CN105076151A - Sterilization composition - Google Patents
Sterilization composition Download PDFInfo
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- CN105076151A CN105076151A CN201510510345.6A CN201510510345A CN105076151A CN 105076151 A CN105076151 A CN 105076151A CN 201510510345 A CN201510510345 A CN 201510510345A CN 105076151 A CN105076151 A CN 105076151A
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- pyrrole metsulfovax
- nitre benzene
- benzene bacterium
- bactericidal composition
- bacterium ester
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Abstract
The invention relates to the technical field of pesticide combination and particularly relates to a sterilization combination. The sterilization combination comprises effective ingredients and auxiliary ingredients, wherein the effective ingredients are compounded by two components of nitrobenzene azoxystrobin and penthiopyrad. The sterilization combination has an obvious synergetic effect on crop powdery mildew and is capable of improving the prevention and treatment effects; furthermore, since the pesticide effect is improved, the field pesticide dosage is greatly reduced, pesticide residues and environmental pollution are reduced, and the production cost and the use cost are lowered; in addition, the effective ingredients in sterilization combination are different in active mechanism, so that the pressure in single selection on pathogenic bacteria is reduced, generation of disease resistance is well avoided and the disease pesticide resistance generation speed is well delayed.
Description
Technical field
The present invention relates to technical field of pesticide combination, particularly relate to a kind of bactericidal composition.
Background technology
Nitre benzene bacterium ester is non-internal-absorting miticide, has certain contact bactericidal action simultaneously.This medicine is developed by The Dow Agrosciences, LLC., nitre benzene bacterium ester be separate from 6 kinds of isomer of sterilization (mite) agent karathane there is one of isomer of most high bioactivity.Be mainly used in preventing and treating apple, oranges and tangerines, pears, grape, cucumber, muskmelon, watermelon, pumpkin, strawberry, the two spotted spider mite of rose and ornamental plants and powdery mildew, there is good control efficiency to mulberry tree powdery mildew and eggplant two spotted spider mite, also there is the effect of killing mite ovum simultaneously.Different pungent-4, the 6-dinitrophenyl-2-butenoic acids of its chemical name: 2-, its molecular structural formula:
Pyrrole metsulfovax is a kind of pyrazole amide series bactericidal agent of Mitsui chemical company research and development, is succinate dehydrogenase inhibitors.Pyrrole metsulfovax is the new and effective medicament of control crop powdery mildew, is applicable to fruit tree and vegetables, and to crop and Environmental security, but it is high and have and produce the risk of resistance to be used alone cost.Its chemical name: (RS)-N-[2-(1,3-dimethylbutyl)-3-thiophene phenyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide, its molecular structural formula:
Use the most effective means that chemical agent is controlling plant diseases.But single chemical bactericide is used on long-term continuous high-efficient amount ground, easily cause the problems such as the remaining of medicament, environmental pollution and resistance to pesticide resistance fungi development.Composite or the mixture of rational chemical bactericide has expansion fungicidal spectrum, improve control efficiency, extend dispenser appropriate, reduce dosage, reduce key, reduce and remain, delay Antifungal resistance and the positive feature such as drug-fast generation and development, bactericide compounded is one of the effective method the most solved the problem.Develop new product bactericide price constantly rises, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite and mixture has small investment, the lead time is short and be subject to domestic and international attention, numerous and confused increasing develops dynamics.We are on the basis of lab screening and field trial, filter out nitro bacterium ester and pyrrole metsulfovax carries out composite, have obvious synergistic effect.And about nitro bacterium ester and pyrrole metsulfovax composite bactericidal composition and apply and there is no people at present and reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective pesticide sterilizing composite, is suitable for the various powdery mildews of preventing and treating the ornamental plantss such as fruit tree, vegetables, flowers, field crop.
Technical scheme of the present invention is realized by following measures: a kind of bactericidal composition containing nitre benzene bacterium ester and pyrrole metsulfovax, the active ingredient of this bactericidal composition is that nitre benzene bacterium ester and pyrrole metsulfovax two yuan are composite, and all the other are auxiliary element.In described bactericidal composition, the weight ratio of active ingredient nitre benzene bacterium ester and pyrrole metsulfovax is 1 ~ 50:50 ~ 1, wherein nitre benzene bacterium ester and the optimum weight amount of pyrrole metsulfovax are than being 20:1 ~ 1: 1, in this ratio range, its co-toxicity coefficient is higher, have significant synergistic effect, co-toxicity coefficient is 125.2 ~ 147.5.Bactericidal composition of the present invention is the composition of nitre benzene bacterium ester and pyrrole metsulfovax, form for effective ingredient is composite with nitre benzene bacterium ester and pyrrole metsulfovax, wherein the percetage by weight of active ingredient is 3% ~ 84%, in this ratio range, nitre benzene bacterium ester and pyrrole metsulfovax composite, good control efficiency can be reached.The formulation of described bactericidal composition is missible oil or wetting powder or suspending agent or granule or microemulsion or aqueous emulsion or water-dispersible granules.
Auxiliary element in bactericidal composition of the present invention comprise in emulsifier or solvent or dispersant or wetting agent or disintegrant or thickener or stabilizing agent or defoamer or filler one or more; Wherein emulsifier is selected from calcium dodecyl benzene sulfonate, aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any one in polyoxyethylene aliphatic alcohol ether or more than one any mixtures than composition.
Solvent is selected from dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), and one or more in water equal solvent are arbitrarily than the mixture of composition.
Dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO are arbitrarily than the mixture of composition.
Wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Stabilizing agent is selected from sodium citrate, the one in resorcinol.Antifreezing agent comprises: ethylene glycol, propane diols, one or more in glycerine.
Defoamer is selected from silicone oil, silicone compound, C10-20 saturated fat acid compounds, one or more of C8-10 fatty alcohol.
Filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
In the present invention; nitre benzene bacterium ester belongs to Mitochondria uncoupler, has the contact bactericide of certain osmotically active, by suppressing the respiration of spore germination and fungi and upsetting the metabolism of fungal cell; there is provided protective effect, therapeutic action and eradicant action.
Pyrrole metsulfovax, being a kind of pyrazole amide series bactericidal agent of Mitsui KCC exploitation, is succinate dehydrogenase inhibitors.Pyrrole metsulfovax is the new and effective medicament of control crop powdery mildew, but it is high and have and produce the risk of resistance to be used alone cost.
The composite bactericide that the present invention is active ingredient with nitre benzene bacterium ester and pyrrole metsulfovax has obvious synergistic effect, delay the drug-fast generation in key, and reduce into product cost and use cost, be suitable for the various powdery mildews of the ornamental plantss such as fruit tree, vegetables, flowers, field crop.Said composition preventive effect is significantly higher than the preventive effect adopting separately nitre benzene bacterium ester and pyrrole metsulfovax.
The present invention is compared with single dose, and this bactericidal composition is obvious to disease synergistic effect, improves control efficiency; Simultaneously because drug effect improves, field dosage significantly reduces, and reduces residue of pesticide and environmental pollution, produces and use cost decline; In addition, in bactericidal composition, the mechanism of action of active ingredient is different, reduces the single selection pressure to germ, is conducive to avoiding Disease Resistance to produce and delaying the generation speed of disease drug resistance.
Embodiment
The embodiment of form by the following examples, is described in further detail foregoing of the present invention, but this should be interpreted as that the scope of the above-mentioned theme of the present invention is only limitted to following example.All technology realized based on foregoing of the present invention all belong to scope of the present invention.Except mentioning especially, component ratio is part by weight.
By nitre benzene bacterium ester and pyrrole metsulfovax composite by a certain percentage, its ratio is 1/50,1/20,1/8,1/2,1/1,2/1,10/1,20/1,50/1, contrast with 36% nitre benzene bacterium emulsifiable concentrate and 20% pyrrole metsulfovax suspending agent, for the control of powdery mildew of cucumber and apple mildew.In all embodiments during medication mean temperature of air at 20-25 DEG C, weather based on fine to cloudy.
Embodiment one
3% nitre benzene bacterium ester pyrrole metsulfovax microemulsion
Raw material consists of the former medicine of 2% nitre benzene bacterium ester, the former medicine of 1% pyrrole metsulfovax, 1%N, dinethylformamide, 10% cyclohexanone, 10% toluene, 5% phenethyl phenolformaldehyde resin APEO, 5% calcium dodecyl benzene sulfonate, 6% alkylphenol polyoxyethylene, 5% ethylene glycol, all the other are supplied with water, and micro emulsion mode is prepared routinely.
Field trial 1:
Experimental pharmacy is that 3% nitre benzene bacterium ester pyrrole metsulfovax microemulsion is prepared by embodiment one, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
By the data in table, we find, nitre benzene bacterium ester and pyrrole metsulfovax composite after, have significant preventive effect, and preventive effect is far above the single dose of nitre benzene bacterium ester and pyrrole metsulfovax, bactericidal effect is good.
Field control effectiveness test 2:
Experimental pharmacy is that 3% nitre benzene bacterium ester pyrrole metsulfovax microemulsion is prepared by embodiment one, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating apple mildew, result is as follows:
Embodiment two
8% nitre benzene bacterium ester kresoxim-methyl missible oil
Raw material forms: the former medicine of 4% nitre benzene bacterium ester, the former medicine of 4% pyrrole metsulfovax, 2%N, dinethylformamide, 10% acetone, 5% calcium dodecyl benzene sulfonate, 6% triphenoethyl benzene phenol polyethenoxy ether, 4% phenethyl phenolformaldehyde resin APEO, all the other are supplied with toluene.Missible oil mode is prepared routinely.
Field trial 1:
Experimental pharmacy is that 8% nitre benzene bacterium ester pyrrole metsulfovax missible oil is prepared by embodiment two, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field trial 2:
Experimental pharmacy is that 8% nitre benzene bacterium ester pyrrole metsulfovax missible oil is prepared by embodiment two, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating apple mildew, result is as follows:
Embodiment three
11% nitre benzene bacterium ester pyrrole metsulfovax aqueous emulsion
Raw material forms: the former medicine of 10% nitre benzene bacterium ester, the former medicine of 1% pyrrole metsulfovax, 5% acetone, 15% dimethylbenzene, 3% calcium dodecyl benzene sulfonate, 2% triphenoethyl benzene phenol polyethenoxy ether, 3% phenethyl phenolformaldehyde resin APEO, 8% polyoxyethylene nonylphenol ether, 5% ethylene glycol, all the other are supplied with water.Water and milk mode is joined routinely.
Field trial 1:
Experimental pharmacy is that 11% nitre benzene bacterium ester pyrrole metsulfovax aqueous emulsion is prepared by embodiment three, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field trial 2:
Experimental pharmacy is that 11% nitre benzene bacterium ester pyrrole metsulfovax aqueous emulsion is prepared by embodiment three, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating apple mildew, result is as follows:
Embodiment four
15% nitre benzene bacterium ester pyrrole metsulfovax suspending agent;
Raw material consists of the former medicine of 5% nitre benzene bacterium ester, the former medicine of 10% pyrrole metsulfovax, 1.5% pulls open powder, 2% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.5% calcium dodecyl benzene sulfonate, 4% triphenoethyl benzene phenol polyethenoxy ether, 2% white carbon, 0.20% xanthans, all the other are supplied with water, suspending agent mode of production preparation routinely.
Field trial 1:
Experimental pharmacy is that 15% nitre benzene bacterium ester pyrrole metsulfovax floats agent and prepares by embodiment four, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field control effectiveness test 2:
Experimental pharmacy is that 15% nitre benzene bacterium ester pyrrole metsulfovax suspending agent is prepared by embodiment four, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); Prevent and treat apple mildew, result is as follows:
Embodiment five
42% nitre benzene bacterium ester pyrrole metsulfovax suspending agent;
Raw material consists of the former medicine of 40% nitre benzene bacterium ester, the former medicine of 2% pyrrole metsulfovax, 1.2% polyoxyethylene alkyl ether, and 1% dispersant pulls open powder, 4% calcium dodecyl benzene sulfonate, 2% white carbon, 0.15% xanthans, 5% ethylene glycol, all the other are supplied with water, suspending agent mode of production preparation routinely.
Field trial 1:
Experimental pharmacy is 42% nitre benzene bacterium ester pyrrole metsulfovax suspending agent; Prepare by embodiment five, contrast medicament is 36% nitre benzene bacterium emulsifiable concentrate (market is bought, and Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field control effectiveness test 2:
Experimental pharmacy is 42% nitre benzene bacterium ester pyrrole metsulfovax suspending agent; Prepare by embodiment five, contrast medicament is 36% nitre benzene bacterium emulsifiable concentrate (market is bought, and Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating apple mildew, result is as follows:
Embodiment six
45% nitre benzene bacterium ester pyrrole metsulfovax water-dispersible granules
Raw material consists of the former medicine of 5% nitre benzene bacterium ester, the former medicine of 40% pyrrole metsulfovax, 3% calcium dodecyl benzene sulfonate, 15% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 4% naphthalenesulfonate formaldehyde condensation compound, 5% calcium lignosulfonate, 5% sodium carboxymethyl starch, all the other are supplied with ammonium sulfate, and extruder grain mode is prepared routinely.
Field trial 1:
Experimental pharmacy is 45% nitre benzene bacterium ester pyrrole metsulfovax water-dispersible granules, prepare by embodiment six, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax water dispersible granules (laboratory preparation); Prevent and treat powdery mildew of cucumber, result is as follows:
Field control effectiveness test 2:
Experimental pharmacy is 45% nitre benzene bacterium ester pyrrole metsulfovax water-dispersible granules, prepare by embodiment six, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); Prevent and treat apple mildew, result is as follows:
Embodiment seven
51% nitre benzene bacterium ester pyrrole metsulfovax wetting powder
Raw material consists of the former medicine of 50% nitre benzene bacterium ester, the former medicine of 1% pyrrole metsulfovax, and 10% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% lauryl sodium sulfate, 6% calcium lignosulfonate, all the other are supplied with ammonium sulfate.Can wet-milling mode prepare routinely.
Field trial 1:
Experimental pharmacy is that 51% nitre benzene bacterium ester pyrrole metsulfovax wetting powder is prepared by embodiment seven, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field control effectiveness test 2:
Experimental pharmacy is that 51% nitre benzene bacterium ester pyrrole metsulfovax wetting powder is prepared by embodiment seven, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); Prevent and treat apple mildew, result is as follows:
Embodiment eight
84% nitre benzene bacterium ester pyrrole metsulfovax wetting powder
Raw material consists of the former medicine of 4% nitre benzene bacterium ester, the former medicine of 80% pyrrole metsulfovax, and 15% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 4% lauryl sodium sulfate, all the other are supplied with ammonium sulfate.Can wet-milling mode prepare routinely.
Field trial 1:
Experimental pharmacy is that 84% nitre benzene bacterium ester pyrrole metsulfovax wetting powder is prepared by embodiment eight, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field control effectiveness test 2:
Experimental pharmacy is that 84% nitre benzene bacterium ester pyrrole metsulfovax wetting powder is prepared by embodiment eight, contrast medicament is that 36% nitre benzene bacterium emulsifiable concentrate (buy by market, Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating apple mildew, result is as follows:
Embodiment nine
51% nitre benzene bacterium ester pyrrole metsulfovax suspending agent;
Raw material consists of the former medicine of 1% nitre benzene bacterium ester, the former medicine of 50% pyrrole metsulfovax, 1.3% polyoxyethylene alkyl ether, and 1% dispersant pulls open powder, 5% calcium dodecyl benzene sulfonate, 2% white carbon, 0.12% xanthans, 4% ethylene glycol, all the other are supplied with water, suspending agent mode of production preparation routinely.
Field trial 1:
Experimental pharmacy is 51% nitre benzene bacterium ester pyrrole metsulfovax suspending agent; Prepare by embodiment nine, contrast medicament is 36% nitre benzene bacterium emulsifiable concentrate (market is bought, and Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating powdery mildew of cucumber, result is as follows:
Field control effectiveness test 2:
Experimental pharmacy is 51% nitre benzene bacterium ester pyrrole metsulfovax suspending agent; Prepare by embodiment nine, contrast medicament is 36% nitre benzene bacterium emulsifiable concentrate (market is bought, and Beijing rich hundred million obtains agricultural science and technology responsibility Co., Ltd), 20% pyrrole metsulfovax suspending agent (laboratory preparation); For preventing and treating apple mildew, result is as follows:
As can be seen from above-mentioned all embodiments: using dosage is 13-15 gram of effective ingredient/mu, spray medicine 2 ~ 3 days, successful, preventive effect such as crop powdery mildew such as control cucumber and apple etc. more than 90%; The compound product successful of nitre benzene bacterium ester and pyrrole metsulfovax is better than respective single-dose product, wherein the most outstanding with 1/1 to 20/1 effect.Field experiment result fully shows, nitre benzene bacterium ester and the composite rear synergistic effect of pyrrole metsulfovax obvious.Therefore, the present composition have reduce costs, the beneficial effect of delaying drug resistance, minimizing spraying times and residue of pesticide.
Claims (6)
1. a bactericidal composition, is characterized in that: described bactericidal composition comprises active ingredient and auxiliary element, and wherein active ingredient is nitre benzene bacterium ester and pyrrole metsulfovax, and the percetage by weight of active ingredient in bactericidal composition is 3% ~ 84%.
2. a kind of bactericidal composition according to claim 1, is characterized in that: described nitre benzene bacterium ester and the weight ratio of pyrrole metsulfovax are 1 ~ 50: 50 ~ 1.
3. a kind of bactericidal composition according to claim 1, is characterized in that: described nitre benzene bacterium ester and the weight ratio of pyrrole metsulfovax are 20:1 ~ 1: 1.
4. a kind of bactericidal composition according to claim 1, is characterized in that: the formulation of described bactericidal composition is missible oil or wetting powder or suspending agent or granule or microemulsion or aqueous emulsion or water-dispersible granules.
5. a kind of bactericidal composition according to claim 1, is characterized in that: the auxiliary element in described bactericidal composition be selected from emulsifier or solvent or dispersant or wetting agent or disintegrant or thickener or stabilizing agent or defoamer or filler one or more.
6. a kind of bactericidal composition according to claim 1, is characterized in that: this bactericidal composition is for preventing and treating crop powdery mildew.
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| CN201510510345.6A CN105076151A (en) | 2015-08-19 | 2015-08-19 | Sterilization composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106857539A (en) * | 2017-03-13 | 2017-06-20 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing biphenyl pyrrole bacterium amine and its application |
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| CN101541174A (en) * | 2006-11-21 | 2009-09-23 | 三井化学株式会社 | Plant disease control composition and method for the prevention and control of plant diseases |
| WO2014086756A1 (en) * | 2012-12-03 | 2014-06-12 | Bayer Cropscience Ag | Composition comprising a biological control agent and an insecticide |
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- 2015-08-19 CN CN201510510345.6A patent/CN105076151A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101060780A (en) * | 2004-10-14 | 2007-10-24 | 美国陶氏益农公司 | Isomeric mixtures of dinitro-octylphenyl esters and synergistic fungicidal mixtures therefrom |
| CN101541174A (en) * | 2006-11-21 | 2009-09-23 | 三井化学株式会社 | Plant disease control composition and method for the prevention and control of plant diseases |
| WO2014086756A1 (en) * | 2012-12-03 | 2014-06-12 | Bayer Cropscience Ag | Composition comprising a biological control agent and an insecticide |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106857539A (en) * | 2017-03-13 | 2017-06-20 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing biphenyl pyrrole bacterium amine and its application |
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