CN105017992A - Adhesive for moisture-proof corrugated board, and preparation method thereof - Google Patents
Adhesive for moisture-proof corrugated board, and preparation method thereof Download PDFInfo
- Publication number
- CN105017992A CN105017992A CN201510361906.0A CN201510361906A CN105017992A CN 105017992 A CN105017992 A CN 105017992A CN 201510361906 A CN201510361906 A CN 201510361906A CN 105017992 A CN105017992 A CN 105017992A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive
- water
- sizing agent
- tannin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses an adhesive for a moisture-proof corrugated board. The adhesive comprises cassava starch, sodium aliphatate, oxalic acid, tributyl phosphate, sodium hydroxide, sodium trimetaphosphate, melamine-formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulfate, polyvinyl alcohol and water. The adhesive has high initial adhesion force, good moisture-proof ability, good stability, fast drying speed and short adhesion time, and realizes adhesion in 5min, and a preparation method of the adhesive is simple. The corrugated board formed through bonding by the adhesive has good waterproof and moisture-proof effects, is completely penetrated in 45min, has good quality, and can well protect packaged articles.
Description
Technical field
The present invention relates to a kind of corrugated cardboard sizing agent and preparation method thereof, particularly a kind of moistureproof corrugated paper sizing agent and preparation method thereof.
Background technology
Corrugated cardboard started from for 18 end of the centurys, and 19 beginnings of the century are because its amount is light and low price, of many uses, make simple and easy, and can reclaim and even reuse, its application is had significant growth.To 20 beginnings of the century, obtain and packed and comprehensively universal, promotion and application into various commodity make.The packaging vessel made owing to using corrugated cardboard is to beautifying and protecting in-built commodity to have performance and the advantage of its uniqueness; therefore; with the competition of various packaging materials in obtain great success, become long with not waning and presenting one of main raw of the making packaging vessel of fast development up to now.
Fluting board is the plate object be bonded through sizing agent by the fluting board of sheet lining and waveform, in use may be drenched by rainwater, seawater, affects it and uses.But existing fluting board sizing agent exists that initial adhesive force is low, moisture protection is poor and the problem such as the poor stability of glue own, with the fluting board that it is bonded, do not possess waterproof, moistureproof effect, generally all permeated in 5 minutes, preferably maximum just all infiltrations in 15 minutes.Can not good protective package product, quality product can not be guaranteed.In addition during existing sizing agent bonding, rate of drying is slow, and the bonding time is long, and generally at least need ability bonding in 10 minutes, preparation technology is more complicated also.
Summary of the invention
Object of the present invention, is to provide a kind of moistureproof corrugated paper sizing agent and preparation method thereof.Described sizing agent initial adhesive force is high, and moisture protection is good, good stability, and rate of drying is fast, and the bonding time is short, and general needs within 5 minutes, just can bond, and preparation technology is simple.The corrugated paper board waterproof be bonded with this sizing agent, moistureproof effective, the four layers of combined corrugated board be bonded into could all infiltrations in 45 minutes, and quality is good, can good protective package product.
The present invention realizes like this.A kind of moistureproof corrugated paper sizing agent, calculate by weight, comprise tapioca (flour) 100-150 part, sodium soap 0.8-2 part, oxalic acid 1-7 part, tributyl phosphate 0.1-2 part, sodium hydroxide 5-25 part, Trisodium trimetaphosphate 0.2-1.8 part, melamine formaldehyde resin 1-5 part, light calcium carbonate 1-15 part, bentonite 5-20 part, borax 2-7 part, tannin 55-70 part, ammonium persulphate 1-1.5 part, polyvinyl alcohol 0.5-1.5 part and water 300-450 part.
Aforesaid moistureproof corrugated paper sizing agent, calculate by weight, comprise tapioca (flour) 120-130 part, sodium soap 1-1.5 part, oxalic acid 2.5-3 part, tributyl phosphate 0.6-1.0 part, sodium hydroxide 13-15 part, Trisodium trimetaphosphate 0.9-1.2 part, melamine formaldehyde resin 2-2.5 part, light calcium carbonate 5-8 part, bentonite 10-15 part, borax 3-5 part, tannin 60-65 part, ammonium persulphate 1.2-1.3 part, polyvinyl alcohol 0.8-1.2 part and water 360-380 part.
Aforesaid moistureproof corrugated paper sizing agent, calculate by weight, comprise tapioca (flour) 115 parts, sodium soap 1.2 parts, oxalic acid 2.8 parts, tributyl phosphate 0.8 part, 14 parts, sodium hydroxide, Trisodium trimetaphosphate 1.1 parts, melamine formaldehyde resin 2.3 parts, light calcium carbonate 6.5 parts, bentonite 12 parts, borax 4 parts, tannin 62 parts, ammonium persulphate 1.2 parts, polyvinyl alcohol 1.0 parts and 370 parts, water.
The preparation method of aforesaid moistureproof corrugated paper sizing agent, tapioca (flour) is got by formula, add the water of formula ratio 10%, stir, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, to obtain final product.
Applicant gets the sizing agent (being prepared by embodiment 1) that the present invention obtains respectively, commercially available sizing agent 1(Shanghai Ke Wang tackiness agent company limited produces) and the production of commercially available sizing agent 2(Taizhou City great virtue novel material Science and Technology Ltd.).Be sticked with into four layers of combined corrugated board 20 pieces respectively, then to paperboard surface water spray, paperboard surface water content is 2mL/cm
2, the time that recording paper sheet permeates completely, often group record results averaged.The results are shown in Table 1:
As seen from table, the fluting board glued with sizing agent of the present invention, could all permeate in 80 minutes, and waterproof is effective with protection against the tide.
Applicant still tests other performances of sizing agent of the present invention, namely get the sizing agent (being prepared by embodiment 2) that the present invention obtains respectively, commercially available sizing agent 1(Shanghai Ke Wang tackiness agent company limited produce) and commercially available sizing agent 2(Taizhou City great virtue novel material Science and Technology Ltd. produce), be used for bonding fluting board sheet material respectively and make four layers of combined corrugated board 20 pieces.Record its viscosity, just sticky time and bond strength respectively, test result is averaged, and the results are shown in Table 2.
As seen from table, the viscosity of sizing agent of the present invention is higher, and just the sticky time is shorter with the complete sticky time, and bond strength is high.
Compared with the prior art, the present invention by adding the chemical added ingredients such as tributyl phosphate, Trisodium trimetaphosphate in tapioca (flour), each component has good synergy, make the sizing agent initial adhesive force of preparation high, moisture protection is good, good stability, rate of drying is fast, the bonding time is short, only need within 5 minutes, just can bond, and preparation technology is simple.The corrugated paper board waterproof be bonded with this sizing agent, moistureproof effective, at least could all infiltrations in 45 minutes, quality is good, can good protective package product.
Embodiment
Embodiment 1.
Formula: tapioca (flour) 115g, sodium soap 1.2g, oxalic acid 2.8g, tributyl phosphate 0.8g, sodium hydroxide 14g, Trisodium trimetaphosphate 1.1g, melamine formaldehyde resin 2.3g, light calcium carbonate 6.5g, bentonite 12g, borax 4g, tannin 62g, ammonium persulphate 1.2g, polyvinyl alcohol 1.0g and water 370g.
Preparation technology: get tapioca (flour) by formula, add the water of formula ratio 10%, stir, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, obtains sizing agent.
Embodiment 2.
Formula: comprise tapioca (flour) 130g, sodium soap 1.5g, oxalic acid 3g, tributyl phosphate 1.0g, sodium hydroxide 15g, Trisodium trimetaphosphate 1.2g, melamine formaldehyde resin 2.5g, light calcium carbonate 8g, bentonite 15g, borax 5g, tannin 65g, ammonium persulphate 1.3g, polyvinyl alcohol 1.2g and water 380g.
Preparation technology: get tapioca (flour) by formula, add the water of formula ratio 10%, stir, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, obtains sizing agent.
Embodiment 3.
Formula: comprise tapioca (flour) 120g, sodium soap 1g, oxalic acid 2.5g, tributyl phosphate 0.6g, sodium hydroxide 13g, Trisodium trimetaphosphate 0.9g, melamine formaldehyde resin 2g, light calcium carbonate 5g, bentonite 10g, borax 3g, tannin 60g, ammonium persulphate 1.2g, polyvinyl alcohol 0.8g and and water 360g.
Preparation technology: get tapioca (flour) by formula, add the water of formula ratio 10%, stir, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, obtains sizing agent.
Embodiment 4.
Formula: tapioca (flour) 100g, sodium soap 0.8g, oxalic acid 1g, tributyl phosphate 0.1g, sodium hydroxide 5g, Trisodium trimetaphosphate 0.2g, melamine formaldehyde resin 1g, light calcium carbonate 1g, bentonite 5g, borax 2g, tannin 55g, ammonium persulphate 1g, polyvinyl alcohol 0.5g and water 300g.
Preparation technology: get tapioca (flour) by formula, add the water of formula ratio 10%, stir, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, obtains sizing agent.
Embodiment 5.
Formula: tapioca (flour) 150g, sodium soap 2g, oxalic acid 7g, tributyl phosphate 2g, sodium hydroxide 25g, Trisodium trimetaphosphate 1.8g, melamine formaldehyde resin 5g, light calcium carbonate 15g, bentonite 20g, borax 7g, tannin 70g, ammonium persulphate 1.5g, polyvinyl alcohol 1.5g and water 450g.
Preparation technology: get tapioca (flour) by formula, add the water of formula ratio 10%, stir, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, obtains sizing agent.
Claims (4)
1. a moistureproof corrugated paper sizing agent, it is characterized in that: calculate by weight, comprise tapioca (flour) 100-150 part, sodium soap 0.8-2 part, oxalic acid 1-7 part, tributyl phosphate 0.1-2 part, sodium hydroxide 5-25 part, Trisodium trimetaphosphate 0.2-1.8 part, melamine formaldehyde resin 1-5 part, light calcium carbonate 1-15 part, bentonite 5-20 part, borax 2-7 part, tannin 55-70 part, ammonium persulphate 1-1.5 part, polyvinyl alcohol 0.5-1.5 part and water 300-450 part.
2. moistureproof corrugated paper sizing agent according to claim 1, it is characterized in that: calculate by weight, comprise tapioca (flour) 120-130 part, sodium soap 1-1.5 part, oxalic acid 2.5-3 part, tributyl phosphate 0.6-1.0 part, sodium hydroxide 13-15 part, Trisodium trimetaphosphate 0.9-1.2 part, melamine formaldehyde resin 2-2.5 part, light calcium carbonate 5-8 part, bentonite 10-15 part, borax 3-5 part, tannin 60-65 part, ammonium persulphate 1.2-1.3 part, polyvinyl alcohol 0.8-1.2 part and water 360-380 part.
3. moistureproof corrugated paper sizing agent as claimed in claim 2, it is characterized in that: calculate by weight, comprise tapioca (flour) 115 parts, sodium soap 1.2 parts, oxalic acid 2.8 parts, tributyl phosphate 0.8 part, 14 parts, sodium hydroxide, Trisodium trimetaphosphate 1.1 parts, melamine formaldehyde resin 2.3 parts, light calcium carbonate 6.5 parts, bentonite 12 parts, borax 4 parts, tannin 62 parts, ammonium persulphate 1.2 parts, polyvinyl alcohol 1.0 parts and 370 parts, water.
4. the preparation method of the moistureproof corrugated paper sizing agent according to any one of claim 1-3, it is characterized in that: get tapioca (flour) by formula, add the water of formula ratio 10%, after stirring, add the water of sodium soap, oxalic acid, tributyl phosphate, sodium hydroxide, Trisodium trimetaphosphate, melamine formaldehyde resin, light calcium carbonate, bentonite, borax, tannin, ammonium persulphate, polyvinyl alcohol and residual content more successively, mixing, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510361906.0A CN105017992A (en) | 2015-06-26 | 2015-06-26 | Adhesive for moisture-proof corrugated board, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510361906.0A CN105017992A (en) | 2015-06-26 | 2015-06-26 | Adhesive for moisture-proof corrugated board, and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105017992A true CN105017992A (en) | 2015-11-04 |
Family
ID=54408306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510361906.0A Pending CN105017992A (en) | 2015-06-26 | 2015-06-26 | Adhesive for moisture-proof corrugated board, and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105017992A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349968A (en) * | 2016-06-17 | 2017-01-25 | 临泉县亚泰包装有限公司 | Moisture-proof carton |
| CN112277392A (en) * | 2020-10-26 | 2021-01-29 | 无锡市辰华包装有限公司 | Preparation method of antibacterial anti-static corrugated board |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709958A (en) * | 2013-12-16 | 2014-04-09 | 中山火炬职业技术学院 | Low-temperature boron-free paper starch adhesive and preparation method thereof |
| CN104369513A (en) * | 2014-11-05 | 2015-02-25 | 南通传人印务包装有限公司 | Impermeable four-layer composite corrugated board |
| CN104479585A (en) * | 2014-12-23 | 2015-04-01 | 安徽助成信息科技有限公司 | Quick-drying and water-resistant type starch adhesive |
-
2015
- 2015-06-26 CN CN201510361906.0A patent/CN105017992A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709958A (en) * | 2013-12-16 | 2014-04-09 | 中山火炬职业技术学院 | Low-temperature boron-free paper starch adhesive and preparation method thereof |
| CN104369513A (en) * | 2014-11-05 | 2015-02-25 | 南通传人印务包装有限公司 | Impermeable four-layer composite corrugated board |
| CN104479585A (en) * | 2014-12-23 | 2015-04-01 | 安徽助成信息科技有限公司 | Quick-drying and water-resistant type starch adhesive |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349968A (en) * | 2016-06-17 | 2017-01-25 | 临泉县亚泰包装有限公司 | Moisture-proof carton |
| CN112277392A (en) * | 2020-10-26 | 2021-01-29 | 无锡市辰华包装有限公司 | Preparation method of antibacterial anti-static corrugated board |
| CN112277392B (en) * | 2020-10-26 | 2022-05-10 | 无锡市辰华包装有限公司 | Preparation method of antibacterial anti-static corrugated board |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4377649A (en) | Wax compositions | |
| CN104845550A (en) | Adhesion agent, preparation method thereof and corrugated board | |
| CA2656822C (en) | Adhesive system and method of producing a wood based product | |
| CN105602472A (en) | Damp-proofing displacement-proofing corrugated carton | |
| CN105017992A (en) | Adhesive for moisture-proof corrugated board, and preparation method thereof | |
| CN103360987A (en) | Adhesive for packaging paper material and preparation method thereof | |
| JP5049079B2 (en) | Starch-based water-resistant adhesive for corrugated board containing no formaldehyde | |
| CN108424723A (en) | A kind of corrugated case adhesive | |
| CN102994030A (en) | Application of starch adhesive and preparation method of urea-formaldehyde resin adhesive | |
| US2193630A (en) | Hardener for formaldehyde-urea adhesives | |
| JPS5964683A (en) | Resinous adhesive for particle board | |
| CN104789152B (en) | Cyanurotriamide modified urea resin filler and preparation method thereof | |
| CN103360992A (en) | Packaging paper adhesive and preparation method thereof | |
| CN107160530A (en) | High strength fiberboard and preparation method thereof | |
| US4307206A (en) | Urea-formaldehyde resin adhesive | |
| US2380239A (en) | Adhesives | |
| CN103649144A (en) | Adhesive system | |
| CN108864986A (en) | Starch phosphate adhesive | |
| CN104263280A (en) | Adhesive for binding paper products and preparation method thereof | |
| CN102828412A (en) | Adhesive for textiles | |
| CN101979452B (en) | Method for preparing waterproof adhesive for corrugated paper production | |
| KR20180117930A (en) | Adhesive composition from natural materials for water proof plywood and its preparation method | |
| CN107139540B (en) | A kind of production technology of corrugated board | |
| JPS59187071A (en) | Adhesive for lateral bonding of raw wood veneer | |
| FI116678B (en) | Phenolic resole veneer resin, process and manufacture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151104 |
|
| RJ01 | Rejection of invention patent application after publication |