CN105014994A - Continuous fiber reinforced thermoplastic resin composite material melting soaking device - Google Patents

Continuous fiber reinforced thermoplastic resin composite material melting soaking device Download PDF

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Publication number
CN105014994A
CN105014994A CN201410165115.6A CN201410165115A CN105014994A CN 105014994 A CN105014994 A CN 105014994A CN 201410165115 A CN201410165115 A CN 201410165115A CN 105014994 A CN105014994 A CN 105014994A
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China
Prior art keywords
noncontact
composite material
continuous fiber
fiber reinforced
thermoplastic resin
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Pending
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CN201410165115.6A
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Chinese (zh)
Inventor
苑会林
孙立坤
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Beijing University of Chemical Technology
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Beijing University of Chemical Technology
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Priority to CN201410165115.6A priority Critical patent/CN105014994A/en
Publication of CN105014994A publication Critical patent/CN105014994A/en
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Abstract

The invention discloses a continuous fiber reinforced thermoplastic resin composite material melting soaking device which comprises a tooth-shaped structure (4), a group of non-contact soaking rollers (5), contact tension rollers (6), and a group of non-contact rollers (7). A melting soaking method comprises the following steps: (1) continuous fiber bundles enter from a fiber inlet (3) and are subjected to pre-dispersing by the tooth-shaped structure (4); and (2) the pre-dispersed continuous fiber bundles penetrate through the group of non-contact soaking rollers (5), then bypass the contact tension rollers (6) in an alternated manner and finally penetrate through the group of non-contact rollers (7), simultaneously a thermoplastic polymer melt is extruded into a melting soaking mold (1) by an extruder connection device connector (2), so that the continuous fiber bundles and the thermoplastic polymer melt can be subjected to melting soaking to obtain a mixed material, and the mixed material is subjected to pulling and cooling to obtain a continuous fiber reinforced thermoplastic resin composite material. The continuous fiber reinforced thermoplastic resin composite material prepared by adopting the device disclosed by the invention is good in soaking effect and excellent in performance.

Description

A kind of continuous fiber reinforced thermoplastic resin composite material melt impregnation device
One, technical field
The present invention relates to continuous fiber reinforced thermoplastic resin composite material, particularly relate to a kind of continuous fiber reinforced thermoplastic resin composite material melt impregnation preparation method.
Two, background technology
Continuous fiber reinforced thermoplastic resin composite material adopts a kind of special immersion system, continuous fiber fully contact, abundant dipping and a kind of one-way fiber of obtaining is arranged and the enhanced type composite material that its length is equal with resin particle length wherein with the thermoplastic resin of molten condition.Thermoplastic resin is uniformly distributed between the fibers, plays the effect of anchoring fiber, transmitted load.It is compared with short fiber reinforced thermoplastic resin, there is intensity high, shock resistance is good, and the exsertile feature of dimensionally stable, heat resistance, is thus widely used in fields such as automobile, space flight, electronic apparatus, plant equipment, weapon industry, construction equipment, furniture and exercises.
, some prepare the immersion system of continuous fiber reinforced thermoplastic resin composite material, such as: be in the Chinese invention patent of CN1037679 and CN101152767A at publication number, the impregnating unit of the melt impregnation device mentioned is generally less, usually single " crest ", " trough " formula curved channel or simple jockey pulley composition is only had, due to the fault of construction of immersion system, continuous tow poor dispersion, damage is large, is difficult to obtain desirable dipping effect.
Three, summary of the invention
The object of this invention is to provide a kind of continuous fiber reinforced thermoplastic resin composite material melt impregnation device.
Continuous fiber reinforced thermoplastic resin composite material melt impregnation device provided by the invention, comprises dentalation (4), noncontact dip roll (5), contact jockey pulley (6) and noncontact roller (7).
In wherein said dentalation (4), two tooth peak level intervals are 20-50mm, and tooth peak is 8-20mm to the vertical interval of tooth paddy; Described noncontact dip roll (5), diameter is 4-10mm, and upper and lower noncontact dip roll intermediate gaps width is 0.5-2mm; Described contact jockey pulley (6), diameter is 4-10mm, and the distance between adjacent two roller horizontal directions is 10-25mm; Described noncontact roller (7), diameter is 4-10mm, and upper and lower noncontact roller intermediate gaps width is 0.5-2mm, and noncontact dip roll (5) is 45-90mm with the level interval of noncontact roller (7).
Provided by the inventionly utilize above-mentioned continuous fiber reinforced thermoplastic resin composite material melt impregnation device to prepare the method for continuous fiber reinforced thermoplastic resin composite material, comprise the steps:
1) continuous tow is entered by fiber entry (3), walk around described dentalation (4), continuous tow is obtained pre-dispersed;
2) by step 1) continuous tow that disperseed is through noncontact dip roll (5) described in a group, again through alternately walking around described contact jockey pulley (6), eventually pass through described noncontact roller (7), simultaneously, melt of thermoplastic polymers is clamp-oned described melt impregnation mould (1) by extruder jockey interface (2), make continuous tow and melt of thermoplastic polymers carry out melt impregnation, obtain continuous fiber reinforced thermoplastic composite material finally by traction cooling.
The step 1 of said method) in, described continuous tow is selected from least one of glass fibre and carbon fiber; Described step 2) in, described thermoplastic polymer is selected from least one in polypropylene, nylon 6, nylon66 fiber, polyformaldehyde.
The present invention adopts dentalation and noncontact dip roll, contact the melt impregnation mould structure that jockey pulley combines, make fibre bundle through repeatedly disperseing and flooding, dentalation provides the first dispersion of fibre bundle, and contact jockey pulley provides twice dispersing, the use of noncontact dip roll, make the two-sided pressurized of fibre bundle dipping process, narrow gap runner, makes melt under Strong shear effect, and viscosity reduces, well permeate combination with processbearing astrocyte, substantially increase the degree of impregnation of fiber.
Compared with prior art, the present invention has the following advantages:
(1) the invention provides melt impregnation device impregnating unit many, provide better dipping and dispersion effect;
(2) traditional melt impregnation mould is generally single " crest ", " trough " formula curved channel or jockey pulley composition.Fibre bundle is when by these curved channels or jockey pulley, and due to one-sided pressurized, fibre bundle can only obtain one-sided dipping, and dipping effect is poor.And except dentalation also contains noncontact dip roll except contacting jockey pulley in melt impregnation mould of the present invention, fibre bundle by dentalation be one-sided dipping when contacting jockey pulley, by being two-sided pressurized when noncontact dip roll and noncontact roller, both sides obtain dipping simultaneously, and thermoplastic polymer resin is when flowing through the narrowed flow path of noncontact dip roll, be subject to Strong shear effect, melt viscosity reduces, and fiber impregnation degree obtains and improves.
Four, accompanying drawing explanation
Fig. 1 is the main pseudosection of continuous fiber reinforced thermoplastic resin composite material melt impregnation device of the present invention;
Fig. 2 is the present invention's contact jockey pulley used vertical cross-section schematic diagram.
Wherein, 1 is melt impregnation mould; 2 is extruder jockey interface; 3 is fiber entry; 4 is dentalation; 5 is noncontact dip roll; 6 is contact jockey pulley; 7 is noncontact roller.
Five, concrete embodiment
Described method is conventional method if no special instructions.Described material all can obtain from open approach if no special instructions.
As shown in Figure 1 and Figure 2, a kind of melt impregnation device preparing continuous fiber reinforced thermoplastic resin composite material, comprises melt impregnation mould (1); Extruder jockey interface (2); Fiber entry (3), bottom is communicated with extruder jockey interface (2); Dentalation (4); Noncontact dip roll (5), 2 symmetrical roller compositions; Contact jockey pulley (6), 3 horizontal roller compositions; Noncontact roller (7), 2 symmetrical roller compositions; A branch of continuous fiber is incorporated in melt impregnation mould (1) by fiber entry (2); This bundle continuous fiber walks around dentalation (4); By the space of noncontact dip roll (5); Involve after alternately walking around 3 contacts jockey pulley (6); Polymer melt enters melt impregnation mould (1) by extruder jockey interface (2); One-sided dipping is there is by the curved channel of dentalation (4) and fiber; Then, polymer melt flows through noncontact dip roll (5), because melt is subject to the stop of roller, produce backflow and eddy flow, the intensive shear effect of minimum roll gap generation in addition, makes melt viscosity decline, and from both sides press-in fibrous inside, make fibre bundle obtain double-steeping; Then, melt flows through the one-sided dipping that contact jockey pulley (6) creates again fiber, adds degree of impregnation; Afterwards, melt flows through the final dipping that noncontact roller (7) completes fiber; Finally by the pellet of continuous fiber reinforced thermoplastic resin composite material cooling, draw, be cut into certain length.

Claims (6)

1. a continuous fiber reinforced thermoplastic resin composite material melt impregnation device, comprises dentalation (4), noncontact dip roll (5), contact jockey pulley (6) and noncontact roller (7).
2. melt impregnation device according to claim 1, is characterized in that: described continuous fiber reinforced thermoplastic resin composite material melt impregnation device is made up of described dentalation (4), described noncontact dip roll (5), described contact jockey pulley (6) and described noncontact roller (7).
3. melt impregnation device according to claim 1 and 2, is characterized in that: in described dentalation (4), and two tooth peak level intervals are 20-50mm, and tooth peak is 8-20mm to the vertical interval of tooth paddy; Described noncontact dip roll (5), diameter is 4-10mm, and upper and lower noncontact dip roll intermediate gaps width is 0.5-2mm; Described contact jockey pulley (6), diameter is 4-10mm, and the distance between adjacent two roller horizontal directions is 11mm; Described noncontact roller (7), diameter is 4-10mm, and upper and lower noncontact dip roll intermediate gaps width is 0.5-2mm, and noncontact dip roll (5) is 45-90mm with the level interval of noncontact roller (7).
4. utilize the arbitrary described continuous fiber reinforced thermoplastic resin composite material melt impregnation device of claim 1-3 to prepare a method for continuous fiber reinforced thermoplastic resin composite material, comprise the steps:
1) continuous tow is entered by fiber entry (3), walk around described dentalation (4), continuous tow is obtained pre-dispersed;
2) by step 1) continuous tow that disperseed is through noncontact dip roll (5) described in a group, again through alternately walking around described jockey pulley (6), eventually pass through described noncontact roller (7), simultaneously, melt of thermoplastic polymers is clamp-oned described melt impregnation mould (1) by extruder jockey interface (2), make continuous tow and melt of thermoplastic polymers carry out melt impregnation, obtain continuous fiber reinforced thermoplastic composite material finally by traction cooling.
5. method according to claim 4, is characterized in that: described step 1) in, described continuous tow is selected from least one of glass fibre and carbon fiber; Described step 2) in, described thermoplastic polymer is selected from least one in polypropylene, nylon 6, nylon66 fiber, polyformaldehyde.
6. the arbitrary described method of claim 4-5 prepares gained continuous fiber reinforced thermoplastic resin composite material.
CN201410165115.6A 2014-04-22 2014-04-22 Continuous fiber reinforced thermoplastic resin composite material melting soaking device Pending CN105014994A (en)

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CN201410165115.6A CN105014994A (en) 2014-04-22 2014-04-22 Continuous fiber reinforced thermoplastic resin composite material melting soaking device

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Application Number Priority Date Filing Date Title
CN201410165115.6A CN105014994A (en) 2014-04-22 2014-04-22 Continuous fiber reinforced thermoplastic resin composite material melting soaking device

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106626444A (en) * 2016-07-27 2017-05-10 山东极威新材料科技有限公司 Production technology of continuous fiber reinforced thermoplastic composites (CFRTP) pultruded profiles
CN107746189A (en) * 2017-10-31 2018-03-02 安徽丹凤电子材料股份有限公司 A kind of glass fiber wire-drawing infiltration apparatus
CN110789027A (en) * 2019-11-28 2020-02-14 丰县冠珂工程科技有限公司 Forced hot-pressing spoon-biting dispersion machine
CN111070723A (en) * 2018-10-22 2020-04-28 上海杰事杰新材料(集团)股份有限公司 Continuous fiber reinforced thermoplastic composite material impregnation die
CN111732834A (en) * 2020-06-30 2020-10-02 诺思贝瑞新材料科技(苏州)有限公司 Continuous fiber composite material for 3D printing and preparation method thereof
CN114434672A (en) * 2020-10-30 2022-05-06 中国石油化工股份有限公司 Dipping die, dipping method and manufacturing system comprising dipping die
CN114466739A (en) * 2019-10-08 2022-05-10 克劳斯马菲技术有限公司 Extrusion device for curved profiles
WO2022175723A1 (en) 2021-02-17 2022-08-25 Universidade Do Minho Impregnation device to produce continuous fibre reinforced thermoplastic filaments for 3d printing, and impregnation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0707939A2 (en) * 1994-10-18 1996-04-24 Polyplastics Co. Ltd. Cross-head die and method for manufacturing a resin structure reinforced with long fibers
JP2005161676A (en) * 2003-12-02 2005-06-23 Daicel Chem Ind Ltd Method and die for manufacturing long fiber reinforced thermoplastic resin structure
CN102328443A (en) * 2011-09-30 2012-01-25 台州市家得宝日用品有限公司 Method and equipment for producing continuous fiber-reinforced thermoplastic composite material prepreg tape
CN102729483A (en) * 2011-04-15 2012-10-17 中国海洋石油总公司 Continuous long fiber-reinforced thermoplastic resin and its preparation method and molding equipment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0707939A2 (en) * 1994-10-18 1996-04-24 Polyplastics Co. Ltd. Cross-head die and method for manufacturing a resin structure reinforced with long fibers
JP2005161676A (en) * 2003-12-02 2005-06-23 Daicel Chem Ind Ltd Method and die for manufacturing long fiber reinforced thermoplastic resin structure
CN102729483A (en) * 2011-04-15 2012-10-17 中国海洋石油总公司 Continuous long fiber-reinforced thermoplastic resin and its preparation method and molding equipment
CN102328443A (en) * 2011-09-30 2012-01-25 台州市家得宝日用品有限公司 Method and equipment for producing continuous fiber-reinforced thermoplastic composite material prepreg tape

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106626444A (en) * 2016-07-27 2017-05-10 山东极威新材料科技有限公司 Production technology of continuous fiber reinforced thermoplastic composites (CFRTP) pultruded profiles
CN107746189A (en) * 2017-10-31 2018-03-02 安徽丹凤电子材料股份有限公司 A kind of glass fiber wire-drawing infiltration apparatus
CN111070723A (en) * 2018-10-22 2020-04-28 上海杰事杰新材料(集团)股份有限公司 Continuous fiber reinforced thermoplastic composite material impregnation die
CN111070723B (en) * 2018-10-22 2023-05-26 上海杰事杰新材料(集团)股份有限公司 Continuous fiber reinforced thermoplastic composite material impregnation die
CN114466739A (en) * 2019-10-08 2022-05-10 克劳斯马菲技术有限公司 Extrusion device for curved profiles
CN110789027A (en) * 2019-11-28 2020-02-14 丰县冠珂工程科技有限公司 Forced hot-pressing spoon-biting dispersion machine
CN111732834A (en) * 2020-06-30 2020-10-02 诺思贝瑞新材料科技(苏州)有限公司 Continuous fiber composite material for 3D printing and preparation method thereof
CN114434672A (en) * 2020-10-30 2022-05-06 中国石油化工股份有限公司 Dipping die, dipping method and manufacturing system comprising dipping die
WO2022175723A1 (en) 2021-02-17 2022-08-25 Universidade Do Minho Impregnation device to produce continuous fibre reinforced thermoplastic filaments for 3d printing, and impregnation method thereof

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