Summary of the invention
For above-mentioned prior art, the object of the invention is to overcome the uvioresistant performance good LOW-E glass problem that often cost is higher in prior art, thus provide one can effective uvioresistant, and the preparation method of the higher LOW-E glass matrix material composition of cost performance and LOW-E glass basis.
To achieve these goals, the invention provides a kind of LOW-E glass matrix material composition, wherein, described composition comprises silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood; Wherein,
Relative to the described silicon-dioxide of 100 weight parts, the content of described sodium carbonate is 10-30 weight part, and the content of described manganese powder is 1-5 weight part, and the content of described fluorite is 5-20 weight part, the content of described Wingdale is 10-30 weight part, and the content of described salt of wormwood is 1-5 weight part.
Present invention also offers a kind of preparation method of LOW-E glass basis, wherein, described preparation method comprises: carry out melting and cooling forming after silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood being mixed, obtained LOW-E glass basis; Wherein,
Relative to the described silicon-dioxide of 100 weight parts, the consumption of described sodium carbonate is 10-30 weight part, and the consumption of described manganese powder is 1-5 weight part, and the consumption of described fluorite is 5-20 weight part, the consumption of described Wingdale is 10-30 weight part, and the consumption of described salt of wormwood is 1-5 weight part.
Pass through technique scheme, silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood carry out mixing and carrying out melting by the present invention in certain proportion, thus make the LOW-E glass basis by aforementioned proportion is obtained have better uvioresistant performance when reality uses, and then substantially increase its use properties, the cost of the glass basis simultaneously obtained by above-mentioned materials is also lower, significantly reduces production cost.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of LOW-E glass matrix material composition, wherein, described composition comprises silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood; Wherein,
Relative to the described silicon-dioxide of 100 weight parts, the content of described sodium carbonate is 10-30 weight part, and the content of described manganese powder is 1-5 weight part, and the content of described fluorite is 5-20 weight part, the content of described Wingdale is 10-30 weight part, and the content of described salt of wormwood is 1-5 weight part.
Above-mentioned design is by carrying out silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood in certain proportion mixing and carrying out melting, thus make the LOW-E glass basis by aforementioned proportion is obtained have better uvioresistant performance when reality uses, and then substantially increase its use properties, the cost of the glass basis simultaneously obtained by above-mentioned materials is also lower, significantly reduces production cost.
In order to make the LOW-E glass basis obtained, there is better uvioresistant performance, one of the present invention preferred embodiment in, relative to the described silicon-dioxide of 100 weight parts, the content of described sodium carbonate is 15-25 weight part, the content of described manganese powder is 2-4 weight part, the content of described fluorite is 10-15 weight part, and the content of described Wingdale is 15-25 weight part, and the content of described salt of wormwood is 2-4 weight part.
Certainly, in order to make the LOW-E glass basis obtained have better uvioresistant performance, one of the present invention more preferred embodiment in, can also anti ultraviolet agent be comprised in described composition; Wherein, relative to the described silicon-dioxide of 100 weight parts, the content of described anti ultraviolet agent is 1-5 weight part.
Present invention also offers a kind of preparation method of LOW-E glass basis, wherein, described preparation method comprises: carry out melting and cooling forming after silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood being mixed, obtained LOW-E glass basis; Wherein,
Relative to the described silicon-dioxide of 100 weight parts, the consumption of described sodium carbonate is 10-30 weight part, and the consumption of described manganese powder is 1-5 weight part, and the consumption of described fluorite is 5-20 weight part, the consumption of described Wingdale is 10-30 weight part, and the consumption of described salt of wormwood is 1-5 weight part.
Similarly, in order to make the uvioresistant performance of the LOW-E glass basis obtained better, its use properties of further raising, one of the present invention preferred embodiment in, relative to the described silicon-dioxide of 100 weight parts, the consumption of described sodium carbonate is 15-25 weight part, the consumption of described manganese powder is 2-4 weight part, the consumption of described fluorite is 10-15 weight part, and the consumption of described Wingdale is 15-25 weight part, and the consumption of described salt of wormwood is 2-4 weight part.
More even in order to make to mix between above-mentioned each raw material, one of the present invention preferred embodiment in, silicon-dioxide, sodium carbonate, manganese powder, fluorite, Wingdale and salt of wormwood grind before can also being included in melting by described preparation method.
Certainly, the particle diameter after grinding can be not construed as limiting, such as, one of the present invention preferred embodiment in, described grinding can be not more than 0.5mm for being ground to particle diameter.
Certainly, in order to improve the uvioresistant performance of obtained LOW-E glass basis further, one of the present invention preferred embodiment in, described preparation method can also comprise and add anti ultraviolet agent and carry out melting.
One of the present invention more preferred embodiment in, relative to the described silicon-dioxide of 100 weight parts, the consumption of described anti ultraviolet agent is 1-5 weight part.
Described fusion process can operate under the melting condition of this area routine, such as, one of the present invention preferred embodiment in, the smelting temperature of described fusion process can be 1200-1800 DEG C.
Below will be described the present invention by embodiment.In following examples, described silicon-dioxide, described sodium carbonate, described manganese powder, described fluorite, described Wingdale and described salt of wormwood are conventional commercial product, and described anti ultraviolet agent is the conventional commercial anti ultraviolet agent of Ding Guo plastic cement firm supply.
Embodiment 1
The mixing of 100g silicon-dioxide, 15g sodium carbonate, 2g manganese powder, 10g fluorite, 15g Wingdale, 1g anti ultraviolet agent and 2g salt of wormwood being placed on temperature is carry out melting and cooling forming, obtained LOW-E glass basis A1 under the condition of 1200 DEG C.
Embodiment 2
The mixing of 100g silicon-dioxide, 25g sodium carbonate, 4g manganese powder, 15g fluorite, 25g Wingdale, 5g anti ultraviolet agent and 4g salt of wormwood being placed on temperature is carry out melting and cooling forming, obtained LOW-E glass basis A2 under the condition of 1800 DEG C.
Embodiment 3
The mixing of 100g silicon-dioxide, 20g sodium carbonate, 3g manganese powder, 12g fluorite, 20g Wingdale, 3g anti ultraviolet agent and 3g salt of wormwood being placed on temperature is carry out melting and cooling forming, obtained LOW-E glass basis A3 under the condition of 1500 DEG C.
Embodiment 4
Be prepared according to the preparation method of embodiment 1, unlike, the consumption of described sodium carbonate is 10g, the consumption of described manganese powder is 1g, and the consumption of described fluorite is 5g, and the consumption of described Wingdale is 10g, the consumption of described salt of wormwood is 1g, does not add anti ultraviolet agent, obtained LOW-E glass basis A4.
Embodiment 5
Be prepared according to the preparation method of embodiment 2, unlike, the consumption of described sodium carbonate is 30g, the consumption of described manganese powder is 5g, and the consumption of described fluorite is 20g, and the consumption of described Wingdale is 30g, the consumption of described salt of wormwood is 5g, does not add anti ultraviolet agent, obtained LOW-E glass basis A5.
Comparative example 1
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described sodium carbonate is 5g, and the consumption of described fluorite is 1g, and the consumption of described Wingdale is 5g, obtained LOW-E glass basis D1.
Comparative example 2
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described sodium carbonate is 50g, the consumption of described manganese powder is 10g, and the consumption of described fluorite is 50g, and the consumption of described Wingdale is 50g, the consumption of described salt of wormwood is 10g, obtained LOW-E glass basis D2.
Test case
Above-mentioned obtained A1-A5, D1 and D2 are detected its ultraviolet cutoff rate respectively, and the result obtained is as shown in table 1.
Table 1
Numbering |
Ultraviolet cutoff rate (%) |
A1 |
86 |
A2 |
85 |
A3 |
82 |
A4 |
65 |
A5 |
68 |
D1 |
26 |
D2 |
15 |
Can be found out by table 1, LOW-E glass basis obtained within the scope of the present invention has better ultraviolet cutoff rate when reality uses, thus it has better uvioresistant performance, but then do not possess this good uvioresistant performance at the LOW-E glass basis that the scope of the invention obtains outward, simultaneously, LOW-E glass basis obtained in preferable range of the present invention then possesses better uvioresistant performance, substantially increases its use properties.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.