CN105086332A - Hard ABS (acrylonitrile butadiene styrene) pipe and production method thereof - Google Patents
Hard ABS (acrylonitrile butadiene styrene) pipe and production method thereof Download PDFInfo
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- CN105086332A CN105086332A CN201510525663.XA CN201510525663A CN105086332A CN 105086332 A CN105086332 A CN 105086332A CN 201510525663 A CN201510525663 A CN 201510525663A CN 105086332 A CN105086332 A CN 105086332A
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Abstract
The invention relates to the field of composite materials, in particular to a hard ABS (acrylonitrile butadiene styrene) pipe and a production method thereof. The ABS pipe comprises, by weight, 120 to 140 parts of ABS, 6 to 8 parts of chlorinated polyethylene, 10 to 20 parts of nano calcium carbonate, 3 to 4 parts of glass fiber, 4 to 5 parts of titanium white, 2 to 3 parts of PE (polyethylene) wax, 2 to 4 parts of calcium-zinc stabilizer, and 4 to 5 parts of ACR. By using the hard ABS pipe, the hard ABS pipe is usable at a high temperature, processability is optimized, high-speed processing of ABS plates is facilitated, and processing efficiency of products is improved.
Description
Technical field
The present invention relates to field of compound material, specifically a kind of hard ABS tubing and preparation method thereof.
Background technology
ABS major ingredient is polyvinyl chloride, adds other one-tenth in addition and assigns to strengthen its thermotolerance, toughness, ductility etc.In building-up process, ABS tubing needs multiple starting material, cost is relatively high, because ABS pipe has higher stability to be often used in the pipeline of the transport liquids such as water pipe, in use once will there is the accident of a large amount of leak of liquid because external force extruding occurs to rupture, hard ABS tubing compressive strength in the market all has much room for improvement.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of hard ABS tubing and preparation method thereof.
The solution of the present invention is by realizing like this:
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS120-140 part, chlorinatedpolyethylene 6-8 part, nano-calcium carbonate 10-20 part, glass fibre 3-4 part, titanium dioxide 4-5 part, PE wax 2-3 part, calcium zinc stabilizer 2-4 part, ACR4-5 part.
Preferably, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS120 part, chlorinatedpolyethylene 8 parts, nano-calcium carbonate 15 parts, 3 parts, glass fibre, titanium dioxide 5 parts, 2 parts, PE wax, calcium zinc stabilizer 3 parts, ACR4 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS120-140 part, chlorinatedpolyethylene 6-8 part, nano-calcium carbonate 10-20 part, glass fibre 3-4 part, titanium dioxide 4-5 part, PE wax 2-3 part, calcium zinc stabilizer 2-4 part, ACR4-5 part are added in homogenizer and stir, reach 110-130 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 35-50 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 160-190 DEG C.
Preferably, in step (1), stop stirring when temperature of charge reaches 125 DEG C.
Preferably, in step (2), discharging when temperature of charge is down to 45 DEG C.
Preferably, in step (3), twin screw extruder processing temperature is 180 DEG C.
The present invention possesses following good result:
(1) the ABS pipe resistance to compression shock resistance prepared of the present invention is excellent, is applicable to making the workpiece that various high strength requires.
(2) in the present invention, ABS tubing is easy to processing, and between each feed composition, homogeny is good.
(3) with low cost, the remarkable in economical benefits of ABS tubing of the present invention.
Embodiment
Describe a kind of hard ABS tubing of the present invention and preparation method thereof below in conjunction with embodiment, these descriptions are not be further limited content of the present invention.
embodiment 1
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS120 part, chlorinatedpolyethylene 8 parts, nano-calcium carbonate 15 parts, 3 parts, glass fibre, titanium dioxide 5 parts, 2 parts, PE wax, calcium zinc stabilizer 3 parts, ACR4 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS120 part, chlorinatedpolyethylene 8 parts, nano-calcium carbonate 15 parts, 3 parts, glass fibre, titanium dioxide 5 parts, 2 parts, PE wax, calcium zinc stabilizer 3 parts, ACR4 part are added in homogenizer and stir, reach 125 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 45 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 180 DEG C.
embodiment 2
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS140 part, chlorinatedpolyethylene 6 parts, nano-calcium carbonate 10 parts, 4 parts, glass fibre, titanium dioxide 5 parts, 3 parts, PE wax, calcium zinc stabilizer 2 parts, ACR4-5 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS140 part, chlorinatedpolyethylene 6 parts, nano-calcium carbonate 10 parts, 4 parts, glass fibre, titanium dioxide 5 parts, 3 parts, PE wax, calcium zinc stabilizer 2 parts, ACR4-5 part are added in homogenizer and stir, reach 125 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 45 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 180 DEG C.
embodiment 3
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS130 part, chlorinatedpolyethylene 7 parts, nano-calcium carbonate 20 parts, 3 parts, glass fibre, titanium dioxide 4 parts, 3 parts, PE wax, calcium zinc stabilizer 4 parts, ACR5 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS130 part, chlorinatedpolyethylene 7 parts, nano-calcium carbonate 20 parts, 3 parts, glass fibre, titanium dioxide 4 parts, 3 parts, PE wax, calcium zinc stabilizer 4 parts, ACR5 part are added in homogenizer and stir, reach 125 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 45 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 180 DEG C.
embodiment 4
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS120 part, chlorinatedpolyethylene 8 parts, nano-calcium carbonate 15 parts, 3 parts, glass fibre, titanium dioxide 5 parts, 2 parts, PE wax, calcium zinc stabilizer 3 parts, ACR4 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS120 part, chlorinatedpolyethylene 8 parts, nano-calcium carbonate 15 parts, 3 parts, glass fibre, titanium dioxide 5 parts, 2 parts, PE wax, calcium zinc stabilizer 3 parts, ACR4 part are added in homogenizer and stir, reach 110 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 35 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 160 DEG C.
embodiment 5
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS130 part, chlorinatedpolyethylene 7 parts, nano-calcium carbonate 20 parts, 3 parts, glass fibre, titanium dioxide 4 parts, 3 parts, PE wax, calcium zinc stabilizer 4 parts, ACR5 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS130 part, chlorinatedpolyethylene 7 parts, nano-calcium carbonate 20 parts, 3 parts, glass fibre, titanium dioxide 4 parts, 3 parts, PE wax, calcium zinc stabilizer 4 parts, ACR5 part are added in homogenizer and stir, reach 130 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 50 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 190 DEG C.
embodiment 6
A kind of hard ABS tubing, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS140 part, chlorinatedpolyethylene 6 parts, nano-calcium carbonate 10 parts, 4 parts, glass fibre, titanium dioxide 5 parts, 3 parts, PE wax, calcium zinc stabilizer 2 parts, ACR4-5 part.
The preparation method of above-mentioned hard ABS tubing, comprises the following steps:
(1) first ABS140 part, chlorinatedpolyethylene 6 parts, nano-calcium carbonate 10 parts, 4 parts, glass fibre, titanium dioxide 5 parts, 3 parts, PE wax, calcium zinc stabilizer 2 parts, ACR4-5 part are added in homogenizer and stir, reach 120 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 40 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 170 DEG C.
Claims (6)
1. a hard ABS tubing, it is characterized in that, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS120-140 part, chlorinatedpolyethylene 6-8 part, nano-calcium carbonate 10-20 part, glass fibre 3-4 part, titanium dioxide 4-5 part, PE wax 2-3 part, calcium zinc stabilizer 2-4 part, ACR4-5 part.
2. hard ABS tubing according to claim 1, it is characterized in that, this tubing comprises the raw material of following weight ratio: ABS tubing comprises following feed composition and weight part: ABS120 part, chlorinatedpolyethylene 8 parts, nano-calcium carbonate 15 parts, 3 parts, glass fibre, titanium dioxide 5 parts, 2 parts, PE wax, calcium zinc stabilizer 3 parts, ACR4 part.
3. a preparation method for hard ABS tubing, is characterized in that, comprises the following steps:
(1) first ABS120-140 part, chlorinatedpolyethylene 6-8 part, nano-calcium carbonate 10-20 part, glass fibre 3-4 part, titanium dioxide 4-5 part, PE wax 2-3 part, calcium zinc stabilizer 2-4 part, ACR4-5 part are added in homogenizer and stir, reach 110-130 DEG C to temperature of charge and stop stirring;
(2) then transport material in cold mixer and stir cooling, when temperature of charge is down to 35-50 DEG C, discharging;
(3) finally compound is delivered to extrusion moulding in twin screw extruder and make tubing, twin screw extruder processing temperature is 160-190 DEG C.
4. the preparation method of activeness and quietness ABS tubing according to claim 3, is characterized in that, in step (1), stops stirring when temperature of charge reaches 125 DEG C.
5. the preparation method of activeness and quietness ABS tubing according to claim 3, is characterized in that, in step (2), and discharging when temperature of charge is down to 45 DEG C.
6. the preparation method of activeness and quietness ABS tubing according to claim 3, is characterized in that, in step (3), twin screw extruder processing temperature is 180 DEG C.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102558741A (en) * | 2010-12-16 | 2012-07-11 | 合肥杰事杰新材料股份有限公司 | Flame-retarded Acrylonitrile Butadiene Styrene (ABS) resin with good low-temperature toughness and preparation method of flame-retarded ABS resin |
CN102675810A (en) * | 2012-05-11 | 2012-09-19 | 江苏安格特科技发展有限公司 | High-impact extrusion grade ABS (Acrylonitrile Butadiene Styrene) nanocomposite material |
CN103570893A (en) * | 2013-10-16 | 2014-02-12 | 青岛华瑞胶业设备有限公司 | High-hardness ABS (acrylonitrile-butadiene-styrene) material |
CN104211873A (en) * | 2014-08-29 | 2014-12-17 | 青岛承天伟业机械制造有限公司 | High-strength composite plastic |
CN104292741A (en) * | 2014-09-30 | 2015-01-21 | 苏州润佳工程塑料股份有限公司 | ABS (acrylonitrile butadiene styrene copolymers) composite material and preparation method thereof |
CN104371264A (en) * | 2014-11-28 | 2015-02-25 | 苏州银禧科技有限公司 | High-hardness transparent flame-retardant ABS (acrylonitrile butadiene styrene) composite and preparation method thereof |
-
2015
- 2015-08-25 CN CN201510525663.XA patent/CN105086332A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102558741A (en) * | 2010-12-16 | 2012-07-11 | 合肥杰事杰新材料股份有限公司 | Flame-retarded Acrylonitrile Butadiene Styrene (ABS) resin with good low-temperature toughness and preparation method of flame-retarded ABS resin |
CN102675810A (en) * | 2012-05-11 | 2012-09-19 | 江苏安格特科技发展有限公司 | High-impact extrusion grade ABS (Acrylonitrile Butadiene Styrene) nanocomposite material |
CN103570893A (en) * | 2013-10-16 | 2014-02-12 | 青岛华瑞胶业设备有限公司 | High-hardness ABS (acrylonitrile-butadiene-styrene) material |
CN104211873A (en) * | 2014-08-29 | 2014-12-17 | 青岛承天伟业机械制造有限公司 | High-strength composite plastic |
CN104292741A (en) * | 2014-09-30 | 2015-01-21 | 苏州润佳工程塑料股份有限公司 | ABS (acrylonitrile butadiene styrene copolymers) composite material and preparation method thereof |
CN104371264A (en) * | 2014-11-28 | 2015-02-25 | 苏州银禧科技有限公司 | High-hardness transparent flame-retardant ABS (acrylonitrile butadiene styrene) composite and preparation method thereof |
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Application publication date: 20151125 |