CN104975688B - A kind of preparation process of beauty fire-resisting stair handrail - Google Patents
A kind of preparation process of beauty fire-resisting stair handrail Download PDFInfo
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- CN104975688B CN104975688B CN201510343102.8A CN201510343102A CN104975688B CN 104975688 B CN104975688 B CN 104975688B CN 201510343102 A CN201510343102 A CN 201510343102A CN 104975688 B CN104975688 B CN 104975688B
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Abstract
The invention discloses a kind of preparation processes of beautiful fire-resisting stair handrail, the handrail includes rectangular handrail body, handrail body is outer in terms of cross section, ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice layer, hollow cavity, in the handrail body, it is equipped with two reinforcing ribs staggeredly within microcrystal glass plate, is covered by glass-ceramic layer at the top of the balustrade;It is preparation process present invention improves over high-temperature resistance plastice layer.The balustrade novel appearance of the present invention is beautiful, light-weight, few with material, and environmental protection has excellent fire resistance.
Description
Technical field
The present invention relates to a kind of preparation process of balustrade, more particularly to a kind of preparation work of beautiful fire-resisting stair handrail
Skill.
Background technology
Balustrade is the supporting rod of stair railing.Balustrade is classified as by material:Stair macromolecule handrail, stair
Iron skill handrail, stair stainless steel handrail, stair glass handrail, stair solid wood handrail.Also some special balustrades:Stair are sent out
Light handrail.The handrail for being currently used for garden landscape building mostly uses pure wooden armrest, and perishable, the service life is low, and unsightly;Also have
Using the handrail of steel, this handrail is of high cost, cannot insulate, there are security risks;In recent years also have using circular solids wood moulding
Handrail, consumptive material is more, of high cost, and shape is dull, unsightly.But existing balustrade often unified appearance, dull coloring;
In addition, weight is larger, fire protecting performance is also very poor, is badly in need of beautiful, environmental protection, the balustrade of fire resisting.
Polyvinyl chloride (PVC) is one of five big general-purpose plastics, cheap, modified high comprehensive performance, total output
It is only second to polyethylene, it is each to be widely used in industry, agricultural, building, electric, communications and transportation, electric power, telecommunication, packaging etc.
A field.PVC is in yellowish translucent, and glossy, transparency is less than polystyrene higher than polyethylene, polypropylene.PVC is not
Easy firing, intensity are high, weatherability and excellent size stability.PVC has very strong resistance to oxidant, reducing agent and strong acid
Power, but can be corroded by the concentrated sulfuric acid, concentrated nitric acid etc..The shrinking percentage of PVC is relatively low, and generally 0.2% ~ 0.6%.PVC makees in light, heat
Stability under is poor, under high temperature action or through a long time exposure in sunshine, can decompose generation hydrogen chloride, and further automatic
It is catalytically decomposed and changes colour, physical and mechanical property can also decline rapidly, must be added to stabilizer in practical applications to improve to heat
With the stability of light.PVC is difficult to, and because its melting temperature is close to decomposition temperature, and mobility is poor, and processing technology range is very
It is narrow, therefore usually require that other auxiliary agents such as plasticizer, lubricant, processing aid are added.According to the difference of plasticizer consumption, PVC
Product can be divided into soft and two kinds of hard.Hard PVC high mechanical strength, it is durable, for produce structural member, shell, toy,
Plank, tubing etc..
The present invention is intended to provide a kind of preparation process of beauty fire-resisting stair handrail, can produce beauty, and environmental protection, fire resisting
Balustrade.
Invention content
Technical problems based on background technology, the present invention provide a kind of preparation process of beautiful fire-resisting stair handrail.
Technical scheme is as follows:
A kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:90-100 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 2-3 parts, receive
Rice SiO20.8-1.2 parts, 2-3 parts of dibutyl tin laurate;1-5 parts of tribasic lead sulfate;0.2-0.5 parts of tin laurate;Firmly
0.5-1 parts of resin acid barium;0.5-1 parts of dibasic lead stearate;Ricinoleic acid calcium is 1-2 parts;Calcium carbonate is 10-15 parts;Liquid stone
0.8-1 parts of wax;1-1.2 parts of AC foaming agents;3-6 parts of DOP is realized using extruder and is molded;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice
Layer, hollow cavity are equipped with two reinforcing ribs staggeredly in the hollow cavity, are covered by glass-ceramic layer at the top of the balustrade
Lid combines all components, in junction soft glue encapsulation process according to the structures to form.
Preferably, the group of the high-temperature resistance plastice layer is divided into:
90 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 3 parts, Nano-meter SiO_220.8 part, tin dilaurate two
3 parts of butyl tin;1 part of tribasic lead sulfate;0.5 part of tin laurate;0.5 part of barium stearate;1 part of dibasic lead stearate;Castor-oil plant
Calcium oleate is 1 part;Calcium carbonate is 15 parts;0.8 part of atoleine;1.2 parts of AC foaming agents;3 parts of DOP.
Preferably, the reinforcing rib is reinforcing bar.
The invention has the beneficial effects that:
The balustrade preparation process of the present invention is simple, is suitble to industrialization production;The handrail appearance looks elegant produced, it is micro-
Crystal glass can have very a variety of different colors, moulding, can there are many variation;With fireproof glass blanket layer with excellent
Fire resistance;The production technology of high-temperature resistance plastice is optimized, valence makes its good supporting force, heat-resisting, ageing-resistant;By described
Reinforcing rib is set in the hollow cavity of handrail body, makes the balustrade in the case where reducing materials'use, ensure that building
The compression strength of ladder rail;Meanwhile hollow cavity and mineral wool carpet veneer make handrail have very light weight.
Description of the drawings
Fig. 1 is the structural schematic diagram of the cross section for the balustrade that the balustrade preparation process of the present invention produces.
Specific implementation mode
Embodiment 1:
A kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:90 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 3 parts, Nano-meter SiO_22
0.8 part, 3 parts of dibutyl tin laurate;1 part of tribasic lead sulfate;0.5 part of tin laurate;0.5 part of barium stearate;Dibasic
1 part of lead stearate;Ricinoleic acid calcium is 1 part;Calcium carbonate is 15 parts;0.8 part of atoleine;1.2 parts of AC foaming agents; DOP 3
Part, it is realized and is molded using extruder;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice
Layer, hollow cavity are equipped with two reinforcing ribs staggeredly in the hollow cavity, are covered by glass-ceramic layer at the top of the balustrade
Lid combines all components, in junction soft glue encapsulation process according to the structures to form.
The parameter of high-temperature resistance plastice layer:Uninterrupted 2000 hours of imitative sunshine ultraviolet light is colour-fast not to change character, stretches strong
Spend 30MPa, impact strength 18MPa, resistance to 200 DEG C of high temperature.
Embodiment 2:
A kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:100 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 2 parts, Nano-meter SiO_22
1.2 parts, 2 parts of dibutyl tin laurate;5 parts of tribasic lead sulfate;0.2 part of tin laurate;1 part of barium stearate;Dibasic is hard
0.5 part of resin acid lead;Ricinoleic acid calcium is 2 parts;Calcium carbonate is 10 parts;1 part of atoleine;1 part of AC foaming agents;6 parts of DOP, makes
It is realized and is molded with extruder;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice
Layer, hollow cavity are equipped with two reinforcing ribs staggeredly in the hollow cavity, are covered by glass-ceramic layer at the top of the balustrade
Lid combines all components, in junction soft glue encapsulation process according to the structures to form.
The parameter of high-temperature resistance plastice layer:Uninterrupted 2000 hours of imitative sunshine ultraviolet light is colour-fast not to change character, stretches strong
Spend 25MPa, impact strength 22MPa, resistance to 180 DEG C of high temperature.
Embodiment 3:
A kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:95 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 3 parts, Nano-meter SiO_22
0.9 part, 3 parts of dibutyl tin laurate;2 parts of tribasic lead sulfate;0.3 part of tin laurate;0.7 part of barium stearate;Dibasic
0.8 part of lead stearate;Ricinoleic acid calcium is 1 part;Calcium carbonate is 11 parts;0.9 part of atoleine;1.1 parts of AC foaming agents; DOP
It 4 parts, is realized and is molded using extruder;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice
Layer, hollow cavity are equipped with two reinforcing ribs staggeredly in the hollow cavity, are covered by glass-ceramic layer at the top of the balustrade
Lid combines all components, in junction soft glue encapsulation process according to the structures to form.
The parameter of high-temperature resistance plastice layer:Uninterrupted 2000 hours of imitative sunshine ultraviolet light is colour-fast not to change character, stretches strong
Spend 28MPa, impact strength 19MPa, resistance to 189 DEG C of high temperature.
Embodiment 4:
A kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:98 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 2 parts, Nano-meter SiO_22
1.1 parts, 2 parts of dibutyl tin laurate;4 parts of tribasic lead sulfate;0.4 part of tin laurate;0.6 part of barium stearate;Dibasic
0.7 part of lead stearate;Ricinoleic acid calcium is 2 parts;Calcium carbonate is 14 parts;0.8 part of atoleine;1.2 parts of AC foaming agents; DOP
It 5 parts, is realized and is molded using extruder;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice
Layer, hollow cavity are equipped with two reinforcing ribs staggeredly in the hollow cavity, are covered by glass-ceramic layer at the top of the balustrade
Lid combines all components, in junction soft glue encapsulation process according to the structures to form.
The parameter of high-temperature resistance plastice layer:Uninterrupted 2000 hours of imitative sunshine ultraviolet light is colour-fast not to change character, stretches strong
Spend 26MPa, impact strength 21MPa, resistance to 196 DEG C of high temperature.
Embodiment 5:
A kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:92 parts of epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2 2 parts, Nano-meter SiO_22
0.9 part, 3 parts of dibutyl tin laurate;4 parts of tribasic lead sulfate;0.3 part of tin laurate;0.6 part of barium stearate;Dibasic
0.9 part of lead stearate;Ricinoleic acid calcium is 1 part;Calcium carbonate is 11 parts;1 part of atoleine;1.2 parts of AC foaming agents; DOP 5
Part, it is realized and is molded using extruder;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice
Layer, hollow cavity are equipped with two reinforcing ribs staggeredly in the hollow cavity, are covered by glass-ceramic layer at the top of the balustrade
Lid combines all components, in junction soft glue encapsulation process according to the structures to form.
The parameter of high-temperature resistance plastice layer:Uninterrupted 2000 hours of imitative sunshine ultraviolet light is colour-fast not to change character, stretches strong
Spend 29MPa, impact strength 20MPa, resistance to 195 DEG C of high temperature.
In short, the balustrade preparation process of the present invention is simple, the balustrade appearance looks elegant prepared is light-weight,
Few with material, environmental protection has excellent fire resistance.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (1)
1. a kind of preparation method of beauty fire-resisting stair handrail, its step are as follows:
(1)Prepare high-temperature resistance plastice layer:
The following raw material is melted in mixing:Epoxy aliphatic acid methyl ester graft modification PVC;Nano-TiO2, Nano-meter SiO_22, two fourth of tin dilaurate
Ji Xi;Tribasic lead sulfate;Tin laurate;Barium stearate;Dibasic lead stearate;Ricinoleic acid calcium;Calcium carbonate;Liquid stone
Wax;Foaming agent;DOP is realized using extruder and is molded;
(2)It splices and combines:
The structure of handrail is:Handrail body ecto-entad includes glass-ceramic layer, fireproof glass blanket layer, high-temperature resistance plastice layer,
Hollow cavity is equipped with two reinforcing ribs staggeredly in the hollow cavity, is covered by glass-ceramic layer at the top of the balustrade,
All components are combined according to the structures to form;
The concrete component proportioning of the high-temperature resistance plastice layer is, according to mass fraction:Epoxy aliphatic acid methyl ester graft modification PVC
90-100 parts;Nano-TiO2 2-3 parts, Nano-meter SiO_220.8-1.2 parts, 2-3 parts of dibutyl tin laurate;Tribasic lead sulfate
1-5 parts;0.2-0.5 parts of tin laurate;0.5-1 parts of barium stearate;0.5-1 parts of dibasic lead stearate;Ricinoleic acid calcium is 1-
2 parts;Calcium carbonate is 10-15 parts;0.8-1 parts of atoleine;1-1.2 parts of foaming agent;3-6 parts of DOP, is implemented as using extruder
Type;
Wherein, in junction soft glue encapsulation process;
The foaming agent is AC foaming agents.
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CN201510343102.8A CN104975688B (en) | 2015-06-19 | 2015-06-19 | A kind of preparation process of beauty fire-resisting stair handrail |
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CN201510343102.8A CN104975688B (en) | 2015-06-19 | 2015-06-19 | A kind of preparation process of beauty fire-resisting stair handrail |
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CN104975688A CN104975688A (en) | 2015-10-14 |
CN104975688B true CN104975688B (en) | 2018-10-09 |
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Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4193585A (en) * | 1977-11-14 | 1980-03-18 | Roger Eandi | Handrail assembly for curved staircase |
JPH09100610A (en) * | 1995-10-06 | 1997-04-15 | Echo Chem Kk | Handrail |
CN2637619Y (en) * | 2003-08-08 | 2004-09-01 | 王繁桥 | Imitation jewel crystal jade staircase railing |
CN103342468B (en) * | 2013-06-28 | 2016-03-09 | 北京晶雅石科技有限公司 | Composite sheet of foam pyroceram and pure devitrified glass and preparation method thereof |
CN103739979A (en) * | 2013-11-25 | 2014-04-23 | 吴江市董鑫塑料包装厂 | Stair handrail plastic |
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