CN105019232A - Efficient polyamide fiber spinning winding oiling process for netting twine - Google Patents
Efficient polyamide fiber spinning winding oiling process for netting twine Download PDFInfo
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- CN105019232A CN105019232A CN201510511895.XA CN201510511895A CN105019232A CN 105019232 A CN105019232 A CN 105019232A CN 201510511895 A CN201510511895 A CN 201510511895A CN 105019232 A CN105019232 A CN 105019232A
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- oiling
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- netting twine
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Abstract
The invention relates to an efficient polyamide fiber spinning winding oiling process for a netting twine. An oiling oil solution comprises, by weight, 75.7% of a soluble oil composition A, 12.9% of a modifier composition B and 11.4% of a modifier composition C. The three compositions are sequentially added to a mixing tank according to the ratios and are evenly mixed, and then the oil solution is prepared. After the oil solution is prepared, oiling can be conducted through a spraying device or an oiling roller or an immersion trough, and the oiling rate is adjusted according to the process. The oil solution capable of directly conducting oiling can be used at any stage of fiber manufacturing (after spinning-out of the spinning process and before winding of the spinning process) and fiber processing (the drafting false twisting processing process, the warping process, the spooling process and the like) according to needs. The efficient polyamide fiber spinning winding oiling process is very useful for the drafting false twisting processing process at the high speed of more than 800 m/min.
Description
Technical field
The present invention relates to the fiber finish (straight oil) directly oiled.Particularly about the oiling process that reels at efficient netting twine extrusion spinning.
Background technology
In recent years, polyamide fibre manufacturing processing technic using high production rate, rationalize as target just in accelerated development.Such as, drafting false twisting processing as the master operation of the processed filament production of the thermoplasticity such as polyester, polyamide synthesis polyamide fibre divides more than 1000m/, but in the finish directly oiled all the time used in order to the weaving after successfully processing etc., there is the dispersing significantly of oil, workshop is polluted, the problem of finish loss.For this reason, following suggestion is had: the hydrophilic silicon oil (JP 60-146083 publication) of interpolation poly alkylene glycol modification in finish; Oil body index improver (United States Patent (USP) 4,098,703) is added in finish; And the polymer (Unexamined Patent 2-33380 publication) etc. added in finish containing carboxylic acid alkyl ester monomer etc.
These above-mentioned finishes have certain effect preventing dispersing, but it is more and more higher for the quality requirements of the polyamide fibre that attached to the finish directly oiled recently, not only dispersing of finish will be lacked, and require that the silk fluffing after attached to the finish directly oiled is few, when cleaning, finish is easily cleaned, do not go wrong during dyeing, and these finishes can not fully meet the demands.
The result that the present inventors study repeatedly in order to solve the problem, finds the finish combined according to a specific ratio by the composition of specific composition, to the obvious effect that solved the problem, thus completes the present invention.
Summary of the invention
The object of this invention is to provide a kind of efficient netting twine extrusion spinning to reel oiling process, adopt the finish that can directly oil can use in any stage of the manufacture of fiber (after the spinning of spinning technique, before winding), processing (drafting false twisting processing technology, warping technology, winding process etc.) as required.Divide above high speed drafting false twisting processing technology by extremely useful for 800m/.
Technical scheme of the present invention so realizes: a kind of efficient netting twine extrusion spinning reels oiling process, described in oil and comprise following three compositions with finish, be made up of each component of following parts by weight respectively:
Soluble oil composition A:
Ethyl oleate potassium sulfonate 25-30
Emulphor FM 15-16
Cetanol polyoxyethylene ether 2-5
Oleic acid 20-25
Sodium alkyl sulfonate 4-8
Water 30-40;
Modifier composite B:
Antistatic additive PK 8-10
Ethoxylated dodecyl alcohol 12-15
Hexadecanol phosphate kalium salt 20-30
Titanium dioxide 1-4
Triethanolamine 1-4
Polyvinyl n-butyl ether 2-5;
Modifier composite C:
Polyethylene glycol stearate diester 30-35
Fatty acid polyethylene glycol ester 10-20
Beet alkali ampholytic surface active agent 4-6
Polyglycereol ethyoxyl ether 5-7
Dimethicone 11-15;
By weight percentage containing soluble oil composition A 75.7% in described finish; Modifier composite B 12.9%; Modifier composite C 11.4%; Above-mentioned three components is added in mixing kettle successively by ratio, stirs; After finish prepares, namely oil by spray equipment, oiling roller or immersion trough, oil applying rate adjusts by technique.Described technological process is: polymerization → extraction → oven dry → spinning → winding → traction → preliminary drying → rewinding → finished product, the temperature of described winding is 18-25 DEG C.
Preferably, described oil agent comprises following three compositions, is made up of respectively the following component of following parts by weight:
Soluble oil composition A:
Ethyl oleate potassium sulfonate 28
Emulphor FM 15.5
Cetanol polyoxyethylene ether 3
Oleic acid 22.5
Sodium alkyl sulfonate 6
Water 35;
Modifier composite B:
Antistatic additive PK 9
Ethoxylated dodecyl alcohol 13.5
Hexadecanol phosphate kalium salt 25
Titanium dioxide 2.6
Triethanolamine 3
Polyvinyl n-butyl ether 3.5
Modifier composite C:
Polyethylene glycol stearate diester 33
Fatty acid polyethylene glycol ester 15
Beet alkali ampholytic surface active agent 5
Polyglycereol ethyoxyl ether 6
Dimethicone 13.
Preferably, the particle diameter of described titanium dioxide is about 10-100nm.
The invention has the advantages that
Finish of the present invention can use in any stage of the manufacture of fiber (after the spinning of spinning technique, before winding), processing (drafting false twisting processing technology, warping technology, winding process etc.) as required.Be useful especially for drafting false twisting processing technology, and divide above high speed drafting false twisting processing technology by extremely useful for 800m/.
As the fiber that can be suitable for the finish directly oiled of the present invention, the synthetic fiber of polyamide fibre, polyamide, polypropylene nitrile, polypropylene, polyethylene, aromatic polyamides etc. can be enumerated, the chemical fibre of artificial silk, acetate fibre etc., the natural fabric of cotton, hair, silk etc. and the blended ratio of these fibers and combined yarn, particularly play good effect for synthetic fiber polyamide fibre.
The finish directly oiled of the present invention, to the adhesion amount of fiber, normally relative to fibre weight, is 0.2 ~ 5.0 % by weight, preferably 0.5 ~ 2.5 % by weight.
Detailed description of the invention
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment one:
A kind of efficient netting twine extrusion spinning reels oiling process, described in oil and comprise following three compositions with finish, be made up of each component of following parts by weight respectively:
Soluble oil composition A:
Ethyl oleate potassium sulfonate 25
Emulphor FM 15
Cetanol polyoxyethylene ether 2
Oleic acid 20
Sodium alkyl sulfonate 4
Water 30;
Modifier composite B:
Antistatic additive PK 8
Ethoxylated dodecyl alcohol 12
Hexadecanol phosphate kalium salt 20
Titanium dioxide 1
Triethanolamine 1
Polyvinyl n-butyl ether 2;
Modifier composite C:
Polyethylene glycol stearate diester 30
Fatty acid polyethylene glycol ester 10
Beet alkali ampholytic surface active agent 4
Polyglycereol ethyoxyl ether 5
Dimethicone 11;
By weight percentage containing soluble oil composition A 75.7% in described finish; Modifier composite B 12.9%; Modifier composite C 11.4%; Above-mentioned three components is added in mixing kettle successively by ratio, stirs; After finish prepares, namely oil by spray equipment, oiling roller or immersion trough, oil applying rate adjusts by technique.Described technological process is: polymerization → extraction → oven dry → spinning → winding → traction → preliminary drying → rewinding → finished product, the temperature of described winding is 18 DEG C.
Embodiment two:
A kind of efficient netting twine extrusion spinning reels oiling process, described in oil and comprise following three compositions with finish, be made up of each component of following parts by weight respectively:
Soluble oil composition A:
Ethyl oleate potassium sulfonate 28
Emulphor FM 15.5
Cetanol polyoxyethylene ether 3
Oleic acid 22.5
Sodium alkyl sulfonate 6
Water 35;
Modifier composite B:
Antistatic additive PK 9
Ethoxylated dodecyl alcohol 13.5
Hexadecanol phosphate kalium salt 25
Titanium dioxide 2.6
Triethanolamine 3
Polyvinyl n-butyl ether 3.5;
Modifier composite C:
Polyethylene glycol stearate diester 33
Fatty acid polyethylene glycol ester 15
Beet alkali ampholytic surface active agent 5
Polyglycereol ethyoxyl ether 6
Dimethicone 13;
By weight percentage containing soluble oil composition A 75.7% in described finish; Modifier composite B 12.9%; Modifier composite C 11.4%; Above-mentioned three components is added in mixing kettle successively by ratio, stirs; After finish prepares, namely oil by spray equipment, oiling roller or immersion trough, oil applying rate adjusts by technique.Described technological process is: polymerization → extraction → oven dry → spinning → winding → traction → preliminary drying → rewinding → finished product, the temperature of described winding is 25 DEG C.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (4)
1. efficient netting twine extrusion spinning reels an oiling process, it is characterized in that, oils to comprise following three compositions with finish, is made up of respectively each component of following parts by weight:
Soluble oil composition A:
Ethyl oleate potassium sulfonate 25-30
Emulphor FM 15-16
Cetanol polyoxyethylene ether 2-5
Oleic acid 20-25
Sodium alkyl sulfonate 4-8
Water 30-40;
Modifier composite B:
Antistatic additive PK 8-10
Ethoxylated dodecyl alcohol 12-15
Hexadecanol phosphate kalium salt 20-30
Titanium dioxide 1-4
Triethanolamine 1-4
Polyvinyl n-butyl ether 2-5;
Modifier composite C:
Polyethylene glycol stearate diester 30-35
Fatty acid polyethylene glycol ester 10-20
Beet alkali ampholytic surface active agent 4-6
Polyglycereol ethyoxyl ether 5-7
Dimethicone 11-15;
By weight percentage containing soluble oil composition A 75.7% in described finish; Modifier composite B 12.9%; Modifier composite C 11.4%; Above-mentioned three kinds of compositions are added in mixing kettle successively by ratio, stir; After finish prepares, namely oil by spray equipment, oiling roller or immersion trough, oil applying rate adjusts by technique.
2. technological process described in is: polymerization → extraction → oven dry → spinning → winding → traction → preliminary drying → rewinding → finished product, the temperature of described winding is 18-25 DEG C.
3. the efficient netting twine extrusion spinning of one according to claim 1 reels oiling process, and it is characterized in that, described oil agent comprises following three compositions, is made up of respectively the following component of following parts by weight:
Soluble oil composition A:
Ethyl oleate potassium sulfonate 28
Emulphor FM 15.5
Cetanol polyoxyethylene ether 3
Oleic acid 22.5
Sodium alkyl sulfonate 6
Water 35;
Modifier composite B:
Antistatic additive PK 9
Ethoxylated dodecyl alcohol 13.5
Hexadecanol phosphate kalium salt 25
Titanium dioxide 2.6
Triethanolamine 3
Polyvinyl n-butyl ether 3.5
Modifier composite C:
Polyethylene glycol stearate diester 33
Fatty acid polyethylene glycol ester 15
Beet alkali ampholytic surface active agent 5
Polyglycereol ethyoxyl ether 6
Dimethicone 13.
4. the efficient netting twine extrusion spinning of one according to claim 1 reels oiling process, and it is characterized in that, the particle diameter of described titanium dioxide is about 10-100nm.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008223198A (en) * | 2007-03-15 | 2008-09-25 | Nippon Ester Co Ltd | Method for producing polyamide fiber |
CN102400324A (en) * | 2010-09-09 | 2012-04-04 | 王纯 | Nylon filament oiling agent for fishing net |
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2015
- 2015-08-20 CN CN201510511895.XA patent/CN105019232A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008223198A (en) * | 2007-03-15 | 2008-09-25 | Nippon Ester Co Ltd | Method for producing polyamide fiber |
CN102400324A (en) * | 2010-09-09 | 2012-04-04 | 王纯 | Nylon filament oiling agent for fishing net |
Non-Patent Citations (3)
Title |
---|
宋小平: "《纺织染整添加剂生产与应用技术》", 30 April 2007, 中国石化出版社 * |
李友森: "《轻化工业助剂使用手册》", 31 July 2002, 化学工业出版社 * |
黄玉媛: "《轻化工助剂配方》", 31 August 2008, 中国纺织出版社 * |
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