CN105019223A - Flame resistant fabric - Google Patents
Flame resistant fabric Download PDFInfo
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- CN105019223A CN105019223A CN201510331458.XA CN201510331458A CN105019223A CN 105019223 A CN105019223 A CN 105019223A CN 201510331458 A CN201510331458 A CN 201510331458A CN 105019223 A CN105019223 A CN 105019223A
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- infiltrate
- composite fibre
- flame
- graphene
- shitosan
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Abstract
The present invention relates to a flame resistant fabric, wherein warp uses graphene modified composite fiber warps, shaped weft uses polyester fibers or polyurethane fibers, protein fibers and bamboo fibers are woven to form the composite fibers, and nanometer zinc oxide is coated on the outer surface of the fabric. According to the present invention, the cost is low, and the produced fabric has characteristics of good flame retardant effect, deodorizing, antibacterial and good style, and can be used for production of blankets, clothing, shoes and socks, and the like.
Description
Technical field
The invention belongs to spinning field, relate to a kind of flame-retardant textile.
Background technology
Along with spinning, weave, the lifting of the continuous advancement of Final finishing industrial technology and people's living standard, wear washability and get more and more, people pay attention to comfortableness and the ergonomics performance of socks gradually, in order to adapt to consumer demand, adopt new raw material can produce various Fresh fats material in conjunction with new spinning technology, improved by the hindlimb unload that matches again, increase, improving product wear function, making product cater to market development demand, is also the development trend of new product from now on.
China Patent Publication No. CN 101407962 A, publication date on April 15th, 2009, name is called Outlast air-conditioning fiber polar fleece and production technology thereof, this application case discloses a kind of Outlast air-conditioning fiber polar fleece and production technology is using Outlast air-conditioning fiber as wire gauze, using polyester filament as loop yarn, weave and process, wherein the content of Outlast air-conditioning fiber is 35-65%.A production technology for Outlast air-conditioning fiber polar fleece, step comprise weave, stamp, dry, roll fluffing and pre-setting, plucking, sizing, carding, cropping after plucking, shake grain and shake grain after shape.Its weak point is, fabric feeling and comfort level poor.
Summary of the invention
The object of the invention is to, in order to solve prior art fabric feeling and comfort level good but can not temperature adjustment defect and a kind of fire-retardant, comfort level good, deodorization is fungi-proofing flame-retardant textile is provided.
To achieve these goals, the present invention is by the following technical solutions:
A kind of flame-retardant textile, warp adopts by the composite fibre organizine through Graphene modification, and sizing tram adopts polyester fiber or polyurethane fiber, and wherein, composite fibre is woven by protein fibre and bamboo fibre and forms, and fabric exterior is coated with nano zine oxide.
As preferably, composite fibre is woven by 3-8 radixin matter fiber and 6-12 root bamboo fibre and forms.
As preferably, the composite fibre of Graphene modification is dried through segmentation after composite fibre being placed in infiltrate ultrasonic immersion 75-90min, obtains the composite fibre that Graphene is modified.
As preferably, the mass ratio of described composite fibre and infiltrate is 1:5-10, infiltrate is the aqueous solution of shitosan, acetic acid, trehalose, castor oil polyoxyethylene ether and quaternary ammonium salt, wherein the mass percent concentration of each component is: Graphene 25-30%, shitosan 1.5-3.5%, acetic acid 1-1.5%, trehalose 5-10%, polyethylene glycol adipate 5-7%, castor oil polyoxyethylene ether 0.3-0.5%, quaternary ammonium salt 0.1-0.3%.
As preferably, described infiltrate obtains by the following method: after first measuring Graphene, shitosan, acetic acid, trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether, quaternary ammonium salt and water successively by the mass percent concentration of component each in infiltrate, successively that acetic acid, shitosan is soluble in water again, add Graphene again and carry out ultrasonic disperse, finally add trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether and quaternary ammonium salt to stir simultaneously, obtain infiltrate.
As preferably, the concrete steps that segmentation is dried are: first at 125-135 DEG C, dry 10-20min, then dry at 60-70 DEG C.
As preferably, Particle Size of Nanometer ZnO is 100-120nm, and nano oxidized spelter coating accounts for more than 98% of cloth outer surface, and nano zinc oxide particles is coated in design on fabric surface in ultrasonic wave mode by nano oxidized spelter coating.
The present invention is with low cost, and the flame retardant effect of the cloth produced is good, and can be used for producing woollen blanket, clothing, footgear etc., deodorization is fungi-proofing and Fabric Style is good.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further explained:
Embodiment 1
A kind of flame-retardant textile, warp adopts by the composite fibre organizine through Graphene modification, and sizing tram adopts polyester fiber, and wherein, composite fibre is woven by protein fibre and bamboo fibre and forms, and fabric exterior is coated with nano zine oxide; Composite fibre is woven by 3 radixin matter fibers and 6 bamboo fibres and forms; The composite fibre of Graphene modification is dried through segmentation after composite fibre being placed in infiltrate ultrasonic immersion 75min, obtains the composite fibre that Graphene is modified; The mass ratio of described composite fibre and infiltrate is 1:5, infiltrate is the aqueous solution of shitosan, acetic acid, trehalose, castor oil polyoxyethylene ether and quaternary ammonium salt, wherein the mass percent concentration of each component is: Graphene 25%, shitosan 1.5%, acetic acid 1%, trehalose 5%, polyethylene glycol adipate 5%, castor oil polyoxyethylene ether 0.3%, quaternary ammonium salt 0.1%; Described infiltrate obtains by the following method: after first measuring Graphene, shitosan, acetic acid, trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether, quaternary ammonium salt and water successively by the mass percent concentration of component each in infiltrate, successively that acetic acid, shitosan is soluble in water again, add Graphene again and carry out ultrasonic disperse, finally add trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether and quaternary ammonium salt to stir simultaneously, obtain infiltrate; The concrete steps that segmentation is dried are: first at 125 DEG C, dry 10min, then dry at 60 DEG C; Particle Size of Nanometer ZnO is 100nm, and nano oxidized spelter coating accounts for more than 98% of cloth outer surface, and nano zinc oxide particles is coated in design on fabric surface in ultrasonic wave mode by nano oxidized spelter coating.
Embodiment 2
A kind of flame-retardant textile, warp adopts by the composite fibre organizine through Graphene modification, and sizing tram adopts polyurethane fiber, and wherein, composite fibre is woven by protein fibre and bamboo fibre and forms, and fabric exterior is coated with nano zine oxide; Composite fibre is woven by 5 radixin matter fibers and 10 bamboo fibres and forms; The composite fibre of Graphene modification is dried through segmentation after composite fibre being placed in infiltrate ultrasonic immersion 80min, obtains the composite fibre that Graphene is modified; The mass ratio of described composite fibre and infiltrate is 1:8.5, infiltrate is the aqueous solution of shitosan, acetic acid, trehalose, castor oil polyoxyethylene ether and quaternary ammonium salt, wherein the mass percent concentration of each component is: Graphene 28%, shitosan 2.2%, acetic acid 1.2%, trehalose 7%, polyethylene glycol adipate 6%, castor oil polyoxyethylene ether 0.4%, quaternary ammonium salt 0.2%; Described infiltrate obtains by the following method: after first measuring Graphene, shitosan, acetic acid, trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether, quaternary ammonium salt and water successively by the mass percent concentration of component each in infiltrate, successively that acetic acid, shitosan is soluble in water again, add Graphene again and carry out ultrasonic disperse, finally add trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether and quaternary ammonium salt to stir simultaneously, obtain infiltrate; The concrete steps that segmentation is dried are: first at 130 DEG C, dry 15min, then dry at 65 DEG C; Particle Size of Nanometer ZnO is 110nm, and nano oxidized spelter coating accounts for more than 98% of cloth outer surface, and nano zinc oxide particles is coated in design on fabric surface in ultrasonic wave mode by nano oxidized spelter coating.
Embodiment 3
A kind of flame-retardant textile, warp adopts by the composite fibre organizine through Graphene modification, and sizing tram adopts polyester fiber, and wherein, composite fibre is woven by protein fibre and bamboo fibre and forms, and fabric exterior is coated with nano zine oxide; Composite fibre is woven by 8 radixin matter fibers and 12 bamboo fibres and forms; The composite fibre of Graphene modification is dried through segmentation after composite fibre being placed in infiltrate ultrasonic immersion 90min, obtains the composite fibre that Graphene is modified; The mass ratio of described composite fibre and infiltrate is 1:10, infiltrate is the aqueous solution of shitosan, acetic acid, trehalose, castor oil polyoxyethylene ether and quaternary ammonium salt, wherein the mass percent concentration of each component is: Graphene 30%, shitosan 3.5%, acetic acid 1.5%, trehalose 10%, polyethylene glycol adipate 7%, castor oil polyoxyethylene ether 0.5%, quaternary ammonium salt 0.3%; Described infiltrate obtains by the following method: after first measuring Graphene, shitosan, acetic acid, trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether, quaternary ammonium salt and water successively by the mass percent concentration of component each in infiltrate, successively that acetic acid, shitosan is soluble in water again, add Graphene again and carry out ultrasonic disperse, finally add trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether and quaternary ammonium salt to stir simultaneously, obtain infiltrate; The concrete steps that segmentation is dried are: first at 135 DEG C, dry 20min, then dry at 70 DEG C; Particle Size of Nanometer ZnO is 120nm, and nano oxidized spelter coating accounts for more than 98% of cloth outer surface, and nano zinc oxide particles is coated in design on fabric surface in ultrasonic wave mode by nano oxidized spelter coating.
The present invention is with low cost, and the flame retardant effect of the cloth produced is good, and can be used for producing woollen blanket, clothing, footgear etc., deodorization is fungi-proofing and Fabric Style is good.
Claims (7)
1. a flame-retardant textile, is characterized in that, warp adopts by the composite fibre organizine through Graphene modification, sizing tram adopts polyester fiber or polyurethane fiber, wherein, composite fibre is woven by protein fibre and bamboo fibre and forms, and fabric exterior is coated with nano zine oxide.
2. a kind of flame-retardant textile according to claim 1, is characterized in that, composite fibre is woven by 3-8 radixin matter fiber and 6-12 root bamboo fibre and forms.
3. a kind of flame-retardant textile according to claim 1, is characterized in that, the composite fibre of Graphene modification is dried through segmentation after composite fibre being placed in infiltrate ultrasonic immersion 75-90min, obtains the composite fibre that Graphene is modified.
4. a kind of flame-retardant textile according to claim 3, it is characterized in that, the mass ratio of described composite fibre and infiltrate is 1:5-10, and infiltrate is the aqueous solution of shitosan, acetic acid, trehalose, castor oil polyoxyethylene ether and quaternary ammonium salt, and wherein the mass percent concentration of each component is: Graphene 25-30%, shitosan 1.5-3.5%, acetic acid 1-1.5%, trehalose 5-10%, polyethylene glycol adipate 5-7%, castor oil polyoxyethylene ether 0.3-0.5%, quaternary ammonium salt 0.1-0.3%.
5. a kind of flame-retardant textile according to claim 3 or 4, it is characterized in that, described infiltrate obtains by the following method: after first measuring Graphene, shitosan, acetic acid, trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether, quaternary ammonium salt and water successively by the mass percent concentration of component each in infiltrate, successively that acetic acid, shitosan is soluble in water again, add Graphene again and carry out ultrasonic disperse, finally add trehalose, polyethylene glycol adipate, castor oil polyoxyethylene ether and quaternary ammonium salt to stir simultaneously, obtain infiltrate.
6. a kind of flame-retardant textile according to claim 3, is characterized in that, the concrete steps that segmentation is dried are: first at 125-135 DEG C, dry 10-20min, then dries at 60-70 DEG C.
7. a kind of flame-retardant textile according to claim 1, it is characterized in that, Particle Size of Nanometer ZnO is 100-120nm, and nano oxidized spelter coating accounts for more than 98% of cloth outer surface, and nano zinc oxide particles is coated in design on fabric surface in ultrasonic wave mode by nano oxidized spelter coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510331458.XA CN105019223B (en) | 2015-06-16 | 2015-06-16 | A kind of flame-retardant textile |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510331458.XA CN105019223B (en) | 2015-06-16 | 2015-06-16 | A kind of flame-retardant textile |
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| CN105019223A true CN105019223A (en) | 2015-11-04 |
| CN105019223B CN105019223B (en) | 2017-09-19 |
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| CN201510331458.XA Active CN105019223B (en) | 2015-06-16 | 2015-06-16 | A kind of flame-retardant textile |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107100012A (en) * | 2017-05-25 | 2017-08-29 | 浙江汉邦化工有限公司 | Multi-functional temperature sensitive discoloration curtain intellectual material |
| CN116043529A (en) * | 2022-12-30 | 2023-05-02 | 诸暨市锦晨纺织有限公司 | Flame-retardant graphene-phosphorus-containing chitosan crosslinked grafted cotton fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102443932A (en) * | 2011-10-31 | 2012-05-09 | 苏州创宇织造有限公司 | Fine-spinning woolen fabric containing PLA (polylactic acid) fiber and bamboo fiber |
| CN103485024A (en) * | 2013-09-05 | 2014-01-01 | 吴江秦邦纺织有限公司 | Multifunctional saliva towel |
| CN103966844A (en) * | 2014-05-23 | 2014-08-06 | 青岛大学 | Preparation method of graphene electroconductive composite fiber |
-
2015
- 2015-06-16 CN CN201510331458.XA patent/CN105019223B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102443932A (en) * | 2011-10-31 | 2012-05-09 | 苏州创宇织造有限公司 | Fine-spinning woolen fabric containing PLA (polylactic acid) fiber and bamboo fiber |
| CN103485024A (en) * | 2013-09-05 | 2014-01-01 | 吴江秦邦纺织有限公司 | Multifunctional saliva towel |
| CN103966844A (en) * | 2014-05-23 | 2014-08-06 | 青岛大学 | Preparation method of graphene electroconductive composite fiber |
Non-Patent Citations (1)
| Title |
|---|
| 郝新敏，杨元: "《功能纺织材料和防护服装》", 30 November 2010, 中国纺织出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107100012A (en) * | 2017-05-25 | 2017-08-29 | 浙江汉邦化工有限公司 | Multi-functional temperature sensitive discoloration curtain intellectual material |
| CN116043529A (en) * | 2022-12-30 | 2023-05-02 | 诸暨市锦晨纺织有限公司 | Flame-retardant graphene-phosphorus-containing chitosan crosslinked grafted cotton fabric and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN105019223B (en) | 2017-09-19 |
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Effective date of registration: 20180124 Address after: 6 417A room, building No. 1188, west two ring road, Shengze Town, Wujiang District, Jiangsu, Suzhou, 215228 Patentee after: Suzhou hair textile Co., Ltd. Address before: 313100, Zhejiang, Huzhou province Changxing County Town, Hong Kong Industrial Park Patentee before: CHANGXING DACHENG LIGHT TEXTILE CO., LTD. |
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