CN105001646A - Heat-resistant, thermally-conductive and insulating shield - Google Patents
Heat-resistant, thermally-conductive and insulating shield Download PDFInfo
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- CN105001646A CN105001646A CN201510391983.0A CN201510391983A CN105001646A CN 105001646 A CN105001646 A CN 105001646A CN 201510391983 A CN201510391983 A CN 201510391983A CN 105001646 A CN105001646 A CN 105001646A
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Abstract
The invention discloses a heat-resistant, thermally-conductive and insulating shield. The shield is made from a rubber material. raw materials of the rubber material contain, by weight, 40-60 parts of silicone rubber, 20-40 parts of teflon, 20-40 parts of an ethylene-vinyl acetate copolymer, 50-70 parts of modified aluminium nitride, 20-40 parts of fumed silica, 20-30 parts of silane-coupling magnesium hydrate, 1-3 parts of melamine polyphosphate, 7-9 parts of microencapsulated red phosphorus, 8-12 parts of epoxidized fatty acid methyl ester, 20-40 parts of epoxidized soybean oil, 0.5-3 parts of dicumyl peroxide, 0.5-1.5 parts of a promoter TMTD, 0.5-1 part of dibutyltin dilaurate, 5-6 parts of a Ca/Zn composite stabilizing agent, 2-4 parts of magnesium stearate, 0.2-0.4 part of an anti-aging agent IPPD, 0.6-1 part of an anti-aging agent RD and 2-4 parts of polyethylene wax.
Description
Technical field
The present invention relates to insulating shield technical field, particularly relate to a kind of heat-resisting heat conductive insulating guard shield.
Background technology
Elastomeric material is a kind of macromolecular material that can recover rapidly deformation under gross distortion.In recent years, developing rapidly of rubber industry, has higher requirement to rubber item, elastomeric material must towards functionalization, become more meticulous and the future development of diversification.Traditional single elastomeric material can not meet the service requirements developed rapidly completely.Modified rubber is the effective way improving material property.
Phenylene silicone rubber is the class silicon rubber introducing penylene base in polysiloxane backbone.Due to the introducing of penylene base, thus make the radiation resistance of silicon rubber greatly improve, simultaneously because the existence of aromatic ring makes molecule chain rigidity increase, kindliness reduces, and second-order transition temperature improves, and cold tolerance declines, and tensile strength then increases to some extent.Phenylene silicone rubber has excellent high temperature resistant, radiation resistance, high temperature resistantly reaches 250-300 DEG C, and has the characteristic such as good electrical insulation capability and the resistance to water vapour of moistureproof and mildewproof.
Tetrafluoroethylene has excellent high temperature resistant, low temperature resistant, corrosion-resistant, weather, highly to lubricate, does not adhere to, toxicological harmless, electrical insulating property.
Along with industrial production and scientific and technical development, electric, electronic product is widely used, and people it is also proposed higher requirement to thermally conductive material.There is the materials such as the pottery of excellent heat conductivity performance, metal, due to its electrical insulating property with processing characteristics is poor, cost is high, be difficult to the demand adapting to modern technologies development.Therefore, development of new heat-conductive composite material is needed.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of heat-resisting heat conductive insulating guard shield, the present invention is heat-resisting, good heat conductivity, and insulating property are high, corrosion-resistant, and physical strength is high.
The heat-resisting heat conductive insulating guard shield of one that the present invention proposes, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: silicon rubber 40-60 part, tetrafluoroethylene 20-40 part, ethylene-vinyl acetate copolymer 20-40 part, modification aluminium nitride 50-70 part, aerosil 20-40 part, silane coupled magnesium hydroxide 20-30 part, melamine phosphate 1-3 part, microencapsulated powder oil 7-9 part, epoxy aliphatic acid methyl ester 8-12 part, epoxy soybean oil 20-40 part, dicumyl peroxide 0.5-3 part, Vulcanization accelerator TMTD 0.5-1.5 part, dibutyl tin laurate 0.5-1 part, Ca/Zn one package stabilizer 5-6 part, Magnesium Stearate 2-4 part, anti-aging agent IPPD 0.2-0.4 part, anti-aging agent RD 0.6-1 part, polyethylene wax 2-4 part.
Preferably, silicon rubber is phenylene silicone rubber, and wherein, the content of vinyl is 0.6-0.8wt%.
Preferably, the preparation method of modification aluminium nitride is: added by aluminium nitride in acetone, ultrasonicly obtains aluminium nitride slurries; Added in ethanol by vinyltriethoxysilane and mix, add aluminium nitride slurries, be warming up to 60-80 DEG C, stir 10-14h, filter, washing, drying obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2-3.
Preferably, the preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 1-3 times of acetone that is benchmark, ultrasonic 2-3h obtains aluminium nitride slurries; Being added by vinyltriethoxysilane with vinyltriethoxysilane weight is mix in benchmark 5-7 ethanol doubly, add aluminium nitride slurries, be warming up to 65-75 DEG C, 11-13h is stirred with the speed of 800-1000r/min, filter, by washing with alcohol 4-6 time, be warming up to 70-90 DEG C, dry 13-17h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2.2-2.6.
Preferably, the particle diameter of aerosil is 7-35 μm.
Preferably, the weight ratio of particle diameter to be the aerosil of 25-35 μm and particle diameter the be aerosil of 7-15 μm is 1:1-3.
Preferably, the raw material of its elastomeric material comprises by weight: silicon rubber 45-55 part, tetrafluoroethylene 25-35 part, ethylene-vinyl acetate copolymer 25-35 part, modification aluminium nitride 55-65 part, aerosil 25-35 part, silane coupled magnesium hydroxide 22-28 part, melamine phosphate 1.5-2.5 part, microencapsulated powder oil 7.5-8.5 part, epoxy aliphatic acid methyl ester 9-11 part, epoxy soybean oil 25-35 part, dicumyl peroxide 1.5-2.5 part, Vulcanization accelerator TMTD 0.8-1.2 part, dibutyl tin laurate 0.7-0.9 part, Ca/Zn one package stabilizer 5.3-5.7 part, Magnesium Stearate 2.5-3.5 part, anti-aging agent IPPD 0.25-0.35 part, anti-aging agent RD 0.7-0.9 part, polyethylene wax 2.5-3.5 part.
Elastomeric material preparation method is as follows: add in Banbury mixer by silicon rubber, tetrafluoroethylene, ethylene-vinyl acetate copolymer, be warming up to 120 DEG C, with the speed banburying 6min of 100r/min, add modification aluminium nitride and aerosil banburying 5min obtains rubber major ingredient; Successively silane coupled magnesium hydroxide, melamine phosphate, microencapsulated powder oil, epoxy aliphatic acid methyl ester, epoxy soybean oil, Ca/Zn one package stabilizer, Magnesium Stearate, anti-aging agent IPPD, anti-aging agent RD and polyethylene wax are added in the Banbury mixer containing rubber major ingredient, be warming up to 140 DEG C, with the speed banburying 10min of 400r/min, continue to add dicumyl peroxide, Vulcanization accelerator TMTD and dibutyl tin laurate, be warming up to 150 DEG C, with the speed banburying 5min of 500r/min, thin-pass obtains heat-resisting heat conductive insulating guard shield elastomeric material for 6 times.
The silicon rubber that the present invention selects, tetrafluoroethylene all have excellent electrical insulating property, high thermal resistance, erosion resistance, and two-way interaction can increase electrical insulating property of the present invention, high thermal resistance, and phenylene silicone rubber has good mechanical property, machinery of the present invention can be increased slight, aluminium nitride and aerosil can increase the heat conductivility of rubber, the aluminium nitride modified through vinyltriethoxysilane contains carbon-carbon double bond, can and silicon rubber, tetrafluoroethylene, double bond in ethylene-vinyl acetate copolymer is polymerized, increase aluminium nitride at silicon rubber, tetrafluoroethylene, consistency in ethylene-vinyl acetate copolymer, aluminium nitride is dispersed in rubber uniformly, with silicon rubber, tetrafluoroethylene, ethylene-vinyl acetate copolymer interacts, increase heat conductivility of the present invention, and then greatly increase high thermal resistance of the present invention, mechanical property of the present invention can be increased simultaneously, the aerosil of different-grain diameter is easier to be uniformly distributed in rubber, interacts, increase thermal conductivity of the present invention and mechanical property with silicon rubber, tetrafluoroethylene, ethylene-vinyl acetate copolymer, aluminium nitride, aerosil can also with silane coupled magnesium hydroxide, melamine phosphate, microencapsulated powder oil interacts increases flame retardant properties of the present invention, dicumyl peroxide, Vulcanization accelerator TMTD and dibutyl tin laurate make rubber major ingredient be cross-linked to form reticulated structure, silane coupled magnesium hydroxide, melamine phosphate, microencapsulated powder oil, epoxy aliphatic acid methyl ester, epoxy soybean oil, Ca/Zn one package stabilizer, Magnesium Stearate, anti-aging agent IPPD, anti-aging agent RD and polyethylene wax can be dispersed in reticulated structure, and then increase the physical strengths such as stretch-proof of the present invention, anti tear, epoxy soybean oil and hard magnesium, Ca/Zn one package stabilizer acts synergistically increases stability of the present invention, anti-aging agent IPPD and anti-aging agent RD can increase resistance of aging of the present invention, polyethylene wax can increase the convenient processing of mobility of material.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of heat-resisting heat conductive insulating guard shield, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: contents of ethylene is the phenylene silicone rubber 40 parts of 0.8wt%, tetrafluoroethylene 40 parts, ethylene-vinyl acetate copolymer 20 parts, modification aluminium nitride 70 parts, aerosil 20 parts, silane coupled magnesium hydroxide 30 parts, melamine phosphate 1 part, microencapsulated powder oil 9 parts, epoxy aliphatic acid methyl ester 8 parts, epoxy soybean oil 40 parts, dicumyl peroxide 0.5 part, Vulcanization accelerator TMTD 1.5 parts, dibutyl tin laurate 0.5 part, Ca/Zn one package stabilizer 6 parts, Magnesium Stearate 2 parts, anti-aging agent IPPD 0.4 part, anti-aging agent RD 0.6 part, polyethylene wax 4 parts, wherein, it is 1:1 that particle diameter is respectively 25-35 μm with the weight ratio of the aerosil of 7-15 μm,
The preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 3 times of acetone that are benchmark, ultrasonic 2h obtains aluminium nitride slurries; Vinyltriethoxysilane is added mix in the vinyltriethoxysilane weight 7 times of ethanol that are benchmark, add aluminium nitride slurries, be warming up to 60 DEG C, stir 10h with the speed of 1000r/min, filter, washing, by washing with alcohol 6 times, be warming up to 70 DEG C, dry 17h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2.
Embodiment 2
A kind of heat-resisting heat conductive insulating guard shield, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: contents of ethylene is the phenylene silicone rubber 60 parts of 0.6wt%, tetrafluoroethylene 20 parts, ethylene-vinyl acetate copolymer 40 parts, modification aluminium nitride 50 parts, aerosil 40 parts, silane coupled magnesium hydroxide 20 parts, melamine phosphate 3 parts, microencapsulated powder oil 7 parts, epoxy aliphatic acid methyl ester 12 parts, epoxy soybean oil 20 parts, dicumyl peroxide 3 parts, Vulcanization accelerator TMTD 0.5 part, dibutyl tin laurate 1 part, Ca/Zn one package stabilizer 5 parts, Magnesium Stearate 4 parts, anti-aging agent IPPD 0.2 part, anti-aging agent RD 1 part, polyethylene wax 2 parts, wherein, it is 1:3 that particle diameter is respectively 25-35 μm with the weight ratio of the aerosil of 7-15 μm,
The preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 1 times of acetone that is benchmark, ultrasonic 3h obtains aluminium nitride slurries; Vinyltriethoxysilane is added mix in the vinyltriethoxysilane weight 5 times of ethanol that are benchmark, add aluminium nitride slurries, be warming up to 80 DEG C, stir 14h with the speed of 800r/min, filter, washing, by washing with alcohol 4 times, be warming up to 90 DEG C, dry 13h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:3.
Embodiment 3
A kind of heat-resisting heat conductive insulating guard shield, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: contents of ethylene is the phenylene silicone rubber 55 parts of 0.65wt%, tetrafluoroethylene 25 parts, ethylene-vinyl acetate copolymer 35 parts, modification aluminium nitride 55 parts, aerosil 35 parts, silane coupled magnesium hydroxide 22 parts, melamine phosphate 2.5 parts, microencapsulated powder oil 7.5 parts, epoxy aliphatic acid methyl ester 11 parts, epoxy soybean oil 25 parts, dicumyl peroxide 2.5 parts, Vulcanization accelerator TMTD 0.8 part, dibutyl tin laurate 0.9 part, Ca/Zn one package stabilizer 5.3 parts, Magnesium Stearate 3.5 parts, anti-aging agent IPPD0.25 part, anti-aging agent RD 0.9 part, polyethylene wax 2.5 parts, wherein, it is 1:2.5 that particle diameter is respectively 25-35 μm with the weight ratio of the aerosil of 7-15 μm,
The preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 1.5 times of acetone that are benchmark, ultrasonic 2.7h obtains aluminium nitride slurries; Vinyltriethoxysilane is added mix in the vinyltriethoxysilane weight 5.5 times of ethanol that are benchmark, add aluminium nitride slurries, be warming up to 75 DEG C, 13h is stirred with the speed of 850r/min, filter, by washing with alcohol 4 times, be warming up to 85 DEG C, dry 13h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2.6.
Embodiment 4
A kind of heat-resisting heat conductive insulating guard shield, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: contents of ethylene is the phenylene silicone rubber 45 parts of 0.75wt%, tetrafluoroethylene 35 parts, ethylene-vinyl acetate copolymer 25 parts, modification aluminium nitride 65 parts, aerosil 25 parts, silane coupled magnesium hydroxide 28 parts, melamine phosphate 1.5 parts, microencapsulated powder oil 8.5 parts, epoxy aliphatic acid methyl ester 9 parts, epoxy soybean oil 35 parts, dicumyl peroxide 1.5 parts, Vulcanization accelerator TMTD 1.2 parts, dibutyl tin laurate 0.7 part, Ca/Zn one package stabilizer 5.7 parts, Magnesium Stearate 2.5 parts, anti-aging agent IPPD 0.35 part, anti-aging agent RD 0.7 part, polyethylene wax 3.5 parts, wherein, it is 1:1.5 that particle diameter is respectively 25-35 μm with the weight ratio of the aerosil of 7-15 μm,
The preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 2.5 times of acetone that are benchmark, ultrasonic 2.3h obtains aluminium nitride slurries; Vinyltriethoxysilane is added mix in the vinyltriethoxysilane weight 6.5 times of ethanol that are benchmark, add aluminium nitride slurries, be warming up to 65 DEG C, 11h is stirred with the speed of 950r/min, filter, by washing with alcohol 6 times, be warming up to 75 DEG C, dry 17h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2.2.
Embodiment 5
A kind of heat-resisting heat conductive insulating guard shield, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: contents of ethylene is the phenylene silicone rubber 50 parts of 0.7wt%, tetrafluoroethylene 30 parts, ethylene-vinyl acetate copolymer 30 parts, modification aluminium nitride 60 parts, aerosil 30 parts, silane coupled magnesium hydroxide 25 parts, melamine phosphate 2 parts, microencapsulated powder oil 8 parts, epoxy aliphatic acid methyl ester 10 parts, epoxy soybean oil 30 parts, dicumyl peroxide 2 parts, Vulcanization accelerator TMTD 1 part, dibutyl tin laurate 0.8 part, Ca/Zn one package stabilizer 5.5 parts, Magnesium Stearate 3 parts, anti-aging agent IPPD 0.3 part, anti-aging agent RD 0.8 part, polyethylene wax 3 parts, wherein, it is 1:2 that particle diameter is respectively 25-35 μm with the weight ratio of the aerosil of 7-15 μm,
The preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 2 times of acetone that are benchmark, ultrasonic 2.5h obtains aluminium nitride slurries; Vinyltriethoxysilane is added mix in the vinyltriethoxysilane weight 6 times of ethanol that are benchmark, add aluminium nitride slurries, be warming up to 70 DEG C, 12h is stirred with the speed of 900r/min, filter, by washing with alcohol 5 times, be warming up to 80 DEG C, dry 15h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2.5.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. a heat-resisting heat conductive insulating guard shield, it is characterized in that, its guard shield elastomeric material is made, the raw material of its elastomeric material comprises by weight: silicon rubber 40-60 part, tetrafluoroethylene 20-40 part, ethylene-vinyl acetate copolymer 20-40 part, modification aluminium nitride 50-70 part, aerosil 20-40 part, silane coupled magnesium hydroxide 20-30 part, melamine phosphate 1-3 part, microencapsulated powder oil 7-9 part, epoxy aliphatic acid methyl ester 8-12 part, epoxy soybean oil 20-40 part, dicumyl peroxide 0.5-3 part, Vulcanization accelerator TMTD 0.5-1.5 part, dibutyl tin laurate 0.5-1 part, Ca/Zn one package stabilizer 5-6 part, Magnesium Stearate 2-4 part, anti-aging agent IPPD 0.2-0.4 part, anti-aging agent RD 0.6-1 part, polyethylene wax 2-4 part.
2. heat-resisting heat conductive insulating guard shield according to claim 1, it is characterized in that, silicon rubber is phenylene silicone rubber, and wherein, the content of vinyl is 0.6-0.8wt%.
3. heat-resisting heat conductive insulating guard shield according to claim 1 or 2, is characterized in that, the preparation method of modification aluminium nitride is: added by aluminium nitride in acetone, ultrasonicly obtains aluminium nitride slurries; Added in ethanol by vinyltriethoxysilane and mix, add aluminium nitride slurries, be warming up to 60-80 DEG C, stir 10-14h, filter, washing, drying obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2-3.
4. heat-resisting heat conductive insulating guard shield according to any one of claim 1-3, is characterized in that, the preparation method of modification aluminium nitride is: added by aluminium nitride with in the aluminium nitride weight 1-3 times of acetone that is benchmark, ultrasonic 2-3h obtains aluminium nitride slurries; Being added by vinyltriethoxysilane with vinyltriethoxysilane weight is mix in benchmark 5-7 ethanol doubly, add aluminium nitride slurries, be warming up to 65-75 DEG C, 11-13h is stirred with the speed of 800-1000r/min, filter, by washing with alcohol 4-6 time, be warming up to 70-90 DEG C, dry 13-17h obtains modification aluminium nitride, and wherein the weight ratio of aluminium nitride and vinyltriethoxysilane is 100:2.2-2.6.
5. heat-resisting heat conductive insulating guard shield according to any one of claim 1-4, is characterized in that, the particle diameter of aerosil is 7-35 μm.
6. heat-resisting heat conductive insulating guard shield according to any one of claim 1-4, is characterized in that, the weight ratio of particle diameter to be the aerosil of 25-35 μm and particle diameter the be aerosil of 7-15 μm is 1:1-3.
7. heat-resisting heat conductive insulating guard shield according to any one of claim 1-6, it is characterized in that, the raw material of its elastomeric material comprises by weight: silicon rubber 45-55 part, tetrafluoroethylene 25-35 part, ethylene-vinyl acetate copolymer 25-35 part, modification aluminium nitride 55-65 part, aerosil 25-35 part, silane coupled magnesium hydroxide 22-28 part, melamine phosphate 1.5-2.5 part, microencapsulated powder oil 7.5-8.5 part, epoxy aliphatic acid methyl ester 9-11 part, epoxy soybean oil 25-35 part, dicumyl peroxide 1.5-2.5 part, Vulcanization accelerator TMTD 0.8-1.2 part, dibutyl tin laurate 0.7-0.9 part, Ca/Zn one package stabilizer 5.3-5.7 part, Magnesium Stearate 2.5-3.5 part, anti-aging agent IPPD 0.25-0.35 part, anti-aging agent RD 0.7-0.9 part, polyethylene wax 2.5-3.5 part.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368059A (en) * | 2015-12-15 | 2016-03-02 | 苏州鑫德杰电子有限公司 | Anti-abrasion heat-conducting silicon rubber material and preparation method thereof |
| CN105440464A (en) * | 2015-12-08 | 2016-03-30 | 宁国市开源橡塑汽车零部件有限公司 | Damping rubber material |
| CN106928611A (en) * | 2017-04-30 | 2017-07-07 | 国网江苏省电力公司职业技能训练基地 | A kind of piezoresistor insulation cover of heatproof |
| CN109076718A (en) * | 2016-04-27 | 2018-12-21 | 北川工业株式会社 | The manufacturing method of heat exchange sheet and heat exchange sheet |
| CN110283422A (en) * | 2019-07-10 | 2019-09-27 | 安徽伊法拉电力科技有限公司 | A kind of fuse insulating shield material and preparation method thereof |
| CN113956563A (en) * | 2021-10-18 | 2022-01-21 | 远东电缆有限公司 | High-thermal-conductivity low-smoke halogen-free flame-retardant polyolefin cable material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757651A (en) * | 2012-06-12 | 2012-10-31 | 安徽华海特种电缆集团有限公司 | Silicone rubber insulating fluororubber cable material and preparation method thereof |
| CN103122148A (en) * | 2013-01-22 | 2013-05-29 | 安徽华津电缆集团有限公司 | Heat-resistant silicon rubber insulation material for wind power generation torsion-resistant flexible cables and preparation method thereof |
| CN103483821A (en) * | 2013-09-27 | 2014-01-01 | 昆山市奋发绝缘材料有限公司 | Thermal-conduction, insulating and flame-retardant rubber |
-
2015
- 2015-07-06 CN CN201510391983.0A patent/CN105001646A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757651A (en) * | 2012-06-12 | 2012-10-31 | 安徽华海特种电缆集团有限公司 | Silicone rubber insulating fluororubber cable material and preparation method thereof |
| CN103122148A (en) * | 2013-01-22 | 2013-05-29 | 安徽华津电缆集团有限公司 | Heat-resistant silicon rubber insulation material for wind power generation torsion-resistant flexible cables and preparation method thereof |
| CN103483821A (en) * | 2013-09-27 | 2014-01-01 | 昆山市奋发绝缘材料有限公司 | Thermal-conduction, insulating and flame-retardant rubber |
Non-Patent Citations (2)
| Title |
|---|
| 张玉龙，等: "《塑料模压成型工艺与实例》", 28 February 2011 * |
| 薛茹君，等: "《无机纳米材料的表面修饰改性与物性研究》", 31 October 2009 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440464A (en) * | 2015-12-08 | 2016-03-30 | 宁国市开源橡塑汽车零部件有限公司 | Damping rubber material |
| CN105368059A (en) * | 2015-12-15 | 2016-03-02 | 苏州鑫德杰电子有限公司 | Anti-abrasion heat-conducting silicon rubber material and preparation method thereof |
| CN105368059B (en) * | 2015-12-15 | 2018-08-14 | 深圳市杰美特科技股份有限公司 | A kind of wear-resisting heat-conducting silicon rubber material and preparation method thereof |
| CN109076718A (en) * | 2016-04-27 | 2018-12-21 | 北川工业株式会社 | The manufacturing method of heat exchange sheet and heat exchange sheet |
| CN106928611A (en) * | 2017-04-30 | 2017-07-07 | 国网江苏省电力公司职业技能训练基地 | A kind of piezoresistor insulation cover of heatproof |
| CN110283422A (en) * | 2019-07-10 | 2019-09-27 | 安徽伊法拉电力科技有限公司 | A kind of fuse insulating shield material and preparation method thereof |
| CN113956563A (en) * | 2021-10-18 | 2022-01-21 | 远东电缆有限公司 | High-thermal-conductivity low-smoke halogen-free flame-retardant polyolefin cable material and preparation method thereof |
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Application publication date: 20151028 |