CN104988352B - Alpaka alloy and its component - Google Patents
Alpaka alloy and its component Download PDFInfo
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- CN104988352B CN104988352B CN201510399282.1A CN201510399282A CN104988352B CN 104988352 B CN104988352 B CN 104988352B CN 201510399282 A CN201510399282 A CN 201510399282A CN 104988352 B CN104988352 B CN 104988352B
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- alpaka
- alpaka alloy
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Abstract
The invention belongs to technical field of alloy material, more particularly, to a kind of Alpaka alloy and its component.It solves existing manufacturing cost height, the technical problems such as mechanical performance deficiency.This Alpaka alloy component includes following quality components: Ni 10-12%;Fe is 1.5-1.8%;Mn is 0.6-0.9%;Pb is 0-0.025%;Zn is 0-0.25%;P is 0-0.025%;C is 0.0035-0.0045%;S is 0.004-0.005%;Al is 0-1.2%;Remaining is Gu.Compared with prior art, this Alpaka alloy and its advantages of component are: nickel content is lower, and material cost can be greatly reduced, reduce cost.Good mechanical performance realizes balance between material cost and mechanical performance.
Description
Technical field
The invention belongs to technical field of alloy material, more particularly, to a kind of Alpaka alloy and its component.
Background technique
Alpaka is the acid bronze alloy using nickel as main adding elements, is silvery white in color, and has metallic luster, therefore named Alpaka.
Can be infinitely dissolved each other between cupro-nickel, to form continuous solid solution, though that is, mutual ratio how much, and permanent is the single-phase conjunction of α-
Gold.It is fused into red metal when nickel, when content is more than 16% or more, the alloy color of generation just becomes pure white as silver-colored, and nickel content is got over
Height, color are whiter.The content of nickel is generally 25% in Alpaka.Pure copper plus nickel can significantly improve intensity, corrosion resistance, hardness, electricity
Resistance and pyroelectricity, and reduce temperature coefficient of resistivity.Therefore Alpaka is all different compared with the mechanical performance of other copper alloys, physical property
It is often good, ductility is good, hardness is high, it is in beautiful color, corrosion-resistant, rich in deep drawability, be widely used in shipbuilding, petroleum
The fields such as work, electric appliance, instrument, medical instrument, daily necessities, craftwork, and also it is important resistance and thermocouple metal.Alpaka
The shortcomings that be that main adding elements-nickel belongs to rare strategic materials, price is more expensive.
For example, Chinese patent literature disclose a kind of ferrimanganic copper-nickel tube preparation method [application number:
200910185341.X], the weight percent of the ferrimanganic copper-nickel tube each element are as follows: nickel 29-32%, manganese 1.5-2.5%, iron
1.7-2.3%, mischmetal 0.008%, surplus are cathode copper, and the summation of each element is 100%.The mischmetal by lanthanum,
Cerium and yttrium are by lanthanum: cerium: yttrium=2: 2: 1 weight ratio mixes.Preparation method comprises the following steps that: take cathode copper,
Nickel, manganese and iron are placed in low-frequency electric furnace, and heating is vibrated, and mischmetal is added in melting, are cast using the method for horizontal casting
Cause solid billet;Heating, is squeezed into shell;Rolling;It stretches;Pickling;Multi-pass stretching is carried out, until finished product, finished product move back
Fire.The present invention can be improved the surface quality of billet, and refining alloy crystal grain, mention due to being added to mischmetal in the alloy
High cold working performance can add better manganese and iron in the alloy, and high manganese high-speed rail can greatly improve ferrimanganic copper-nickel tube
Corrosion-resistant and flushing resistance.
Obviously, in above scheme nickel too high levels, lead to higher cost, economy is poor.On the other hand, although having
Preferable corrosion-resistant and flushing resistance, but affect other mechanical performances.
Summary of the invention
Regarding the issue above, the present invention provides a kind of nickel content is lower, rationally, material cost is passed through for component configuration
The Alpaka alloy component of Ji.
Further object of the present invention is to provide a kind of good mechanical property, the low Alpaka alloy of manufacturing cost.
In order to achieve the above objectives, present invention employs following technical proposals: this Alpaka alloy component, which is characterized in that
This Alpaka alloy component includes following quality components: Ni 10-12%;Fe is 1.5-1.8%;Mn is 0.6-0.9%;Pb is
0-0.025%;Zn is 0-0.25%;P is 0-0.025%;C is 0.0035-0.0045%;S is 0.004-0.005%;Al is
0-1.2%;Remaining is Gu.
In above-mentioned Alpaka alloy component, this Alpaka alloy component includes following quality components: Ni is
10.30%;Fe is 1.65%;Mn is 0.79%;Pb is 0-0.02%;Zn is 0-0.2%;P is 0-0.02%;C is
0.0039%;S is 0.0045%;Al is 0;Remaining is Gu.
In above-mentioned Alpaka alloy component, the Pb is 0-0.01%;Zn is 0.10%;The P is
0.01%.
In above-mentioned Alpaka alloy component, this Alpaka alloy component includes following quality components: Ni is
10.30%;Fe is 1.65%;Mn is 0.79%;Pb is 0-0.02%;Zn is 0-0.2%;P is 0-0.02%;C is
0.0039%;S is 0.0045%;Al is 1.2%;Remaining is Gu.
It is a kind of to use Alpaka alloy made from above-mentioned Alpaka alloy component.
In above-mentioned Alpaka alloy, the mechanical performance of the Alpaka alloy is as follows: Rm 341-338N/mm2;
A is 51-52%;Rp0.2 is 129-131N/mm2;Hardness is 105-108HBW.
In above-mentioned Alpaka alloy, the Rm is 340N/mm2;A is 51.5%;Rp0.2 is 130N/mm2;Hardness
For 108HBW.
Compared with prior art, this Alpaka alloy and its advantages of component are: nickel content is lower, can substantially drop
Low material cost, reduces cost.Good mechanical performance realizes balance between material cost and mechanical performance.
Specific embodiment
Embodiment 1:
This Alpaka alloy component includes following quality components: Ni 10-12%;Fe is 1.5-1.8%;Mn is 0.6-
0.9%;Pb is 0-0.025%;Zn is 0-0.25%;P is 0-0.025%;C is 0.0035-0.0045%;S is 0.004-
0.005%;Al is 0-1.2%;Remaining is Gu.Preferably, this Alpaka alloy component includes following quality components: Ni is
10.30%;Fe is 1.65%;Mn is 0.79%;Pb is 0-0.02%;Zn is 0-0.2%;P is 0-0.02%;C is
0.0039%;S is 0.0045%;Al is 0;Remaining is Gu.Wherein, the Pb is 0-0.01%;Zn is 0.10%;Described
P is 0.01%.Using Alpaka alloy made from above-mentioned Alpaka alloy component, the mechanical performance of Alpaka alloy is as follows: Rm
For 341-338N/mm2;A is 51-52%;Rp0.2 is 129-131N/mm2;Hardness is 105-108HBW.
Melting will be carried out according to the raw material of above-mentioned quality component investment smelting furnace, will just refine obtained liquid metal melt and pour into
In container, then by the calmness of liquid metal melt at least 25 minutes, and implement to stir at least once during calmness, by liquid gold
Belong to the impurity removal in melt;Finally the liquid metal melt after calmness is cast, obtains Alpaka alloy.Pass through calmness
The temperature of liquid metal melt can be made to decline, while escape gas, impurity floats, to effectively improve Alpaka conjunction
Golden performance.In the present invention, the calm time of liquid metal melt is longer, while liquid metal melt is implemented during calmness
Stirring can further promote gas evolution and impurity to float.In addition, stirring liquid metal melt can make liquid metal melt
Temperature is uniform, avoids the occurrence of temperature uneven phenomenon, while stirring is also beneficial to gas evolution and impurity floats.When stirring here
Between and stirring number determine as needed.By above-mentioned long-time calmness and long agitation, so that Alpaka alloy structure is equal
It is even, crystal grain refinement.During calmness, other metallic elements can also be added as needed, so that the Alpaka needed for obtaining closes
Gold.Pushing off the slag and pre-deoxidation can be carried out in casting process.
The preferred calmness time is -35 minutes 25 minutes.In the present embodiment, the calm time is divided into 3 periods,
An intermediate period implements the stirring of liquid metal melt.Stirring can be carried out by graphite rod, the graphite rod and blender phase
Connection.The calm time of optimization is 30 minutes, implements the stirring of liquid metal melt at 11-20 minutes.
Embodiment 2:
In the present embodiment, this Alpaka alloy component includes following quality components: Ni 10.30%;Fe is 1.65%;Mn
It is 0.79%;Pb is 0-0.02%;Zn is 0-0.2%;P is 0-0.02%;C is 0.0039%;S is 0.0045%;Al is
1.2%;Remaining is Gu.Using Alpaka alloy made from above-mentioned Alpaka alloy component, the mechanical performance of Alpaka alloy is such as
Under: the Rm is 340N/mm2;A is 51.5%;Rp0.2 is 130N/mm2;Hardness is 108HBW.
The Alpaka alloy melting process and embodiment 1 of the present embodiment are similar, do not repeat them here herein.
Specific embodiment described herein is only an example for the spirit of the invention.The neck of technology belonging to the present invention
The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method
In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
Although term is used more herein, it does not exclude the possibility of using other terms.Use these terms
It is only to be more convenient to describe and explain essence of the invention;Being construed as any additional limitation all is and this
What spirit was disagreed.
Claims (4)
1. a kind of Alpaka alloy component, which is characterized in that this Alpaka alloy component includes following quality components: Ni is
10.30%;Fe is 1.65%;Mn is 0.79%;Pb is 0-0.02%;Zn is 0-0.2%;P is 0-0.02%;C is
0.0039%;S is 0.0045%;Al is 0 or 1.2%;Remaining is Cu;By according to the raw material of above-mentioned quality component put into smelting furnace into
Row melting will just be refined obtained liquid metal melt and be poured into container, then by -35 points of calm 25 minutes of liquid metal melt
Clock, and implement to stir at least once during calmness, the impurity in liquid metal melt is removed;Finally by the liquid after calmness
Molten metal is cast, and Alpaka alloy is obtained;The calm time is divided into 3 periods, in an intermediate period reality
Apply the stirring of liquid metal melt;Pushing off the slag and pre-deoxidation are carried out in casting process;The mechanical performance of the Alpaka alloy is such as
Under: Rm 341-338N/mm2;A is 51-52%;Rp0.2 is 129-131N/mm2;Hardness is 105-108HBW.
2. Alpaka alloy component according to claim 1, which is characterized in that the Pb is 0-0.01%;Zn is
0.10%;The P is 0.01%.
3. Alpaka alloy made from Alpaka alloy component described in any one of -2 according to claim 1.
4. Alpaka alloy according to claim 3, which is characterized in that the Rm is 340N/mm2;A is 51.5%;
Rp0.2 is 130N/mm2;Hardness is 108HBW.
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CN201510399282.1A CN104988352B (en) | 2015-07-06 | 2015-07-06 | Alpaka alloy and its component |
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CN104988352B true CN104988352B (en) | 2019-03-05 |
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DE102010019563A1 (en) * | 2010-05-05 | 2011-11-10 | Kme Germany Ag & Co. Kg | Corrosion protection arrangement for offshore steel structures and a method for its application |
CN102732746A (en) * | 2012-07-18 | 2012-10-17 | 宁波兴业盛泰集团有限公司 | Novel erosion resistant cupronickel alloy and preparation method thereof |
JP6263333B2 (en) * | 2013-03-25 | 2018-01-17 | Dowaメタルテック株式会社 | Cu-Ti copper alloy sheet, method for producing the same, and current-carrying component |
CN104651661A (en) * | 2013-11-21 | 2015-05-27 | 青岛润鑫伟业科贸有限公司 | Novel iron-white copper alloy |
CN103740977B (en) * | 2014-01-16 | 2016-01-20 | 九星控股集团有限公司 | A kind of corrosion-resistant White Copper Tubes and preparation method thereof |
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Inventor after: He Shaoying Inventor after: Chen Xiaojun Inventor before: He Shaoying Inventor before: Li Xiaojun |
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Granted publication date: 20190305 Termination date: 20200706 |