CN105086686A - Multicolor water-based road marking paint taking acrylic resin as matrix and preparation method thereof - Google Patents
Multicolor water-based road marking paint taking acrylic resin as matrix and preparation method thereof Download PDFInfo
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- CN105086686A CN105086686A CN201510487470.XA CN201510487470A CN105086686A CN 105086686 A CN105086686 A CN 105086686A CN 201510487470 A CN201510487470 A CN 201510487470A CN 105086686 A CN105086686 A CN 105086686A
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Abstract
The invention discloses multicolor water-based road marking paint taking acrylic resin as a matrix, and relates to the technical field of chemical industry paint preparation. The multicolor water-based road marking paint is prepared from 35-45 parts of thermoplastic acrylic resin, 5-15 parts of cellulose acetate, 3-5 parts of anti-settling agents, 15-25 parts of inorganic water absorption particles, 3-5 parts of matrix pigment, 5-10 parts of photoinitiators, 3-15 parts of nano wear-resisting emulsion and 5-15 parts of nano oxidation particle metal. The multicolor water-based road marking paint taking the acrylic resin as the matrix and a preparation method thereof have the advantages that through special combination of existing substances in the prior art and processing of all the links, the paint is bright in color, good in color fixing capacity, high in light resistance, not prone to being oxidized and capable of ensuring the corrosion resistance of the paint; the paint is one of indispensable products in future transport industry and is environmentally friendly, free of poison, efficient, high in market value and convenient to use and popularize.
Description
Technical field
The present invention relates to chemistry painting industry preparing technical field, being specifically related to a kind of take acrylic resin as illusion-colour water-based road marking paint of matrix and preparation method thereof.
Background technology
One of key character of road guide line paint is their speed dry after application, because this demonstrate the interruption degree for using needed for their road traffics.This paint is conventional based on the resin be dissolved in organic solvent.Except having potential pollution to environment, this kind solvent is rapid evaporation after paint imposes on road, and the people that to make with it be like this target is exposed among potential Health hazard.Therefore, need the roadmarking that exploitation is more harmless to environment, paint is throughout the year under illumination condition, therefore, photostabilization, anti-oxidant, ageing resistance must reach a standard, meanwhile, present stage different kinds of roads paint be substantially all adopt white for primary colours, but due to the different demands of current roading, the function distinguishing of road also has different divisions, if only adopt white paint to distinguish, is easy to the misunderstanding that can cause people, even also can cause grave error, cause the generation of traffic accident.
Summary of the invention:
Technical problem to be solved by this invention is to provide a kind of formula rationally, and production technique is simple, bright in luster, and antioxidant property is strong, and what photostabilization was stable take acrylic resin as illusion-colour water-based road marking paint of matrix and preparation method thereof.
Technical problem to be solved by this invention realizes by the following technical solutions:
Take acrylic resin as an illusion-colour water-based road marking paint for matrix, it is characterized in that: be made up of following raw material:
Thermoplastic acrylic resin 35-45 part, cellulose acetate 5-15 part, anti-settling agent 3-5 part, inorganic water-absorption particle 15-25 part, base pigments element 3-5 part, light trigger 5-10 part, nano wearproof emulsion 3-15 part, nano oxidized granular metal 5-15 part.
The preferred component of each raw material is:
Thermoplastic acrylic resin 40 parts, cellulose acetate 10 parts, anti-settling agent 4 parts, inorganic water-absorption particle 20 parts, base pigments element 4 parts, light trigger 7 parts, nano wearproof emulsion 9 parts, nano oxidized granular metal 10 parts.
Described inorganic water-absorption particle is ion exchange resin ball grain or superabsorbent gels, potassium type resin cation (R.C.) spherolite.
Described nano wearproof emulsion to be hydrolyzed reaction to the mixing solutions of deionized water, ethanol and silane coupling agent under whipped state, then add nanometer mixed powder and carry out catalyzed reaction and obtain.
Described anti-settling agent is polyethylene wax or hydrogenated castor oil.
Described pigment extracts by herbaceous plant, and all adopts titanium dioxide to carry out fixation treatment, nontoxic;
Treatment process is: pigment and titanium dioxide are selected the component of same proportion to carry out 120-130 DEG C of heat and stir, after then lowering the temperature.
Described nano oxidized granular metal is zinc oxide or calcium oxide.
Described light trigger is sulfo-propoxy-thioxanthone or isopropyl thioxanthone.
Another object of the present invention is to provide a kind of method that the present invention of preparation take acrylic resin as the illusion-colour water-based road marking paint of matrix:
First thermoplastic acrylic resin and cellulose acetate are put into stirrer, abundant stirring 200-300min, then add base pigments element and carry out stirring 50 minutes, add inorganic water-absorption particle, nano wearproof emulsion, nano oxidized granular metal again, continue stirring 60 minutes, finally add anti-settling agent, flow agent and light trigger and stir 80 minutes, cooling discharging.
The present invention, by using thermoplastic acrylic resin as major ingredient, itself has excellent photostabilization and anti-outdoor aging performance, ensure that the working life of marking paint, durable in use;
Pigment is that plants herb extracts, and ensure that the safety non-toxic of itself, uses titanium dioxide to carry out fixation simultaneously, ensure that color dyes, there will not be the look that withers that fades;
The interpolation of inorganic water-absorption particle, ensure the uniform color in marking paint, consolidation, makes moisture content in marking paint little to greatest extent, improves sticking power;
Nano wearproof emulsion, nano oxidized granular metal have higher mutual solubility, ensure that marking paint is fine and smooth evenly, particle is little, improve the adhesive ability of marking paint.
Beneficial effect of the present invention is: the present invention is by having the particular combination of material to prior art, by the process of various link, it can be made bright-colored, and fixation power is good, and colleague's photostabilization is strong, not oxidizable, can also ensure the erosion resistance of itself, be in future transportation industry, one of indispensable product, environment-protecting asepsis, efficient, marketable value is high, is convenient to promote and use.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
Take thermoplastic acrylic resin 35kg, cellulose acetate 5kg, polyethylene wax 3kg, inorganic water-absorption particle 15kg, base pigments element 3kg, sulfo-propoxy-thioxanthone 5kg, nano wearproof emulsion 3kg, zinc oxide 5kg;
Described inorganic water-absorption particle is ion exchange resin ball grain or superabsorbent gels, potassium type resin cation (R.C.) spherolite.
Described nano wearproof emulsion to be hydrolyzed reaction to the mixing solutions of deionized water, ethanol and silane coupling agent under whipped state, then add nanometer mixed powder and carry out catalyzed reaction and obtain.
Preparation method is as follows:
First thermoplastic acrylic resin and cellulose acetate are put into stirrer, abundant stirring 200-300min, then add base pigments element and carry out stirring 50 minutes, add inorganic water-absorption particle, nano wearproof emulsion, zinc oxide again, continue stirring 60 minutes, finally add polyethylene wax and sulfo-propoxy-thioxanthone stirs 80 minutes, cooling discharging.
Embodiment 2
Take thermoplastic acrylic resin 40kg, cellulose acetate 10kg, hydrogenated castor oil 4kg, inorganic water-absorption particle 20kg, base pigments element 4kg, isopropyl thioxanthone 7kg, nano wearproof emulsion 9kg, calcium oxide 10kg;
Described inorganic water-absorption particle is ion exchange resin ball grain or superabsorbent gels, potassium type resin cation (R.C.) spherolite.
Described nano wearproof emulsion to be hydrolyzed reaction to the mixing solutions of deionized water, ethanol and silane coupling agent under whipped state, then add nanometer mixed powder and carry out catalyzed reaction and obtain.
Preparation method is as follows:
First thermoplastic acrylic resin and cellulose acetate are put into stirrer, abundant stirring 200-300min, then add base pigments element and carry out stirring 50 minutes, add inorganic water-absorption particle, nano wearproof emulsion, calcium oxide again, continue stirring 60 minutes, finally add hydrogenated castor oil and isopropyl thioxanthone stirs 80 minutes, cooling discharging.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (9)
1. be an illusion-colour water-based road marking paint for matrix with acrylic resin, it is characterized in that: be made up of following raw material:
Thermoplastic acrylic resin 35-45 part, cellulose acetate 5-15 part, anti-settling agent 3-5 part, inorganic water-absorption particle 15-25 part, base pigments element 3-5 part, light trigger 5-10 part, nano wearproof emulsion 3-15 part, nano oxidized granular metal 5-15 part.
2. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that, the preferred component of each raw material is: thermoplastic acrylic resin 40 parts, cellulose acetate 10 parts, anti-settling agent 4 parts, inorganic water-absorption particle 20 parts, base pigments element 4 parts, light trigger 7 parts, nano wearproof emulsion 9 parts, nano oxidized granular metal 10 parts.
3. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that: described inorganic water-absorption particle is ion exchange resin ball grain or superabsorbent gels, potassium type resin cation (R.C.) spherolite.
4. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that: described nano wearproof emulsion to be hydrolyzed reaction to the mixing solutions of deionized water, ethanol and silane coupling agent under whipped state, then add nanometer mixed powder and carry out catalyzed reaction and obtain.
5. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that: described anti-settling agent is polyethylene wax or hydrogenated castor oil.
6. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that: described pigment extracts by herbaceous plant, and all adopt titanium dioxide to carry out fixation treatment;
Treatment process is: pigment and titanium dioxide are selected the component of same proportion to carry out 120-130 DEG C of heat and stir, after then lowering the temperature.
7. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that: described nano oxidized granular metal is zinc oxide or calcium oxide.
8. according to claim 1 a kind of take acrylic resin as the illusion-colour water-based road marking paint of matrix, it is characterized in that: described light trigger is sulfo-propoxy-thioxanthone or isopropyl thioxanthone.
9. preparing a kind of in claim 1 or 2 take acrylic resin as the method for the illusion-colour water-based road marking paint of matrix, it is characterized in that:
First thermoplastic acrylic resin and cellulose acetate are put into stirrer, abundant stirring 200-300min, then add base pigments element and carry out stirring 50 minutes, add inorganic water-absorption particle, nano wearproof emulsion, nano oxidized granular metal again, continue stirring 60 minutes, finally add anti-settling agent, flow agent and light trigger and stir 80 minutes, cooling discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510487470.XA CN105086686A (en) | 2015-08-05 | 2015-08-05 | Multicolor water-based road marking paint taking acrylic resin as matrix and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510487470.XA CN105086686A (en) | 2015-08-05 | 2015-08-05 | Multicolor water-based road marking paint taking acrylic resin as matrix and preparation method thereof |
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| CN105086686A true CN105086686A (en) | 2015-11-25 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370294A (en) * | 2018-12-17 | 2019-02-22 | 浙江欧路德交通科技有限公司 | A kind of water paint water-absorbing resins microballoon and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181216A (en) * | 2011-06-15 | 2011-09-14 | 江苏雅迪科技发展有限公司 | Apple green paint |
| CN102241933A (en) * | 2011-06-15 | 2011-11-16 | 江苏雅迪科技发展有限公司 | Pearlescent pale yellow paint |
| CN102241932A (en) * | 2011-06-15 | 2011-11-16 | 江苏雅迪科技发展有限公司 | Colorful paint |
-
2015
- 2015-08-05 CN CN201510487470.XA patent/CN105086686A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181216A (en) * | 2011-06-15 | 2011-09-14 | 江苏雅迪科技发展有限公司 | Apple green paint |
| CN102241933A (en) * | 2011-06-15 | 2011-11-16 | 江苏雅迪科技发展有限公司 | Pearlescent pale yellow paint |
| CN102241932A (en) * | 2011-06-15 | 2011-11-16 | 江苏雅迪科技发展有限公司 | Colorful paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370294A (en) * | 2018-12-17 | 2019-02-22 | 浙江欧路德交通科技有限公司 | A kind of water paint water-absorbing resins microballoon and preparation method thereof |
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Application publication date: 20151125 |
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