CN104972716A - Shading composite material - Google Patents
Shading composite material Download PDFInfo
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- CN104972716A CN104972716A CN201410145818.2A CN201410145818A CN104972716A CN 104972716 A CN104972716 A CN 104972716A CN 201410145818 A CN201410145818 A CN 201410145818A CN 104972716 A CN104972716 A CN 104972716A
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Abstract
The invention discloses a shading composite material, which includes, in a laminated manner, a first transparent thin film layer, a first vacuum aluminum-plated layer, a composite adhesive layer, a second transparent thin film layer, a polyethylene coating film layer and a nonwoven cloth layer. The thickness of the first vacuum aluminum-plated layer is 400-700 angstrom. A second vacuum aluminum-plated layer is clamped between the composite adhesive layer and the second transparent thin film layer and is 400-700 angstrom in thickness. The shading composite material has the protective functions of resisting ultraviolet and infrared ray and stopping visible light and the like, and is excellent in popularization and application value.
Description
Technical field
The present invention relates to a kind of shading composite.
Background technology
Current global mainstream thoughts is environmental protection, energy-conservation and safety.In building trade, the window of current building, in manufacture and application, can bring a large amount of energy resource consumptions and light pollution.Such as: when winter opens room heater, because the isolating power of window is poor, indoor a large amount of heat can be caused to be neutralized by the low temperature of outdoor by the heat transfer of window, cause a large amount of energy losses; In like manner, when summer opens air-conditioning, also have and there is identical problem, cause a large amount of energy losses.Meanwhile, city all kinds of lighting installation that is ornamental and advertising view at night also causes day by day serious light pollution, endangers the life of city dweller, rest and health.But building can have window again, so the hot-fluid how intercepted inside and outside window exchanges, and outdoor irradiation enters indoor harmful light source, and this just proposes new challenge to curtain window decorations field of new.
Summary of the invention
Technical problem to be solved by this invention there is provided a kind of and the diverse shading composite of prior art.Shading composite of the present invention, has the multiple-protection-functions such as good uvioresistant, infrared resistant, has good popularizing value.
The invention provides a kind of shading composite, it comprises one first mutually stacked transparent thin film layer, one first vacuum aluminium coated layer, a composite adhesive layer, one second transparent thin film layer, a polyethylene film composite bed and a nonwoven layer; The thickness of the first described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides.
In described shading composite, also can sandwiched one second vacuum aluminium coated layer between described composite adhesive layer and the second described transparent thin film layer, the thickness of the second described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides, or, also can sandwiched one colored paint layer or a colored ink printed layers between the first described transparent thin film layer and the first described vacuum aluminium coated layer.
In described shading composite, the surface of the first described transparent thin film layer also can arrange a colored paint layer or a colored ink printed layers, the first described transparent thin film layer is positioned in the middle of the first described vacuum aluminium coated layer and described colored paint layer, or is positioned in the middle of described colored ink printed layers.
Coating in described colored paint layer can be the coating that this area routine uses, and is preferably pigmented acrylic coating, such as black water acrylic emulsion.In the present invention, the model that described pigmented acrylic coating is preferably produced for Shanghai dongsheng New Materials Co., Ltd is the black water acrylic emulsion of DS-893.
Colored ink in described colored ink printed layers can be the colored ink that this area routine uses, the serial Colored plastic film gravure printing ink that the present invention preferred Shanghai Toyo Ink Manufacturing Co., Ltd produces.The color of described colored ink is preferably milky.The printing dry measure of described colored ink printed layers is preferably 1 ~ 3g/m
2.
Transparent membrane in the first described transparent thin film layer or the second transparent thin film layer can be the transparent membrane that this area routine uses, and is separately preferably pet film (abbreviation PET film).For described pet film, its thickness is preferably 6 ~ 23 microns, is more preferably 10 ~ 12 microns; Its light transmittance is preferably 80% ~ 92%, is more preferably 87% ~ 88%; The glossiness of its 45° angle is preferably 100 ~ 160 gloss unit, is more preferably 120 ~ 140 gloss unit; Its mist degree is preferably 1.5% ~ 3.0%, is more preferably 2.00% ~ 2.50%; The wetting tension in its sided corona treatment face preferably >=48mN/m.
Composite adhesive in described composite adhesive layer can be the composite adhesive of this area routine.Adhesive, ethyl acetate and curing agent mix by the preparation method of described composite adhesive, be more preferably after adhesive is mixed with ethyl acetate, then mix with curing agent.Described adhesive can be adhesive conventional in this area, and the model of preferably producing for Beijing Gaomeng Chemical Industry Co., Ltd is the adhesive of YH2955.Described curing agent can be the curing agent that this area routine uses, and the model of preferably producing for Beijing Gaomeng Chemical Industry Co., Ltd is the curing agent of YH35.Described adhesive and the mass ratio of ethyl acetate are preferably 1:1 ~ 1:2.The addition of described curing agent is preferably 1% ~ 5%, and described percentage refers to that the quality of curing agent accounts for the percentage of adhesive and ethyl acetate gross mass.In described composite adhesive layer, the coating dry measure of composite adhesive is preferably 3 ~ 5g/m
2.
In described polyethylene film composite bed, every square metre contains polyethylene 10 ~ 14 grams.Described polyethylene film composite bed is preferably coloured polyethylene film composite bed, and the technical method by this area routine obtains.Such as, melt extrude after color grain is mixed with polyethylene particles, together with nonwoven layer being pasted with adhesive layer by film compound working procedure, form polyethylene film composite bed.
Described nonwoven layer can be the non-woven fabrics that this area routine uses, and preferably, the unit grammes per square metre of described non-woven fabrics is 10 ~ 200g/m
2, be more preferably 20 ~ 40g/m
2, endwise tensile strength is 45N/5cm ~ 90N/5cm, and transverse tensile strength is 35N/5cm ~ 65N/5cm, and longitudinal fracture percentage elongation is 45% ~ 55%, and transverse breakage percentage elongation is 35% ~ 45%, and thickness is 0.05mm ~ 0.1mm.
In the present invention, the preparation method of described shading composite, it comprises the following step:
Method one:
(1) the non-corona surface of the first transparent membrane is carried out vacuum aluminum-coated processing process, obtain the first vacuum aluminium coated layer; Wherein, the thickness of the first described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides;
(2) by the non-corona surface of the second transparent membrane, adopt composite adhesive to be combined with each other with the first vacuum aluminium coated layer in step (1), obtain double-layer composite material;
(3) corona surface of the second transparent thin film layer in the double-layer composite material in step (2) and non-woven fabrics are combined with each other by the mode of polyethylene film compound;
Method two:
(I) corona surface of the first transparent membrane is carried out vacuum aluminum-coated processing process, obtain the first vacuum aluminium coated layer; Wherein, the thickness of the first described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides;
(II) the non-corona surface of the second transparent membrane is carried out vacuum aluminum-coated processing process, obtain the second vacuum aluminium coated layer, wherein, the thickness of the second described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides;
(III) adopt composite adhesive to be combined with each other the second vacuum aluminium coated layer in the first vacuum aluminium coated layer in step (I) and step (II), obtain double-layer composite material;
(IV) corona surface of the second transparent thin film layer in the double-layer composite material in step (III) and non-woven fabrics are combined with each other by the mode of polyethylene film compound.
In method one,
In step (1), the method for described vacuum aluminum-coated processing process and condition are method and the condition of the vacuum aluminum-coated processing process in this area routine.The present invention preferably adopts number of patent application to be aluminum plating method for plastic film described in 200810033524.5.The preferred following method of the present invention and condition:
A () opens vacuum storehouse, the first transparent membrane film package be placed on unreeling shaft, and be convergent on the refill of Scroll;
B () installs the evaporation boat that 10 ~ 26 wood property are two boron monoxides in vacuum storehouse;
C () installs 10 ~ 26 dish aluminium wires in vacuum storehouse, aluminium wire purity is more than 99.99%;
D vacuum storehouse is closed by ();
E () is bled, the vacuum values in vacuum storehouse is extracted into 3.0 × 10
-4more than mbar;
F the temperature of plated film hub is set as 5 DEG C ~-20 DEG C scopes by ();
G the operating temperature setting value of evaporation boat is 1300 DEG C ~ 1400 DEG C by ();
H the wire feed rate of aluminium wire is set as 500 ~ 1200mm/min by ();
(i) after the winding speed of plated film being set as 3.5 ~ 10m/s, start winding button, when speed reaches more than 3m/s, start baffle plate window and release the button, baffle plate window is opened, and film starts evaporation;
J () opens plasma treatment appts;
K aluminum layer thickness is set as by ()
;
L the uniformity of () on-line checkingi aluminium coated, the requirement of the uniformity is within ± 15%.
In step (2), the method of described compound and condition are method and the condition of this area routine, the preferred following method of the present invention: adopt model to be the coating complex machine of ST1650-21, with the nick version applicator roll that roller number is H20, the non-corona surface of the first vacuum aluminium coated layer in step (1) and the second transparent thin film layer is combined with each other, slaking, cooling.Wherein, the method for described slaking and condition are method and the condition of this area routine, and the temperature of described slaking is preferably 55 DEG C ~ 60 DEG C, and the time of described slaking is preferably more than 24 hours.
In step (3), the method for described film compound and condition are method and the condition of this area routine.In the present invention, the method for described film compound preferably for adopt model be 2200 film compounding machine carry out the operation of film compound.Effective compound width of described film compounding machine is preferably 1000 ~ 2100mm, and heating power is preferably 70 ~ 80kw.
In step (1), the corona surface of the first described transparent membrane also can be printed with color ink further, obtains a colored ink printed layers.The method of described colored ink printing and condition are method and the condition of this area routine.The present invention preferably adopts 1500C type computer to version intaglio press, carries out full version printing to the corona surface of the first transparent thin film layer, and version background color is expired in printing.
In method two,
In step (I) and/or step (II), the method for described vacuum aluminum-coated processing process and condition are the conventional method of this area vacuum aluminum-coated processing process and condition.The present invention preferably adopts number of patent application to be aluminum plating method for plastic film described in 200810033524.5.Particularly, described vacuum aluminum-coated method and condition ditto described in.
In step (III), the method for described compound and condition, and/or in step (IV), described in the method for described film compound and condition are all the same.
In step (I), the corona surface of the first described transparent membrane also can comprise the operation of coating colored paint further, obtains a colored paint layer, on this colored paint layer, then carries out vacuum aluminum-coated processing process, obtain the first vacuum aluminium coated layer.The method of described coating colored paint and condition are method and the condition of this area routine, preferably adopt vast 2100 type coating machines to carry out the operation be coated with.After described coating terminates, preferably also comprise dry operation.Wherein, the temperature of described drying is preferably 85 DEG C ~ 95 DEG C.The time of described drying is preferably 10s ~ 20s.
In the present invention, when actual production curtain, the surface at non-woven fabrics place is generally towards protection main body, therefore for obtaining better beautiful decoration effect, in method one and/or method two, the preparation method of described shading composite, also can comprise the following step further: by described double-layer composite material and non-woven fabrics, be pressed together by the pressure roller engraving certain flower pattern, obtain various ornamental decorative pattern.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, obtain the preferred embodiments of the invention.
Agents useful for same of the present invention and raw material are all commercially.
Positive progressive effect of the present invention is:
Shading composite of the present invention, has uvioresistant, infrared resistant and intercepts the multiple-protection-functions such as visible ray, having good popularizing value.
Accompanying drawing explanation
Fig. 1 is the structural representation of the shading composite of embodiment 1.
Fig. 2 is the structural representation of the shading composite of embodiment 2.
Detailed description of the invention
Mode below by embodiment further illustrates the present invention, but does not therefore limit the present invention among described scope of embodiments.The experimental technique of unreceipted actual conditions in the following example, conventionally and condition, or selects according to catalogue.
Embodiment 1
Fig. 1 is the structural representation of the shading composite of embodiment 1.This shading composite comprises stacked colored ink printed layers 12,1 first transparent thin film layer 11,1 first vacuum aluminium coated layer 13, composite adhesive layer 14,1 second transparent thin film layer 21, polyethylene film composite bed 22 and a nonwoven layer 31 successively.
Raw material used in the preparation method of this shading composite and source:
1. the first transparent thin film layer 11 and the second transparent thin film layer 21 all select thickness to be the PET film of 12 microns, and its light transmittance 88%, 45 ° of glossiness 136 gloss unit, mist degree 2.25%, its surface is wetting tension >=48mN/m after sided corona treatment.Other physical performance indexs meet National Standard of the People's Republic of China GB/T16958-2008 " packaging biaxially oriented polyester film ".
2. printing equipment is purchased from Wenzhou Xin Xu printing packaging Machinery Co., Ltd., and 1500C type computer is to version intaglio press.Purchase the serial Colored plastic film gravure printing ink produced from Shanghai Toyo Ink Manufacturing Co., Ltd.
3. vacuum metallization processes aluminizes equipment purchased from German Lai Bao photoelectricity technology corporation, Ltd., PRO-M2100 type packaging material web coating system.
4. coating complex machine is purchased from Zhongshan City Songde Coating Machine Co., Ltd, model: ST1650-21.
5. applicator roll is the nick version applicator roll that roller number is H20.
6. adhesive is purchased from Beijing Gaomeng Chemical Industry Co., Ltd, model: YH2955.
7. non-woven fabrics spunbond polyester smooth roll base tire (PET) of producing purchased from Guoqiao Ind Co., Ltd., Jiangxi, is 100% polyester material, unit grammes per square metre 40g/m
2, endwise tensile strength 90N/5cm, transverse tensile strength 65N/5cm, longitudinal fracture percentage elongation 45%, transverse breakage percentage elongation 35%, thickness 0.1mm.
8. film compounding machine is the film compounding machine of 2200 purchased from the model of state city Da Li plastics machinery Co., Ltd, maximum compound width 2100mm, heating power 73kW.
Wherein, adhesive in use, after the ratio of 1:1 adds ethyl acetate solvent first in mass ratio, is fully uniformly mixed; Add the curing agent of 1% again, described percentage refers to that the quality of curing agent accounts for the percentage of adhesive and ethyl acetate gross mass, and (purchased from Beijing Gaomeng Chemical Industry Co., Ltd, model is YH35 to curing agent), prepares composite adhesive after mixing, for subsequent use.
The preparation method of this shading composite is as follows:
(1) first carry out the typography of colored ink in the sided corona treatment face of the first transparent thin film layer 11, carry out full version printing to the sided corona treatment face of the first transparent thin film layer 11, milky full version background color in printing, printing dry measure is 1 ~ 3g/m
2.
(2) carry out vacuum aluminum-coated processing to the non-corona treated side of the first transparent thin film layer 11 be completed for printing and process to obtain the first vacuum aluminium coated layer 13, this vacuum aluminum-coated layer thickness is 600 ± 50 Ethylmercurichlorendimides; The method of described vacuum aluminum-coated processing process is as follows:
A () opens vacuum storehouse, the first transparent membrane film package be placed on unreeling shaft, and be convergent on the refill of Scroll;
B () installs the evaporation boat (producing the film of 1530 mm in width) that 16 wood property are two boron monoxides in vacuum storehouse;
C () installs 16 dishes aluminium wire (producing the film of 1530 mm in width) in vacuum storehouse, aluminium wire purity is more than 99.99%;
D vacuum storehouse is closed by ();
E () is bled, the vacuum values in vacuum storehouse is extracted into 3.0 × 10
-4more than mbar;
F the temperature of plated film hub is set as 0 DEG C ~-20 DEG C scopes by ();
G the operating temperature setting value of evaporation boat is 1300 DEG C ~ 1400 DEG C by ();
H the wire feed rate of aluminium wire is set as 500 ~ 1200mm/min by ();
(i) after the winding speed of plated film being set as 3.5 ~ 8m/s, start winding button, when speed reaches more than 3m/s, start baffle plate window and release the button, baffle plate window is opened, and film starts evaporation;
J () opens plasma treatment appts;
K aluminum layer thickness is set as by ()
L the uniformity of () on-line checkingi aluminium coated, the requirement of the uniformity is within ± 15%.
(3) with the second transparent thin film layer 21 compound.Adopt coating complex machine, with applicator roll, (coating dry measure is 3 ~ 5g/m
2), composite adhesive is first coated on the non-corona treated side of the second transparent thin film layer 21, after crossing drying tunnel prebake, compound is carried out with the first vacuum aluminum-coated face of the first transparent thin film layer 11, after entire volume product compound completes, carry out the maturation process of 24 hours in the curing chamber that the film volume that compound is good proceeds to constant temperature 60 DEG C immediately, the complete curing chamber that shifts out immediately of maturation process cools for subsequent use naturally.
(4) film compound working procedure: adopt film compounding machine, using PE(polyethylene) pellet melting extrudes and as bonding agent, is pasted together by the corona surface of nonwoven layer 31 and the second transparent thin film layer 21, PE extrusion capacity 10 ~ 14g/m
2.
Obtained by said method and there is uvioresistant, infrared ray and can the shading composite of shading.This shading composite carries out cutting, sizing, bonding or after making through downstream client, finally can be made into curtain or other shading products of arbitrary shape.
The product grab sample that the shading composite of embodiment 1 is obtained detects, average visible photopic light transmitance 0.055% [design object≤0.1%], infrared light transmission 0.023% [design object≤0.05%], ultraviolet ray transmissivity 0.027% [design object≤0.05%], reach the requirement of design completely, concrete data refer to table 1.
Table 1
| / | Visible light transmissivity | Infrared light transmission | Ultraviolet ray transmissivity |
| Test point 1 | 0.046% | 0.015% | 0.020% |
| Test point 2 | 0.048% | 0.020% | 0.025% |
| Test point 3 | 0.056% | 0.018% | 0.030% |
| Test point 4 | 0.054% | 0.022% | 0.025% |
| Test point 5 | 0.058% | 0.030% | 0.035% |
| Test point 6 | 0.060% | 0.034% | 0.029% |
| Test point 7 | 0.057% | 0.018% | 0.030% |
| Test point 8 | 0.060% | 0.028% | 0.024% |
| Mean value | 0.055% | 0.023% | 0.027% |
Embodiment 2
Fig. 2 is the structural representation of the shading composite of embodiment 2.This shading composite comprises one first stacked transparent thin film layer 11, colored paint layer 10,1 first vacuum aluminium coated layer 13, composite adhesive layer 14,1 second vacuum aluminium coated layer 23,1 second transparent thin film layer 21, film composite bed 22 and a nonwoven layer 31 successively.
Raw material used in the preparation method of this shading composite and source:
1. the first transparent thin film layer 11 and the second transparent thin film layer 21 all select thickness to be the PET film of 12 microns, and light transmittance 87%, 45 ° of glossiness 125 gloss unit, mist degree 2.27%, its surface is wetting tension >=48mN/m after sided corona treatment.Other physical performance indexs meet National Standard of the People's Republic of China GB/T16958-2008 " packaging biaxially oriented polyester film ".
2. coating apparatus adopts vast 2100 type coating machines.Coating is the black water acrylic emulsion of DS-893 purchased from the model that Shanghai dongsheng New Materials Co., Ltd produces.
3. vacuum metallization processes aluminizes equipment purchased from German Lai Bao photoelectricity technology corporation, Ltd., PRO-M2100 type packaging material web coating system.
4. coating complex machine is purchased from Zhongshan City Songde Coating Machine Co., Ltd, model: ST1650-21.
5. adhesive is purchased from Beijing Gaomeng Chemical Industry Co., Ltd, model: YH2955.
6. non-woven fabrics spunbond polyester smooth roll base tire (PET) of producing purchased from Guoqiao Ind Co., Ltd., Jiangxi, is 100% polyester material, its unit grammes per square metre 20g/m
2, endwise tensile strength 45N/5cm, transverse tensile strength 35N/5cm, longitudinal fracture percentage elongation 55%, transverse breakage percentage elongation 45%, thickness 0.05mm.
7. film compounding machine is the film compounding machine of 2200 purchased from the model of state city Da Li plastics machinery Co., Ltd, and the maximum compound width of this compounding machine is 2100mm, and heating power is 73kW.
Wherein, adhesive in use, after the ratio of 1:1 adds ethyl acetate solvent first in mass ratio, is fully uniformly mixed; Add the curing agent of 5% again, described percentage refers to that the quality of curing agent accounts for the percentage (purchased from Beijing Gaomeng Chemical Industry Co., Ltd, model is YH35) of adhesive and ethyl acetate gross mass, prepares composite adhesive after mixing, for subsequent use.
The preparation method of this shading composite is as follows:
(I) coating of coating is carried out in the sided corona treatment face of the first transparent thin film layer 11.Carry out drying process after coating, dry temperature is 85 ~ 95 DEG C.2100 type coating machines have 9 joint drying tunnels, wherein, dry temperature is set as: drying tunnel one is 85 DEG C, drying tunnel two is 85 DEG C, drying tunnel three is 90 DEG C, drying tunnel four is 92 DEG C, drying tunnel five is 95 DEG C, drying tunnel six is 95 DEG C, drying tunnel seven is 95 DEG C, drying tunnel eight is 90 DEG C, drying tunnel nine is 85 DEG C.Dry total duration is 10 ~ 20 seconds, and anilox roll of coating machine selects 160 orders, and coating dry measure is 3g/m
2.
(II) vacuum aluminum-coated processing is carried out to colored paint layer 10 surface of the first transparent thin film layer 11 be coated with and process to obtain the first vacuum aluminium coated layer 13.The thickness of this vacuum aluminium coated layer is 450 ± 50 Ethylmercurichlorendimides; The method of described vacuum aluminum-coated processing process is as follows:
A () opens vacuum storehouse, the first transparent membrane film package be placed on unreeling shaft, and be convergent on the refill of Scroll;
B () installs the evaporation boat (producing the film of 1530 mm in width) that 20 wood property are two boron monoxides in vacuum storehouse;
C () needs according to the fabric width of aluminizer, in vacuum storehouse, install 20 dishes aluminium wire (producing the film of 1850 mm in width), aluminium wire purity is more than 99.99%;
D vacuum storehouse is closed by ();
E () is bled, the vacuum values in vacuum storehouse is extracted into 3.0 × 10
-4more than mbar;
F the temperature of plated film hub is set as 5 DEG C ~-10 DEG C scopes by ();
G the operating temperature setting value of evaporation boat is 1300 DEG C ~ 1400 DEG C by ();
H the wire feed rate of aluminium wire is set as 500 ~ 1300mm/min by ();
(i) after the winding speed of plated film being set as 4.5 ~ 10m/s, start winding button, when speed reaches more than 3m/s, start baffle plate window and release the button, baffle plate window is opened, and film starts evaporation;
J () opens plasma treatment appts;
K aluminum layer thickness is set as by ()
L the uniformity of () on-line checkingi aluminium coated, the requirement of the uniformity is within ± 10%.
(III) the first transparent thin film layer 11 and the second transparent thin film layer 21 are combined with each other.Adopt coating complex machine, with applicator roll, (coating dry measure is 3 ~ 5g/m
2), composite adhesive is first coated on the surface of the first vacuum aluminium coated layer 13 of the first transparent thin film layer 11, after crossing drying tunnel prebake, with the second vacuum aluminium coated layer 23(second transparent thin film layer 21 of the second transparent thin film layer 21 carry out vacuum aluminum-coated process the method that processes and obtain vacuum aluminum-coated and condition the same) carry out compound, after entire volume product compound completes, carry out the maturation process of 24 hours in the curing chamber that the film volume that compound is good should proceed to constant temperature 55 DEG C immediately, the complete curing chamber that should shift out immediately of maturation process cools for subsequent use naturally.
(IV) film compound working procedure: adopt film compounding machine, using PE(polyethylene) pellet melting extrudes as bonding agent, the corona surface of nonwoven layer 31 and the second transparent thin film layer 21 is pasted together, PE extrusion capacity 10 ~ 14g/m
2.
Obtained by said method and there is uvioresistant, infrared ray and can the shading composite of shading.This shading composite carries out cutting, sizing, bonding or after making through downstream client, finally can be made into curtain or other shading products of arbitrary shape.
The product grab sample that the shading composite of embodiment 2 is obtained detects, average visible photopic light transmitance 0.095% [design object≤0.1%], infrared light transmission 0.042% [design object≤0.05%], ultraviolet ray transmissivity 0.048% [design object≤0.05%], reach designing requirement, concrete data refer to table 2.
Table 2
| / | Visible light transmissivity | Infrared light transmission | Ultraviolet ray transmissivity |
| Test point 1 | 0.092% | 0.044% | 0.050% |
| Test point 2 | 0.090% | 0.038% | 0.048% |
| Test point 3 | 0.099% | 0.035% | 0.044% |
| Test point 4 | 0.092% | 0.040% | 0.049% |
| Test point 5 | 0.094% | 0.048% | 0.046% |
| Test point 6 | 0.095% | 0.043% | 0.048% |
| Test point 7 | 0.096% | 0.043% | 0.050% |
| Test point 8 | 0.098% | 0.044% | 0.048% |
| Mean value | 0.095% | 0.042% | 0.048% |
Comparative example 1
When the vacuum aluminum-coated layer thickness in shading composite is lower than 400 Ethylmercurichlorendimide, the product that this shading composite is obtained, its uvioresistant and ultrared function not good, the structural representation of composite obtained in comparative example 1 can see the structural representation in embodiment 2.
Except separately explaining, all the other concrete operation methods and condition are see embodiments of the invention 2.
Vacuum aluminum-coated layer thickness is 300 ± 50 Ethylmercurichlorendimides; The method of described vacuum aluminum-coated processing process is as follows:
A () opens vacuum storehouse, the first transparent membrane film package be placed on unreeling shaft, and be convergent on the refill of Scroll;
B () installs the evaporation boat (producing the film of 1550 mm in width) that 16 wood property are two boron monoxides in vacuum storehouse;
C () installs 16 dishes aluminium wire (producing the film of 1550 mm in width) in vacuum storehouse, aluminium wire purity is more than 99.99%;
D vacuum storehouse is closed by ();
E () is bled, the vacuum values in vacuum storehouse is extracted into 3.0 × 10
-4more than mbar;
F the temperature of plated film hub is set as 5 DEG C ~-10 DEG C scopes by ();
G the operating temperature setting value of evaporation boat is 1300 DEG C ~ 1400 DEG C by ();
H the wire feed rate of aluminium wire is set as 500 ~ 1200mm/min by ();
(i) after the winding speed of plated film being set as 5.5 ~ 12m/s, start winding button, when speed reaches more than 4m/s, start baffle plate window and release the button, baffle plate window is opened, and film starts evaporation;
J () opens plasma treatment appts;
K aluminum layer thickness is set as by ()
L the uniformity of () on-line checkingi aluminium coated, the requirement of the uniformity is within ± 10%.
The product grab sample that the shading composite of comparative example 1 is obtained detects, average visible photopic light transmitance 0.106% [design object≤0.1%], infrared light transmission 0.052% [design object≤0.05%], ultraviolet ray transmissivity 0.058% [design object≤0.05%], do not reach designing requirement, concrete data refer to table 3.
Table 3
| / | Visible light transmissivity | Infrared light transmission | Ultraviolet ray transmissivity |
| Test point 1 | 0.110% | 0.055% | 0.058% |
| Test point 2 | 0.096% | 0.049% | 0.060% |
| Test point 3 | 0.094% | 0.053% | 0.054% |
| Test point 4 | 0.098% | 0.046% | 0.058% |
| Test point 5 | 0.120% | 0.049% | 0.055% |
| Test point 6 | 0.114% | 0.050% | 0.058% |
| Test point 7 | 0.098% | 0.054% | 0.058% |
| Test point 8 | 0.114% | 0.058% | 0.060% |
| Mean value | 0.106% | 0.052% | 0.058% |
Comparative example 2
When the vacuum aluminum-coated layer thickness in shading composite is higher than 700 Ethylmercurichlorendimide, the product that this shading composite is obtained, its uvioresistant and ultrared function are not good yet, and the structural representation of shading composite obtained in comparative example 2 also can see the structural representation in embodiment 2.
Except separately explaining, all the other concrete methods of operating and condition are see embodiments of the invention 2.
Vacuum aluminum-coated layer thickness is 750 ± 50 Ethylmercurichlorendimides; The method of described vacuum aluminum-coated processing process is as follows:
A () opens vacuum storehouse, the first transparent membrane film package be placed on unreeling shaft, and be convergent on the refill of Scroll;
B () installs the evaporation boat (producing the film of 1550 mm in width) that 16 wood property are two boron monoxides in vacuum storehouse;
C () installs 16 dishes aluminium wire (producing the film of 1550 mm in width) in vacuum storehouse, aluminium wire purity is more than 99.99%;
D vacuum storehouse is closed by ();
E () is bled, the vacuum values in vacuum storehouse is extracted into 3.0 × 10
-4more than mbar;
F the temperature of plated film hub is set as-5 DEG C ~-20 DEG C scopes by ();
G the operating temperature setting value of evaporation boat is 1300 DEG C ~ 1400 DEG C by ();
H the wire feed rate of aluminium wire is set as 800 ~ 1200mm/min by ();
(i) after the winding speed of plated film being set as 3.0 ~ 5.5m/s, start winding button, when speed reaches more than 3.0m/s, start baffle plate window and release the button, baffle plate window is opened, and film starts evaporation;
J () opens plasma treatment appts;
K aluminum layer thickness is set as by ()
L the uniformity of () on-line checkingi aluminium coated, the requirement of the uniformity is within ± 20%.
The product grab sample that the shading composite of comparative example 2 is obtained detects, average visible photopic light transmitance 0.036% [design object≤0.1%], infrared light transmission 0.017% [design object≤0.05%], ultraviolet ray transmissivity 0.033% [design object≤0.05%], but on standard detection lamp box, inspect the irregular diaphanous spot can seeing that diameter 0.5 ~ 3.0 millimeter does not wait, therefore instructions for use can not be met, the detected value some some during random detection exceedes design object value, and concrete numerical value refers to table 4.
Table 4
| / | Visible light transmissivity | Infrared light transmission | Ultraviolet ray transmissivity |
| Test point 1 | 0.028% | 0.010% | 0.060% |
| Test point 2 | 0.020% | 0.009% | 0.024% |
| Test point 3 | 0.015% | 0.016% | 0.021% |
| Test point 4 | 0.025% | 0.057% | 0.017% |
| Test point 5 | 0.015% | 0.008% | 0.015% |
| Test point 6 | 0.014% | 0.006% | 0.052% |
| Test point 7 | 0.012% | 0.012% | 0.030% |
| Test point 8 | 0.023% | 0.014% | 0.045% |
| Mean value | 0.036% | 0.0517% | 0.033% |
Claims (11)
1. a shading composite, is characterized in that comprising one first mutually stacked transparent thin film layer, one first vacuum aluminium coated layer, a composite adhesive layer, one second transparent thin film layer, a polyethylene film composite bed and a nonwoven layer; The thickness of the first described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides.
2. shading composite as claimed in claim 1, it is characterized in that, the surface of the first described transparent thin film layer also arranges a colored paint layer or a colored ink printed layers, the first described transparent thin film layer is positioned in the middle of the first described vacuum aluminium coated layer and described colored paint layer, or is positioned in the middle of described colored ink printed layers.
3. shading composite as claimed in claim 1, is characterized in that, between described composite adhesive layer and the second described transparent thin film layer, go back sandwiched one second vacuum aluminium coated layer, the thickness of the second described vacuum aluminium coated layer is 400 ~ 700 Ethylmercurichlorendimides.
4. shading composite as claimed in claim 3, is characterized in that, between the first described transparent thin film layer and the first described vacuum aluminium coated layer, go back sandwiched one colored paint layer or a colored ink printed layers.
5. the shading composite as described in claim 2 or 4, is characterized in that, the colored paint in described colored paint layer is pigmented acrylic coating; And/or the printing dry measure of described colored ink printed layers is 1 ~ 3g/m
2.
6. shading composite as claimed in claim 1, is characterized in that, the transparent membrane in the first described transparent thin film layer or the second described transparent thin film layer is separately pet film.
7. shading composite as claimed in claim 6, it is characterized in that, described pet film, thickness is 6 ~ 23 microns; Light transmittance is 80% ~ 92%; The glossiness of 45° angle is 100 ~ 160 gloss unit; Mist degree is 1.5% ~ 3.0%; Wetting tension >=the 48mN/m in sided corona treatment face.
8. shading composite as claimed in claim 1, it is characterized in that, the composite adhesive in described composite adhesive layer is obtained by following preparation method: adhesive, ethyl acetate and curing agent are mixed.
9. shading composite as claimed in claim 8, it is characterized in that, in the preparation method of described composite adhesive, described adhesive and the mass ratio of ethyl acetate are 1:1 ~ 1:2; The addition of described curing agent is 1% ~ 5%, and described percentage refers to that the quality of curing agent accounts for the percentage of adhesive and ethyl acetate gross mass; And/or the coating dry measure of composite adhesive is 3 ~ 5g/m in described composite adhesive layer
2.
10. shading composite as claimed in claim 1, is characterized in that, in described polyethylene film composite bed, every square metre contains polyethylene 10 ~ 14 grams.
11. shading composites as claimed in claim 1, it is characterized in that, in described nonwoven layer, the unit grammes per square metre of non-woven fabrics is 10 ~ 200g/m
2, endwise tensile strength is 45N/5cm ~ 90N/5cm, and transverse tensile strength is 35N/5cm ~ 65N/5cm, and longitudinal fracture percentage elongation is 45% ~ 55%, and transverse breakage percentage elongation is 35% ~ 45%, and thickness is 0.05mm ~ 0.1mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410145818.2A CN104972716A (en) | 2014-04-11 | 2014-04-11 | Shading composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410145818.2A CN104972716A (en) | 2014-04-11 | 2014-04-11 | Shading composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104972716A true CN104972716A (en) | 2015-10-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410145818.2A Pending CN104972716A (en) | 2014-04-11 | 2014-04-11 | Shading composite material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11186070B2 (en) | 2017-02-06 | 2021-11-30 | Hunter Douglas Inc. | Room darkening material and architectural covering made from same |
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| WO2001068360A1 (en) * | 2000-03-15 | 2001-09-20 | Cpfilms, Inc. | Flame retardant optical films |
| CN2570432Y (en) * | 2002-09-13 | 2003-09-03 | 高迎州 | Draw-rolling type sun-shading curtain |
| CN201727332U (en) * | 2009-12-08 | 2011-02-02 | 陈旃 | Transparent heat-isolating and energy-saving curtain |
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| WO2001068360A1 (en) * | 2000-03-15 | 2001-09-20 | Cpfilms, Inc. | Flame retardant optical films |
| CN2570432Y (en) * | 2002-09-13 | 2003-09-03 | 高迎州 | Draw-rolling type sun-shading curtain |
| CN201727332U (en) * | 2009-12-08 | 2011-02-02 | 陈旃 | Transparent heat-isolating and energy-saving curtain |
| CN203110898U (en) * | 2013-02-28 | 2013-08-07 | 周新怀 | Car heat-insulating cover |
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| US11186070B2 (en) | 2017-02-06 | 2021-11-30 | Hunter Douglas Inc. | Room darkening material and architectural covering made from same |
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