CN105000651A - Electroplating wastewater treatment agent - Google Patents
Electroplating wastewater treatment agent Download PDFInfo
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- CN105000651A CN105000651A CN201510526513.0A CN201510526513A CN105000651A CN 105000651 A CN105000651 A CN 105000651A CN 201510526513 A CN201510526513 A CN 201510526513A CN 105000651 A CN105000651 A CN 105000651A
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Abstract
The invention discloses an electroplating wastewater treatment agent, consisting of a reducing agent, a composite flocculant, a heavy metal ion collector DTCR, starch xanthate, cross-linked rectorite, quaternary ammonium salt lignin, sodium silicate, an alkaline substance and an adsorption filler. According to the treatment agent, the materials realize a synergistic effect, multiple heavy metal ions can be effectively removed, heavy metal ions with multiple ions coexisting also can be effectively removed, the treatment effect on electroplating wastewater is excellent, the performance is stable, the sedimentation effect is good, and the sedimentation speed is high; besides, the electroplating wastewater treatment agent is reasonable in ratio, non-poisonous and free of environment pollution.
Description
Technical field
The present invention relates to water-treatment technology field, specifically a kind of compound for treatment of electroplating wastes.
Background technology
There are plating piece rinse water, spent plating bath and other waste water in the source of electroplating wastewater.The water quality of electroplating wastewater, the water yield and the processing condition of Electroplating Production, the factors such as load, operational administrative and water use model of producing are relevant.The water quality of electroplating wastewater is complicated, and composition is wayward, and wherein containing heavy metal ion and prussiates etc. such as chromium, good fortune, nickel, copper, zinc, gold and silver, waste component is complicated.
The method for comprehensively treating waste liquid that current electroplating wastewater adopts has a lot, as chemical method, ion exchange method, electroosmose process, electrolytic process etc., wherein chemical method is the method comparatively commonly used, it adds reductive agent (as ferrous sulfate, iron powder etc.) in containing the waste water of hexavalent chromium, after hexavalent chrome reduction is become trivalent chromium, add waste water conditioner sodium hydroxide, the pH value of adjustment waste water, heavy metal ion in fractionation precipitation waste water, finally also needs could be discharged by the supernatant liquor pH value of acid adding adjustment after precipitation.Adopt such waste water conditioner process electroplating wastewater, there is the shortcoming that raw material dosage is large, sewage treatment technology process long, occupation of land is many, energy consumption large, operational management difficulty is large, labor strength is large and running cost is high, but also can not ensure that wastewater treatment stably runs.
Therefore, need provide a kind of and reduce processing cost, treatment effect stablizes and the compound for treatment of electroplating wastes of non-secondary pollution.
Summary of the invention
The object of the present invention is to provide a kind of compound for treatment of electroplating wastes, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of compound for treatment of electroplating wastes, be made up of the raw material of following weight part: reductive agent 30 ~ 36 parts, composite flocculation agent 30 ~ 40 parts, heavy metal capturing agent DTCR12 ~ 16 part, starch xanthate 18 ~ 22 parts, cross-linked rectorite 22 ~ 24 parts, 18 ~ 24 parts, quaternary ammonium salt xylogen, water glass 16 ~ 20 parts, alkaline matter 25 ~ 35 parts, adsorption stuffing 30 ~ 40 parts.
As the further scheme of the present invention: described reductive agent is that 2 ~ 4:1 forms by sodium sulphite and ferrous sulfate in mass ratio.
As the further scheme of the present invention: described composite flocculation agent is made up of for 1:1:3 ~ 5 in mass ratio polyacrylamide, sodium polyacrylate and aluminum chloride.
As the further scheme of the present invention: described alkaline matter is made up of for 1:2 ~ 4 in mass ratio sodium hydroxide and calcium hydroxide.
As the present invention's further scheme: described adsorption stuffing is the one in diatomite, gac, kaolin, flyash or wilkinite.
Compared with prior art, the invention has the beneficial effects as follows: each raw material for the treatment of agent of the present invention plays synergy, effectively can remove contents of many kinds of heavy metal ion, also the heavy metal ion that different kinds of ions coexists can effectively be removed, very good to the treatment effect of electroplating wastewater, and stable performance, sedimentation effect is good, and precipitation is fast; And treatment agent reasonable ratio of the present invention, nontoxic, environmentally safe.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
A kind of compound for treatment of electroplating wastes, is made up of the raw material of following weight part: reductive agent 30 parts, composite flocculation agent 30 parts, heavy metal capturing agent DTCR16 part, starch xanthate 22 parts, cross-linked rectorite 22 parts, 24 parts, quaternary ammonium salt xylogen, water glass 16 parts, alkaline matter 35 parts, 30 parts, diatomite.
Wherein, reductive agent by sodium sulphite and ferrous sulfate in mass ratio for 2:1 forms.
Composite flocculation agent by polyacrylamide, sodium polyacrylate and aluminum chloride in mass ratio for 1:1:3 forms.
Alkaline matter by sodium hydroxide and calcium hydroxide in mass ratio for 1:2 forms.
Embodiment 2
A kind of compound for treatment of electroplating wastes, is made up of the raw material of following weight part: reductive agent 33 parts, composite flocculation agent 35 parts, heavy metal capturing agent DTCR14 part, starch xanthate 20 parts, cross-linked rectorite 23 parts, 22 parts, quaternary ammonium salt xylogen, water glass 18 parts, alkaline matter 30 parts, kaolin 35 parts.
Wherein, reductive agent by sodium sulphite and ferrous sulfate in mass ratio for 3:1 forms.
Composite flocculation agent by polyacrylamide, sodium polyacrylate and aluminum chloride in mass ratio for 1:1:4 forms.
Alkaline matter by sodium hydroxide and calcium hydroxide in mass ratio for 1:3 forms.
Embodiment 3
A kind of compound for treatment of electroplating wastes, is made up of the raw material of following weight part: reductive agent 36 parts, composite flocculation agent 40 parts, heavy metal capturing agent DTCR12 part, starch xanthate 18 parts, cross-linked rectorite 24 parts, 18 parts, quaternary ammonium salt xylogen, water glass 20 parts, alkaline matter 25 parts, wilkinite 30 parts.
Wherein, reductive agent by sodium sulphite and ferrous sulfate in mass ratio for 4:1 forms.
Composite flocculation agent by polyacrylamide, sodium polyacrylate and aluminum chloride in mass ratio for 1:1:5 forms.
Alkaline matter by sodium hydroxide and calcium hydroxide in mass ratio for 1:4 forms.
Embodiment 4
A kind of compound for treatment of electroplating wastes, is made up of the raw material of following weight part: reductive agent 35 parts, composite flocculation agent 33 parts, heavy metal capturing agent DTCR13 part, starch xanthate 21 parts, cross-linked rectorite 23 parts, 21 parts, quaternary ammonium salt xylogen, water glass 19 parts, alkaline matter 28 parts, gac 38 parts.
Reductive agent by sodium sulphite and ferrous sulfate in mass ratio for 2:1 forms.
Composite flocculation agent by polyacrylamide, sodium polyacrylate and aluminum chloride in mass ratio for 1:1:5 forms.
Alkaline matter by sodium hydroxide and calcium hydroxide in mass ratio for 1:2 forms.
Experimental example: the compound for treatment of electroplating wastes prepared by above-described embodiment 1-4 carries out electroplating wastewater processing, and treatment effect is as follows, unit (mg/L).
As can be known from the above table, compound for treatment of electroplating wastes of the present invention is to COD, SS, the Zn in electroplating wastewater
2+, Cu
2+, Pb
2+, Ni
2+, Cr
6+, manganese, mercury all has very high clearance, treatment effect is good.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
Claims (5)
1. a compound for treatment of electroplating wastes, it is characterized in that, be made up of the raw material of following weight part: reductive agent 30 ~ 36 parts, composite flocculation agent 30 ~ 40 parts, heavy metal capturing agent DTCR12 ~ 16 part, starch xanthate 18 ~ 22 parts, cross-linked rectorite 22 ~ 24 parts, 18 ~ 24 parts, quaternary ammonium salt xylogen, water glass 16 ~ 20 parts, alkaline matter 25 ~ 35 parts, adsorption stuffing 30 ~ 40 parts.
2. compound for treatment of electroplating wastes according to claim 1, is characterized in that, reductive agent is that 2 ~ 4:1 forms by sodium sulphite and ferrous sulfate in mass ratio.
3. compound for treatment of electroplating wastes according to claim 1, is characterized in that, described composite flocculation agent is made up of for 1:1:3 ~ 5 in mass ratio polyacrylamide, sodium polyacrylate and aluminum chloride.
4. compound for treatment of electroplating wastes according to claim 1, is characterized in that, described alkaline matter is made up of for 1:2 ~ 4 in mass ratio sodium hydroxide and calcium hydroxide.
5. compound for treatment of electroplating wastes according to claim 1, is characterized in that, described adsorption stuffing is the one in diatomite, gac, kaolin, flyash or wilkinite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510526513.0A CN105000651A (en) | 2015-08-25 | 2015-08-25 | Electroplating wastewater treatment agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510526513.0A CN105000651A (en) | 2015-08-25 | 2015-08-25 | Electroplating wastewater treatment agent |
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| CN105000651A true CN105000651A (en) | 2015-10-28 |
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| CN201510526513.0A Pending CN105000651A (en) | 2015-08-25 | 2015-08-25 | Electroplating wastewater treatment agent |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105347505A (en) * | 2015-11-10 | 2016-02-24 | 太仓中化环保化工有限公司 | Fluorine-containing heavy-metal-ion-containing waste water processing agent and fluorine-containing heavy-metal-ion-containing waste water processing method |
| CN105384201A (en) * | 2015-12-11 | 2016-03-09 | 马鞍山清净环保科技有限公司 | Treatment agent for treating heavy metal sewage, and preparation method and application thereof |
| CN105399159A (en) * | 2015-12-16 | 2016-03-16 | 江苏盖亚环境工程有限公司 | Electroplating wastewater treatment agent and preparation method thereof |
| CN105413650A (en) * | 2016-01-07 | 2016-03-23 | 苏州法斯特信息科技有限公司 | Rectorite wastewater adsorption material and preparation method thereof |
| CN105692771A (en) * | 2016-04-21 | 2016-06-22 | 苏州云舒新材料科技有限公司 | Material for treating wastewater containing heavy metal |
| CN105731616A (en) * | 2016-01-22 | 2016-07-06 | 南通海陵环境检测有限公司 | Printing and dyeing wastewater decoloration flocculating agent and preparation method thereof |
| CN105858748A (en) * | 2016-05-31 | 2016-08-17 | 陈萍 | Wastewater treating agent special for waste lithium battery electrolyte and preparation method of wastewater treating agent |
| CN105858756A (en) * | 2016-05-31 | 2016-08-17 | 陈萍 | Sewage treatment agent special for electroplating and preparation method thereof |
| CN106186151A (en) * | 2015-12-11 | 2016-12-07 | 马鞍山清净环保科技有限公司 | The processing method of a kind of heavy metal containing sewage and the sewage-treating agent of employing thereof and application |
| CN106334542A (en) * | 2016-10-21 | 2017-01-18 | 黄景珍 | Composite chelating agent and preparation method thereof |
| CN106365225A (en) * | 2016-11-22 | 2017-02-01 | 镇江市和云工业废水处置有限公司 | Electroplating wastewater treating agent |
| CN106365287A (en) * | 2016-11-22 | 2017-02-01 | 镇江市和云工业废水处置有限公司 | Wastewater treating agent for electroplating |
| CN107311248A (en) * | 2017-07-19 | 2017-11-03 | 湖南沃邦环保科技有限公司 | A kind of electroplating wastewater with heavy metal ions processing inorganic agent and preparation method thereof |
| CN107585918A (en) * | 2017-10-20 | 2018-01-16 | 中山市中康化工科技有限公司 | A kind of efficient water treatment agent |
| CN107777785A (en) * | 2017-11-30 | 2018-03-09 | 天峨县平昌生态农业有限公司 | Silk reeling wastewater inorganic agent and preparation method thereof |
| CN108589337A (en) * | 2018-04-08 | 2018-09-28 | 南宁市夏阳化工科技有限责任公司 | A kind of reactive dye alkali and preparation method thereof |
| CN109136932A (en) * | 2018-07-03 | 2019-01-04 | 南京舜业环保科技有限公司 | A kind of regeneration treatment agent and preparation method thereof for sulfur acid etching waste liquor |
| CN109694113A (en) * | 2019-01-31 | 2019-04-30 | 环境保护部华南环境科学研究所 | Inorganic agent for coupling processing electroplating wastewater contents of many kinds of heavy metal ion |
| CN112694159A (en) * | 2019-10-22 | 2021-04-23 | 中国石油化工股份有限公司 | Wastewater treatment agent containing metal sulfide and wastewater treatment method |
-
2015
- 2015-08-25 CN CN201510526513.0A patent/CN105000651A/en active Pending
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105347505A (en) * | 2015-11-10 | 2016-02-24 | 太仓中化环保化工有限公司 | Fluorine-containing heavy-metal-ion-containing waste water processing agent and fluorine-containing heavy-metal-ion-containing waste water processing method |
| CN105384201A (en) * | 2015-12-11 | 2016-03-09 | 马鞍山清净环保科技有限公司 | Treatment agent for treating heavy metal sewage, and preparation method and application thereof |
| CN106186151A (en) * | 2015-12-11 | 2016-12-07 | 马鞍山清净环保科技有限公司 | The processing method of a kind of heavy metal containing sewage and the sewage-treating agent of employing thereof and application |
| CN105399159A (en) * | 2015-12-16 | 2016-03-16 | 江苏盖亚环境工程有限公司 | Electroplating wastewater treatment agent and preparation method thereof |
| CN105413650A (en) * | 2016-01-07 | 2016-03-23 | 苏州法斯特信息科技有限公司 | Rectorite wastewater adsorption material and preparation method thereof |
| CN105731616A (en) * | 2016-01-22 | 2016-07-06 | 南通海陵环境检测有限公司 | Printing and dyeing wastewater decoloration flocculating agent and preparation method thereof |
| CN105692771B (en) * | 2016-04-21 | 2018-11-23 | 苏州云舒新材料科技有限公司 | A kind of heavy metal-polluted water process material |
| CN105692771A (en) * | 2016-04-21 | 2016-06-22 | 苏州云舒新材料科技有限公司 | Material for treating wastewater containing heavy metal |
| CN105858748A (en) * | 2016-05-31 | 2016-08-17 | 陈萍 | Wastewater treating agent special for waste lithium battery electrolyte and preparation method of wastewater treating agent |
| CN105858756A (en) * | 2016-05-31 | 2016-08-17 | 陈萍 | Sewage treatment agent special for electroplating and preparation method thereof |
| CN106334542A (en) * | 2016-10-21 | 2017-01-18 | 黄景珍 | Composite chelating agent and preparation method thereof |
| CN106365225A (en) * | 2016-11-22 | 2017-02-01 | 镇江市和云工业废水处置有限公司 | Electroplating wastewater treating agent |
| CN106365287A (en) * | 2016-11-22 | 2017-02-01 | 镇江市和云工业废水处置有限公司 | Wastewater treating agent for electroplating |
| CN107311248A (en) * | 2017-07-19 | 2017-11-03 | 湖南沃邦环保科技有限公司 | A kind of electroplating wastewater with heavy metal ions processing inorganic agent and preparation method thereof |
| CN107585918A (en) * | 2017-10-20 | 2018-01-16 | 中山市中康化工科技有限公司 | A kind of efficient water treatment agent |
| CN107777785A (en) * | 2017-11-30 | 2018-03-09 | 天峨县平昌生态农业有限公司 | Silk reeling wastewater inorganic agent and preparation method thereof |
| CN108589337A (en) * | 2018-04-08 | 2018-09-28 | 南宁市夏阳化工科技有限责任公司 | A kind of reactive dye alkali and preparation method thereof |
| CN108589337B (en) * | 2018-04-08 | 2021-09-24 | 广西夏阳环保科技有限公司 | Alkali for reactive dye and preparation method thereof |
| CN109136932A (en) * | 2018-07-03 | 2019-01-04 | 南京舜业环保科技有限公司 | A kind of regeneration treatment agent and preparation method thereof for sulfur acid etching waste liquor |
| CN109694113A (en) * | 2019-01-31 | 2019-04-30 | 环境保护部华南环境科学研究所 | Inorganic agent for coupling processing electroplating wastewater contents of many kinds of heavy metal ion |
| CN112694159A (en) * | 2019-10-22 | 2021-04-23 | 中国石油化工股份有限公司 | Wastewater treatment agent containing metal sulfide and wastewater treatment method |
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Application publication date: 20151028 |
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| WD01 | Invention patent application deemed withdrawn after publication |