CN103360987A - Adhesive for packaging paper material and preparation method thereof - Google Patents

Adhesive for packaging paper material and preparation method thereof Download PDF

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Publication number
CN103360987A
CN103360987A CN2013102808808A CN201310280880A CN103360987A CN 103360987 A CN103360987 A CN 103360987A CN 2013102808808 A CN2013102808808 A CN 2013102808808A CN 201310280880 A CN201310280880 A CN 201310280880A CN 103360987 A CN103360987 A CN 103360987A
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China
Prior art keywords
parts
adhesive
water
paper material
minute
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Granted
Application number
CN2013102808808A
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Chinese (zh)
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CN103360987B (en
Inventor
毕全中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Ling Bridge Industry and Trade Co., Ltd.
Original Assignee
Quanjiao Haifeng Printing Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Quanjiao Haifeng Printing Packaging Co Ltd filed Critical Quanjiao Haifeng Printing Packaging Co Ltd
Priority to CN201310280880.8A priority Critical patent/CN103360987B/en
Publication of CN103360987A publication Critical patent/CN103360987A/en
Application granted granted Critical
Publication of CN103360987B publication Critical patent/CN103360987B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention relates to an adhesive for a packaging paper material. The adhesive is characterized by being prepared from the following raw materials in parts by weight: 8-10 parts of polyvinyl alcohol, 3-4 parts of acrylonitrile, 6-8 parts of starch, 2-3 parts of silane coupling agent KH550, 1-2 parts of acrylamide, 3-4 parts of borax, 3-4 parts of hydroxyethyl cellulose, 1-2 parts of water-soluble melamine formaldehyde resin, 1-2 parts of morpholine, 9-11 parts of ethylene-vinyl acetate copolymer emulsion, 2-3 parts of sodium hydroxide and 120-125 parts of water. The adhesive for the packaging paper material has the advantages that the adhesive property is excellent, the mechanical strength is good after the adhesive is applied to paper packaging boxes, and the adhesive property is still good after the adhesive is subjected to a destructive test.

Description

Tackiness agent that a kind of wrapping paper material is used and preparation method thereof
Technical field
The present invention relates to a kind of chemical materials, more specifically relate to a kind of tackiness agent.
Background technology
At present, be used for cardboard box glue stick kind a lot, three-aldehyde glue and white glue with vinyl etc. are arranged.Some tackiness agent can discharge free state formaldehyde in production and application process, serious to human body and environmental hazard; Some tackiness agent, water tolerance and wet fastness are poor, easily moisture absorption in damp atmosphere, bonding strength is not high; At high temperature use to produce creep, Joint strength is descended, storing easy freezing below-5 ℃, emulsion is damaged, therefore cause its application greatly limited.The bonding strength that needs research to make new advances is high, the tackiness agent of safety and environmental protection, good stability.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, tackiness agent that a kind of wrapping paper material uses and preparation method thereof is provided.
Technical scheme of the present invention is as follows:
The tackiness agent that a kind of wrapping paper material is used is characterized in that being made by the raw material of following weight part: polyvinyl alcohol 8-10, vinyl cyanide 3-4, starch 6-8, Silane coupling agent KH550 2-3, acrylamide 1-2, borax 3-4, Natvosol 3-4, water-soluble terpolycyantoamino-formaldehyde resin 1-2, morpholine 1-2, ethylene-vinyl acetate copolymer emulsion 9-11, sodium hydroxide 2-3, water 120-125.
The preparation method of the tackiness agent that described wrapping paper material is used, it is characterized in that may further comprise the steps: (1), will starch, sodium hydroxide adds in the part water and dissolves, be heated to 90-100 ℃, stirred 10-15 minute, adding vinyl cyanide, acrylamide, borax, Natvosol stirred 60-90 minute;
(2), polyvinyl alcohol is added in the residue water, be heated to 90-100 ℃, add Silane coupling agent KH550, morpholine, water-soluble terpolycyantoamino-formaldehyde resin, stirred 30-45 minute;
(3), step (1), (2) material and other remaining component are mixed, be heated to 80-90 ℃, stirring reaction 2-3 hour, and get final product.
The tackiness agent that wrapping paper material provided by the invention is used has excellent adhesive property, and for behind the packing case, physical strength is good, after destructive test, still has good adhesive property.
 
Embodiment
The tackiness agent that a kind of wrapping paper material is used is made by the raw material of following weight part (kilogram): polyvinyl alcohol 8, vinyl cyanide 3, starch 6, Silane coupling agent KH550 3, acrylamide 1, borax 4, Natvosol 3, water-soluble terpolycyantoamino-formaldehyde resin 2, morpholine 1, ethylene-vinyl acetate copolymer emulsion 9, sodium hydroxide 2, water 120.
The preparation method of the tackiness agent that the wrapping paper material is used may further comprise the steps:
(1), starch, sodium hydroxide added in the part water dissolves, be heated to 90-100 ℃, stirred 10-15 minute, added vinyl cyanide, acrylamide, borax, Natvosol stirring 60-90 minute;
(2), polyvinyl alcohol is added in the residue water, be heated to 90-100 ℃, add Silane coupling agent KH550, morpholine, water-soluble terpolycyantoamino-formaldehyde resin, stirred 30-45 minute;
(3), with step (1)
The tackiness agent of the present invention's preparation, through detecting: after 4 hours, bonding strength reaches 12Mpa, water-tolerant.

Claims (2)

1. the tackiness agent that the wrapping paper material is used is characterized in that being made by the raw material of following weight part: polyvinyl alcohol 8-10, vinyl cyanide 3-4, starch 6-8, Silane coupling agent KH550 2-3, acrylamide 1-2, borax 3-4, Natvosol 3-4, water-soluble terpolycyantoamino-formaldehyde resin 1-2, morpholine 1-2, ethylene-vinyl acetate copolymer emulsion 9-11, sodium hydroxide 2-3, water 120-125.
2. the preparation method of the tackiness agent used of wrapping paper material according to claim 1, it is characterized in that may further comprise the steps: (1), will starch, sodium hydroxide adds in the part water and dissolves, be heated to 90-100 ℃, stirred 10-15 minute, adding vinyl cyanide, acrylamide, borax, Natvosol stirred 60-90 minute;
(2), polyvinyl alcohol is added in the residue water, be heated to 90-100 ℃, add Silane coupling agent KH550, morpholine, water-soluble terpolycyantoamino-formaldehyde resin, stirred 30-45 minute;
(3), step (1), (2) material and other remaining component are mixed, be heated to 80-90 ℃, stirring reaction 2-3 hour, and get final product.
CN201310280880.8A 2013-07-05 2013-07-05 Tackiness agent of a kind of wrapping paper material and preparation method thereof Expired - Fee Related CN103360987B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310280880.8A CN103360987B (en) 2013-07-05 2013-07-05 Tackiness agent of a kind of wrapping paper material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310280880.8A CN103360987B (en) 2013-07-05 2013-07-05 Tackiness agent of a kind of wrapping paper material and preparation method thereof

Publications (2)

Publication Number Publication Date
CN103360987A true CN103360987A (en) 2013-10-23
CN103360987B CN103360987B (en) 2016-03-30

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952095A (en) * 2014-03-24 2014-07-30 铜陵市松马食品包装机械制造有限责任公司 High temperature-resistant heat-sealing glue for medicinal aluminum foil package and preparation method thereof
CN104804654A (en) * 2015-04-22 2015-07-29 句容市鼎盛纸箱包装有限公司 High-strength paper packaging adhesive formula
CN104818649A (en) * 2015-03-31 2015-08-05 苏州市鼎立包装有限公司 Composite packaging material and preparation method thereof
CN104845552A (en) * 2015-05-28 2015-08-19 句容市茂源织造厂 Adhesive for soft packaging for food and preparation method of adhesive
CN104845582A (en) * 2015-05-28 2015-08-19 句容市茂源织造厂 Adhesive for plastic flexible packaging and preparation method thereof
CN105176457A (en) * 2015-07-29 2015-12-23 湖南工业大学 Environmentally-friendly aqueous binder
CN107936877A (en) * 2017-12-06 2018-04-20 常德金德新材料科技股份有限公司 One kind packaging glue and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050014908A1 (en) * 2001-09-05 2005-01-20 Takaaki Kutsuna Adhesive for gas barrier laminates and laminated films
CN102585736A (en) * 2012-01-12 2012-07-18 浙江顶立胶业有限公司 Hot-pressing veneer adhesive and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050014908A1 (en) * 2001-09-05 2005-01-20 Takaaki Kutsuna Adhesive for gas barrier laminates and laminated films
CN102585736A (en) * 2012-01-12 2012-07-18 浙江顶立胶业有限公司 Hot-pressing veneer adhesive and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘家聚: "解析软包装复合胶的配方、生产和技术要求", 《湖南包装》, 31 December 2006 (2006-12-31) *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952095A (en) * 2014-03-24 2014-07-30 铜陵市松马食品包装机械制造有限责任公司 High temperature-resistant heat-sealing glue for medicinal aluminum foil package and preparation method thereof
CN103952095B (en) * 2014-03-24 2016-02-03 铜陵市松马食品包装机械制造有限责任公司 A kind of high temperature heat-resistant sealing and preparation method thereof being applied to medicinal aluminum foil packaging
CN104818649A (en) * 2015-03-31 2015-08-05 苏州市鼎立包装有限公司 Composite packaging material and preparation method thereof
CN104804654A (en) * 2015-04-22 2015-07-29 句容市鼎盛纸箱包装有限公司 High-strength paper packaging adhesive formula
CN104845552A (en) * 2015-05-28 2015-08-19 句容市茂源织造厂 Adhesive for soft packaging for food and preparation method of adhesive
CN104845582A (en) * 2015-05-28 2015-08-19 句容市茂源织造厂 Adhesive for plastic flexible packaging and preparation method thereof
CN105176457A (en) * 2015-07-29 2015-12-23 湖南工业大学 Environmentally-friendly aqueous binder
CN107936877A (en) * 2017-12-06 2018-04-20 常德金德新材料科技股份有限公司 One kind packaging glue and preparation method thereof

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Publication number Publication date
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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Feng Qianyu

Inventor before: Bi Quanzhong

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170721

Address after: 529700 Guangdong city of Jiangmen province Heshan City, the ancient town of labor three industrial zone

Patentee after: Guangdong Ling Bridge Industry and Trade Co., Ltd.

Address before: 239500 Anhui city of Chuzhou province Quanjiao County town of six liquor farmers Park

Patentee before: Quanjiao Haifeng Printing Packaging Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160330

Termination date: 20180705