0.028 0.011
The liner plate preparation technology parameter of table 2
The liner plate mechanical performance of table 3
Alloy ultra-high strength and toughness liner plate mechanical performance is as shown in table 3 during disintegrating machine is used, with reference to accompanying drawing 3, accompanying drawing 4, the and of accompanying drawing 5 Tissue understands that the even tissue of embodiment 1 is tiny in accompanying drawing 6, and main phase composition is bainite, can be provided for liner plate well Toughness;The main phase composition of embodiment 2 is martensite, and martensite possesses high intensity, excellent hardness is provided for liner plate;Embodiment 3rd, a small amount of retained austenite can be substantially observed in embodiment 4, retained austenite can produce phase transformation in the course of the work, to tool There are martensite and the bainite transformation of premium properties, a small amount of austenite can also organize the extension of crackle, further improve The toughness of liner plate.

Claims (4)

  1. Alloy ultra-high strength and toughness liner plate during 1. a kind of disintegrating machine is used, it is characterised in that:The weight percent of the liner plate chemical composition Than for:
    The percent by volume of the liner plate tissue be 50%~55% lower bainite, 40%~45% lath martensite and Less than 5% retained austenite, impact flexibility is in 100J/cm2~300J/cm2Between;
    Preparation method comprises the following steps:
    (1) pure iron is melted in vaccum sensitive stove, in 1500~1550 DEG C of tappings, alloy is added into vaccum sensitive stove before tapping Alloying is carried out, while carrying out desulfurization, deoxidation, detecting and adjust chemical element component content;
    (2) when temperature drops to 1450~1470 DEG C in vaccum sensitive stove, it is poured into sand mold mould die cavity;After casting terminates Natural cooling 1.5h~2h, unpacks after cooling and casting is cleared up;
    (3) Technology for Heating Processing:Casting is heated to 550~650 DEG C from normal temperature with 80~100 DEG C/h speed, with liner plate most General goal thickness determines soaking time, is incubated 1~2h, then is heated to 900~950 DEG C with 150~200 DEG C/h speed, with liner plate Maximum thickness determine soaking time, be incubated 2~5h, air cooling or oil quenching afterwards, temperature are 300~350 DEG C, with liner plate Maximum thickness determine soaking time, be incubated 3~6h, after tempering take out casting air cooling.
  2. Alloy ultra-high strength and toughness liner plate during 2. disintegrating machine according to claim 1 is used, it is characterised in that:The step (1) Add alterant within ten minutes before middle tapping and carry out Metamorphism treatment, alterant is Y based heavy rare earths alterants, and particle diameter size is less than 11mm, the gained after 150~180 DEG C of temperature baking carries out Metamorphism treatment using method is poured in bag to molten steel.
  3. Alloy ultra-high strength and toughness liner plate during 3. disintegrating machine according to claim 1 is used, it is characterised in that:The tapping temperature For 1550 DEG C, pouring temperature is 1455 DEG C.
  4. Alloy ultra-high strength and toughness liner plate during 4. disintegrating machine according to claim 1 is used, it is characterised in that:The liner plate thickness For 75~100mm, casting is heated to 550~600 DEG C by heat treatment with 90~100 DEG C/h speed from normal temperature, and insulation 1.5~ 2h, then 930~950 DEG C are heated to 180~200 DEG C/h speed, 3~3.5h is incubated, temperature is 300~340 DEG C, is protected 4~6h of temperature.
CN201510585731.1A 2015-09-16 2015-09-16 Alloy ultra-high strength and toughness liner plate and preparation method during a kind of disintegrating machine is used Active CN105088084B (en)

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CN105543706B (en) * 2016-01-25 2017-08-25 山西中条山机电设备有限公司 A kind of high-strength and high-ductility abrasion-resistant cast steel material and preparation method thereof
CN115354217B (en) * 2022-07-04 2023-03-03 钢铁研究总院有限公司 Impact-abrasion-resistant complex-phase structure hammer head and preparation method thereof

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CN101660106A (en) * 2009-09-10 2010-03-03 洛阳瑞图机械有限公司 Wear-resistant high-ductility vanadium, niobium and rare earth alloy steel liner plate and manufacture technology
CN101956140A (en) * 2010-09-28 2011-01-26 河南科技大学 Lining plate for large ball mill and casting method thereof
CN104532130A (en) * 2015-01-21 2015-04-22 北京科技大学 High-strength and toughness anticorrosive lining plate for wet ball mill and preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101660106A (en) * 2009-09-10 2010-03-03 洛阳瑞图机械有限公司 Wear-resistant high-ductility vanadium, niobium and rare earth alloy steel liner plate and manufacture technology
CN101956140A (en) * 2010-09-28 2011-01-26 河南科技大学 Lining plate for large ball mill and casting method thereof
CN104532130A (en) * 2015-01-21 2015-04-22 北京科技大学 High-strength and toughness anticorrosive lining plate for wet ball mill and preparation method

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