CN105018208A - High temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition - Google Patents

High temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition Download PDF

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Publication number
CN105018208A
CN105018208A CN201510427761.XA CN201510427761A CN105018208A CN 105018208 A CN105018208 A CN 105018208A CN 201510427761 A CN201510427761 A CN 201510427761A CN 105018208 A CN105018208 A CN 105018208A
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CN
China
Prior art keywords
agent
resistant
high temperature
lubricating grease
grease composition
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Pending
Application number
CN201510427761.XA
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Chinese (zh)
Inventor
黄福川
邓富康
李康春
韦开焕
马骁飞
黄旖瑶
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Guangxi University
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Guangxi University
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Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201510427761.XA priority Critical patent/CN105018208A/en
Publication of CN105018208A publication Critical patent/CN105018208A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a high temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition. The lubricating grease composition utilizes poly(alpha-alkene)-metallocene PAO (synthetic base oil) compound as base oil and a plurality of additives such as a densifier, an anti-oxidant, an antirust agent, an extreme pressure agent, an antiwear agent, a metal fatigue-resistant agent, a binder, an antioxidant antiseptic, an assistant and a strengthening agent. The high temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition has high temperature resistance, good lubrication effects, heavy load resistance, impact resistance, excellent extreme pressure property and good water resistance, is not lost, softened and deteriorated under the condition of cooling water spraying, has good pumping performances, ensures full lubrication of all lubrication parts, has good adhesiveness, prevents bearing separation in bearing operation, has good mechanical stability, is not diluted and lost under action of mechanical shearing, has good corrosion resistance and does not corrode a lubrication part.

Description

A kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition
Technical field
The invention belongs to lubricating grease field, particularly the high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition of one.
Background technology
When Nuclear power plants and nuclear power source boat run, under normal circumstances, lubricating grease, after changing the radiation exposure of doses, because grease structure is damaged in various degree, can cause grease dropping point to reduce, denseness deliquescing or sclerosis, and then putrid and deteriorated.This kind of equipment contacted with radioactivity, is required that lubricating grease has good radiation resistance.Meet that high temperature, humidity or water drench, the lubricant of the special operation condition of wear-resistant, high bearing capacity simultaneously, slideway abrasion loss is had substantial degradation.It has high temperature resistant, normally can work at-20 ~ 250 DEG C of temperature; Do not run off, noncoking, not blocking pipe, can play good lubrication; Anti-heavy loading, shock resistance, have excellent extreme pressure property; Water resisting property is good, under cool water shower condition, does not run off, not softening rotten; Pump-conveying property is good, guarantees the sufficient lubrication of each lubricant housings; Good adhesivity, when ensureing bearing operation, is not thrown out of; Good mechanical stability is not thinning, loss by mechanical shearing; Good non-corrosibility, does not corrode lubricant housings.
Summary of the invention
The technical problem to be solved in the present invention is to provide one and has high temperature resistant, can play good lubrication; Anti-heavy loading, shock resistance, have excellent extreme pressure property; Water resisting property is good, under cool water shower condition, does not run off, not softening rotten; Pump-conveying property is good, guarantees the sufficient lubrication of each lubricant housings; Good adhesivity, when ensureing bearing operation, is not thrown out of; Good mechanical stability, by not thinning during mechanical shearing, loss; Good non-corrosibility, does not corrode the high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition of lubricant housings.
The present invention adopts following technical scheme to solve the problems of the technologies described above:
A kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition, adopt the poly-alpha olefins of mass ratio 50% and the metallocene PAO synthetic base oil of 50% to be complex as base oil, coordinate multiple additives, its each component and mass percent thereof are:
Component Mass percent content
Base oil Surplus
Viscosifying agent 11%~16%
Oxidation inhibitor 0.6%~1%
Rust-preventive agent 2%~3%
Extreme pressure agent 3%~6%
Anti-wear agent 2%~3%
The tired agent of anti-metal 2.2%~3%
Adhesive agent 3%~4.5%
Antioxidant preservative 2%~3%
Auxiliary agent 0.3%~0.6%
Strengthening agent 1%~2%
Viscosifying agent is the 2,4 toluene diisocyanate of mass ratio 44% and 34% 4,4 ,-benzidine and 22% lime acetate compound.
Oxidation inhibitor is the phenyl-a-naphthylamine of mass ratio 50% and 2,2, the 4-dimethyl dihydroquinoline compounds of 50%.
Rust-preventive agent is the sebacic acid sodium of mass ratio 50% and the alkenyl succinic acid T746 compound of 50%.
Extreme pressure agent is No. 1 oildag.
Anti-wear agent is thiophosphoric acid amine salt T308.
The tired agent of anti-metal is aryl boric acid.
Adhesive agent is polyisobutene T603D.
Antioxidant preservative is dialkyldithiocarbamacompositions sulfuration oxygen molybdenum.
Auxiliary agent is Isosorbide-5-Nitrae-diaza-bicyclo octane; Strengthening agent is sulphur phosphorus fourth octyl group zinc salt T202.
Remarkable advantage of the present invention is:
Have high temperature resistant, good lubrication can be played; Anti-heavy loading, shock resistance, have excellent extreme pressure property; Water resisting property is good, under cool water shower condition, does not run off, not softening rotten; Pump-conveying property is good, guarantees the sufficient lubrication of each lubricant housings; Good adhesivity, when ensureing bearing operation, is not thrown out of; Good mechanical stability, by not thinning during mechanical shearing, loss; Good non-corrosibility, does not corrode lubricant housings.
Embodiment
Embodiment 1:
Each component is in harmonious proportion by following mass percent and forms:
Embodiment 2:
Each component is in harmonious proportion by following mass percent and forms:
Embodiment 3:
Each component is in harmonious proportion by following mass percent and forms:
The main physical and chemical index of embodiment 3 product:
Project Quality index
Drawing cone in-degree/0.1mm 295
Dropping point/DEG C 265
Ladder nurse is agree (Timken) and is tested 0K load/kg 29
Four-ball tester method sintering load P D/kgf 480
Integrated abrasion value ZMZ/kgf 78
Four-ball tester wearing and tearing (1800r/min, 20kgf, 54 DEG C, 1h)/mm 0.35
Divide oil (24h, 25 DEG C)/% 1
Wheel bearing life-span/h 330
Extend Drawing cone in-degree (100,000 times)/0.1mm 395

Claims (10)

1. a high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition, is characterized in that: adopt the poly-alpha olefins of mass ratio 50% and the metallocene PAO synthetic base oil of 50% to be complex as base oil, coordinate multiple additives, its each component and mass percent thereof are:
Base oil surplus,
Viscosifying agent 11% ~ 16%,
Oxidation inhibitor 0.6% ~ 1%,
Rust-preventive agent 2% ~ 3%,
Extreme pressure agent 3% ~ 6%,
Anti-wear agent 2% ~ 3%,
The tired agent 2.2% ~ 3% of anti-metal,
Adhesive agent 3% ~ 4.5%,
Antioxidant preservative 2% ~ 3%,
Auxiliary agent 0.3% ~ 0.6%,
Strengthening agent 1% ~ 2%.
2. high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1 a kind of, it is characterized in that, viscosifying agent is the 2,4 toluene diisocyanate of mass ratio 44% and 34% 4,4 '-benzidine and 22% lime acetate compound.
3. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, oxidation inhibitor is the phenyl-a-naphthylamine of mass ratio 50% and 2,2, the 4-dimethyl dihydroquinoline compounds of 50%.
4. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, rust-preventive agent is the sebacic acid sodium of mass ratio 50% and the alkenyl succinic acid T746 compound of 50%.
5. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, extreme pressure agent is No. 1 oildag.
6. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, anti-wear agent is thiophosphoric acid amine salt T308.
7. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, is characterized in that, the tired agent of anti-metal is aryl boric acid.
8. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, adhesive agent is polyisobutene T603D.
9. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, antioxidant preservative is dialkyldithiocarbamacompositions sulfuration oxygen molybdenum.
10. a kind of high temperature resistant resistance to trickle radiation hardness antiwear lubricating grease composition as claimed in claim 1, it is characterized in that, auxiliary agent is Isosorbide-5-Nitrae-diaza-bicyclo octane; Strengthening agent is sulphur phosphorus fourth octyl group zinc salt T202.
CN201510427761.XA 2015-07-20 2015-07-20 High temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition Pending CN105018208A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510427761.XA CN105018208A (en) 2015-07-20 2015-07-20 High temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510427761.XA CN105018208A (en) 2015-07-20 2015-07-20 High temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition

Publications (1)

Publication Number Publication Date
CN105018208A true CN105018208A (en) 2015-11-04

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CN201510427761.XA Pending CN105018208A (en) 2015-07-20 2015-07-20 High temperature-resistant water spraying-resistant radiation-resistant wear-resistant lubricating grease composition

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CN (1) CN105018208A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116515545A (en) * 2023-04-27 2023-08-01 亚培烯科技(上海)有限公司 Lubricating grease and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101855329A (en) * 2007-09-27 2010-10-06 雪佛龙美国公司 Grease composition and preparation
CN103710108A (en) * 2013-12-18 2014-04-09 广西大学 Lubricant for drawing and extruding brass blank
CN103937585A (en) * 2014-04-15 2014-07-23 淄博鲁特润滑油有限公司 Fully synthetic ester-based gasoline-injection engine lubricating oil and preparation process thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101855329A (en) * 2007-09-27 2010-10-06 雪佛龙美国公司 Grease composition and preparation
CN103710108A (en) * 2013-12-18 2014-04-09 广西大学 Lubricant for drawing and extruding brass blank
CN103937585A (en) * 2014-04-15 2014-07-23 淄博鲁特润滑油有限公司 Fully synthetic ester-based gasoline-injection engine lubricating oil and preparation process thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116515545A (en) * 2023-04-27 2023-08-01 亚培烯科技(上海)有限公司 Lubricating grease and preparation method and application thereof
CN116515545B (en) * 2023-04-27 2024-01-30 亚培烯科技(上海)有限公司 Lubricating grease and preparation method and application thereof

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Application publication date: 20151104

RJ01 Rejection of invention patent application after publication