CN105001894A - Modifier for converting biomass into crude oil, production method and application process thereof - Google Patents
Modifier for converting biomass into crude oil, production method and application process thereof Download PDFInfo
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- CN105001894A CN105001894A CN201410155819.5A CN201410155819A CN105001894A CN 105001894 A CN105001894 A CN 105001894A CN 201410155819 A CN201410155819 A CN 201410155819A CN 105001894 A CN105001894 A CN 105001894A
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- biomass
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- correcting agent
- fat
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Abstract
The present invention discloses a modifier for converting biomass into crude oil, a production method and an application process thereof, and relates to the technical field of new energy sources, especially to the technical field of modification production of crude oil from biomass waste. The specific technical scheme comprises that the modifier is characterized by comprising effective components obtained by extracting and crushing high lipoid content plant seeds, magnesium carbonate, organic nutrient source, and yeast flora according to a ratio of 7.4:3:57.6:1. With the modifier of the present invention, the waste biomass resources can be effectively utilized while the crude oil with high value can be produced.
Description
Technical field
The present invention relates to technical field of new energies, especially relate to a kind of technical field of biomass waste modification being produced crude oil.
Background technology
Petroleum resources, as seriously rare and with a kind of natural resources of huge effectiveness, be the indispensable Mineral resources of modern society and human future, but it are exploited in a large number as Nonrenewable resources.Along with the continuous increase to energy demand in the continuous exhaustion of petroleum resources and global range, development fungible energy source becomes inexorable trend.Various fungible energy source being is all actively is being researched and developed in current countries in the world, but mostly all because working condition is harsh, cost is too high and flammable liquid yield is low, in Laboratory Production, can only not possess mass-produced ability, also do not have a kind of technology can popularize in worldwide for now.The biofuel that research is the hottest in current worldwide, the recyclability good because of it and combustionproperty and extensively concerned, but the production of biofuel may cause rising steadily of agricultural product price and fluctuate, and affects the steady progression of the future economy.In addition, chemical reagent required in production of biodiesel process and distill with high costs and oil yield is low, does not possess the ability put goods on the market.And simultaneously in recent years, along with rapid development of economy, people's lives and scientific and technological level are all improving constantly, and corresponding biomass waste total amount is also in rising trend, it is also becoming increasingly conspicuous to the harm of ecotope and biomass energy waste problem.From environment and new energy field angle, while disposing biomass waste (as the press filtration mud after wastewater treatment, animal excrement, food-processing waste residue and other agricultural and life solid-state biomass etc.), how to be used to it is also a problem demanding prompt solution.
Summary of the invention
For above-mentioned prior art Problems existing, the invention provides and a kind of simple and effectively modification is carried out to biomass waste, in order to produce the novel method of crude oil.The method is mainly undertaken by a kind of properties-correcting agent.Its concrete technical scheme is: a kind of properties-correcting agent making Wood Adhesives from Biomass crude oil, it is characterized in that this properties-correcting agent is made up of in the ratio of 7.4:3:57.6:1 the effective constituent proposed through fragmentation containing the high plant seed of fat and magnesiumcarbonate, organotrophy source, yeast flora.
In order to better implement the present invention, its scheme can also further specifically be refined as:
Wherein said organotrophy source refers to the mixture that protein, fat, humic acid and calcium lactate combine by 8:3.1:29.5:17.
The wherein said plant seed high containing fat refers to fat converting Enzyme through the effective constituent that fragmentation proposes.
The production method of this properties-correcting agent is: the effective constituent that the plant seed high containing fat proposes through fragmentation mixed in the ratio of 7.4:3:57.6:10:1 with magnesiumcarbonate, organotrophy source, pure water, yeast flora, dehydrate after micro-oxygen complex reaction, the flour be ground into.
The application art of the properties-correcting agent of Wood Adhesives from Biomass crude oil is made to be, properties-correcting agent after activation is evenly sprayed the biomass waste surface in water ratio 50%-60%, waste generates its own heat under anoxia condition, before beginning modification, carry out machinery every 8 hours in 72-96 hour turn over buttress, volatilize moisture, SO
2and NH
3gas, and be mineral manure through Wingdale sorption enhanced; Afterwards along with generates its own heat temperature raises, waste starts to carry out fat conversion, and portion carbohydrate is converted into hydrocarbon polymer and lipid, within 10-60 days, completes modifying process.
This properties-correcting agent can convert the fiber of biomass, half fiber, albumen, carbohydrate and starch conversion to crude oil, and the press filtration mud namely after correctability sewage disposal, animal excrement, food-processing waste residue and the biomass waste such as agricultural and life solid-state biomass produce crude oil; In modifying process, the nitrogen in biomass waste and sulphur can be converted into NH
3and SO
2, and mineral manure is made after liming absorbs.
The invention has the advantages that: 1, biomass effectively can be changed into crude oil by properties-correcting agent of the present invention in short tens of sky, and the generation for crude oil provides a new solution route, alleviate the nervous problem of resource that crude oil exhaustion brings; 2, properties-correcting agent of the present invention converts the fiber of biomass, half fiber, albumen, carbohydrate and starch conversion to crude oil, by biomass waste modification for the production of crude oil, so just can solve biomass waste pollution on the environment while production crude oil.
Embodiment
The production of properties-correcting agent: this properties-correcting agent is dehydrated after micro-oxygen complex reaction by the effective constituent proposed through fragmentation containing the high plant seed of fat and magnesiumcarbonate, organotrophy source, pure water, yeast, the flour be ground into.Organotrophy source wherein refers to the mixture that protein, fat, humic acid and calcium lactate combine by 8:3.1:29.5:17; The effective constituent proposed through fragmentation containing the plant seed (as plant seeds such as peanut, soybean, sesames) that fat is high refers to fat converting Enzyme.Concrete production method is: the effective constituent that the plant seed high containing fat proposes through fragmentation mixed in the ratio of 7.4:3:57.6:10:1 with magnesiumcarbonate, organotrophy source, pure water, yeast flora, dehydrate after micro-oxygen complex reaction, the flour be ground into.
utilize modifier treatment biomass waste to produce a method for crude oil, the step of its embody rule technique is:
A, build biomass waste modification ditch and liming collecting tank: build biomass waste modification ditch, what be mainly used in sample turns over buttress, modification, and modification ditch specification is determined according to sample size to be modified and industrial scale.The object building liming collecting tank is to absorb the SO discharged in modifying process
2and NH
3gas.
B, in modification ditch, carry out sample modification: after modification ditch builds up, add sample to be modified (ensureing water ratio 50%-60%) wherein and keep even its flat presentation.Water-soluble for a certain amount of properties-correcting agent activation was sprayed in sample surfaces to be modified after 24 hours, sprays while stir.After properties-correcting agent sprays and stirs, sample stack up is started modifying process.
In C, modifying process sample turn over buttress: biomass waste generates its own heat under anoxic conditions, turn over after buttress (every minor tick 8 hours) through machinery and volatilize moisture, SO
2and NH
3gas, and be collected in liming collecting tank through induced draft fan and generate the mineral manure such as calcium sulfate, ammonium sulfate, this process about needs 72-96 hour.Afterwards along with heat production temperature raises, sample starts to carry out fat conversion, and this process about needs 10-60 days.
Distill after D, sample modification terminate: after modification terminates, modified sample is distilled, carry out under the condition without the need to any catalytic cracking agent low-temperature atmosphere-pressure distillation can obtain 10%-40%(account for distillation sample dry weight) flammable liquid (crude oil).Can be directly used in vehicle fuel burning after being purified by crude oil, the outer operation building materials of remaining ash content use.
above-mentioned four steps relation is each other described in further detail:
Steps A: build biomass waste modification ditch, object is the biomass waste of accommodation certain capacity and adopts method of the present invention to turn over buttress, modification to it.Biomass waste modification ditch is applicable to building up rectangle, so that turn over the operation of buttress equipment.
Step B: ensure that modified sample water ratio is at 50%-60%, object promotes that properties-correcting agent gives full play to effect, for yeast flora heat production provides ecotopia.By water-soluble for properties-correcting agent activation after 24 hours, stir evenly with a certain amount of water dilution and evenly spray the sample surfaces to be modified in tiling with Sprayable, spraying while stir.For ensureing improved effect, a small amount of repeatedly spraying method can be taked.For the sample that degree of compactness is higher, need to add some materials that such as hole such as rice husk, wood shavings is larger before spraying properties-correcting agent, to ensure the micro-oxygen environment in successive modified process.After sample fully mixes with properties-correcting agent, sample generates its own heat dehydration under anoxic conditions.
Step C: early stage carried out turning over buttress at interval of 8 hours, and object is the SO by moisture and generation
2and NH
3gaseous volatilization, wherein SO
2and NH
3gas causes liming collecting tank through induced draft fan and generates calcium sulfate, ammonium sulfate and make mineral manure, to guarantee subsequent technique non-secondary pollution and finally to heat up in a steamer to obtain the quality of oil product.After modified sample moisture is lower than 60%, himself heat production temperature raises (temperature is at 40 DEG C-60 DEG C), portion carbohydrate in waste is converted into hydrocarbon polymer and lipid, according to the difference of organic content in biomass and chemical composition, this process required time is 10-60 days.
Step D: after modifying process terminates (moisture < 20%), can 250-350 DEG C, distill under normal pressure and the condition without catalytic cracking agent, oil product is proposed.The flammable liquid (crude oil) of 10%-40% finally can be changed according to the difference of organic content and composition.Motor vehicles and machines fuel combustion can be directly applied to after being purified by crude oil.
Claims (8)
1. make a properties-correcting agent for Wood Adhesives from Biomass crude oil, it is characterized in that this properties-correcting agent is made up of in the ratio of 7.4:3:57.6:1 the effective constituent proposed through fragmentation containing the high plant seed of fat and magnesiumcarbonate, organotrophy source, yeast flora.
2. the Wood Adhesives from Biomass that makes according to claim 1 is the properties-correcting agent of crude oil, it is characterized in that described organotrophy source refers to the mixture that protein, fat, humic acid and calcium lactate combine by 8:3.1:29.5:17.
3. the Wood Adhesives from Biomass that makes according to claim 1 is the properties-correcting agent of crude oil, it is characterized in that the described plant seed high containing fat refers to fat converting Enzyme through the effective constituent that fragmentation proposes.
4. the properties-correcting agent making Wood Adhesives from Biomass crude oil according to claim 1, is characterized in that this properties-correcting agent can convert the fiber of biomass, half fiber, protein, carbohydrate and starch conversion to grease.
5. the properties-correcting agent making Wood Adhesives from Biomass crude oil according to claim 1, is characterized in that the press filtration mud after sewage disposal, animal excrement, food-processing waste residue and the biomass waste such as agricultural and life solid-state biomass can be produced crude oil by this properties-correcting agent.
6. the Wood Adhesives from Biomass that makes according to claim 1 is the properties-correcting agent of crude oil, it is characterized in that the nitrogen in biomass and sulphur to be converted into NH in modifying process
3and SO
2.
7. the production method making the properties-correcting agent of Wood Adhesives from Biomass crude oil according to claim 1, it is characterized in that: the effective constituent that the plant seed high containing fat proposes through fragmentation is mixed in the ratio of 7.4:3:57.6:10:1 with magnesiumcarbonate, organotrophy source, pure water, yeast flora, dehydrate after micro-oxygen complex reaction, the flour be ground into.
8. the application art of the properties-correcting agent of Wood Adhesives from Biomass crude oil that makes according to claim 1 is, it is characterized in that: the properties-correcting agent after activation is evenly sprayed the biological surface in water ratio 50%-60%, waste generates its own heat under anoxia condition, before beginning modification, carry out machinery every 8 hours in 72-96 hour turn over buttress, volatilize moisture, SO
2and NH
3gas, and be mineral manure through Wingdale sorption enhanced; Afterwards along with generates its own heat temperature raises, biomass start to carry out fat conversion, and portion carbohydrate is converted into hydrocarbon polymer and lipid, within 10-60 days, complete modifying process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410155819.5A CN105001894A (en) | 2014-04-18 | 2014-04-18 | Modifier for converting biomass into crude oil, production method and application process thereof |
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|---|---|---|---|
| CN201410155819.5A CN105001894A (en) | 2014-04-18 | 2014-04-18 | Modifier for converting biomass into crude oil, production method and application process thereof |
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Citations (4)
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| CN101155925A (en) * | 2005-04-12 | 2008-04-02 | 纳幕尔杜邦公司 | System and process for biomass treatment |
| US20080118961A1 (en) * | 2004-11-09 | 2008-05-22 | Setsuo Sato | Biodiesel Production From Soapstock |
| CN102094046A (en) * | 2010-11-26 | 2011-06-15 | 黄虹寓 | Method for preparing biomass fuel ethanol by multienzyme system cell culture solution |
| CN102321722A (en) * | 2011-07-23 | 2012-01-18 | 天津北洋百川生物技术有限公司 | Method for producing ethanol fuel from kitchen waste |
-
2014
- 2014-04-18 CN CN201410155819.5A patent/CN105001894A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080118961A1 (en) * | 2004-11-09 | 2008-05-22 | Setsuo Sato | Biodiesel Production From Soapstock |
| CN101155925A (en) * | 2005-04-12 | 2008-04-02 | 纳幕尔杜邦公司 | System and process for biomass treatment |
| CN102094046A (en) * | 2010-11-26 | 2011-06-15 | 黄虹寓 | Method for preparing biomass fuel ethanol by multienzyme system cell culture solution |
| CN102321722A (en) * | 2011-07-23 | 2012-01-18 | 天津北洋百川生物技术有限公司 | Method for producing ethanol fuel from kitchen waste |
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Application publication date: 20151028 |