CN105040437A - Flame-retardant antibacterial auxiliary agent for textiles - Google Patents
Flame-retardant antibacterial auxiliary agent for textiles Download PDFInfo
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- CN105040437A CN105040437A CN201510560386.6A CN201510560386A CN105040437A CN 105040437 A CN105040437 A CN 105040437A CN 201510560386 A CN201510560386 A CN 201510560386A CN 105040437 A CN105040437 A CN 105040437A
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Abstract
The invention relates to a flame-retardant antibacterial auxiliary agent for textiles. The flame-retardant antibacterial auxiliary agent for the textiles is composed of, by mass, 36-40 parts of deacetylated chitin, 38-42 parts of benzoin, 34-38 parts of sodium cocoate, 38-42 parts of trichloro-sym-diphenylurea, 34-38 parts of potassium peroxodisulfate, 38-42 parts of polyvinyl alcohol, 34-38 parts of hydroxyethyl salicylate, 40-44 parts of hydroxyethyl methacrylate, 34-38 parts of zinc borate, 38-42 parts of antimonous oxide, 34-38 parts of ammonium hydrogen phosphate, 38-42 parts of 2-(diethylamino)ethyl methacrylate, 34-38 parts of pentaerythritol, 38-42 parts of dinonyl-naphthalenesulfonic aci barium salt, 34-38 parts of aluminium triphosphate, 38-42 parts of lupenyl palmitate and 1000-2000 parts of water. The flame-retardant antibacterial auxiliary agent for the textiles is simple in preparation technology and method, the prepared product has the excellent flame-retardant, waterproof and antibacterial properties, the auxiliary agent is suitable for being used in the textile field, and the product properties are improved.
Description
Technical field
The present invention relates to a kind of weaving flame-proof antibiotic auxiliary agent, belong to technical field of textile auxiliary agent.
Background technology
Textile auxiliary is chemicals necessary in textile production process.Textile auxiliary has indispensable important function to the product quality and surcharge that improve textiles, it can not only give the various specific function of textiles and style, as soft, wrinkle resistant, shrinkproof, waterproof, antibacterial, antistatic, fire-retardant etc., dyeing and finishing technology can also be improved, the effect played economize energy He cut down finished cost.Textile auxiliary is vital to the lifting integral level of textile industry and the effect in Textile Chain.
Summary of the invention
The object of the present invention is to provide a kind of weaving flame-proof antibiotic auxiliary agent, to realize the function of weaving flame-proof antibiotic auxiliary agent better.
To achieve these goals, technical scheme of the present invention is as follows.
Flame-proof antibiotic auxiliary agent is used in a kind of weaving, be made up of the component of following mass fraction: chitosan 36 ~ 40 parts, styrax 38 ~ 42 parts, 34 ~ 38 parts, coconut oil sodium, TCC 38 ~ 42 parts, potassium peroxydisulfate 34 ~ 38 parts, polyvinyl alcohol 38 ~ 42 parts, ethylene glycol salicylate 34 ~ 38 parts, hydroxyethyl methylacrylate 40 ~ 44 parts, Firebrake ZB 34 ~ 38 parts, antimonous oxide 38 ~ 42 parts, phosphoric acid cyanamide 34 ~ 38 parts, diethyl aminoethyl methacrylate 38 ~ 42 parts, pentaerythrite 34 ~ 38 parts, dinonyl naphthalene sulfonate barium 38 ~ 42 parts, aluminium triphosphate 34 ~ 38 parts, Lupenyl palmitate 38 ~ 42 parts, 1000 ~ 2000 parts, water.
Further, above-mentioned weaving flame-proof antibiotic auxiliary agent, is made up of the component of following mass fraction: chitosan 36 parts, styrax 38 parts, 34 parts, coconut oil sodium, TCC 38 parts, potassium peroxydisulfate 34 parts, polyvinyl alcohol 38 parts, ethylene glycol salicylate 34 parts, hydroxyethyl methylacrylate 40 parts, Firebrake ZB 34 parts, antimonous oxide 38 parts, phosphoric acid cyanamide 34 parts, diethyl aminoethyl methacrylate 38 parts, pentaerythrite 34 parts, dinonyl naphthalene sulfonate barium 38 parts, aluminium triphosphate 34 parts, Lupenyl palmitate 38 parts, 1000 parts, water.
Further, above-mentioned weaving flame-proof antibiotic auxiliary agent, is made up of the component of following mass fraction: chitosan 38 parts, styrax 40 parts, 36 parts, coconut oil sodium, TCC 40 parts, potassium peroxydisulfate 36 parts, polyvinyl alcohol 40 parts, ethylene glycol salicylate 36 parts, hydroxyethyl methylacrylate 42 parts, Firebrake ZB 36 parts, antimonous oxide 40 parts, phosphoric acid cyanamide 36 parts, diethyl aminoethyl methacrylate 40 parts, pentaerythrite 36 parts, dinonyl naphthalene sulfonate barium 40 parts, aluminium triphosphate 36 parts, Lupenyl palmitate 40 parts, 1500 parts, water.
Further, above-mentioned weaving flame-proof antibiotic auxiliary agent, is made up of the component of following mass fraction: chitosan 40 parts, styrax 42 parts, 38 parts, coconut oil sodium, TCC 42 parts, potassium peroxydisulfate 38 parts, polyvinyl alcohol 42 parts, ethylene glycol salicylate 38 parts, hydroxyethyl methylacrylate 44 parts, Firebrake ZB 38 parts, antimonous oxide 42 parts, phosphoric acid cyanamide 38 parts, diethyl aminoethyl methacrylate 42 parts, pentaerythrite 38 parts, dinonyl naphthalene sulfonate barium 42 parts, aluminium triphosphate 38 parts, Lupenyl palmitate 42 parts, 2000 parts, water.
Further, above-mentioned weaving flame-proof antibiotic auxiliary agent preparation method step is as follows:
(1) chitosan of described mass fraction, styrax, coconut oil sodium, TCC, potassium peroxydisulfate, polyvinyl alcohol, ethylene glycol salicylate, hydroxyethyl methylacrylate, Firebrake ZB, antimonous oxide, phosphoric acid cyanamide, pentaerythrite, aluminium triphosphate, Lupenyl palmitate are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion about 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the diethyl aminoethyl methacrylate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion about 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the dinonyl naphthalene sulfonate barium of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion about 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix this product that rear obtained solid content is about 20 ~ 70%.
Above-mentioned each component function is as follows:
(1) chitosan: the chitin extensively existed by nature obtains through deacetylation.The premium properties such as the biological functionality of this natural polymer and compatibility, blood compatibility, security, microbic resolvability, by all trades and professions extensive concern, achieve major progress in the application study of the numerous areas such as medicine, food, chemical industry, cosmetics, water treatment, METAL EXTRACTION and recovery, biochemistry and biomedical engineering.
(2) styrax: the agglomerate that spheric granules pressure is formed, differs in size, and outside rufous, to taupe brown, is embedded with yellow-white and canescence opaque almond sample particle, and rough surface is uneven.Gas fragrance, taste are micro-pungent.
(3) coconut oil sodium: there is excellent washing, wetting, emulsification and dispersibility.Low irritant, and the excitant that can reduce other surfactant.
(4) TCC: a kind of efficient, broad spectrum antimicrobicide, it possesses lasting, safe, stable sterilization feature, there is fabulous compatibility with skin, and to gram-positive bacteria, Gram-negative bacteria, fungi, saccharomycete, virus, all there is efficient inhibitory or killing effect.Outstanding advantages is that stability and compatibility are fabulous, do not have niff, and consumption is few, lasting medicine.It is added to perfumed soap, shampoo, shower cream, hand cleanser, mildy wash, beautifying liquid, remove acne frost, washing powder, liquid detergent, trauma agent/ointment, cosmetics, palpus foam cream, toothpaste, mouthwash, antibacterial dish washing detergent, wound disinfection agent, fabric antimicrobial finishing agent, medical disinfectant, fiber textile and except sterilization in underarm odor and beriberi series products, antibacterial and deodorizing.
(5) potassium peroxydisulfate: inorganic compound, white crystals, odorlessness, has hygroscopy.Combustion-supporting, tool excitant.Main as bleaching agent, strong oxidizer, photographic chemical, analytical reagent, polymerization accelerant etc.
(6) ethylene glycol salicylate: water white transparency thick liquid, for antirheumatic, anti-irritant, also for daily cosmetics and essence.
(7) hydroxyethyl methylacrylate: water white transparency mobile liquid.Be dissolved in OOS.Miscible with water.Be mainly used in the modification of resin and coating.For the production of coating, automobile finish and priming paint resin.
(8) Firebrake ZB: a kind of non-halogen flame retardant of environment-friendly type, nontoxic, the feature such as low aqueous solubility, high thermal stability, granularity are little, proportion is little, good dispersion, is widely used in the fields such as plastics, rubber, coating as a kind of efficient flame-retarding agent.This product can be applied to paper, fabric, decorative panel, plastic floor leather, wallpaper, carpet, ceramic glaze, bactericide, in the production of coating, to improve fire resistance.
(9) antimonous oxide: white powder, water insoluble, be dissolved in sodium hydroxide solution and acid.For Chinese white, paint and plastics, play pigment and fire-retardant; For catalyst, mordant, fabric, paper, fire-retardant for plastic, glassmaker's soap.
(10) phosphoric acid cyanamide: white crystalline powder.Stable in the air.Be slightly soluble in ethanol, be insoluble to acetone.The aqueous solution is in acid.As the fireproof agent of phosphate fertilizer and timber, paper, fabric, also for pharmacy etc.
(11) diethyl aminoethyl methacrylate: colourless transparent liquid.Obtained by methacrylic acid and diethylaminoethanol effect.These product have reactive amino and polymerizable vinyl, cohesiveness, thermosetting can be increased, due to the effect of ionic bond, the tinctorial property of bridging property and dyestuff and pigment can be improved, can be used for preparing thermohardening lacquer, antistatic additive, dyeing assistant, lube oil additive, adhesive, leather processing finishing agent, combustion adjuvant etc.
(12) pentaerythrite: white crystals or powder, water-soluble, ethanol, glycerine, ethylene glycol, formamide.Be insoluble to acetone, benzene, carbon tetrachloride, ether and benzinum etc.Flammable, easily by general esterifying organic acid, produce alkyd resins, synthesis quality lubricant, plasticizer, surfactant and the raw material such as medicine, explosive for coatings industry in a large number.Mainly be used in coatings industry, can, in order to manufacture phthalic resin coating, the hardness of paint film, gloss and durability can be made to be improved.It is also used as the required abietinic raw material such as colored paint, varnish and printing-ink, and can drying oil processed, smolderability coating and aeroengine oil etc.
(13) dinonyl naphthalene sulfonate barium: a kind of widely used rust-inhibiting additive, all have excellent rustless property to various metal and product thereof, it has the molten stability of good oil, good lubrication and abrasion resistance, and the stability under dampness is also fine.
(14) aluminium triphosphate: the nuisanceless white rust resisting pigment of a new generation is plumbous, that the poisonous rush-resisting material of chromium system is desirable regeneration product.This pigment is widely used in various priming paint and bottom surface unification coating, good with varnish affinity, can with various pigment, filler with the use of, also can share with various rust resisting pigment, various high-performance anticorrosion coating can be prepared.Be applicable to phenolic resins, alkyd resins, epoxy resin, epoxy polyester and acrylic resin equal solvent type coating and various water-soluble resin coating; Can also apply and high build paint, powdery paints, organic titanium anticorrosive coating, on rust paint and pitch prill paint, zinc rich primer, fireproof paint, heat-resisting paint etc.
(15) Lupenyl palmitate: a kind of good fibrous raw material, has the features such as good permeability, hygroscopicity be strong, soft, antibacterial, cool in summer and warm in winter.
This beneficial effect of the invention is: this weaving is simple with flame-proof antibiotic auxiliary agent process of preparing, and prepared product has comparatively superior fire-retardant, water-proof antibiotic performance, is adapted at field of textiles and uses, improve properties of product.
Detailed description of the invention
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
embodiment 1
Weaving in the present embodiment flame-proof antibiotic auxiliary agent, is made up of the component of following mass fraction: chitosan 36 parts, styrax 38 parts, 34 parts, coconut oil sodium, TCC 38 parts, potassium peroxydisulfate 34 parts, polyvinyl alcohol 38 parts, ethylene glycol salicylate 34 parts, hydroxyethyl methylacrylate 40 parts, Firebrake ZB 34 parts, antimonous oxide 38 parts, phosphoric acid cyanamide 34 parts, diethyl aminoethyl methacrylate 38 parts, pentaerythrite 34 parts, dinonyl naphthalene sulfonate barium 38 parts, aluminium triphosphate 34 parts, Lupenyl palmitate 38 parts, 1000 parts, water.
Above-mentioned weaving flame-proof antibiotic auxiliary agent preparation method step is as follows:
(1) chitosan of described mass fraction, styrax, coconut oil sodium, TCC, potassium peroxydisulfate, polyvinyl alcohol, ethylene glycol salicylate, hydroxyethyl methylacrylate, Firebrake ZB, antimonous oxide, phosphoric acid cyanamide, pentaerythrite, aluminium triphosphate, Lupenyl palmitate are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5400r/min, jitter time is 60min;
(2) add the diethyl aminoethyl methacrylate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5200r/min, and jitter time is 50min;
(3) add the dinonyl naphthalene sulfonate barium of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 4800r/min, and jitter time is 40min; Mix this product that rear obtained solid content is about 20%.
embodiment 2
Weaving in the present embodiment flame-proof antibiotic auxiliary agent, is made up of the component of following mass fraction: chitosan 38 parts, styrax 40 parts, 36 parts, coconut oil sodium, TCC 40 parts, potassium peroxydisulfate 36 parts, polyvinyl alcohol 40 parts, ethylene glycol salicylate 36 parts, hydroxyethyl methylacrylate 42 parts, Firebrake ZB 36 parts, antimonous oxide 40 parts, phosphoric acid cyanamide 36 parts, diethyl aminoethyl methacrylate 40 parts, pentaerythrite 36 parts, dinonyl naphthalene sulfonate barium 40 parts, aluminium triphosphate 36 parts, Lupenyl palmitate 40 parts, 1500 parts, water.
Above-mentioned weaving flame-proof antibiotic auxiliary agent preparation method step is as follows:
(1) chitosan of described mass fraction, styrax, coconut oil sodium, TCC, potassium peroxydisulfate, polyvinyl alcohol, ethylene glycol salicylate, hydroxyethyl methylacrylate, Firebrake ZB, antimonous oxide, phosphoric acid cyanamide, pentaerythrite, aluminium triphosphate, Lupenyl palmitate are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 5200r/min, jitter time is 45min;
(2) add the diethyl aminoethyl methacrylate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 27kHz, rate of dispersion about 5000r/min, and jitter time is 40min;
(3) add the dinonyl naphthalene sulfonate barium of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 25kHz, rate of dispersion about 4700r/min, and jitter time is 30min; Mix this product that rear obtained solid content is about 35%.
embodiment 3
Weaving in the present embodiment flame-proof antibiotic auxiliary agent, is made up of the component of following mass fraction: chitosan 40 parts, styrax 42 parts, 38 parts, coconut oil sodium, TCC 42 parts, potassium peroxydisulfate 38 parts, polyvinyl alcohol 42 parts, ethylene glycol salicylate 38 parts, hydroxyethyl methylacrylate 44 parts, Firebrake ZB 38 parts, antimonous oxide 42 parts, phosphoric acid cyanamide 38 parts, diethyl aminoethyl methacrylate 42 parts, pentaerythrite 38 parts, dinonyl naphthalene sulfonate barium 42 parts, aluminium triphosphate 38 parts, Lupenyl palmitate 42 parts, 2000 parts, water.
Above-mentioned weaving flame-proof antibiotic auxiliary agent preparation method step is as follows:
(1) chitosan of described mass fraction, styrax, coconut oil sodium, TCC, potassium peroxydisulfate, polyvinyl alcohol, ethylene glycol salicylate, hydroxyethyl methylacrylate, Firebrake ZB, antimonous oxide, phosphoric acid cyanamide, pentaerythrite, aluminium triphosphate, Lupenyl palmitate are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, jitter time is 30min;
(2) add the diethyl aminoethyl methacrylate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 35kHz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) add the dinonyl naphthalene sulfonate barium of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 4600r/min, and jitter time is 20min; Mix this product that rear obtained solid content is about 70%.
Carry out performance measurement for the coating in embodiment 1, embodiment 2 and embodiment 3 and certain commercial coating, measured data are as shown in table 1.Fire protection flame retarding level estimate adopts UL94 standard.
Table 1 the performance test results
Visible, material of the present invention has good fire protection flame retarding, waterproof, antibacterial and mouldproof sex change energy.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. flame-proof antibiotic auxiliary agent is used in a weaving, it is characterized in that: be made up of the component of following mass fraction: chitosan 36 ~ 40 parts, styrax 38 ~ 42 parts, 34 ~ 38 parts, coconut oil sodium, TCC 38 ~ 42 parts, potassium peroxydisulfate 34 ~ 38 parts, polyvinyl alcohol 38 ~ 42 parts, ethylene glycol salicylate 34 ~ 38 parts, hydroxyethyl methylacrylate 40 ~ 44 parts, Firebrake ZB 34 ~ 38 parts, antimonous oxide 38 ~ 42 parts, phosphoric acid cyanamide 34 ~ 38 parts, diethyl aminoethyl methacrylate 38 ~ 42 parts, pentaerythrite 34 ~ 38 parts, dinonyl naphthalene sulfonate barium 38 ~ 42 parts, aluminium triphosphate 34 ~ 38 parts, Lupenyl palmitate 38 ~ 42 parts, 1000 ~ 2000 parts, water.
2. weaving flame-proof antibiotic auxiliary agent according to claim 1, it is characterized in that: described weaving flame-proof antibiotic auxiliary agent is made up of the component of following mass fraction: chitosan 36 parts, styrax 38 parts, 34 parts, coconut oil sodium, TCC 38 parts, potassium peroxydisulfate 34 parts, polyvinyl alcohol 38 parts, ethylene glycol salicylate 34 parts, hydroxyethyl methylacrylate 40 parts, Firebrake ZB 34 parts, antimonous oxide 38 parts, phosphoric acid cyanamide 34 parts, diethyl aminoethyl methacrylate 38 parts, pentaerythrite 34 parts, dinonyl naphthalene sulfonate barium 38 parts, aluminium triphosphate 34 parts, Lupenyl palmitate 38 parts, 1000 parts, water.
3. according to the flame-proof antibiotic auxiliary agent of the weaving described in claim 1 to 2, it is characterized in that: described weaving flame-proof antibiotic auxiliary agent is made up of the component of following mass fraction: chitosan 38 parts, styrax 40 parts, 36 parts, coconut oil sodium, TCC 40 parts, potassium peroxydisulfate 36 parts, polyvinyl alcohol 40 parts, ethylene glycol salicylate 36 parts, hydroxyethyl methylacrylate 42 parts, Firebrake ZB 36 parts, antimonous oxide 40 parts, phosphoric acid cyanamide 36 parts, diethyl aminoethyl methacrylate 40 parts, pentaerythrite 36 parts, dinonyl naphthalene sulfonate barium 40 parts, aluminium triphosphate 36 parts, Lupenyl palmitate 40 parts, 1500 parts, water.
4. the flame-proof antibiotic auxiliary agent of the weaving according to claims 1 to 3, it is characterized in that: described weaving flame-proof antibiotic auxiliary agent is made up of the component of following mass fraction: chitosan 40 parts, styrax 42 parts, 38 parts, coconut oil sodium, TCC 42 parts, potassium peroxydisulfate 38 parts, polyvinyl alcohol 42 parts, ethylene glycol salicylate 38 parts, hydroxyethyl methylacrylate 44 parts, Firebrake ZB 38 parts, antimonous oxide 42 parts, phosphoric acid cyanamide 38 parts, diethyl aminoethyl methacrylate 42 parts, pentaerythrite 38 parts, dinonyl naphthalene sulfonate barium 42 parts, aluminium triphosphate 38 parts, Lupenyl palmitate 42 parts, 2000 parts, water.
5. the flame-proof antibiotic auxiliary agent of the weaving according to claim 1 or 4, is characterized in that: described weaving flame-proof antibiotic auxiliary agent preparation method step is as follows:
(1) chitosan of described mass fraction, styrax, coconut oil sodium, TCC, potassium peroxydisulfate, polyvinyl alcohol, ethylene glycol salicylate, hydroxyethyl methylacrylate, Firebrake ZB, antimonous oxide, phosphoric acid cyanamide, pentaerythrite, aluminium triphosphate, Lupenyl palmitate are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion about 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the diethyl aminoethyl methacrylate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion about 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the dinonyl naphthalene sulfonate barium of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion about 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix this product that rear obtained solid content is about 20 ~ 70%.
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| CN105625044A (en) * | 2016-03-31 | 2016-06-01 | 太仓市锦达印染有限公司 | Pretreatment technology for fabric printing and dyeing |
| CN105714558A (en) * | 2016-04-20 | 2016-06-29 | 吴江福汇缘家纺有限公司 | Textile auxiliary containing antibiotic constituents and preparation method thereof |
| CN105734964A (en) * | 2016-04-20 | 2016-07-06 | 吴江福汇缘家纺有限公司 | Textile auxiliary agent for auxiliary textile sizing and preparation method thereof |
| CN106192403A (en) * | 2016-07-10 | 2016-12-07 | 中山市绿浪助剂有限公司 | A kind of natural mixed textile whole dye Antibacterial accessory ingredient |
| CN109098002A (en) * | 2018-08-17 | 2018-12-28 | 深圳市南硕明泰科技有限公司 | A kind of fire resisting antibacterial contton cloth and preparation method thereof |
| CN110714327A (en) * | 2019-10-18 | 2020-01-21 | 安徽职业技术学院 | Flame-retardant, moisture-proof and antibacterial treating agent for painting and calligraphy artworks and preparation method thereof |
| CN112481814A (en) * | 2020-11-24 | 2021-03-12 | 江西美宝利医用敷料有限公司 | Production process of antibacterial non-woven fabric |
| CN112494567A (en) * | 2020-11-24 | 2021-03-16 | 中科恩吉瑞特(烟台)科技发展有限公司 | Skin surface disinfectant with efficient sterilization function |
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| CN112494567A (en) * | 2020-11-24 | 2021-03-16 | 中科恩吉瑞特(烟台)科技发展有限公司 | Skin surface disinfectant with efficient sterilization function |
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Application publication date: 20151111 |