CN105060826B - Thermal insulation mortar for building external walls and preparation method thereof - Google Patents

Thermal insulation mortar for building external walls and preparation method thereof Download PDF

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Publication number
CN105060826B
CN105060826B CN201510505166.3A CN201510505166A CN105060826B CN 105060826 B CN105060826 B CN 105060826B CN 201510505166 A CN201510505166 A CN 201510505166A CN 105060826 B CN105060826 B CN 105060826B
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parts
paper mill
mill sludge
sludge ash
water
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CN105060826A (en
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蔡东豪
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Dongguan Ourui Construction Co ltd
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Dongguan Taifeng Steel Structure Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The invention discloses a thermal insulation mortar for building external walls. The thermal insulation mortar consists of sulfate aluminium cement, papermaking sewage sludge ash, polystyrene granules, glazed hollow beads, cellulose ether, an air-entraining agent, a polycarboxylate superplasticizer, alkali-resistant glass fibers and water, and further discloses a preparation method of the thermal insulation mortar. As paper mill sludge ash replaces part of cement, the compactness and the water resistance are very good, the thermal insulation mortar is stable in physical property, free of cracks, ageing-resistant, long in service life and excellent in thermal insulation performance. Not only is harmless utilization of paper mill sludge ash realized to protect the environment, but also resources are saved, waste is changed into valuable, the consumption of cement is reduced, the cost is lowered, and favorable economic and social benefits are achieved. The preparation method is simple, can be completed according to the conventional technology and is low in production cost.

Description

A kind of heat preservation mortar for outer wall of buildings and preparation method thereof
Technical field
The invention belongs to building material field is and in particular to a kind of heat preservation mortar for outer wall of buildings and preparation method thereof.
Background technology
Thermal insulation mortar is mainly with cement as Binder Materials, and with light material as aggregate, the modification of admixture specific components is mixed Close material, and introduce a certain amount of additive, after agitated machine stirring, for building the basic unit's mortar in exterior wall heat-preserving system.Closely Nian Lai, usually to replace traditional Binder Materials and aggregate using some new materials, the granulated blast furnace ore deposit that main inclusion is levigate Slag, flyash, silica flour, glass, rubber and cable waste etc. of milling.
Consumption with expanding economy paper is increasing, and the annual mud producing of paper industry brings to environment Serious pollution.In Europe, paper pulp and paper industry produce about 8,000,000 tons of paper mill sludges every year.Dehydration paper mill sludge is generally adopted Realize minimizing with incinerating method, this generates paper mill sludge ash (psa).And the residue after burning also is not suitable at present Processing method it is easy to cause secondary pollution.In China, when often producing one ton of paper, just have 700 kilograms of water content 30% Paper mill sludge to 98% produces, and sludge yield is 5 to 10 times of same size sewage treatment plant.These paper mill sludges master at present If by landfill disposal or being used as discarded object stacking, not only to take a large amount of soils, also can cause soil pollution.Cause How this, processed and be the key issue that paper-making industry need solve using these mud effectively.Application publication number Cn103030257a (a kind of paper mill sludge burn and harmless treatment method) a kind of paper mill sludge of Invention Announce burn And the method for harmless treatment.This invention describes the method producing paper mill sludge ash, but is not described in detail paper mill sludge The processing method of ash and utilization obstacle.
Content of the invention
The present invention is directed to the deficiencies in the prior art, there is provided a kind of heat preservation mortar for outer wall of buildings.
Present invention also offers a kind of preparation method of heat preservation mortar for outer wall of buildings.
For achieving the above object, the following technical scheme of present invention offer:
A kind of heat preservation mortar for outer wall of buildings, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, makes Paper sludge ash 20-25 part, granular polystyrene 5-8 part, glass bead 8-12 part, cellulose ether 0.5-0.8 part, air entraining agent 0.3-0.6 Part, polycarboxylate water-reducer 0.6-0.9 part, alkali-resistant glass fibre 0.3-0.5 part, water 60-80 part.
Further scheme, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, paper mill sludge ash 20 parts, 5 parts of granular polystyrene, 8 parts of glass bead, 0.5 part of cellulose ether, 0.3 part of air entraining agent, 0.6 part of polycarboxylate water-reducer, alkaline-resisting 0.3 part of glass fibre, 60 parts of water.
Further scheme, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, paper mill sludge ash 23 parts, 6 parts of granular polystyrene, 10 parts of glass bead, 0.6 part of cellulose ether, 0.5 part of air entraining agent, 0.8 part of polycarboxylate water-reducer, resistance to 0.4 part of alkali containing glass fibre, 70 parts of water.
Further scheme, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, paper mill sludge ash 25 parts, 8 parts of granular polystyrene, 12 parts of glass bead, 0.8 part of cellulose ether, 0.6 part of air entraining agent, 0.9 part of polycarboxylate water-reducer, resistance to 0.5 part of alkali containing glass fibre, 80 parts of water.
Described, paper mill sludge ash burns gained powder, 200 mesh sieve screenings for paper mill sludge at 400-850 DEG C, tails over little In 10%.
Described, the main component of paper mill sludge ash is calcium aluminosilicate and dead plaster.
Described, the particle diameter of granular polystyrene is 2-5mm, and bulk density is 8.9kg/m3.
Described, air entraining agent is neopelex.
Described, 18-20 μm of alkali-resistant glass fibre filament diameter, length 6mm.
A kind of preparation method of heat preservation mortar for outer wall of buildings, comprises the following steps:
(1) weigh sulphate aluminium cement, paper mill sludge ash, cellulose ether and air entraining agent according to weight portion, fully mix, obtain Mixed powder.
(2) alkali-resistant glass fibre is added in water, stirs 20min under 40-60r/min, add polycarboxylate water-reducer Continue stirring 1min, obtain mixing liquid.
(3) mixed powder is added in mixing liquid, 160-180r/min stirs 3min, adds 50% vitreous micro- Pearl, 100-140r/min stirs 30s, adds granular polystyrene, and 160-180r/min stirs 10s, and 100-140r/min stirs 20s, is eventually adding remaining glass bead, and 100-140r/min stirs 1min, you can the prepared present invention's is grey containing paper mill sludge Thermal insulation mortar.
Beneficial effects of the present invention:
1. the present invention uses paper mill sludge ash to replace part of cement, not only achieves the innoxious use of paper mill sludge, protects Retaining ring border, can also economize on resources, turn waste into wealth, and reduce cement consumption, reduces cost, have good economy and society's effect Benefit.
2. the thermal insulation mortar of the present invention with the addition of paper mill sludge ash, has good compactness and water resistance, product thing Reason stable performance, does not ftracture, and anti-aging, long service life has good heat-insulating property, is modern architecture energy-saving material field Bring and significantly improve.
3. the preparation method of the present invention is simple, can complete by existing technical matters, low production cost.
Specific embodiment
Hereinafter the preferred embodiments of the present invention are illustrated it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of heat preservation mortar for outer wall of buildings, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, makes 20 parts of paper sludge ash, 5 parts of granular polystyrene, 8 parts of glass bead, 0.5 part of cellulose ether, 0.3 part of air entraining agent, polycarboxylate water-reducer 0.6 part, 0.3 part of alkali-resistant glass fibre, 60 parts of water.
Described, paper mill sludge ash burns gained powder, 200 mesh sieve screenings for paper mill sludge at 400-850 DEG C, tails over little In 10%.
Described, the main component of paper mill sludge ash is calcium aluminosilicate and dead plaster.
Described, the particle diameter of granular polystyrene is 2-5mm, and bulk density is 8.9kg/m3.
Described, air entraining agent is neopelex.
Described, 18-20 μm of alkali-resistant glass fibre filament diameter, length 6mm.
A kind of preparation method of heat preservation mortar for outer wall of buildings, comprises the following steps:
(1) weigh sulphate aluminium cement, paper mill sludge ash, cellulose ether and air entraining agent according to weight portion, fully mix, obtain Mixed powder.
(2) alkali-resistant glass fibre is added in water, under 60r/min, stirs 20min, add polycarboxylate water-reducer and continue Stirring 1min, obtains mixing liquid.
(3) mixed powder is added in mixing liquid, 160r/min stirs 3min, adds 50% glass bead, 140r/min stirs 30s, adds granular polystyrene, and 160r/min stirs 10s, and 140r/min stirs 20s, is eventually adding remaining glass Change microballon, 140r/min stirs 1min, you can the thermal insulation mortar containing paper mill sludge ash of the prepared present invention.
Embodiment 2
A kind of heat preservation mortar for outer wall of buildings, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, makes 23 parts of paper sludge ash, 6 parts of granular polystyrene, 10 parts of glass bead, 0.6 part of cellulose ether, 0.5 part of air entraining agent, polycarboxylate water-reducer 0.8 part, 0.4 part of alkali-resistant glass fibre, 70 parts of water.
Described, paper mill sludge ash burns gained powder, 200 mesh sieve screenings for paper mill sludge at 400-850 DEG C, tails over little In 10%.
Described, the main component of paper mill sludge ash is calcium aluminosilicate and dead plaster.
Described, the particle diameter of granular polystyrene is 2-5mm, and bulk density is 8.9kg/m3.
Described, air entraining agent is neopelex.
Described, 18-20 μm of alkali-resistant glass fibre filament diameter, length 6mm.
A kind of preparation method of heat preservation mortar for outer wall of buildings, comprises the following steps:
(1) weigh sulphate aluminium cement, paper mill sludge ash, cellulose ether and air entraining agent according to weight portion, fully mix, obtain Mixed powder.
(2) alkali-resistant glass fibre is added in water, under 50r/min, stirs 20min, add polycarboxylate water-reducer and continue Stirring 1min, obtains mixing liquid.
(3) mixed powder is added in mixing liquid, 170r/min stirs 3min, adds 50% glass bead, 120r/min stirs 30s, adds granular polystyrene, and 170r/min stirs 10s, and 120r/min stirs 20s, is eventually adding remaining glass Change microballon, 120r/min stirs 1min, you can the thermal insulation mortar containing paper mill sludge ash of the prepared present invention.
Embodiment 3
A kind of heat preservation mortar for outer wall of buildings, is made up of the raw material of following weight portion: 110 parts of sulphate aluminium cement, makes 25 parts of paper sludge ash, 8 parts of granular polystyrene, 12 parts of glass bead, 0.8 part of cellulose ether, 0.6 part of air entraining agent, polycarboxylate water-reducer 0.9 part, 0.5 part of alkali-resistant glass fibre, 80 parts of water.
Described, paper mill sludge ash burns gained powder, 200 mesh sieve screenings for paper mill sludge at 400-850 DEG C, tails over little In 10%.
Described, the main component of paper mill sludge ash is calcium aluminosilicate and dead plaster.
Described, the particle diameter of granular polystyrene is 2-5mm, and bulk density is 8.9kg/m3.
Described, air entraining agent is neopelex.
Described, 18-20 μm of alkali-resistant glass fibre filament diameter, length 6mm.
A kind of preparation method of heat preservation mortar for outer wall of buildings, comprises the following steps:
(1) weigh sulphate aluminium cement, paper mill sludge ash, cellulose ether and air entraining agent according to weight portion, fully mix, obtain Mixed powder.
(2) alkali-resistant glass fibre is added in water, under 40r/min, stirs 20min, add polycarboxylate water-reducer and continue Stirring 1min, obtains mixing liquid.
(3) mixed powder is added in mixing liquid, 180r/min stirs 3min, adds 50% glass bead, 100r/min stirs 30s, adds granular polystyrene, and 180r/min stirs 10s, and 100r/min stirs 20s, is eventually adding remaining glass Change microballon, 100r/min stirs 1min, you can the thermal insulation mortar containing paper mill sludge ash of the prepared present invention.
Performance test
With reference to the regulation of gb/t 20473-2006 " building heat-insulating mortar ", the thermal insulation mortar that embodiment 1-3 is obtained is carried out Performance parameter test,
The performance test results are as shown in table 1.
Performance Embodiment 1 Embodiment 2 Embodiment 3 Standard
Resistance to compression/mpa 0.72 0.71 0.73 > 0.4
Anti- folding/mpa 0.77 0.74 0.78 -
Linear shrinkage/% 0.2 0.21 0.19 < 0.3
Water absorption rate/% 7 7 7 -
Dry density/kg/m3 388 400 401 301-400
Coefficient of softing 0.88 0.89 0.81 > 0.5
Burning rank a2 a2 a2 a
Although embodiment of the present invention is disclosed as above, it is not restricted to listed in specification and embodiment With, it can be applied to various suitable the field of the invention completely, for those skilled in the art, can be easily Realize other modification, therefore under the universal being limited without departing substantially from claim and equivalency range, the present invention does not limit In specific details.

Claims (4)

1. a kind of heat preservation mortar for outer wall of buildings is it is characterised in that be made up of the raw material of following weight portion: sulphate aluminium cement 110 parts, paper mill sludge ash 20-25 part, granular polystyrene 5-8 part, glass bead 8-12 part, cellulose ether 0.5-0.8 part, air entraining agent 0.3-0.6 part, polycarboxylate water-reducer 0.6-0.9 part, alkali-resistant glass fibre 0.3-0.5 part, water 60-80 part;
Described paper mill sludge ash burns gained powder, 200 mesh sieve screenings for paper mill sludge at 400-850 DEG C, tails over less than 10%;
The main component of described paper mill sludge ash is calcium aluminosilicate and dead plaster;
The particle diameter of described granular polystyrene is 2-5mm, and bulk density is 8.9kg/m3
Described air entraining agent is neopelex;
18-20 μm of described alkali-resistant glass fibre filament diameter, length 6mm;
Its preparation method comprises the following steps:
(1) weigh sulphate aluminium cement, paper mill sludge ash, cellulose ether and air entraining agent according to weight portion, fully mix, obtain mixing Powder;
(2) alkali-resistant glass fibre is added in water, under 40-60r/min, stirs 20min, add polycarboxylate water-reducer and continue Stirring 1min, obtains mixing liquid;
(3) mixed powder is added in mixing liquid, 160-180r/min stirs 3min, adds 50% glass bead, 100-140r/min stirs 30s, adds granular polystyrene, and 160-180r/min stirs 10s, and 100-140r/min stirs 20s, Add remaining glass bead afterwards, 100-140r/min stirs 1min, you can the insulation containing paper mill sludge ash of the prepared present invention Mortar.
2. heat preservation mortar for outer wall of buildings according to claim 1 is it is characterised in that be made up of the raw material of following weight portion : 110 parts of sulphate aluminium cement, 20 parts of paper mill sludge ash, 5 parts of granular polystyrene, 8 parts of glass bead, 0.5 part of cellulose ether, draw 0.3 part of gas agent, 0.6 part of polycarboxylate water-reducer, 0.3 part of alkali-resistant glass fibre, 60 parts of water.
3. heat preservation mortar for outer wall of buildings according to claim 1 is it is characterised in that be made up of the raw material of following weight portion : 110 parts of sulphate aluminium cement, 23 parts of paper mill sludge ash, 6 parts of granular polystyrene, 10 parts of glass bead, 0.6 part of cellulose ether, draw 0.5 part of gas agent, 0.8 part of polycarboxylate water-reducer, 0.4 part of alkali-resistant glass fibre, 70 parts of water.
4. heat preservation mortar for outer wall of buildings according to claim 1 is it is characterised in that be made up of the raw material of following weight portion : 110 parts of sulphate aluminium cement, 25 parts of paper mill sludge ash, 8 parts of granular polystyrene, 12 parts of glass bead, 0.8 part of cellulose ether, draw 0.6 part of gas agent, 0.9 part of polycarboxylate water-reducer, 0.5 part of alkali-resistant glass fibre, 80 parts of water.
CN201510505166.3A 2015-08-11 2015-08-11 Thermal insulation mortar for building external walls and preparation method thereof Active CN105060826B (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497375B (en) * 2016-11-01 2018-10-19 宏岳塑胶集团股份有限公司 A kind of pipeline antimicrobial form antiwear powder paint and preparation method thereof
CN106904917B (en) * 2017-03-21 2019-03-15 济南大学 Polystyrene containing paper mill sludge-calcium silicate heat-preserving mortar and preparation method thereof
CN107673707A (en) * 2017-10-27 2018-02-09 济南大学 A kind of thermal insulation mortar using modified paper mill sludge particle
CN108793841A (en) * 2018-06-12 2018-11-13 佛山市华强协兴陶瓷有限公司 A kind of heat preservation mortar for outer wall and its production method
CN111943622A (en) * 2020-08-12 2020-11-17 重庆富皇建筑工业化制品有限公司 Full-machine-made sand wet-mixed mortar and processing method thereof

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CN101781918A (en) * 2009-01-16 2010-07-21 同济大学 Insulation block and method of using thermal insulation mortar to prepare insulation block
CN101863601A (en) * 2009-04-14 2010-10-20 株式会社安农津技研 Flocculation curing agent, composition thereof and stabilization improvement method of silt type soil
CN103172314A (en) * 2013-03-28 2013-06-26 海达建设集团有限公司 Polycrystal inorganic lightweight aggregate thermal insulation mortar
CN103553480A (en) * 2013-09-27 2014-02-05 安唛杰节能建材科技(上海)有限公司 A1-grade fireproof insulation mortar and preparation method thereof
CN103601454A (en) * 2013-11-22 2014-02-26 济南大学 Preparation method of light-weight thermal mortar

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101781918A (en) * 2009-01-16 2010-07-21 同济大学 Insulation block and method of using thermal insulation mortar to prepare insulation block
CN101863601A (en) * 2009-04-14 2010-10-20 株式会社安农津技研 Flocculation curing agent, composition thereof and stabilization improvement method of silt type soil
CN103172314A (en) * 2013-03-28 2013-06-26 海达建设集团有限公司 Polycrystal inorganic lightweight aggregate thermal insulation mortar
CN103553480A (en) * 2013-09-27 2014-02-05 安唛杰节能建材科技(上海)有限公司 A1-grade fireproof insulation mortar and preparation method thereof
CN103601454A (en) * 2013-11-22 2014-02-26 济南大学 Preparation method of light-weight thermal mortar

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