CN104983033A - 一种食品抗氧化剂 - Google Patents
一种食品抗氧化剂 Download PDFInfo
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- 235000019261 food antioxidant Nutrition 0.000 title claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 23
- 239000003963 antioxidant agent Substances 0.000 abstract description 21
- 235000006708 antioxidants Nutrition 0.000 abstract description 21
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract description 14
- 235000013305 food Nutrition 0.000 abstract description 11
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 abstract description 6
- 229930003268 Vitamin C Natural products 0.000 abstract description 6
- 235000019154 vitamin C Nutrition 0.000 abstract description 6
- 239000011718 vitamin C Substances 0.000 abstract description 6
- -1 lanostane compound Chemical class 0.000 abstract description 5
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001509 sodium citrate Substances 0.000 abstract description 4
- 239000003508 Dilauryl thiodipropionate Substances 0.000 abstract description 3
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 abstract description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 230000035943 smell Effects 0.000 abstract 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 abstract 1
- 235000010262 sodium metabisulphite Nutrition 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- 239000004519 grease Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- 238000006701 autoxidation reaction Methods 0.000 description 2
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000013332 fish product Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000011083 sodium citrates Nutrition 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229940072107 ascorbate Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000008452 baby food Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000005515 coenzyme Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 235000008446 instant noodles Nutrition 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001550 time effect Effects 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3535—Organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3499—Organic compounds containing oxygen with doubly-bound oxygen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3544—Organic compounds containing hetero rings
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/358—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Microbiology (AREA)
- Inorganic Chemistry (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Abstract
本发明属于抗氧化剂领域,具体涉及一种食品抗氧化剂,由以下重量份的组分组成:硫代二丙酸二月桂酯10-20份,维生素C 30-50份,焦亚硫酸钠15-35份,三聚磷酸钠25-40份,环羊毛甾烷化合物0.1-0.5份,柠檬酸钠5-20份,二氧化硅1-5份。本发明的有益效果是:抗氧化效果好,组分中不含有害物质,配比合理,添加本发明的抗氧化剂后,食品的保鲜期延长、色泽好、无异味。
Description
技术领域
本发明属于抗氧化剂领域,具体涉及一种食品抗氧化剂。
背景技术
抗氧化剂在食品加工中主要作用就是防止油脂氧化。油脂因含有不饱和脂肪酸,在有氧环境中容易氧化酸败。防止方式有的是抗氧化剂自身氧化,消耗油脂中的氧,油脂中没有氧,自然也就不氧化;有的抗氧化剂给出电子或氢原子,阻断油脂分子自动氧化的链式反应;有的抗氧化剂通过抑制氧化酶的活性而使油脂不被氧化。只有具备无毒无害、加入后检测方便的抗氧化剂才能作为食用抗氧化剂添加到食品中。
目前,食品中常用的抗氧化剂有2,6-二叔丁基甲酚(BHT),主要用于食用油脂、干鱼制品;叔丁基对羟基茴香醚,主要用于食用油脂;没食子酸丙酯,主要用于油炸食品、方便面和罐头;维生素E,主要用于婴儿食品、奶粉;维生素C和异维生素C,主要用于鱼肉制品、冷冻食品等。但是,现有的添加到食品中的抗氧化剂在阻止氧化、延长产品保鲜时间上存在欠缺,而且抗氧化剂的添加量不合理,抗氧化效果下降。
发明内容
本发明的目的在于克服现有技术中抗氧化剂添加量不合理、抗氧化效果下降的技术不足,提供一种用量合理,抗氧化效果好的食品抗氧化剂。
为解决上述技术问题,本发明采用的技术方案如下:
一种食品抗氧化剂,由以下重量份的组分组成:
进一步的,所述环羊毛甾烷化合物选自:9、19-环羊毛甾烷-3-醇和24-亚甲基-9、19-环羊毛甾烷-3-醇中的至少一种。
进一步的,所述食品抗氧化剂由以下重量份的组分组成:
本发明的食品抗氧化剂的作用机理是:
(1)抗氧化剂借助还原反应,降低食品体系及周围的氧含量,即抗氧化剂本身就极易氧化,因此在有氧化食品因素存在的时,如光照、氧气、加热等,抗氧化剂就先于食品与氧化因素作用,避免了食品被氧化;
(2)抗氧化剂释放出氢离子将氧化过程中产生的过氧化物破坏分解,使氧化反应无法继续进行。
本发明采用硫代二丙酸二月桂酯的目的是:硫代二丙酸二月桂酯简称DLTP,为白色粉末或鳞片状物,密度为0.915,熔点为39~40℃,溶于苯、甲苯、丙酮、汽油等溶剂。具有分解过氧化物的作用,可作为聚乙烯、聚丙烯、ABS树脂、聚氯乙烯等的辅助抗氧剂。有不污染、不着色、高温加工时不分解的特点。
本发明采用维生素C的目的是:维生素C的药效基团是抗坏血酸离子。在生物体内,维生素C是一种抗氧化剂,因为它能够保护身体免于氧化剂的威胁,维生素C同时也是一种辅酶。维生素C是一种强的还原剂,当它作为食品添加剂,维生素C成为一种抗氧化剂和防腐剂的酸度调节剂。
本发明采用柠檬酸钠的目的是:柠檬酸钠(sodium citrate),又称枸橼酸钠是一种有机化合物,为一种钠盐,其化学式为Na3C6H5O7,外观为白色到无色晶体,有肥皂水的味道,在食品、饮料工业中用作风味剂、稳定剂。
本发明的有益效果是:抗氧化效果好,组分中不含有害物质,配比合理,添加本发明的抗氧化剂后,食品的保鲜期延s长、色泽好、无异味。
具体实施方式
下面根据具体实施方式来对本发明做进一步阐述,并非用于限制本发明的权利要求范围。
实施例1
一种食品抗氧化剂,由以下重量份的组分组成:
实施例2
一种食品抗氧化剂,由以下重量份的组分组成:
本实施例为最佳实施方式。
实施例3
一种食品抗氧化剂,由以下重量份的组分组成:
。
Claims (3)
1.一种食品抗氧化剂,其特征在于由以下重量份的组分组成:
。
2.根据权利要求1所述的一种食品抗氧化剂,其特征在于所述环羊毛甾烷化合物选自:9、19-环羊毛甾烷-3-醇和24-亚甲基-9、19-环羊毛甾烷-3-醇中的至少一种。
3.根据权利要求1所述的一种食品抗氧化剂,其特征在于由以下重量份的组分组成:
。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109757646A (zh) * | 2017-11-09 | 2019-05-17 | 丹阳市博元安全生产服务有限公司 | 一种食品抗氧化剂 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101223984A (zh) * | 2008-02-01 | 2008-07-23 | 河南兴泰科技实业有限公司 | 熟肉制品护色复合改良剂 |
CN102216317A (zh) * | 2008-11-19 | 2011-10-12 | 森永乳业株式会社 | 抗氧化剂 |
CN102783696A (zh) * | 2012-08-27 | 2012-11-21 | 唐洪权 | 安全高效的复配食品抗氧化剂 |
CN103876243A (zh) * | 2012-12-21 | 2014-06-25 | 贵州天刺力食品科技有限责任公司 | 复配抗氧化剂 |
-
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- 2015-06-12 CN CN201510323369.0A patent/CN104983033A/zh not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101223984A (zh) * | 2008-02-01 | 2008-07-23 | 河南兴泰科技实业有限公司 | 熟肉制品护色复合改良剂 |
CN102216317A (zh) * | 2008-11-19 | 2011-10-12 | 森永乳业株式会社 | 抗氧化剂 |
CN102783696A (zh) * | 2012-08-27 | 2012-11-21 | 唐洪权 | 安全高效的复配食品抗氧化剂 |
CN103876243A (zh) * | 2012-12-21 | 2014-06-25 | 贵州天刺力食品科技有限责任公司 | 复配抗氧化剂 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109757646A (zh) * | 2017-11-09 | 2019-05-17 | 丹阳市博元安全生产服务有限公司 | 一种食品抗氧化剂 |
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