CN105000759A - Imidacloprid waste water treating technology - Google Patents
Imidacloprid waste water treating technology Download PDFInfo
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- CN105000759A CN105000759A CN201510475334.9A CN201510475334A CN105000759A CN 105000759 A CN105000759 A CN 105000759A CN 201510475334 A CN201510475334 A CN 201510475334A CN 105000759 A CN105000759 A CN 105000759A
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- waste water
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- imidacloprid
- alkaline hydrolysis
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Abstract
The invention discloses an imidacloprid waste water treating technology and relates to the field of environmental protection. The imidacloprid waste water treating technology comprises the five steps of chemical phosphorus removal, alkaline hydrolysis, ammonia nitrogen air stripping, microelectrolysis and biochemical combination. The method is set out from the water quality characteristics of waste water, the design experience of treatment of degradation-resistant organic waste water including other kinds of pesticide waste water is used for reference, the practicability and the economical efficiency of the selected technology are taken into consideration, the technical route of chemical phosphorus removal, alkaline hydrolysis, ammonia nitrogen air stripping, microelectrolysis and biochemical combination is determined, and finally the quality of the treated water can reach a very high level.
Description
Technical field
The present invention relates to field of Environment Protection, be specifically related to a kind of imidacloprid wastewater treatment process.
Background technology
Provado is efficient with it, the feature of low toxicity, low residue, becomes the representative of agricultural chemicals of new generation, has good market outlook.But but there is no ripe technique to the process of its factory effluent can follow, and the not qualified discharge of this waste water, causes serious pollution to environment.Therefore, not only can remove difficulties and alleviate sufferings for enterprise to the research of Provado factory effluent Processing tecchnics, a kind of effective process means can also be sought for the improvement of high concentration hard-degraded organic waste water.
The feature such as high according to its organic concentration, water quality is complicated, biodegradability is poor, adopts chemical dephosphorization-alkaline hydrolysis-ammonia-nitrogen desorption-light electrolysis-biochemistry combination process to administer this waste water.
Summary of the invention
Problem to be solved by this invention is to provide a kind of imidacloprid wastewater treatment process.
To achieve these goals, the technical scheme that the present invention takes is a kind of imidacloprid wastewater treatment process, comprises the steps:
(1) chemical dephosphorization: utilize precipitation agent process imidacloprid wastewater, is formed insoluble phosphate precipitation, is then removed from sewage by phosphorus by solid-liquid separation;
(2) alkaline hydrolysis: utilize 20%NaOH solution to dissolve in step (1) waste water afterwards, be placed in 30-60 DEG C of thermostat water bath, keeps 1-3h;
(3) ammonia-nitrogen desorption: utilize 20%NaOH solution regulating step (3) waste water ph within the scope of 7-10, recycling oxygen dissolved aerator carries out static stripping, can realize the removal of ammonia nitrogen;
(4) light electrolysis: utilize dilute hydrochloric acid that the water after step (3) is regulated initial pH to 7-10, then be placed in light electrolysis post and carry out static aeration;
(5) biochemical combination: utilize the waste water after active bacteria liquid biofilm treatment step (4) of configuration.
Preferably, the precipitation agent that described step (1) uses is the one in aluminium salt, calcium salt and molysite or arbitrary combination.
Preferably, described step (2) alkaline hydrolysis temperature is 40-50 DEG C.
Adopt technical scheme of the present invention, the present invention is from the water quality characteristic of waste water, use for reference the design experiences of the organic wastewater with difficult degradation thereby improvement comprising other kind agricultural chemicals waste water, take into account the practicality of selected technique, economy, determine chemical dephosphorization-alkaline hydrolysis-ammonia-nitrogen desorption-light electrolysis-biochemistry combination process route, after finally making process, effluent quality reaches very high level.
Embodiment
The technique means realized for making the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with embodiment, setting forth the present invention further.
Embodiment 1:
(1) chemical dephosphorization: utilize precipitation agent process imidacloprid wastewater, is formed insoluble phosphate precipitation, is then removed from sewage by phosphorus by solid-liquid separation;
(2) alkaline hydrolysis: utilize 20%NaOH solution to dissolve in step (1) waste water afterwards, be placed in 45 DEG C of thermostat water baths, keeps 1h;
(3) ammonia-nitrogen desorption: utilize 20%NaOH solution regulating step (3) waste water ph 8, recycling oxygen dissolved aerator carries out static stripping, can realize the removal of ammonia nitrogen;
(4) light electrolysis: utilize dilute hydrochloric acid to regulate initial pH value to 8 in the water after step (3), then be placed in light electrolysis post and carry out static aeration;
(5) biochemical combination: utilize the waste water after active bacteria liquid biofilm treatment step (4) of configuration.
Based on above-mentioned, the present invention is from the water quality characteristic of waste water, use for reference the design experiences of the organic wastewater with difficult degradation thereby improvement comprising other kind agricultural chemicals waste water, take into account the practicality of selected technique, economy, determine chemical dephosphorization-alkaline hydrolysis-ammonia-nitrogen desorption-light electrolysis-biochemistry combination process route, after finally making process, effluent quality reaches very high level.
Obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.
Claims (3)
1. an imidacloprid wastewater treatment process, is characterized in that: comprise the steps:
(1) chemical dephosphorization: utilize precipitation agent process imidacloprid wastewater, is formed insoluble phosphate precipitation, is then removed from sewage by phosphorus by solid-liquid separation;
(2) alkaline hydrolysis: utilize 20%NaOH solution to dissolve in step (1) waste water afterwards, be placed in 30-60 DEG C of thermostat water bath, keeps 1-3h;
(3) ammonia-nitrogen desorption: utilize 20%NaOH solution regulating step (3) waste water ph within the scope of 7-10, recycling oxygen dissolved aerator carries out static stripping, can realize the removal of ammonia nitrogen;
(4) light electrolysis: utilize dilute hydrochloric acid that the water after step (3) is regulated initial pH to 7-10, then be placed in light electrolysis post and carry out static aeration;
(5) biochemical combination: utilize the waste water after active bacteria liquid biofilm treatment step (4) of configuration.
2. a kind of imidacloprid wastewater treatment process according to claim 1, is characterized in that: the precipitation agent that described step (1) uses is the one in aluminium salt, calcium salt and molysite or arbitrary combination.
3. a kind of imidacloprid wastewater treatment process according to claim 1, is characterized in that: described step (2) alkaline hydrolysis temperature is 40-50 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510475334.9A CN105000759A (en) | 2015-08-05 | 2015-08-05 | Imidacloprid waste water treating technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510475334.9A CN105000759A (en) | 2015-08-05 | 2015-08-05 | Imidacloprid waste water treating technology |
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| CN105000759A true CN105000759A (en) | 2015-10-28 |
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| CN201510475334.9A Pending CN105000759A (en) | 2015-08-05 | 2015-08-05 | Imidacloprid waste water treating technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110143659A (en) * | 2019-05-25 | 2019-08-20 | 天津金辰博科环保科技发展有限公司 | A kind of sewage denitrification and dephosphorization agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040318A (en) * | 2010-11-28 | 2011-05-04 | 江苏蓝星环保科技有限公司 | Imidacloprid pesticide wastewater treatment method |
| CN103145302A (en) * | 2013-03-27 | 2013-06-12 | 南京工业大学 | Pre-treatment process of imidacloprid wastewater |
| KR101372416B1 (en) * | 2013-04-10 | 2014-03-11 | 한국원자력연구원 | Multiple feeding of influent in the bio-electrochemical waste-water treating apparatus and treatment method of waste-water using the same |
| CN103937722A (en) * | 2014-04-24 | 2014-07-23 | 烟台海上传奇生物科技有限公司 | Ochrobactrum intermedium, microbial agent and applications of ochrobactrum intermedium and microbial agent |
| CN104150567A (en) * | 2014-06-04 | 2014-11-19 | 盐城工学院 | Method for electrochemical pretreatment of imidacloprid pesticide wastewater |
-
2015
- 2015-08-05 CN CN201510475334.9A patent/CN105000759A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040318A (en) * | 2010-11-28 | 2011-05-04 | 江苏蓝星环保科技有限公司 | Imidacloprid pesticide wastewater treatment method |
| CN103145302A (en) * | 2013-03-27 | 2013-06-12 | 南京工业大学 | Pre-treatment process of imidacloprid wastewater |
| KR101372416B1 (en) * | 2013-04-10 | 2014-03-11 | 한국원자력연구원 | Multiple feeding of influent in the bio-electrochemical waste-water treating apparatus and treatment method of waste-water using the same |
| CN103937722A (en) * | 2014-04-24 | 2014-07-23 | 烟台海上传奇生物科技有限公司 | Ochrobactrum intermedium, microbial agent and applications of ochrobactrum intermedium and microbial agent |
| CN104150567A (en) * | 2014-06-04 | 2014-11-19 | 盐城工学院 | Method for electrochemical pretreatment of imidacloprid pesticide wastewater |
Non-Patent Citations (4)
| Title |
|---|
| 杨晓燕等: "微电解-芬顿法预处理吡虫啉农药生产废水", 《南京工业大学学报(自然科学版)》 * |
| 陆雪梅等: "应用钙法除磷-碱解-微电解组合工艺预处理吡虫啉农药废水", 《环境工程学报》 * |
| 陈雷等: "碱解―微电解工艺对吡虫啉农药生产废水预处理的研究", 《工业水处理》 * |
| 马维峥: "吡虫啉农药生产废水治理工艺的研究", 《中国优秀博硕士学位论文全文数据库（硕士） 工程科技Ⅰ辑》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110143659A (en) * | 2019-05-25 | 2019-08-20 | 天津金辰博科环保科技发展有限公司 | A kind of sewage denitrification and dephosphorization agent and preparation method thereof |
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Application publication date: 20151028 |