CN105086357A - Pouring-type modified urea resin foaming thermal-insulation material - Google Patents
Pouring-type modified urea resin foaming thermal-insulation material Download PDFInfo
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- CN105086357A CN105086357A CN201510492053.4A CN201510492053A CN105086357A CN 105086357 A CN105086357 A CN 105086357A CN 201510492053 A CN201510492053 A CN 201510492053A CN 105086357 A CN105086357 A CN 105086357A
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- formaldehyde resin
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- thermal
- modified urea
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Abstract
The invention discloses a pouring-type modified urea resin foaming thermal-insulation material. The pouring-type modified urea resin foaming thermal-insulation material is composed of a group A of materials and a group B of materials, the group B of materials comprises phosphoric acid, foaming agents, foam stabilizers and water, sodium dodecyl sulfate is selected to be the foaming agents, silicon resin polyether emulsion is selected to be the foam stabilizers, the group A of materials comprises a urea resin water solution and cross-linking agents, and polyhydric alcohol is selected to be the cross-linking agents. In the using process, the group A of materials and the group B of materials are mixed to be foamed so as to obtain the thermal-insulation material, foaming speed is high, and the obtained thermal-insulation material is good in thermal-insulation effect, high in tenacity, not likely to crack and capable of meeting requirements for thermal-insulation materials in building industry construction due to non-pulverization.
Description
Technical field
The invention belongs to building trade lagging material technical field used, be specifically related to a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating.
Background technology
The foaming thermal-insulating used in building trade has the material of foaming in advance, also has casting type material, and casting type material needs fast pouring shaping at the construction field (site).
Urea-formaldehyde resin foaming thermal insulation material is a class lagging material conventional at present, owing to belonging to water base property resin, physical foaming method is adopted during use, therefore environmental protection, urea-formaldehyde resin class foaming thermal-insulating has excellent insulation, heat-proof quality in addition, and cheap, therefore apply very extensive.
But existing urea-formaldehyde resin foaming thermal insulation material expansion rate is slow, and cast-in-site toughness is poor, easily cracking and efflorescence, therefore still needs to improve.
Summary of the invention
The object of this invention is to provide that a kind of high insulating effect, expansion rate are fast, toughness by force, the urea-formaldehyde resin foaming thermal insulation material of efflorescence not easy to crack.
In order to realize object of the present invention, inventor provide following technical scheme.
A kind of casting type modified urea-formaldehyde resin foaming thermal-insulating, be made up of A group and B group two groups of materials, B group material comprises phosphoric acid, whipping agent, suds-stabilizing agent, water, and A group material comprises urea-formaldehyde resin aqueous solution, linking agent, and described linking agent is polyol resin.
Above-mentioned casting type modified urea-formaldehyde resin foaming thermal-insulating, the weight percent composition of described B group material comprises phosphoric acid 5-8%, pore forming material 1-2%, suds-stabilizing agent 1-2%, water 90%.
Above-mentioned casting type modified urea-formaldehyde resin foaming thermal-insulating, the ratio of weight and number composition of described A group material comprises urea-formaldehyde resin aqueous solution 100 parts, linking agent 10-25 part.
Above-mentioned casting type modified urea-formaldehyde resin foaming thermal-insulating, the ratio of weight and number of A group material and B group material is 1-1.5:1.
Above-mentioned casting type modified urea-formaldehyde resin foaming thermal-insulating, described whipping agent is sodium lauryl sulphate.
Above-mentioned casting type modified urea-formaldehyde resin foaming thermal-insulating, described suds-stabilizing agent is silicone resin polyethers emulsion suds-stabilizing agent.
Above-mentioned casting type modified urea-formaldehyde resin foaming thermal-insulating, in described urea-formaldehyde resin aqueous solution, the weight percent content of solid is 50-55%.
Urea-formaldehyde resin foaming thermal insulation material provided by the present invention, Easy dosing, with low cost, cast-in-site is easy to use, excellent thermal insulation performance, and expansion rate is fast, and toughness is strong, not easy to crack, efflorescence, can meet the requirement to lagging material in building operation, is suitable for suitability for industrialized production application.
Embodiment
In conjunction with specific embodiments content of the present invention is described in further detail.
embodiment 1
B group material: phosphoric acid 5kg, sodium lauryl sulphate (K12) 1kg, silicone resin polyethers emulsion 1kg, water 90kg, mix for subsequent use.
A group material: urea-formaldehyde resin aqueous solution 100kg(is containing urea-formaldehyde resin 50kg), polyol resin 10kg, mixes for subsequent use.
Get A group material 50kg, B group material 50kg, at a high speed mixing foaming.
embodiment 2
B group material: phosphatase 11 2kg, sodium lauryl sulphate (K12) 2kg, silicone resin polyethers emulsion 2kg, water 85kg, mix for subsequent use.
A group material: urea-formaldehyde resin aqueous solution 100kg(is containing urea-formaldehyde resin 55kg), polyol resin 25kg, mixes for subsequent use.
Get A group material 75kg, B group material 50kg, at a high speed mixing foaming.
embodiment 3
B group material: phosphoric acid 7kg, sodium lauryl sulphate (K12) 1.5kg, silicone resin polyethers emulsion 1.5kg, water 90kg, mix for subsequent use.
A group material: urea-formaldehyde resin aqueous solution 100kg(is containing urea-formaldehyde resin 53kg), polyol resin 18kg, mixes for subsequent use.
Get A group material 65kg, B group material 50kg, at a high speed mixing foaming.
In order to investigate the performance of urea-formaldehyde resin foaming thermal insulation material of the present invention, contriver has carried out tensile strength detection to the product that embodiment 1-3 obtains, and all at more than 0.2MPa, toughness is good; Thermal conductivity is all at 0.030W/(m
.k) below, heat insulation effect is good.
Claims (7)
1. a casting type modified urea-formaldehyde resin foaming thermal-insulating, it is characterized in that, be made up of A group and B group two groups of materials, B group material comprises phosphoric acid, pore forming material, suds-stabilizing agent, water, A group material comprises urea-formaldehyde resin aqueous solution, linking agent, and described linking agent is polyol resin.
2. a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating according to claim 1, is characterized in that, the weight percent composition of described B group material comprises phosphoric acid 5-8%, whipping agent 1-2%, suds-stabilizing agent 1-2%, water 90%.
3. a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating according to claim 1, is characterized in that, the ratio of weight and number composition of described A group material comprises urea-formaldehyde resin aqueous solution 100 parts, linking agent 10-25 part.
4. a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating according to claim 1, is characterized in that, the ratio of weight and number of A group material and B group material is 1-1.5:1.
5. a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating according to claim 1 and 2, it is characterized in that, described whipping agent is sodium lauryl sulphate.
6. a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating according to claim 1 and 2, is characterized in that, described suds-stabilizing agent is silicone resin polyethers emulsion suds-stabilizing agent.
7. a kind of casting type modified urea-formaldehyde resin foaming thermal-insulating according to claim 1 or 3, it is characterized in that, in described urea-formaldehyde resin aqueous solution, the weight percent content of solid is 50-55%.
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CN201510492053.4A CN105086357A (en) | 2015-08-12 | 2015-08-12 | Pouring-type modified urea resin foaming thermal-insulation material |
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CN201510492053.4A CN105086357A (en) | 2015-08-12 | 2015-08-12 | Pouring-type modified urea resin foaming thermal-insulation material |
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CN201510492053.4A Pending CN105086357A (en) | 2015-08-12 | 2015-08-12 | Pouring-type modified urea resin foaming thermal-insulation material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112745058A (en) * | 2021-01-06 | 2021-05-04 | 北京市高强混凝土有限责任公司 | Foaming agent and foam concrete containing same |
Citations (5)
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CN101289567A (en) * | 2007-04-16 | 2008-10-22 | 天津优宁福姆建筑节能科技开发有限公司 | Urea-formaldehyde resin foaming thermal insulation material |
CN102964773A (en) * | 2012-12-13 | 2013-03-13 | 天津优宁福姆建筑节能科技开发有限公司 | Inflaming retarding type urea resin foam insulation material |
CN103194042A (en) * | 2013-04-02 | 2013-07-10 | 沈阳德汇新型材料有限公司 | Urea-formaldehyde foam plastic insulation board and preparation method thereof |
CN103613904A (en) * | 2013-11-27 | 2014-03-05 | 山东圣泉化工股份有限公司 | Low-density low-acidicity phenol formaldehyde foam board and preparation technique thereof |
CN103834137A (en) * | 2014-03-10 | 2014-06-04 | 安飞 | Embedded polyethylene glycol foam board and preparation method thereof |
-
2015
- 2015-08-12 CN CN201510492053.4A patent/CN105086357A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101289567A (en) * | 2007-04-16 | 2008-10-22 | 天津优宁福姆建筑节能科技开发有限公司 | Urea-formaldehyde resin foaming thermal insulation material |
CN102964773A (en) * | 2012-12-13 | 2013-03-13 | 天津优宁福姆建筑节能科技开发有限公司 | Inflaming retarding type urea resin foam insulation material |
CN103194042A (en) * | 2013-04-02 | 2013-07-10 | 沈阳德汇新型材料有限公司 | Urea-formaldehyde foam plastic insulation board and preparation method thereof |
CN103613904A (en) * | 2013-11-27 | 2014-03-05 | 山东圣泉化工股份有限公司 | Low-density low-acidicity phenol formaldehyde foam board and preparation technique thereof |
CN103834137A (en) * | 2014-03-10 | 2014-06-04 | 安飞 | Embedded polyethylene glycol foam board and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112745058A (en) * | 2021-01-06 | 2021-05-04 | 北京市高强混凝土有限责任公司 | Foaming agent and foam concrete containing same |
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Application publication date: 20151125 |