CN105038103A - Novel glass fiber reinforced plastics - Google Patents
Novel glass fiber reinforced plastics Download PDFInfo
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- CN105038103A CN105038103A CN201510487554.3A CN201510487554A CN105038103A CN 105038103 A CN105038103 A CN 105038103A CN 201510487554 A CN201510487554 A CN 201510487554A CN 105038103 A CN105038103 A CN 105038103A
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- reinforced plastic
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- fiber reinforced
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Abstract
The invention relates to novel glass fiber reinforced plastics, which consist of the following ingredients in parts by weight: 30 to 35 parts of bisphenol-A epoxide vinylester resin, 46 to 49 parts of phenolic resin, 25 to 30 parts of polyimide resin, 1 to 1.4 parts of demoulding agents, 3 to 6 parts of fluorescent agents, 1.5 to 2.5 parts of anti-tendering agents, 10 to 15 parts of pigments, 35 to 39 parts of glass fiber and 15 to 20 parts of calcium carbonate. The novel glass fiber reinforced plastics have the advantages that the weight is light; the intensity is light; an anti-corrosion effect is achieved; the water resistance is high; the anti-tendering effect is achieved; the color cannot easily fade; the heat-resistant performance is high; the service life is long.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of new glass fibre reinforced plastic.
Background technology
Glass reinforced plastic has that quality is light, hardness is strong, the advantage of corrosion-resistant, good electrical property, more and more wider by what use in life, also application has gradually been had in safe direction board, and the plastics nowadays still used in traffic sign and obstacle etc., owing to being often placed in outdoor place, expose to the sun and rain indicate and obstacle easily brittle, sign and obstacle on color easily come off, work-ing life is short.
Summary of the invention
The object of the invention is, in order to overcome above deficiency, to provide intensity high, corrosion-resistant, water tolerance is strong, has anti-embrittling effect, color difficult drop-off, a kind of new glass fibre reinforced plastic of long service life.
Technical scheme provided by the invention is: a kind of new glass fibre reinforced plastic, and described new glass fibre reinforced plastic is made up of the raw material of following parts by weight proportioning:
Bisphenol-A epoxy Vinylite 30-35 part;
Resol 46-49 part;
Polyimide resin 25-30 part;
Releasing agent 1-1.4 part;
Fluorescent agent 3-6 part;
Anti-labilizer 1.5-2.5 part;
Pigment 10-15 part;
Glass fibre 35-39 part;
Calcium carbonate 15-20 part.
Further improvement of the present invention is: described releasing agent is emulsifying wax.
Further improvement of the present invention is: described fluorescent agent is the derivative of phenylpyrrazolin.
Further improvement of the present invention is: described anti-labilizer is sodium acetate.
The invention has the advantages that: the present invention has used these three kinds of resins of bisphenol-A epoxy Vinylite, resol and polyimide resin, fixed line speed is fast, can be very fast obtain working strength, there are good erosion resistance, water tolerance and alkali resistance, owing to containing more secondary hydroxyl in bisphenol-A epoxy Vinylite, wettability and the station viscosity of glass fibre effectively can be improved; Directly increase pigment in proportioning in the present invention, color is placed in glass reinforced plastic inside, add the steadiness of color, make color difficult drop-off; The fluorescent agent of derivative adding phenylpyrrazolin and so in the present invention, the glass reinforced plastic reflective making this proportioning obtained is better, also can play the effect of instruction when not having light; Add the anti-labilizer of sodium acetate and so in the present invention, greatly reduce glass reinforced plastic brittle speed in extraneous physical environment; Used the releasing agent of emulsifying wax and so in the present invention, make the obtained glass reinforced plastic of this proportioning in the demoulding time more convenient; It is good, practical that resistance toheat is put forward in the present invention's increasing.
embodiment:
Embodiment 1:
Bisphenol-A epoxy Vinylite 30 parts;
49 parts, resol;
Polyimide resin 25 parts;
Emulsifying wax 1 part;
3 parts, the derivative of phenylpyrrazolin;
Sodium acetate 1.5 parts;
Pigment 10 parts;
35 parts, glass fibre;
15 parts, calcium carbonate.
Embodiment 2:
Bisphenol-A epoxy Vinylite 35 parts;
46 parts, resol;
Polyimide resin 30 parts;
Emulsifying wax 1.4 parts;
6 parts, the derivative of phenylpyrrazolin;
Sodium acetate 2.5 parts;
Pigment 15 parts;
39 parts, glass fibre;
20 parts, calcium carbonate.
Embodiment 3:
Bisphenol-A epoxy Vinylite 32.5 parts;
47.5 parts, resol;
Polyimide resin 27.5 parts;
Emulsifying wax 1.2 parts;
4.5 parts, the derivative of phenylpyrrazolin;
Sodium acetate 2 parts;
Pigment 12.5 parts;
37 parts, glass fibre;
17.5 parts, calcium carbonate.
Embodiment 4:
Bisphenol-A epoxy Vinylite 35 parts;
47.5 parts, resol;
Polyimide resin 27.5 parts;
Emulsifying wax 1 part;
6 parts, the derivative of phenylpyrrazolin;
Sodium acetate 2.5 parts;
Pigment 12.5 parts;
35 parts, glass fibre;
17.5 parts, calcium carbonate.
Embodiment 5:
Bisphenol-A epoxy Vinylite 32.5 parts;
46 parts, resol;
Polyimide resin 30 parts;
Emulsifying wax 1.2 parts;
5 parts, the derivative of phenylpyrrazolin;
Sodium acetate 2.1 parts;
Pigment 12 parts;
34 parts, glass fibre;
18 parts, calcium carbonate.
Embodiment 6:
Bisphenol-A epoxy Vinylite 34 parts;
47 parts, resol;
Polyimide resin 26 parts;
Emulsifying wax 1.3 parts;
5 parts, the derivative of phenylpyrrazolin;
Sodium acetate 1.9 parts;
Pigment 12.5 parts;
36 parts, glass fibre;
14 parts, calcium carbonate.
A kind of new glass fibre reinforced plastic obtained by above-described embodiment 1-6 has the technique effect described in following table after tested:
Claims (4)
1. a new glass fibre reinforced plastic, is characterized in that: described new glass fibre reinforced plastic is made up of the raw material of following parts by weight proportioning:
Bisphenol-A epoxy Vinylite 30-35 part;
Resol 46-49 part;
Polyimide resin 25-30 part;
Releasing agent 1-1.4 part;
Fluorescent agent 3-6 part;
Anti-labilizer 1.5-2.5 part;
Pigment 10-15 part;
Glass fibre 35-39 part;
Calcium carbonate 15-20 part.
2. a kind of new glass fibre reinforced plastic according to claim 1, is characterized in that: described releasing agent is emulsifying wax.
3. a kind of new glass fibre reinforced plastic according to claim 1, is characterized in that: described fluorescent agent is the derivative of phenylpyrrazolin.
4. a kind of new glass fibre reinforced plastic according to claim 1, is characterized in that: described anti-labilizer is sodium acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510487554.3A CN105038103B (en) | 2015-08-10 | 2015-08-10 | A kind of fiberglass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510487554.3A CN105038103B (en) | 2015-08-10 | 2015-08-10 | A kind of fiberglass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105038103A true CN105038103A (en) | 2015-11-11 |
| CN105038103B CN105038103B (en) | 2017-06-09 |
Family
ID=54445094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510487554.3A Active CN105038103B (en) | 2015-08-10 | 2015-08-10 | A kind of fiberglass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105038103B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623199A (en) * | 2016-03-01 | 2016-06-01 | 苏州莱特复合材料有限公司 | Carbon fiber composite material used for pipeline and preparation method thereof |
| CN107556720A (en) * | 2017-09-22 | 2018-01-09 | 国网吉林省电力有限公司松原供电公司 | Nano-glass steel facing material for power system electric power cabinet |
| CN109096689A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of flame resistant glass steel pipe and preparation method thereof |
| CN109096688A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of glass reinforced plastic pipe resistant to high temperatures |
| CN110145158A (en) * | 2019-05-31 | 2019-08-20 | 成都辟思航空科技有限公司 | Glass steel course antenna fragile stem |
| CN110174667A (en) * | 2019-05-31 | 2019-08-27 | 成都辟思航空科技有限公司 | Glass steel DME rangefinder fragile stem |
| CN110862648A (en) * | 2019-11-25 | 2020-03-06 | 连云港泓昊复合材料有限公司 | Sinking straight pipe of inclined elbow for desulfurization and preparation method thereof |
Citations (3)
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| CN101051091A (en) * | 2006-04-03 | 2007-10-10 | 亿镫光电科技股份有限公司 | Light increasing element |
| CN103360727A (en) * | 2012-04-01 | 2013-10-23 | 上海杰事杰新材料(集团)股份有限公司 | Modified pultrusion composite material and preparation method thereof |
| CN104672782A (en) * | 2014-12-31 | 2015-06-03 | 国家电网公司 | Fiber-reinforced resin-based composite material core and preparation method thereof |
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2015
- 2015-08-10 CN CN201510487554.3A patent/CN105038103B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101051091A (en) * | 2006-04-03 | 2007-10-10 | 亿镫光电科技股份有限公司 | Light increasing element |
| CN103360727A (en) * | 2012-04-01 | 2013-10-23 | 上海杰事杰新材料(集团)股份有限公司 | Modified pultrusion composite material and preparation method thereof |
| CN104672782A (en) * | 2014-12-31 | 2015-06-03 | 国家电网公司 | Fiber-reinforced resin-based composite material core and preparation method thereof |
Non-Patent Citations (3)
| Title |
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| 洪晔等: "《纱线漂染基础知识》", 31 October 1983, 江苏科学技术出版社 * |
| 陈溥等: "《纺织染整助剂手册》", 31 August 1995, 中国轻工业出版社 * |
| 黄慧荣等: "《汽车美容与护理》", 31 August 2012, 合肥工业大学出版社 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623199A (en) * | 2016-03-01 | 2016-06-01 | 苏州莱特复合材料有限公司 | Carbon fiber composite material used for pipeline and preparation method thereof |
| CN107556720A (en) * | 2017-09-22 | 2018-01-09 | 国网吉林省电力有限公司松原供电公司 | Nano-glass steel facing material for power system electric power cabinet |
| CN109096689A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of flame resistant glass steel pipe and preparation method thereof |
| CN109096688A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of glass reinforced plastic pipe resistant to high temperatures |
| CN110145158A (en) * | 2019-05-31 | 2019-08-20 | 成都辟思航空科技有限公司 | Glass steel course antenna fragile stem |
| CN110174667A (en) * | 2019-05-31 | 2019-08-27 | 成都辟思航空科技有限公司 | Glass steel DME rangefinder fragile stem |
| CN110145158B (en) * | 2019-05-31 | 2020-11-06 | 成都辟思航空科技有限公司 | Glass fiber reinforced plastic course antenna fragile rod |
| CN110174667B (en) * | 2019-05-31 | 2022-11-08 | 成都辟思航空科技有限公司 | Breakable pole of glass steel DME distancer |
| CN110862648A (en) * | 2019-11-25 | 2020-03-06 | 连云港泓昊复合材料有限公司 | Sinking straight pipe of inclined elbow for desulfurization and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105038103B (en) | 2017-06-09 |
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