CN105000903A - Flame retardant and flexible aerated block and preparation method therefor - Google Patents
Flame retardant and flexible aerated block and preparation method therefor Download PDFInfo
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- CN105000903A CN105000903A CN201510409196.4A CN201510409196A CN105000903A CN 105000903 A CN105000903 A CN 105000903A CN 201510409196 A CN201510409196 A CN 201510409196A CN 105000903 A CN105000903 A CN 105000903A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
The present invention discloses a flame retardant and flexible aerated block and a preparation method therefor. The aerated block is prepared by the following raw materials in parts by weight: 100-120 parts of desert sand, 20-30 parts of ceramic polishing residue, 35-45 parts of ordinary portland cement, 8-10 parts of poultry bone powder, 4-6 parts of waste tire rubber powder, 3-5 parts of white mud for paper making, and the like. According to the present invention, combined use of raw materials such as added silicone microsphere, waste tire rubber powder and rosin calcium can greatly reduce the water absorption of the aerated block, provide the aerated block with outstanding water resistance and not prone to get damp, thereby strengthening the anti-mouldy property. Moreover, the aerated block further has stronger compressive strength and flexural strength, a long service life, a wide application range, and a wide market prospect. According to the present invention, an added complex plasticizer composed of di-isodecyl phthalate, [beta]-diketone and ammonium polyphosphate is combined with an ethylene vinyl acetate copolymer, thereby improving the mechanical property and meanwhile improving aging resistance, processability and flexibility; and the ammonium polyphosphate has an effect in a condensed phase.
Description
Technical field
The present invention relates to building material technical field, is more particularly a kind of flame retardant flexible aerated-block and preparation method thereof.
Background technology
" autoclave aerated concrete building block " is for main raw material with siliceous material (sand, flyash and containing silicon tailings etc.) and calcareous material (lime, cement), admixture foaming agent (aluminium powder), through the stirring that adds water, hole is formed, the porous silicate goods made by technological processs such as casting, precuring cutting, steam press maintenances by chemical reaction.
Aerated-block is generally divided into two kinds, sand aerated-block and grey aerated-block.The production of air-entrained concrete building block, can utilize the trade wastes such as flyash, CHARACTERISTICS OF TAILINGS SAND and desulfurated plaster in a large number, meet the strategy of developing a circular economy, belong to the novel wall material of national policy encourage growth.But because each enterprise utilizes the difference of local resources condition, therefore starting material chosen and fill a prescription different, what quartz sand (or mine tailing) generally will be utilized substantially to produce is called " sand aerated-block ".As buildings infilled wall, and it is best self heat insulation wall.Aerated-block is also known as making light cinder brick, foamed brick, light partition wall brick; Also make this material can block sound-also known as do acoustic brick, sound insulation brick; Because containing a large amount of air in material, be called again aerated bricks, aerated blocks; Meanwhile, this material has good heat-insulation and heat-preservation fire resistance, also known as making insulating brick, insulating brick, fire proofing tile, energy-saving brick; Most importantly, it is made with concrete, has very high intensity, so its art name is called-air-entrained concrete building block.
The aerated-block that prior art is produced, in water resisting property and mildew resistance, ageing resistance, flame retardant resistance, snappiness all also exists certain defect, can not meet the requirement of people gradually.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of flame retardant flexible aerated-block and preparation method thereof is provided, improve water tolerance, the flame retardant resistance of aerated-block, increase snappiness.
For achieving the above object, the present invention adopts following technical scheme:
A kind of flame retardant flexible aerated-block, be made up of following raw material: Desert Sand 100-120, ceramic polished slag 20-30, ordinary Portland cement 35-45, fowl bone meal 8-10, waste-tyre rubber-powder 4-6, paper white sludge 3-5, active sludge dry powder 4-6, organosilicon microballoon 3-4, isocyanic ester 2-3, epoxy resin 4-8, aluminium powder 3-6, antimonous oxide 5-10, polyvinyl chloride (PVC) RESINS 10-15, dioctyl sebacate 8-12, dimethyl terephthalate (DMT) 12-15, oxidation inhibitor 616 5-8, PHT4 10-15, polyvinyl chloride (PVC) RESINS 25-35, tall oil-asphalt sodium sulfonate 2-4, sylvic acid calcium 3-5, additive 6-8, water is appropriate,
Described additive is made up of following raw material: 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine 2-3, sodium cocoyl methyl Sodium taurine salt 1.5-2.5, Protanal Ester SD-LB 4-6, sodium polystyrene sulfonate 2-4, calcium lignin sulphonate 3-5, polymeric aluminium ferrum silicate 8-12, dickite 36-48, white cream mud 18-32, glass fibre 2-3; Preparation method is: (a) puts into pulverizer and pulverize after dickite and white cream mud being mixed, and crosses 100-150 mesh sieve; B powder mix that step (a) obtains by (), 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine and sodium cocoyl methyl Sodium taurine salt mix, and add appropriate water and make the slurries that concentration is 40-50%, then under the rotating speed of 200-300r/min, stir 10-15min; C above-mentioned slurries are filtered post-drying by (), then mix with Protanal Ester SD-LB, sodium polystyrene sulfonate, calcium lignin sulphonate, polymeric aluminium ferrum silicate and obtain additive.
A preparation method for flame retardant flexible aerated-block, is made up of following steps:
(1) Desert Sand, ceramic polished slag, paper white sludge are mixed, pulverize, cross 150-250 mesh sieve, add water and make the water content control of compound at 65-75%, then waste-tyre rubber-powder, active sludge dry powder, fowl bone meal, ordinary Portland cement is added, 600-1200r/min adds organosilicon microballoon, isocyanic ester, epoxy resin, tall oil-asphalt sodium sulfonate, sylvic acid calcium after grinding 15-20min, the water content adjusting compound after stirring again stirs 3-5min to 80-85%, 500-1000rpm;
(2) antimonous oxide, polyvinyl chloride (PVC) RESINS, dioctyl sebacate, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4, polyvinyl chloride (PVC) RESINS, aluminium powder, additive are added in the obtained slurry of step (1), foam after stirring 25-30min at 70-75 DEG C of temperature;
(3) in foamed slurry injection moulding mould step (2) obtained, natural curing 35-45h, form removal, obtains green compact;
(4) green compact step (3) obtained temperature be 55-65 DEG C, pressure be the condition of 0.5-1.0MPa under vapor cure 15-25h, obtain aerated-block finished product.
The invention has the advantages that:
The raw material compound use such as organosilicon microballoon, waste-tyre rubber-powder, sylvic acid calcium that the present invention adds, significantly can reduce the water-intake rate of aerated bricks, and make it have excellent water tolerance, not moisture-sensitive, therefore anti-mildew sex change can be also stronger; In addition, this aerated-block also has higher ultimate compression strength and bend resistance intensity, long service life, applied range, wide market.The antimonous oxide that the present invention adds is by the synergy with the chlorine element in polyvinyl chloride (PVC) RESINS, enhance the flame retardant resistance of polyvinyl chloride, plasticizer and the polyvinyl chloride (PVC) RESINS of the dioctyl sebacate added, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4 composition are arranged in pairs or groups, the positive acting of this several softening agent is maximized, decrease the consumption of softening agent while improve the resistance to low temperature of product, increase snappiness.
Embodiment
Embodiment 1
A kind of flame retardant flexible aerated-block, be made up of following weight raw material: Desert Sand 100kg, ceramic polished slag 20kg, ordinary Portland cement 35kg, fowl bone meal 8kg, waste-tyre rubber-powder 4kg, paper white sludge 3kg, active sludge dry powder 4kg, organosilicon microballoon 3kg, isocyanic ester 2kg, epoxy resin 4kg, aluminium powder 3kg, antimonous oxide 5 kg, polyvinyl chloride (PVC) RESINS 10 kg, dioctyl sebacate 8 kg, dimethyl terephthalate (DMT) 12 kg, oxidation inhibitor 616 5 kg, PHT4 10 kg, polyvinyl chloride (PVC) RESINS 25 kg, tall oil-asphalt sodium sulfonate 2kg, sylvic acid calcium 3kg, additive 6kg, water is appropriate,
Described additive is made up of following weight raw material: 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine 2kg, sodium cocoyl methyl Sodium taurine salt 1.5kg, Protanal Ester SD-LB 4kg, sodium polystyrene sulfonate 2kg, calcium lignin sulphonate 3kg, polymeric aluminium ferrum silicate 8kg, dickite 36kg, white cream mud 18kg, glass fibre 2kg; Preparation method is: (a) puts into pulverizer and pulverize after dickite and white cream mud being mixed, and crosses 100 mesh sieves; B powder mix that step (a) obtains by (), 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine and sodium cocoyl methyl Sodium taurine salt mix, and add appropriate water and make the slurries that concentration is 40%, then under the rotating speed of 200r/min, stir 10min; C above-mentioned slurries are filtered post-drying by (), then mix with Protanal Ester SD-LB, sodium polystyrene sulfonate, calcium lignin sulphonate, polymeric aluminium ferrum silicate and obtain additive.
A preparation method for flame retardant flexible aerated-block, is made up of following steps:
(1) Desert Sand, ceramic polished slag, paper white sludge are mixed, pulverize, cross 150-250 mesh sieve, add water and make the water content control of compound at 65-75%, then waste-tyre rubber-powder, active sludge dry powder, fowl bone meal, ordinary Portland cement is added, 600-1200r/min adds organosilicon microballoon, isocyanic ester, epoxy resin, tall oil-asphalt sodium sulfonate, sylvic acid calcium after grinding 15-20min, the water content adjusting compound after stirring again stirs 3-5min to 80-85%, 500-1000rpm;
(2) antimonous oxide, polyvinyl chloride (PVC) RESINS, dioctyl sebacate, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4, polyvinyl chloride (PVC) RESINS, aluminium powder, additive are added in the obtained slurry of step (1), foam after stirring 25-30min at 70-75 DEG C of temperature;
(3) in foamed slurry injection moulding mould step (2) obtained, natural curing 35-45h, form removal, obtains green compact;
(4) green compact step (3) obtained temperature be 55-65 DEG C, pressure be the condition of 0.5-1.0MPa under vapor cure 15-25h, obtain aerated-block finished product.
Embodiment 2
A kind of flame retardant flexible aerated-block, be made up of following weight raw material: Desert Sand 120kg, ceramic polished slag 30kg, ordinary Portland cement 45kg, fowl bone meal 10kg, waste-tyre rubber-powder 6kg, paper white sludge 5kg, active sludge dry powder 6kg, organosilicon microballoon 4kg, isocyanic ester 3kg, epoxy resin 8kg, aluminium powder 6kg, antimonous oxide 10 kg, polyvinyl chloride (PVC) RESINS 15 kg, dioctyl sebacate 12 kg, dimethyl terephthalate (DMT) 15 kg, oxidation inhibitor 616 8 kg, PHT4 15 kg, polyvinyl chloride (PVC) RESINS 35 kg, tall oil-asphalt sodium sulfonate 4kg, sylvic acid calcium 5kg, additive 8kg, water is appropriate,
Described additive is made up of following weight raw material: 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine 3kg, sodium cocoyl methyl Sodium taurine salt 2.5kg, Protanal Ester SD-LB 6kg, sodium polystyrene sulfonate 4kg, calcium lignin sulphonate 5kg, polymeric aluminium ferrum silicate 12kg, dickite 48kg, white cream mud 32kg, glass fibre 3kg; Preparation method is: (a) puts into pulverizer and pulverize after dickite and white cream mud being mixed, and crosses 150 mesh sieves; B powder mix that step (a) obtains by (), 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine and sodium cocoyl methyl Sodium taurine salt mix, and add appropriate water and make the slurries that concentration is 50%, then under the rotating speed of 300r/min, stir 15min; C above-mentioned slurries are filtered post-drying by (), then mix with Protanal Ester SD-LB, sodium polystyrene sulfonate, calcium lignin sulphonate, polymeric aluminium ferrum silicate and obtain additive.
The antimonous oxide that the present invention adds is by the synergy with the chlorine element in polyvinyl chloride (PVC) RESINS, enhance the flame retardant resistance of polyvinyl chloride, plasticizer and the polyvinyl chloride (PVC) RESINS of the dioctyl sebacate added, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4 composition are arranged in pairs or groups, the positive acting of this several softening agent is maximized, decrease the consumption of softening agent while improve the resistance to low temperature of product, increase snappiness.
The preparation method of aerated-block is with embodiment 1.
Claims (2)
1. a flame retardant flexible aerated-block, it is characterized in that: be made up of following raw material: Desert Sand 100-120, ceramic polished slag 20-30, ordinary Portland cement 35-45, fowl bone meal 8-10, waste-tyre rubber-powder 4-6, paper white sludge 3-5, active sludge dry powder 4-6, organosilicon microballoon 3-4, isocyanic ester 2-3, epoxy resin 4-8, aluminium powder 3-6, antimonous oxide 5-10, polyvinyl chloride (PVC) RESINS 10-15, dioctyl sebacate 8-12, dimethyl terephthalate (DMT) 12-15, oxidation inhibitor 616 5-8, PHT4 10-15, polyvinyl chloride (PVC) RESINS 25-35, tall oil-asphalt sodium sulfonate 2-4, sylvic acid calcium 3-5, additive 6-8, water is appropriate,
Described additive is made up of following raw material: 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine 2-3, sodium cocoyl methyl Sodium taurine salt 1.5-2.5, Protanal Ester SD-LB 4-6, sodium polystyrene sulfonate 2-4, calcium lignin sulphonate 3-5, polymeric aluminium ferrum silicate 8-12, dickite 36-48, white cream mud 18-32, glass fibre 2-3; Preparation method is: (a) puts into pulverizer and pulverize after dickite and white cream mud being mixed, and crosses 100-150 mesh sieve; B powder mix that step (a) obtains by (), 1-isobutyl-3,5-dimethylhexylphosphoric acid trimethyl-glycine and sodium cocoyl methyl Sodium taurine salt mix, and add appropriate water and make the slurries that concentration is 40-50%, then under the rotating speed of 200-300r/min, stir 10-15min; C above-mentioned slurries are filtered post-drying by (), then mix with Protanal Ester SD-LB, sodium polystyrene sulfonate, calcium lignin sulphonate, polymeric aluminium ferrum silicate and obtain additive.
2. the preparation method of a kind of flame retardant flexible aerated-block according to claim 1, is characterized in that: be made up of following steps:
(1) Desert Sand, ceramic polished slag, paper white sludge are mixed, pulverize, cross 150-250 mesh sieve, add water and make the water content control of compound at 65-75%, then waste-tyre rubber-powder, active sludge dry powder, fowl bone meal, ordinary Portland cement is added, 600-1200r/min adds organosilicon microballoon, isocyanic ester, epoxy resin, tall oil-asphalt sodium sulfonate, sylvic acid calcium after grinding 15-20min, the water content adjusting compound after stirring again stirs 3-5min to 80-85%, 500-1000rpm;
(2) antimonous oxide, polyvinyl chloride (PVC) RESINS, dioctyl sebacate, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4, polyvinyl chloride (PVC) RESINS, aluminium powder, additive are added in the obtained slurry of step (1), foam after stirring 25-30min at 70-75 DEG C of temperature;
(3) in foamed slurry injection moulding mould step (2) obtained, natural curing 35-45h, form removal, obtains green compact;
(4) green compact step (3) obtained temperature be 55-65 DEG C, pressure be the condition of 0.5-1.0MPa under vapor cure 15-25h, obtain aerated-block finished product.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114349446A (en) * | 2022-02-17 | 2022-04-15 | 广西科技大学 | Papermaking white mud aerated concrete and preparation method thereof |
Citations (5)
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CN1088553A (en) * | 1993-12-14 | 1994-06-29 | 谢盈庭 | High-effect cement mortar, concrete consistence powder agent and preparation method thereof |
CN103449771A (en) * | 2013-08-05 | 2013-12-18 | 潘逸东 | Waterproof aerated brick |
CN104230280A (en) * | 2014-09-12 | 2014-12-24 | 武汉理工大学 | Low-shrinkage sludge ceramsite alkali-activated full-slag foam concrete plate and preparation method thereof |
CN104291739A (en) * | 2013-07-16 | 2015-01-21 | 中国地质大学(北京) | Method for preparing building blocks by using copper and titanium industry waste residue |
CN104591622A (en) * | 2015-01-06 | 2015-05-06 | 无为县严桥双龙建材厂 | Highly anti-bending and wearing-resistant lightweight concrete |
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- 2015-07-14 CN CN201510409196.4A patent/CN105000903A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1088553A (en) * | 1993-12-14 | 1994-06-29 | 谢盈庭 | High-effect cement mortar, concrete consistence powder agent and preparation method thereof |
CN104291739A (en) * | 2013-07-16 | 2015-01-21 | 中国地质大学(北京) | Method for preparing building blocks by using copper and titanium industry waste residue |
CN103449771A (en) * | 2013-08-05 | 2013-12-18 | 潘逸东 | Waterproof aerated brick |
CN104230280A (en) * | 2014-09-12 | 2014-12-24 | 武汉理工大学 | Low-shrinkage sludge ceramsite alkali-activated full-slag foam concrete plate and preparation method thereof |
CN104591622A (en) * | 2015-01-06 | 2015-05-06 | 无为县严桥双龙建材厂 | Highly anti-bending and wearing-resistant lightweight concrete |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114349446A (en) * | 2022-02-17 | 2022-04-15 | 广西科技大学 | Papermaking white mud aerated concrete and preparation method thereof |
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Application publication date: 20151028 |