CN104962210B - One kind not staying residue glue Protection glue band and preparation method thereof - Google Patents
One kind not staying residue glue Protection glue band and preparation method thereof Download PDFInfo
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- CN104962210B CN104962210B CN201510415743.XA CN201510415743A CN104962210B CN 104962210 B CN104962210 B CN 104962210B CN 201510415743 A CN201510415743 A CN 201510415743A CN 104962210 B CN104962210 B CN 104962210B
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Abstract
The present invention relates to one kind not staying residue glue Protection glue band; it is included in containing the U.S. line paper handled by impregnation in immersion liquid; the mould release for being coated on U.S. line paper curl face side and the barrier for being coated on the crimped paper other side, which is characterized in that glue, curing agent and anti-UV agent are coated on barrier.The invention further relates to a kind of preparation methods for not staying residue glue Protection glue band.The adhesive tape of the present invention under various circumstances using residue glue can not stayed for a long time, and with simple production process, harm to the human body is small, environment protection health, while opposite hot-fusible pressure-sensitive adhesive, can saving heat energy, reduce the cost of raw material.
Description
Technical field
The invention belongs to Protection glue band production fields, and in particular to one kind not staying residue glue Protection glue band and preparation method thereof.
Background technology
Protection glue band on the market, in process of production can be to environment one is being made with easy volatile solvents such as benzene classes at present
Certain harm is polluted and also done to human body, and this adhesive tape lacks anti-UV functions, pole is used under light environment
It is easy to aging；Another is using hot melt adhesive as adhesive, and this adhesive is extremely unstable, glue viscosity with temperature liter
Height can gradually change, and after reaching certain temperature, since the cohesive force of glue is bad, residue glue can be left after body surface stripping.
Therefore, for the deficiency of current Protection glue band, a kind of completely new kind need to be developed to solve the defect of prior art processes.
Invention content
The present invention provides to solve existing Protection glue band in the shortcoming in the fields such as technique, production, technology, environment
A kind of Protection glue band not staying residue glue.The present invention has that simple production process, harm to the human body be small, environment protection health, while opposite
Hot-fusible pressure-sensitive adhesive, can saving heat energy, the reduction cost of raw material.
Specifically, one aspect of the present invention be related to it is a kind of not staying residue glue Protection glue band, be included in containing passing through at impregnation in immersion liquid
The U.S. line paper of reason, the mould release for being coated on U.S. line paper curl face side and the barrier for being coated on the U.S. line paper other side, it is special
Sign is, glue, curing agent and anti-UV agent are coated on barrier.
In one embodiment of the invention, described containing the styrene-butadiene latex that immersion liquid is concentration 10%-30%, preferably
Ground, the coating weight containing immersion liquid is in 12g/ ㎡ -15g/ ㎡；Preferably, the moisture of the U.S. line paper of impregnated liquid processing is controlled in 5%-
10%；
In one embodiment of the invention, the mould release is the acrylic acid aqueous solution of concentration 20%-30%；It is excellent
The coating weight of selection of land, mould release is 6g/ ㎡ -8g/ ㎡.
In one embodiment of the invention, the barrier is the modified butadiene-styrene latex of a concentration of 5%-10%；
Preferably, barrier coating weight is 4g/ ㎡ -6g/ ㎡.
In one embodiment of the invention, the glue is acrylic acid aqueous pressure sensitive adhesive；Preferably, curing agent
Addition is 1%-3%；Preferably, the addition of anti-UV agent is 3 ‰ -5 ‰；Preferably, the painting of glue, curing agent and anti-UV agent
Cloth amount is 30g/ ㎡ -40g/ ㎡.
In yet another embodiment of the present invention, of the invention do not stay residue glue Protection glue band, preparation method include such as
Lower step：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier.
Preferably, it is concentration 10%-30% styrene-butadiene latexes containing immersion liquid in step a, treatment temperature is 150 DEG C -180 DEG C, when
Between be 10s-20s；Preferably, the coating weight containing immersion liquid is in 12g/ ㎡ -15g/ ㎡；Preferably, U.S. of impregnated liquid processing is controlled
The moisture of line paper is in 5%-10%.
Preferably, in step b mould release be a concentration of 20%-30% acrylic acid aqueous solution, treatment temperature be 130 DEG C-
160 DEG C, time 8s-15s；Preferably, the coating weight of mould release is 6g/ ㎡ -8g/ ㎡.
Preferably, the modified butadiene-styrene latex that barrier is a concentration of 5%-10% in step c, treatment temperature are 80 DEG C -100
DEG C, time 20s-30s；Preferably, barrier coating weight is 4g-6g.
Preferably, glue is acrylic acid aqueous pressure sensitive adhesive in step d, and treatment temperature is 70 DEG C -90 DEG C, time 20s-
40s；Preferably, the addition of curing agent is 1%-3%；Preferably, the addition of anti-UV agent is 3 ‰ -5 ‰；Preferably, glue
The coating weight of water, curing agent and anti-UV agent is 30g-40g.
Another aspect of the present invention is related to a kind of preparation method for not staying residue glue Protection glue band, includes the following steps：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier.
In an embodiment of the invention, it is concentration 10%-30% styrene-butadiene latexes, processing temperature containing immersion liquid in step a
Degree is 150 DEG C -180 DEG C, time 10s-20s；Preferably, the coating weight containing immersion liquid is in 12g/ ㎡ -15g/ ㎡；Preferably, it controls
The moisture of the U.S. line paper of impregnated liquid processing is made in 5%-10%.
In yet another embodiment of the present invention, mould release is that the acrylic acid of a concentration of 20%-30% is water-soluble in step b
Liquid, treatment temperature are 130 DEG C -160 DEG C, time 8s-15s；Preferably, the coating weight of mould release is 6g/ ㎡ -8g/ ㎡.
In yet further embodiment of the invention, barrier is the modification butadiene-styrene rubber of a concentration of 5%-10% in step c
Breast, treatment temperature are 80 DEG C -100 DEG C, time 20s-30s；Preferably, barrier coating weight is 4g/ ㎡ -6g/ ㎡.
In yet further embodiment of the invention, glue is acrylic acid aqueous pressure sensitive adhesive, treatment temperature 70 in step d
DEG C -90 DEG C, time 20s-40s；Preferably, the addition of curing agent is 1%-3%；Preferably, the addition of anti-UV agent is
3‰-5‰；Preferably, the coating weight of glue, curing agent and anti-UV agent is 30g/ ㎡ -40g/ ㎡.
U.S. line paper is selected to carry out impregnation processing, control temperature and speed using styrene-butadiene latex in the concrete technology flow process of the present invention
Degree ensures impregnation dosage, and guarantee is carried out to do release processing in next step；Using containing impregnated paper acrylic acid aqueous solution is used in wrinkle face
Release processing is carried out, the humidity of paper and the angle of scraper are controlled, ensures mould release coating weight, it is ensured that release effect；Using changing
Property styrene-butadiene latex carry out barrier processing, control dosage, ensure the surface tension of paper；It is being obstructed using acrylic acid aqueous pressure sensitive adhesive
Surface carries out gluing processing, it is ensured that coating weight ensures the using effect of adhesive tape.
The beneficial effects of the present invention are：The present invention carries out impregnation processing using styrene-butadiene latex, so that paper is possessed good
Flexibility, fabulous tensile strength and outstanding elongation percentage.Secondly use acrylic acid as mould release, it is ensured that after its gluing from
The stability of type.Then barrier processing is carried out using modified butadiene-styrene latex, it is ensured that paper coated face possesses stable surface
Power.Finally on process above paper, be coated with acrylic acid water-borne pressure sensitive adhesive, ensure that adhesive tape possess stable cohesive force, just
Viscosity and stripping, make adhesive tape under various circumstances using can for a long time not stay residue glue.
Present invention will be further explained below with reference to specific examples.
Specific implementation mode
Embodiment 1
Residue glue Protection glue band is not stayed in preparation, includes the following steps：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing in a concentration of 10% styrene-butadiene latex, treatment temperature is
150 DEG C, time 10S, coating weight controls the moisture of the U.S. line paper of impregnated liquid processing 5% in 12g/ ㎡；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing, with a concentration of 20%
Acrylic acid aqueous solution carry out release processing, treatment temperature is 130 DEG C, time 8S, and mould release coating weight is 6g/ ㎡；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing, with a concentration of 5%
Modified butadiene-styrene latex carries out barrier processing, and treatment temperature is 80 DEG C, time 20S, and barrier coating weight is 4g/ ㎡；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier, glue are acrylic acid aqueous pressure sensitive adhesive, and
1% curing agent, 3 ‰ anti-UV agent are added, treatment temperature is 70 DEG C, time 20S, and coating weight is 30g/ ㎡.
After tested, gained adhesive tape possesses good flexibility, tensile strength reaches 80N/IN or more, elongation percentage reaches 15%
More than；Coated face possesses stable surface tension；Release stability is good after gluing；Tape performance：Cohesive force can reach 24H with
Upper, tack 20#, peeling force 10N/IN.(burning sun illumination, humidity are rained) use can for a long time not under various circumstances for adhesive tape
Stay residue glue.
Embodiment 2
Residue glue Protection glue band is not stayed in preparation, includes the following steps：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing in a concentration of 30% styrene-butadiene latex, treatment temperature is
180 DEG C, time 20S, coating weight is in 15g/ ㎡, and control moisture is 10%；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing, with a concentration of 30%
Acrylic acid aqueous solution carry out release processing, treatment temperature is 160 DEG C, time 15S, and mould release coating weight is 8g/ ㎡；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing, with a concentration of 10%
Modified butadiene-styrene latex carries out barrier processing, and treatment temperature is 100 DEG C, time 30S, and barrier coating weight is 6g/ ㎡；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier, glue are acrylic acid aqueous pressure sensitive adhesive, and
3% curing agent, 5 ‰ anti-UV agent are added, treatment temperature is 90 DEG C, time 40S, and coating weight is 40g/ ㎡.
After tested, gained adhesive tape possesses good flexibility, tensile strength reaches 80N/IN or more, elongation percentage reaches 15%
More than；Coated face possesses stable surface tension；Release stability is good after gluing；Tape performance：Cohesive force can reach 36H with
Upper, tack 23#, peeling force 12N/IN.(burning sun illumination, humidity are rained) use can for a long time not under various circumstances for adhesive tape
Stay residue glue.
Embodiment 3
Residue glue Protection glue band is not stayed in preparation, includes the following steps：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing in a concentration of 10% styrene-butadiene latex, treatment temperature is
180 DEG C, time 10S, coating weight is in 15g/ ㎡, and control moisture is 5%；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing, with a concentration of 30%
Acrylic acid aqueous solution carry out release processing, treatment temperature is 130 DEG C, time 15S, and mould release coating weight is 6g/ ㎡；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing, with a concentration of 10%
Modified butadiene-styrene latex carries out barrier processing, and treatment temperature is 80 DEG C, time 20S, and barrier coating weight is 6g/ ㎡；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier, glue are acrylic acid aqueous pressure sensitive adhesive, and
1% curing agent, 5 ‰ anti-UV agent are added, treatment temperature is 70 DEG C, time 40S, and coating weight is 30g/ ㎡.
After tested, gained adhesive tape possesses good flexibility, tensile strength reaches 80N/IN or more, elongation percentage reaches 15%
More than；Coated face possesses stable surface tension；Release stability is good after gluing；Tape performance：Cohesive force can reach 36H with
Upper, tack 23#, peeling force 12N/IN.(burning sun illumination, humidity are rained) use can for a long time not under various circumstances for adhesive tape
Stay residue glue.
Embodiment 4
Residue glue Protection glue band is not stayed in preparation, includes the following steps：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing in a concentration of 30% styrene-butadiene latex, treatment temperature is
150 DEG C, time 20S, coating weight is in 12g/ ㎡, and control moisture is 10%；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing, with a concentration of 20%
Acrylic acid aqueous solution carry out release processing, treatment temperature is 160 DEG C, time 8S, and mould release coating weight is 8g/ ㎡；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing, with a concentration of 5%
Modified butadiene-styrene latex carries out barrier processing, and treatment temperature is 100 DEG C, time 20S, and barrier coating weight is 6g/ ㎡；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier, glue are acrylic acid aqueous pressure sensitive adhesive, and
1% curing agent, 5 ‰ anti-UV agent are added, treatment temperature is 70 DEG C, time 40S, and coating weight is 30g/ ㎡.
After tested, gained adhesive tape possesses good flexibility, tensile strength reaches 80N/IN or more, elongation percentage reaches 15%
More than；Coated face possesses stable surface tension；Release stability is good after gluing；Tape performance：Cohesive force can reach 48H with
Upper, tack 20#, peeling force 10N/IN.(burning sun illumination, humidity are rained) use can for a long time not under various circumstances for adhesive tape
Stay residue glue.
Claims (6)
1. one kind not staying residue glue Protection glue band, which is characterized in that be included in containing the U.S. line paper handled by impregnation in immersion liquid, coating
In U.S. line paper curl face side mould release and be coated on the barrier of the U.S. line paper other side, which is characterized in that in barrier
On be coated with glue, curing agent and anti-UV agent；
Wherein, the modified butadiene-styrene latex that the barrier is a concentration of 5%~10%；
The glue is acrylic acid aqueous pressure sensitive adhesive；
Described is the butadiene-styrene latex of concentration 10%~30% containing immersion liquid；
The acrylic acid aqueous solution that the mould release is a concentration of 20%~30%.
2. the preparation method described in claim 1 for not staying residue glue Protection glue band, which is characterized in that include the following steps：
A impregnations are handled：U.S. line paper is selected to carry out impregnation processing；
The release processing of b：It is coated with mould release in the above-mentioned U.S. line paper curl face side by impregnation processing；
C barriers are handled：It is coated with barrier in the other side of the above-mentioned U.S. line paper by impregnation processing；
The processing of d gluings：Glue coating, curing agent, anti-UV agent on barrier.
3. containing immersion liquid it is concentration in wherein step a the preparation method according to claim 2 for not staying residue glue Protection glue band
10%-30% styrene-butadiene latexes, treatment temperature are 150 DEG C~180 DEG C, and the time is 10s~20s.
4. the preparation method according to claim 2 for not staying residue glue Protection glue band, mould release is a concentration of in wherein step b
20%~30% acrylic acid aqueous solution, treatment temperature are 130 DEG C~160 DEG C, and the time is 8s~15s.
5. the preparation method according to claim 2 for not staying residue glue Protection glue band, barrier is a concentration of in wherein step c
The modified butadiene-styrene latex of 5%-10%, treatment temperature are 80 DEG C~100 DEG C, and the time is 20s~30s.
6. the preparation method according to claim 2 for not staying residue glue Protection glue band, glue is propylene sour water in wherein step d
Property pressure sensitive adhesive, treatment temperature be 70 DEG C~90 DEG C, the time be 20s~40s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510415743.XA CN104962210B (en) | 2015-07-15 | 2015-07-15 | One kind not staying residue glue Protection glue band and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510415743.XA CN104962210B (en) | 2015-07-15 | 2015-07-15 | One kind not staying residue glue Protection glue band and preparation method thereof |
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| CN104962210A CN104962210A (en) | 2015-10-07 |
| CN104962210B true CN104962210B (en) | 2018-08-14 |
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| CN105331300A (en) * | 2015-10-16 | 2016-02-17 | 上海晶华胶粘新材料股份有限公司 | Crepe paper adhesive tape, and production method thereof |
| CN107674599A (en) * | 2017-11-14 | 2018-02-09 | 福建省福清友发实业有限公司 | A kind of adhesive tape preparation technology |
| CN110952376A (en) * | 2019-12-31 | 2020-04-03 | 上海永冠众诚新材料科技（集团）股份有限公司 | Degradable printing type environment-friendly paper tape and preparation method and application thereof |
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Address after: 201713 No. 15, Kang Gong Road, Zhujiajue Industrial Park, Qingpu District, Shanghai. Patentee after: Shanghai Yongguan Zhongcheng new material science and Technology (Group) Limited by Share Ltd Address before: 201714 No. 15, Kang Gong Road, Zhujiajue Industrial Park, Qingpu District, Shanghai. Patentee before: SHANGHAI YONGGUAN ADHESIVE PRODUCTS CO., LTD. |
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