CN104974391A - Preparation method of oil-resistant cable sheath material - Google Patents
Preparation method of oil-resistant cable sheath material Download PDFInfo
- Publication number
- CN104974391A CN104974391A CN201510453972.0A CN201510453972A CN104974391A CN 104974391 A CN104974391 A CN 104974391A CN 201510453972 A CN201510453972 A CN 201510453972A CN 104974391 A CN104974391 A CN 104974391A
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature
- sheath material
- oil
- cable sheath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 15
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 10
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 10
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 239000000314 lubricant Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 claims abstract description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 38
- 238000002156 mixing Methods 0.000 claims description 30
- -1 Zinic stearas Substances 0.000 claims description 15
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 14
- 239000004593 Epoxy Substances 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 10
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 235000019359 magnesium stearate Nutrition 0.000 claims description 6
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 238000009776 industrial production Methods 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract 3
- 229960003328 benzoyl peroxide Drugs 0.000 abstract 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 abstract 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 9
- 150000001241 acetals Chemical class 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 7
- 230000003078 antioxidant effect Effects 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 125000005498 phthalate group Chemical class 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000007767 bonding agent Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- XQJMXPAEFMWDOZ-UHFFFAOYSA-N 3exo-benzoyloxy-tropane Natural products CN1C(C2)CCC1CC2OC(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- QQXLDOJGLXJCSE-UHFFFAOYSA-N N-methylnortropinone Natural products C1C(=O)CC2CCC1N2C QQXLDOJGLXJCSE-UHFFFAOYSA-N 0.000 description 1
- QIZDQFOVGFDBKW-DHBOJHSNSA-N Pseudotropine Natural products OC1C[C@@H]2[N+](C)[C@H](C1)CC2 QIZDQFOVGFDBKW-DHBOJHSNSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- CYHOMWAPJJPNMW-JIGDXULJSA-N tropine Chemical compound C1[C@@H](O)C[C@H]2CC[C@@H]1N2C CYHOMWAPJJPNMW-JIGDXULJSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a preparation method of an oil-resistant cable sheath material, which comprises the following steps: compounding 45-67 parts by weight of chloroprene rubber and 8-23 parts by weight of polyvinyl chloride in a Banbury mixer, keeping the temperature, and cooling to room temperature; adding 12-20 parts of decabromodiphenyl oxide, 1-9 parts of ethylene thiourea, 5-15 parts of benzoperoxide, 8-21 parts of aluminum hydroxide, 1-13 parts of dioctyl epoxytetrahydrophthalate and 4-17 parts of polyvinyl butyral, compounding for 3-5 minutes adding 3-14 parts of lubricant and 3-16 parts of antioxidant 1010, and compounding for 2-4 minutes; and carrying out thin passing in an open mill, and extruding through a double screw extruder. The cable sheath material has the advantages of higher volume resistivity, higher vertical burning grade and higher oil resistance. The method has the advantages of simple preparation technique and reasonable time and temperature control settings, and can be widely used in industrial production.
Description
Technical field
The present invention relates to cable production art, particularly a kind of preparation method of oil-resisting type cable sheath material.
Background technology
Cable application is very extensive, relates to the industries such as electric power, building, communication, manufacture, all closely related with all respects of national economy.
CN104119681A discloses a kind of flame resistant cable insulating material preparation method, flame resistant cable insulating material raw material is made up of the raw material of following mass component: aluminium hydroxide 70% ~ 85%, silicon rubber 10% ~ 20%, additive 5 ~ 10%, described additive comprises 96 grades of SiO2 micro mists, explosion-proof fiber and compound resin; Aluminium hydroxide, silicon rubber and additive are mixed by quality proportioning, then bonding agent is added, described bonding agent is made up of dextrose anhydrous, borax, tropine and Industrial Salt, the interpolation quality of described bonding agent accounts for 3 ~ 6% of aluminium hydroxide, silicon rubber and additive total mass, this material improves that cable insulation material is withstand voltage, cracking resistance and fire performance.CN102952311A discloses the preparation method of Low smoke zero halogen flame retardant material for high voltage cable jacket, first high-speed mixing inorganic combustion inhibitor magnesium hydroxide, aluminium hydroxide in high-speed mixer, rotating speed 900rpm-1100rpm, when high-speed mixing is to temperature 80 DEG C ~ 90 DEG C, carries out dewatering and then carry out spraying process with 172 silane coupling agents, through the inorganic combustion inhibitor magnesium hydroxide that 172 silane coupling agents are handled well, aluminium hydroxide and metallocene PE, the ethylene vinyl acetate of melting index between 2 ~ 8, acrylic acid-grafted high density polyethylene(HDPE), organosilicon cave, molybdenumdisulphide, oxidation inhibitor and lubricant add in milling machine together to be mediated, in time mediating temperature of charge and rise to 125 DEG C ~ 135 DEG C, the kneaded material in bulk is put to lift, is delivered to melt taper feeding machine, twin screw delivered to by material by feeding machine, and to carry out extrusion molding mixing, then the granulation of singe screw extruding machine is entered, adopt the fervent granulation process of die face, the particle made enters first step whirlwind cooling separator by blower fan transport pipe, second stage whirlwind cooling separator, air-cooled vibratory screening apparatus, third stage whirlwind cooling separator, namely finished-product material is obtained, the mechanical property of sheath material obtained is like this high, wear resistance and cohesiveness good, make cable in mounting and installation process, the coat layer of power cable is not easy to wear to break.
Because the environment for use of cable is complicated, to the requirement that its performance also will be higher, as the cable of frequent operation in gasoline or diesel pool, because oil-proofness is poor, insulation reduces, and easily breaks down, there is potential safety hazard.
Summary of the invention
In order to overcome above-mentioned defect, the technical problem that the present invention solves is, a kind of preparation method of oil-resisting type cable sheath material is provided, obtained cable sheath material is by the synergy between component, improve volume specific resistance, vertical combustion grade, oil resistance, preparation technology is simple simultaneously, and time and temperature control to arrange rationally, can be widely used in industrial production.
The technical solution used in the present invention is:
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 45-67 part chloroprene rubber and 8-23 part polyvinyl chloride are placed in Banbury mixer mixing, in Banbury mixer, temperature controls at 100-140 DEG C, is cooled to room temperature, obtains mixture one after insulation 10-20min;
(2) in step (1) gained mixture one, 12-20 part decabromodiphynly oxide, 1-9 part ethylene thiourea, 5-15 part benzoyl peroxide, 8-21 part aluminium hydroxide, 1-13 part epoxy tetrahydro-2-ethylhexyl phthalate and 4-17 part polyvinyl butyral acetal is added, mixing 3-5min at 110-135 DEG C of temperature, add 3-14 part lubricant and 3-16 part antioxidant 1010 again, mixing 2-4min at 95-110 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 2-5 time, then is placed in twin screw extruder and extrudes and obtain described oil-resisting type cable sheath material.
In above-mentioned steps (1), the banburying time is 3-5min.
In above-mentioned steps (1), process of cooling controls in 30-50s.
Lubricant is one or more composition in Magnesium Stearate, Zinic stearas, polyethylene wax in above-mentioned steps (2).
In above-mentioned steps (3), extruder barrel one district temperature is 115-130 DEG C, and two district's temperature are 120-140 DEG C, and three district's temperature are 130-155 DEG C, and four district's temperature are 135-170 DEG C.
In above-mentioned steps (3), the head pressure of forcing machine is 2-7MPa.
beneficial effect
The sheath material that the present invention obtains 20 DEG C of temperature lower volume resistivity >=1013 Ω * cm, vertical combustion grade is V-0, in resistance to mineral oil test, under 75 DEG C of * 48h conditions, tensile strength change rate of strength between-14.3 ~-7.6%, between elongation at break velocity of variation-7.3 ~-4.1%; By due to the synergy between component, improve volume specific resistance, vertical combustion grade, oil resistance, preparation technology is simple simultaneously, and time and temperature control to arrange rationally, can be widely used in industrial production.
Embodiment
Embodiment 1
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 45 parts of chloroprene rubbers and 8 parts of polyvinyl chloride are placed in the mixing 3min of Banbury mixer, and in Banbury mixer, temperature controls at 100 DEG C, and insulation 10min, is cooled to room temperature, obtains mixture one in 30s;
(2) in step (1) gained mixture one, add 12 parts of decabromodiphynly oxides, 1 part of ethylene thiourea, 5 parts of benzoyl peroxides, 8 parts of aluminium hydroxides, 1 part of epoxy tetrahydro-2-ethylhexyl phthalate and 4 parts of polyvinyl butyral acetals, mixing 3min at 110 DEG C of temperature, add 3 parts of Magnesium Stearates and 3 parts of antioxidant 1010s again, mixing 2min at 95 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 2 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 115 DEG C, two district's temperature are 120 DEG C, three district's temperature are 130 DEG C, four district's temperature are 135 DEG C, and the head pressure of forcing machine is 2MPa.
Embodiment 2
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 67 parts of chloroprene rubbers and 23 parts of polyvinyl chloride are placed in the mixing 5min of Banbury mixer, and in Banbury mixer, temperature controls at 140 DEG C, and insulation 20min, is cooled to room temperature, obtains mixture one in 50s;
(2) in step (1) gained mixture one, add 20 parts of decabromodiphynly oxides, 9 parts of ethylene thioureas, 15 parts of benzoyl peroxides, 21 parts of aluminium hydroxides, 13 parts of epoxy tetrahydro-2-ethylhexyl phthalates and 17 parts of polyvinyl butyral acetals, mixing 5min at 135 DEG C of temperature, add 14 parts of Zinic stearass and 16 parts of antioxidant 1010s again, mixing 4min at 110 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 5 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 130 DEG C, two district's temperature are 140 DEG C, three district's temperature are 155 DEG C, four district's temperature are 170 DEG C, and the head pressure of forcing machine is 7MPa.
Embodiment 3
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 47 parts of chloroprene rubbers and 11 parts of polyvinyl chloride are placed in the mixing 4min of Banbury mixer, and in Banbury mixer, temperature controls at 110 DEG C, and insulation 12min, is cooled to room temperature, obtains mixture one in 35s;
(2) in step (1) gained mixture one, add 13 parts of decabromodiphynly oxides, 2 parts of ethylene thioureas, 7 parts of benzoyl peroxides, 11 parts of aluminium hydroxides, 3 parts of epoxy tetrahydro-2-ethylhexyl phthalates and 5 parts of polyvinyl butyral acetals, mixing 4min at 115 DEG C of temperature, add 6 parts of polyethylene waxs and 7 parts of antioxidant 1010s again, mixing 3min at 100 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 3 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 120 DEG C, two district's temperature are 125 DEG C, three district's temperature are 140 DEG C, four district's temperature are 145 DEG C, and the head pressure of forcing machine is 3MPa.
Embodiment 4
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 61 parts of chloroprene rubbers and 18 parts of polyvinyl chloride are placed in the mixing 4min of Banbury mixer, and in Banbury mixer, temperature controls at 130 DEG C, and insulation 18min, is cooled to room temperature, obtains mixture one in 45s;
(2) in step (1) gained mixture one, add 18 parts of decabromodiphynly oxides, 8 parts of ethylene thioureas, 12 parts of benzoyl peroxides, 19 parts of aluminium hydroxides, 10 parts of epoxy tetrahydro-2-ethylhexyl phthalates and 15 parts of polyvinyl butyral acetals, mixing 4min at 130 DEG C of temperature, add 5 parts of Zinic stearass, 6 parts of polyethylene waxs and 12 parts of antioxidant 1010s again, mixing 3min at 105 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 4 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 125 DEG C, two district's temperature are 130 DEG C, three district's temperature are 145 DEG C, four district's temperature are 160 DEG C, and the head pressure of forcing machine is 6MPa.
Embodiment 5
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 54 parts of chloroprene rubbers and 17 parts of polyvinyl chloride are placed in the mixing 4min of Banbury mixer, and in Banbury mixer, temperature controls at 125 DEG C, and insulation 16min, is cooled to room temperature, obtains mixture one in 40s;
(2) in step (1) gained mixture one, add 16 parts of decabromodiphynly oxides, 6 parts of ethylene thioureas, 9 parts of benzoyl peroxides, 14 parts of aluminium hydroxides, 8 parts of epoxy tetrahydro-2-ethylhexyl phthalates and 13 parts of polyvinyl butyral acetals, mixing 4min at 120 DEG C of temperature, add 3 parts of Magnesium Stearates, 4 parts of polyethylene waxs and 9 parts of antioxidant 1010s again, mixing 3min at 100 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 3 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 120 DEG C, two district's temperature are 130 DEG C, three district's temperature are 145 DEG C, four district's temperature are 155 DEG C, and the head pressure of forcing machine is 5MPa.
Comparative example 1
Do not add epoxy tetrahydro-2-ethylhexyl phthalate with the difference of embodiment 5.
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 54 parts of chloroprene rubbers and 17 parts of polyvinyl chloride are placed in the mixing 4min of Banbury mixer, and in Banbury mixer, temperature controls at 125 DEG C, and insulation 16min, is cooled to room temperature, obtains mixture one in 40s;
(2) in step (1) gained mixture one, add 16 parts of decabromodiphynly oxides, 6 parts of ethylene thioureas, 9 parts of benzoyl peroxides, 14 parts of aluminium hydroxides and 13 parts of polyvinyl butyral acetals, mixing 4min at 120 DEG C of temperature, add 3 parts of Magnesium Stearates, 4 parts of polyethylene waxs and 9 parts of antioxidant 1010s again, mixing 3min at 100 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 3 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 120 DEG C, two district's temperature are 130 DEG C, three district's temperature are 145 DEG C, four district's temperature are 155 DEG C, and the head pressure of forcing machine is 5MPa.
Comparative example 2
Do not add polyvinyl butyral acetal with the difference of embodiment 5.
A preparation method for oil-resisting type cable sheath material, comprises the following steps:
(1) by weight, 54 parts of chloroprene rubbers and 17 parts of polyvinyl chloride are placed in the mixing 4min of Banbury mixer, and in Banbury mixer, temperature controls at 125 DEG C, and insulation 16min, is cooled to room temperature, obtains mixture one in 40s;
(2) in step (1) gained mixture one, add 16 parts of decabromodiphynly oxides, 6 parts of ethylene thioureas, 9 parts of benzoyl peroxides, 14 parts of aluminium hydroxides and 8 parts of epoxy tetrahydro-2-ethylhexyl phthalates, mixing 4min at 120 DEG C of temperature, add 3 parts of Magnesium Stearates, 4 parts of polyethylene waxs and 9 parts of antioxidant 1010s again, mixing 3min at 100 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 3 times, be placed in twin screw extruder again and extrude and obtain described oil-resisting type cable sheath material, wherein extruder barrel one district temperature is 120 DEG C, two district's temperature are 130 DEG C, three district's temperature are 145 DEG C, four district's temperature are 155 DEG C, and the head pressure of forcing machine is 5MPa.
Performance test:
The cable sheath material of embodiment 1-5 and comparative example 1-2 gained is carried out Performance Detection, and result is as following table:
As can be seen from the above table: sheath material 20 DEG C of temperature lower volume resistivity>=10 that embodiment 1-5 is obtained
13Ω * cm, vertical combustion grade is V-0, in the test of resistance to mineral oil, under 75 DEG C of * 48h conditions, tensile strength change rate of strength between-14.3 ~-7.6%, between elongation at break velocity of variation-7.3 ~-4.1%; Epoxy tetrahydro-2-ethylhexyl phthalate is not added, obtained sheath material 20 DEG C of temperature lower volume resistivity>=10 in comparative example 1
13Ω * cm, vertical combustion grade is V-0, in resistance to mineral oil test, under 75 DEG C of * 48h conditions, tensile strength change rate of strength-23.7%, elongation at break velocity of variation is-12.8%; Viscotrol C is not added, obtained sheath material 20 DEG C of temperature lower volume resistivity>=10 in comparative example 2
13Ω * cm, vertical combustion grade is V-0, in resistance to mineral oil test, under 75 DEG C of * 48h conditions, tensile strength change rate of strength-15.8%.It can thus be appreciated that, the cable sheath material that the present invention obtains be due to component between synergy, improve volume specific resistance, vertical combustion grade, oil resistance, simultaneously preparation technology is simple, and it is reasonable that time and temperature control to arrange, and can be widely used in industrial production.
Claims (6)
1. a preparation method for oil-resisting type cable sheath material, is characterized in that, comprises the following steps:
(1) by weight, 45-67 part chloroprene rubber and 8-23 part polyvinyl chloride are placed in Banbury mixer mixing, in Banbury mixer, temperature controls at 100-140 DEG C, is cooled to room temperature, obtains mixture one after insulation 10-20min;
(2) in step (1) gained mixture one, 12-20 part decabromodiphynly oxide, 1-9 part ethylene thiourea, 5-15 part benzoyl peroxide, 8-21 part aluminium hydroxide, 1-13 part epoxy tetrahydro-2-ethylhexyl phthalate and 4-17 part polyvinyl butyral acetal is added, mixing 3-5min at 110-135 DEG C of temperature, add 3-14 part lubricant and 3-16 part antioxidant 1010 again, mixing 2-4min at 95-110 DEG C of temperature, obtains mixture two;
(3) step (2) gained mixture two is placed in mill thin-pass 2-5 time, then is placed in twin screw extruder and extrudes and obtain described oil-resisting type cable sheath material.
2. the preparation method of oil-resisting type cable sheath material according to claim 1, is characterized in that: in described step (1), the banburying time is 3-5min.
3. the preparation method of oil-resisting type cable sheath material according to claim 1, is characterized in that: in described step (1), process of cooling controls in 30-50s.
4. the preparation method of oil-resisting type cable sheath material according to claim 1, is characterized in that: lubricant is one or more composition in Magnesium Stearate, Zinic stearas, polyethylene wax in described step (2).
5. the preparation method of oil-resisting type cable sheath material according to claim 1, it is characterized in that: in described step (3), extruder barrel one district temperature is 115-130 DEG C, two district's temperature are 120-140 DEG C, and three district's temperature are 130-155 DEG C, and four district's temperature are 135-170 DEG C.
6. the preparation method of oil-resisting type cable sheath material according to claim 1, is characterized in that: in described step (3), the head pressure of forcing machine is 2-7MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510453972.0A CN104974391B (en) | 2015-07-29 | 2015-07-29 | A kind of preparation method of oil-resisting type cable sheath material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510453972.0A CN104974391B (en) | 2015-07-29 | 2015-07-29 | A kind of preparation method of oil-resisting type cable sheath material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104974391A true CN104974391A (en) | 2015-10-14 |
| CN104974391B CN104974391B (en) | 2017-11-17 |
Family
ID=54271383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510453972.0A Active CN104974391B (en) | 2015-07-29 | 2015-07-29 | A kind of preparation method of oil-resisting type cable sheath material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104974391B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111675870A (en) * | 2020-06-30 | 2020-09-18 | 宝胜科技创新股份有限公司 | Low-temperature-resistant oil-resistant ozone-resistant polyvinyl chloride insulating material and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993524A (en) * | 2012-11-13 | 2013-03-27 | 安徽文峰电子科技集团有限公司 | Cable sheath insulation material for coal mines and preparation method thereof |
| CN102993522A (en) * | 2012-11-13 | 2013-03-27 | 安徽文峰电子科技集团有限公司 | High-temperature resistant cable sheath insulation material and preparation method thereof |
| EP2584364A1 (en) * | 2011-10-19 | 2013-04-24 | Raychem International | Self centering, split multicore current sensor |
| CN103265740A (en) * | 2013-04-27 | 2013-08-28 | 安徽省康利亚实业有限公司 | Ozone-resistant cable sheath material |
| CN103374157A (en) * | 2013-06-21 | 2013-10-30 | 安徽荣玖光纤通信科技有限公司 | Flame-retardant cable sheath material and preparation method thereof |
| CN103497380A (en) * | 2013-10-02 | 2014-01-08 | 青岛三立新源电器有限公司 | High-temperatures-resistant polyvinyl chloride (PVC) material for electric wires and cables |
| CN103524930A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Cold-resistant PVC sheath material for cable and preparation method thereof |
| CN104311937A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Acid and alkali resistant cable material with strong stability and preparation method thereof |
-
2015
- 2015-07-29 CN CN201510453972.0A patent/CN104974391B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2584364A1 (en) * | 2011-10-19 | 2013-04-24 | Raychem International | Self centering, split multicore current sensor |
| CN102993524A (en) * | 2012-11-13 | 2013-03-27 | 安徽文峰电子科技集团有限公司 | Cable sheath insulation material for coal mines and preparation method thereof |
| CN102993522A (en) * | 2012-11-13 | 2013-03-27 | 安徽文峰电子科技集团有限公司 | High-temperature resistant cable sheath insulation material and preparation method thereof |
| CN103265740A (en) * | 2013-04-27 | 2013-08-28 | 安徽省康利亚实业有限公司 | Ozone-resistant cable sheath material |
| CN103374157A (en) * | 2013-06-21 | 2013-10-30 | 安徽荣玖光纤通信科技有限公司 | Flame-retardant cable sheath material and preparation method thereof |
| CN103524930A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Cold-resistant PVC sheath material for cable and preparation method thereof |
| CN103497380A (en) * | 2013-10-02 | 2014-01-08 | 青岛三立新源电器有限公司 | High-temperatures-resistant polyvinyl chloride (PVC) material for electric wires and cables |
| CN104311937A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Acid and alkali resistant cable material with strong stability and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 《电线电缆手册》编委会组编: "《电线电缆手册，第2册》", 30 April 2014, 北京：机械工业出版社 * |
| 朱洪法: "《精细化工 常用原材料手册》", 31 December 2003, 北京：金盾出版社 * |
| 汪多仁: "《增塑剂化学品生产配方和合成工艺》", 31 August 1999, 北京：科学技术文献出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111675870A (en) * | 2020-06-30 | 2020-09-18 | 宝胜科技创新股份有限公司 | Low-temperature-resistant oil-resistant ozone-resistant polyvinyl chloride insulating material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104974391B (en) | 2017-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108017826A (en) | A kind of flame-retardant polyethylene sheathing material and preparation method thereof | |
| CN103865165B (en) | A kind of low smoke halogen-free fire retardant polyolefin cable material and preparation method thereof | |
| CN101486814B (en) | Method for producing low-smoke halogen-free non-nitrogen flame-retardant heat-shrinkable material sheathed tube and casing tube | |
| CN1316704C (en) | Bushing tube for buried medium-high voltage power cable and production method thereof | |
| CN102952311B (en) | Preparation method of low-smoke non-halogen flame-retardant material for high-voltage cable sheath | |
| CN109929168B (en) | Modified polyethylene material suitable for electric power insulator and preparation method thereof | |
| CN105504482B (en) | Halogen-free flame-retardant linear low-density polyethylene material | |
| CN104004296A (en) | Antimony-free flame-retardant polyvinyl chloride cable material and preparation method thereof | |
| CN108164805A (en) | One kind can porcelain EVA non-halogen flame-retardant cables and preparation method thereof | |
| CN104004262A (en) | Irradiation crosslinking oil-resistance low-smoke halogen-free flame-retardant polyolefin sheath material and preparation method thereof | |
| CN102690476A (en) | Heat-resisting material and preparing method thereof as well as base station antenna outer cover | |
| CN103509263B (en) | A kind of environmental protection addition type polyethylene anti-flaming master batch and preparation method thereof | |
| CN104559036A (en) | Light-power high-light-stability cable material and preparation method thereof | |
| CN104610646A (en) | High-temperature-resistant, anti-cracking and flame-retardant polyolefin cable material and preparation method thereof | |
| CN105885169A (en) | Wear-proof high-intensity composite power cable material and preparation method thereof | |
| CN103937124B (en) | High speed extrusion cloudy surface polyvinyl chloride cable material and preparation method thereof | |
| CN113912928B (en) | 150 ℃ grade 3000h heat aging resistant halogen-free flame retardant polyolefin cable material and preparation method thereof | |
| CN104974391A (en) | Preparation method of oil-resistant cable sheath material | |
| CN109929169B (en) | Modified polyethylene material for electric power insulator and preparation method thereof | |
| CN109265861A (en) | Network system cable sheath material and preparation method thereof | |
| CN105131464A (en) | Polyvinyl chloride cable material and preparing method thereof | |
| CN101157789B (en) | Non-bittern flame-proof elastomer composite material and method for making same | |
| CN108148336B (en) | Halogen-free conductive TPE cable material and preparation method thereof | |
| CN105949569A (en) | Environment-friendly and aging-resistant power cable insulating material and preparation method thereof | |
| CN106009446A (en) | High-oil-resistance high-wear-resistance irradiation crosslinking halogen-free flame-retardant polyolefin cable material for locomotive cable |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Tang Chengbing Inventor before: Fu Xingqin |
|
| CB03 | Change of inventor or designer information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20171012 Address after: 224014, province, Yancheng City province salt District, 9 D1 Road, four building, 404 building, Yancheng hi tech Pioneer Park, Huarui Road, Huarui Road, Jiangsu Applicant after: YANCHENG KEHENGDA MATERIALS Co.,Ltd. Address before: 644305 Yibin Province, Changning City, the leading town of Sichuan County, the village of the group of 2, No. 105, attached to No. 2 Applicant before: Fu Xingqin |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230404 Address after: 509 Kangrui Times Square, Keyuan Business Building, 39 Huarong Road, Gaofeng Community, Dalang Street, Longhua District, Shenzhen, Guangdong Province, 518000 Patentee after: Shenzhen lizhuan Technology Transfer Center Co.,Ltd. Address before: 224014 room 404 (d), 4th floor, D1 building, Yancheng hi tech Pioneer Park, No. 9, Huarui Middle Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province Patentee before: YANCHENG KEHENGDA MATERIALS Co.,Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20230508 Address after: 430000 Haike Optoelectronics Industrial Park, Miaoshan Fourth Road, Miaoshan Development Zone, Jiangxia District, Wuhan City, Hubei Province Patentee after: Wuhan steel electric wire manufacturing Co.,Ltd. Address before: 509 Kangrui Times Square, Keyuan Business Building, 39 Huarong Road, Gaofeng Community, Dalang Street, Longhua District, Shenzhen, Guangdong Province, 518000 Patentee before: Shenzhen lizhuan Technology Transfer Center Co.,Ltd. |
|
| TR01 | Transfer of patent right |