CN105086137A - Low-temperature-resisting anti-bacteria polypropylene plastic product - Google Patents

Low-temperature-resisting anti-bacteria polypropylene plastic product Download PDF

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Publication number
CN105086137A
CN105086137A CN201510471176.XA CN201510471176A CN105086137A CN 105086137 A CN105086137 A CN 105086137A CN 201510471176 A CN201510471176 A CN 201510471176A CN 105086137 A CN105086137 A CN 105086137A
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China
Prior art keywords
parts
bacteria
polypropylene
low temperature
nano
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Pending
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CN201510471176.XA
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Chinese (zh)
Inventor
王维东
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Zhejiang Tongchuang Electrical Appliance Co Ltd
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Zhejiang Tongchuang Electrical Appliance Co Ltd
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Priority to CN201510471176.XA priority Critical patent/CN105086137A/en
Publication of CN105086137A publication Critical patent/CN105086137A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a low-temperature-resisting anti-bacteria polypropylene plastic product which comprises, by mass, 75-85 parts of polypropylene master batch, 20-30 parts of polyethylene glycol terephthalate, 7-16 parts of POE elastomer toughening agents, 2-7 parts of inorganic nano-silver anti-bacteria master batch, 2-3.5 parts of methyltin mercaptide heat stabilizers, 1-3 parts of benzene 4-benzene dimethylbenzene anhydride, 0.5-2 pars of stearic acid, 1-3 parts of glass fiber, 0.5-1.5 parts of nano inorganic far-infrared materials and 0.3-1 part of an antistatic agent. The low-temperature-resisting anti-bacteria polypropylene plastic product has good gloss, is not prone to embrittlement and fracture at low temperature, has good anti-bacteria performance, has the high far infrared radiation rate with the wave length corresponding to human body radiation absorption, can play the health care effect on the human body, has the effects of resisting ultraviolet light, killing bacteria, eliminating foreign flavor, preventing and treating diseases and the like, can effectively improve human body microcirculation, improves normal microcirculation blood flow by 2-3 times, improves oxygen supply and the metabolism and boosts immunity.

Description

Low temperature resistant Antibacterial polypropylene plastic goods
[technical field]
The present invention relates to the technical field of plastic material, particularly the technical field of low temperature resistant Antibacterial polypropylene plastic goods.
[background technology]
Along with the raising of people's living standard, plastics occupy indispensable status in people's daily life.Polypropylene is a kind of non-toxic plastic, has superior heat resistance and good physicals, is widely used.But it is matt, easily brittle and break at low temperatures, easily polluted by various unwanted bacteria.Under suitable temperature and humidity condition, very easily bacterial growth.
[summary of the invention]
Object of the present invention solves the problems of the prior art exactly, proposes low temperature resistant Antibacterial polypropylene plastic goods, can have good gloss, not easily brittle and break at low temperatures, has good bacteriostasis property.
For achieving the above object, the present invention proposes low temperature resistant Antibacterial polypropylene plastic goods, comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 75 ~ 85 parts, polyethylene terephthalate: 20 ~ 30 parts, POE elastic body toughening agent: 7 ~ 16 parts, inorganic nano-silver antibacterial plastic concentrate: 2 ~ 7 parts, methyl tin heat stabilizer: 2 ~ 3.5 parts, four Australia's phthalate anhydrides: 1 ~ 3 part, stearic acid: 0.5 ~ 2 part, glass fibre: 1 ~ 3 part, nano inorganic far-infrared material: 0.5 ~ 1.5 part, static inhibitor: 0.3 ~ 1 part.
As preferably, described low temperature resistant Antibacterial polypropylene plastic goods comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 75 parts, polyethylene terephthalate: 20 parts, POE elastic body toughening agent: 7 parts, inorganic nano-silver antibacterial plastic concentrate: 2 parts, methyl tin heat stabilizer: 2 parts, four Australia's phthalate anhydrides: 1 part, stearic acid: 0.5 part, glass fibre: 1 part, nano inorganic far-infrared material: 0.5 part, static inhibitor: 0.3 part.
As preferably, described low temperature resistant Antibacterial polypropylene plastic goods comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 85 parts, polyethylene terephthalate: 30 parts, POE elastic body toughening agent: 16 parts, inorganic nano-silver antibacterial plastic concentrate: 7 parts, methyl tin heat stabilizer: 3.5 parts, four Australia's phthalate anhydrides: 3 parts, stearic acid: 2 parts, glass fibre: 3 parts, nano inorganic far-infrared material: 1.5 parts, static inhibitor: 1 part.
As preferably, described static inhibitor is the static inhibitor HDC-202 that Linan, Hangzhou Dechang Chemical Co., Ltd. produces.
As preferably, the intestinal bacteria of described plastics: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter; Streptococcus aureus: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter.
Beneficial effect of the present invention: the present invention improves plastics resistance to low temperature by adopting the agent of POE elastic body toughening, and there is good gloss, the application of inorganic nano-silver antibacterial plastic concentrate, there is antibacterial, can bacteria growing inhibiting, the application of nano inorganic far-infrared material, there is the farsighted infrared emittance absorbing respective wavelength with human body radiation, can play a role in health care to human body, there is uvioresistant, peculiar smell is eliminated in sterilization, the function such as to prevent and cure diseases, effectively can improve microcirculation in human body, normal microcirculation blood flow is impelled to increase by 2 ~ 3 times, improve and organize oxygen supply, improve metabolism, strengthening immunity.
[embodiment]
Embodiment 1
The low temperature resistant Antibacterial polypropylene plastic goods of the present invention, comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 80 parts, polyethylene terephthalate: 25 parts, POE elastic body toughening agent: 8 parts, inorganic nano-silver antibacterial plastic concentrate: 5 parts, methyl tin heat stabilizer: 3 parts, four Australia's phthalate anhydrides: 2 parts, stearic acid: 1 part, glass fibre: 2 parts, nano inorganic far-infrared material: 0.8 part, static inhibitor: 0.6 part.
Described static inhibitor is the static inhibitor HDC-202 that Linan, Hangzhou Dechang Chemical Co., Ltd. produces, the intestinal bacteria of described plastics: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter; Streptococcus aureus: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter.
Embodiment 2
The low temperature resistant Antibacterial polypropylene plastic goods of the present invention, comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 75 parts, polyethylene terephthalate: 20 parts, POE elastic body toughening agent: 7 parts, inorganic nano-silver antibacterial plastic concentrate: 2 parts, methyl tin heat stabilizer: 2 parts, four Australia's phthalate anhydrides: 1 part, stearic acid: 0.5 part, glass fibre: 1 part, nano inorganic far-infrared material: 0.5 part, static inhibitor: 0.3 part.
Described static inhibitor is the static inhibitor HDC-202 that Linan, Hangzhou Dechang Chemical Co., Ltd. produces, the intestinal bacteria of described plastics: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter; Streptococcus aureus: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter.
Embodiment 3
The low temperature resistant Antibacterial polypropylene plastic goods of the present invention, comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 85 parts, polyethylene terephthalate: 30 parts, POE elastic body toughening agent: 16 parts, inorganic nano-silver antibacterial plastic concentrate: 7 parts, methyl tin heat stabilizer: 3.5 parts, four Australia's phthalate anhydrides: 3 parts, stearic acid: 2 parts, glass fibre: 3 parts, nano inorganic far-infrared material: 1.5 parts, static inhibitor: 1 part.
Described static inhibitor is the static inhibitor HDC-202 that Linan, Hangzhou Dechang Chemical Co., Ltd. produces, the intestinal bacteria of described plastics: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter; Streptococcus aureus: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter.
Above-described embodiment is to explanation of the present invention, is not limitation of the invention, anyly all belongs to protection scope of the present invention to the scheme after simple transformation of the present invention.

Claims (5)

1. low temperature resistant Antibacterial polypropylene plastic goods, it is characterized in that: comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 75 ~ 85 parts, polyethylene terephthalate: 20 ~ 30 parts, POE elastic body toughening agent: 7 ~ 16 parts, inorganic nano-silver antibacterial plastic concentrate: 2 ~ 7 parts, methyl tin heat stabilizer: 2 ~ 3.5 parts, four Australia's phthalate anhydrides: 1 ~ 3 part, stearic acid: 0.5 ~ 2 part, glass fibre: 1 ~ 3 part, nano inorganic far-infrared material: 0.5 ~ 1.5 part, static inhibitor: 0.3 ~ 1 part.
2. low temperature resistant Antibacterial polypropylene plastic goods as claimed in claim 1, it is characterized in that: comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 75 parts, polyethylene terephthalate: 20 parts, POE elastic body toughening agent: 7 parts, inorganic nano-silver antibacterial plastic concentrate: 2 parts, methyl tin heat stabilizer: 2 parts, four Australia's phthalate anhydrides: 1 part, stearic acid: 0.5 part, glass fibre: 1 part, nano inorganic far-infrared material: 0.5 part, static inhibitor: 0.3 part.
3. low temperature resistant Antibacterial polypropylene plastic goods as claimed in claim 1, it is characterized in that: comprise following component and the quality proportioning of each component is: polypropylene agglomerate: 85 parts, polyethylene terephthalate: 30 parts, POE elastic body toughening agent: 16 parts, inorganic nano-silver antibacterial plastic concentrate: 7 parts, methyl tin heat stabilizer: 3.5 parts, four Australia's phthalate anhydrides: 3 parts, stearic acid: 2 parts, glass fibre: 3 parts, nano inorganic far-infrared material: 1.5 parts, static inhibitor: 1 part.
4. low temperature resistant Antibacterial polypropylene plastic goods as claimed in claim 1, is characterized in that: described static inhibitor is the static inhibitor HDC-202 that Linan, Hangzhou Dechang Chemical Co., Ltd. produces.
5. the low temperature resistant Antibacterial polypropylene plastic goods according to any one of Claims 1-4, is characterized in that: the intestinal bacteria of described plastics: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter; Streptococcus aureus: 24 hours antibiotic rate >=98%; Colony number < 100/milliliter.
CN201510471176.XA 2015-08-04 2015-08-04 Low-temperature-resisting anti-bacteria polypropylene plastic product Pending CN105086137A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106279983A (en) * 2016-08-12 2017-01-04 苏州柯创电子材料有限公司 A kind of ultra-toughness high impact resistance polypropylene
CN106279984A (en) * 2016-08-12 2017-01-04 苏州柯创电子材料有限公司 A kind of PP composite material of high-strength and high ductility
CN106589593A (en) * 2016-12-10 2017-04-26 汤诗怡 Antibacterial and anti-static polypropylene composite material for inner barrel of washing machine and preparation method of antibacterial and anti-static polypropylene composite material

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CN1580114A (en) * 2003-08-13 2005-02-16 陈卫国 High-lustre antibacterial polypropylene material and its manufacturing method
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CN103421242A (en) * 2013-07-26 2013-12-04 上海盈致橡塑制品有限公司 PP (polypropylene) and PET composite antibacterial plastic alloy
CN103467849A (en) * 2013-09-02 2013-12-25 吴江市物华五金制品有限公司 Antibacterial and mildew-proof PP (polypropylene)/PET (polyethylene terephthalate) packaging material and preparation method thereof
CN104710684A (en) * 2013-12-13 2015-06-17 黑龙江鑫达企业集团有限公司 Modified antibiotic sweat-resistant plastic for keyboards and mice, and preparation method thereof

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CN1580114A (en) * 2003-08-13 2005-02-16 陈卫国 High-lustre antibacterial polypropylene material and its manufacturing method
CN101058663A (en) * 2007-05-15 2007-10-24 中南大学 Far infrared health care macromolecule composite material
CN101108906A (en) * 2007-08-22 2008-01-23 上海景鹏日用品有限公司 Polypropylene plastics and manufacturing method thereof
CN101519512A (en) * 2009-03-24 2009-09-02 山东威高集团医用高分子制品股份有限公司 Polypropylene composite material
CN103421242A (en) * 2013-07-26 2013-12-04 上海盈致橡塑制品有限公司 PP (polypropylene) and PET composite antibacterial plastic alloy
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CN104710684A (en) * 2013-12-13 2015-06-17 黑龙江鑫达企业集团有限公司 Modified antibiotic sweat-resistant plastic for keyboards and mice, and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106279983A (en) * 2016-08-12 2017-01-04 苏州柯创电子材料有限公司 A kind of ultra-toughness high impact resistance polypropylene
CN106279984A (en) * 2016-08-12 2017-01-04 苏州柯创电子材料有限公司 A kind of PP composite material of high-strength and high ductility
CN106279983B (en) * 2016-08-12 2019-02-19 苏州柯创电子材料有限公司 A kind of ultra-toughness high impact resistance polypropylene
CN106279984B (en) * 2016-08-12 2019-02-19 苏州柯创电子材料有限公司 A kind of PP composite material of high-strength and high ductility
CN106589593A (en) * 2016-12-10 2017-04-26 汤诗怡 Antibacterial and anti-static polypropylene composite material for inner barrel of washing machine and preparation method of antibacterial and anti-static polypropylene composite material

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Application publication date: 20151125

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