CN104955331A - Emulsifying pesticide composition having high emulsion stability - Google Patents
Emulsifying pesticide composition having high emulsion stability Download PDFInfo
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- CN104955331A CN104955331A CN201480003106.5A CN201480003106A CN104955331A CN 104955331 A CN104955331 A CN 104955331A CN 201480003106 A CN201480003106 A CN 201480003106A CN 104955331 A CN104955331 A CN 104955331A
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- polar solvent
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- pesticidal emulsifiable
- emulsifiable composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Abstract
To provide an emulsifying pesticide composition that contains a novel isoxazoline-substituted benzamide compound. An emulsifying pesticide composition that comprises (Z)-[5-(3,5-dichlorophenyl)-5-trifluoromethyl-4,5-dihydroisoxazol-3-yl]-N-(methoxyiminomethyl)-2-methylbenzoic acid amide, a polar solvent, a nonpolar solvent and a surfactant. The content of the polar solvent is preferably 7.5-67.5 mass% relative to the emulsifying pesticide composition.
Description
Technical field
The present invention relates to the pesticidal emulsifiable composition of emulsion stability excellence.
Background technology
Known specifically different
isoxazoline-substituted benzamide compound has the insect (such as, insects, mite class, shell-fish and nematoda etc.) in agriculture and garden field or livestock breeding/health field prevents and kill off activity (with reference to patent document 1.)。
In addition, the known agricultural chemicals liquid composition (reference patent document 2) containing this compound, surfactant, the ester solvent suitable with polar solvent, water as required.
Prior art document
Patent document
Patent document 1: International Publication No. 2007/026965 pamphlet
Patent document 2: International Publication No. 2009/031621 pamphlet
Summary of the invention
Invent problem to be solved
Problem to be solved by this invention is to provide containing different
isoxazoline-substituted benzamide compound, the pesticidal emulsifiable composition of effect of pest control excellence.
For solving the method for problem
The present inventor etc. conduct in-depth research, and found that, following containing different
isoxazoline-substituted benzamide compound is as in the pesticidal emulsifiable composition of pesticide activity component, and by controlling the content of polar solvent in specific scope, thus emulsion stability improves.
That is, the present invention relates to pesticidal emulsifiable composition described in following (1) ~ (22) (hereinafter also referred to as the present composition.)。
(1) a pesticidal emulsifiable composition, it comprises: (Z)-[5-(3,5-dichlorophenyl)-5-trifluoromethyl-4,5-dihydro is different
azoles-3-base]-N-(methoxyimino methyl)-2-methyl benzamide is (hreinafter referred to as compd A.), polar solvent, non-polar solven and surfactant.
(2) the pesticidal emulsifiable composition according to above-mentioned (1), relative to the quality of this pesticidal emulsifiable composition, the content of above-mentioned polar solvent is 7.5 ~ 67.5 quality %.
(3) the pesticidal emulsifiable composition according to above-mentioned (1) or (2), above-mentioned polar solvent is be selected from more than at least a kind in ketone, N-alkyl pyrrolidone, ring-type urea, carboxylic acid amide, lactone, nitrogen-containing aromatic compound, cyclic amine, methyl-sulfoxide and carbonic ester.
(4) the pesticidal emulsifiable composition according to above-mentioned (1) or (2), above-mentioned polar solvent is for being selected from 5 ~ 7 yuan of cyclic ketone, N-C
1 ~ 12alkyl pyrrolidone, 5 ~ 6 yuan of ring-type ureas, C
1 ~ 12carboxylic acid amide, 4 ~ 7 yuan of annular lactones, 5 ~ 6 yuan of cyclic nonaromatics comprising more than 1 nitrogen-atoms, 5 ~ 6 yuan of saturated cyclic amine comprising more than 1 nitrogen-atoms, methyl-sulfoxide and carbonic acid C
2 ~ 4more than at least a kind in alkylene ester.
(5) the pesticidal emulsifiable composition according to above-mentioned (4), above-mentioned 5 ~ 6 yuan of saturated cyclic amine comprising more than 1 nitrogen-atoms are 4-acyl group morpholine.
(6) the pesticidal emulsifiable composition according to above-mentioned (1) or (2), above-mentioned polar solvent is for being selected from cyclohexanone, N-methyl-pyrrolidon, N-ethyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolinone, N, N '-dimethyl propylidene urea, N, more than at least a kind in dinethylformamide, DMA, 6-caprolactone, 1-methylimidazole, 4-acetyl morphine, 4-N-formyl morpholine N-, methyl-sulfoxide and propylene carbonate.
(7) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is cyclohexanone, and relative to the quality of this pesticidal emulsifiable composition, the content of this polar solvent is 22.5 ~ 67.5 quality %.
(8) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is METHYLPYRROLIDONE, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
(9) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is N-ethyl-2-pyrrolidone, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
(10) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is DMI, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
(11) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is N, N '-dimethyl propylidene urea, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
(12) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is DMF, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 12.5 ~ 62.5 quality %.
(13) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is DMA, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
(14) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is 6-caprolactone, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 42.5 ~ 57.5 quality %.
(15) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is 1-methylimidazole, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 17.5 ~ 62.5 quality %.
(16) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is 4-acetyl morphine, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 22.5 ~ 62.5 quality %.
(17) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is 4-N-formyl morpholine N-, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 12.5 ~ 67.5 quality %.
(18) the pesticidal emulsifiable composition according to above-mentioned (1), above-mentioned polar solvent is methyl-sulfoxide, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 17.5 ~ 67.5 quality %.
(19) according to the pesticidal emulsifiable composition described in any one be selected from above-mentioned (1) ~ (18), above-mentioned non-polar solven is aromatic hydrocarbon.
(20) according to being selected from the pesticidal emulsifiable composition described in any one in above-mentioned (1) ~ (19), above-mentioned surfactant is be selected from more than a kind in polyoxyalkylene aryl phenyl ether, the formaldehyde condensation products of polyoxyalkylene aryl phenyl ether, polyoxyalkylene vegetable oil and polyoxyethylene polyoxypropylene block copolymer.
(21) the pesticidal emulsifiable composition according to above-mentioned (20), above-mentioned surfactant is be selected from more than at least a kind in polyoxyalkylene aryl phenyl ether and polyoxyalkylene vegetable oil.
(22) the pesticidal emulsifiable composition according to above-mentioned (20), above-mentioned surfactant is be selected from more than at least a kind in polyoxyethylene list styrylphenyl ether, polyoxyethylene diphenylethyllene phenyl ether, polyoxyethylene tri-styryl base phenyl ether, Emulsifier EL-60 ether and polyoxyethylene hardened castor oil ether.
The effect of invention
The present composition plays excellent preventive effect to the insect in agriculture and garden field or livestock breeding/health field.In addition, relative to the present composition, when the content of polar solvent contains 7.5 ~ 67.5 quality %, the present composition is transparent clarification and uniform composition, and the emulsion stability of the liquid modulated by present composition dilute with water is excellent.
Embodiment
So-called pesticidal emulsifiable composition of the present invention, refers to that composition itself is generally solution or suspension, if but dilute with water, become fine droplets and emulsification in water.
Relative to the present composition, the content of compd A is generally 0.05 ~ 25 quality %.The lower limit of content is preferably more than more than 0.1 quality %, more than 1 quality %, more than 3 quality %, more than 4 quality % or 5 quality %.The upper limit of content is preferably below below 20 quality % or 15 quality %.
The present composition can further containing the pesticide activity component, particularly bactericide beyond compd A, bactericide, nematocide, miticide or insecticide.The bactericide that can contain further below, bactericide, nematocide, miticide and insecticide illustrate particularly in the mode of common name.
Bactericide: amisulbrom (amisulbrom), Acibenzolar (acibenzolar), ammonia propyl-phosphine acid (ampropyfos), anilazine (anilazine), oxygen ring azoles (azaconazole), Fluoxastrobin (azoxystrobin), M 9834 (benalaxyl), benodanil (benodanil), benomyl (benomyl), benzamacril, binapacryl (binapacryl), biphenyl (biphenyl), bitertanol (bitertanol), bethoxazine, bordeaux mixture (bordeaux mixture), blasticidin S (blasticidin-S), bromoconazole, bupirimate (bupirimate), buthiobate (buthiobate), lime sulfur (calcium polysulfide), difoltan (captafol), captan (captan), copper oxychloride (copper oxychloride), ring propionyl bacterium amine (carpropamid), carbendazim (carbendazim), carboxin (carboxin), chinomethionat (chinomethionat), chlobenthiazone, chlorfenazol, chloroanisole (chloroneb), tpn (chlorothalonil), chlozolinate (chlozolinate), cufraneb (cufraneb), frost urea cyanogen (cymoxanil), Cyproconazole (cyproconazol), cyprodinil (cyprodinil), cyprofuram (cyprofuram), debacarb (debacarb), antiphen (dichlorophen), diclobutrazol (diclobutrazol), dichlofluanid (dichlofluanid), diclomezin (diclomezine), botran (dicloran), the mould prestige of second (diethofencarb), two chlorine zarilamid (diclocymet), Difenoconazole (difenoconazole), fluorine mepanipyrim (diflumetorim), dimethirimol (dimethirimol), dimethomorph (dimethomorph), olefin conversion (diniconazole), efficient olefin conversion (diniconazole-M), dinitro crotons phenolic ester (dinocap), diphenylamines (diphenylamine), dipyrithione, Plondrel (ditalimfos), dithianon (dithianon), dodemorph (dodemorph), dodine (dodine), drazoxolon (drazoxolon), edifenphos (edifenphos), epoxiconazole (epoxiconazole), etaconazole (etaconazole), the phonetic phenol of second (ethirimol), Grandox fumigant (etridiazole),
cycloheximide triazole (famoxadone), Fenarimol (fenarimol), febuconazole, fenfuram (fenfuram), fenpiclonil (fenpiclonil), fenpropidin (fenpropidin), butadiene morpholine (fenpropimorph), fentin (fentin), ferbam (ferbam), ferimzone (ferimzone), fluazinam (fluazinam), fludioxonil (fludioxonil), fluoromide (fluoroimide), Fluquinconazole (fluquinconazole), Flusilazole (flusilazole), flusulfamide (flusulfamide), flutolanil (flutolanil), Flutriafol (flutriafol), folpet (folpet), phosethyl-Al (fosetyl-aluminium), furidazol (fuberidazole), furalaxyl (furalaxyl), Fenamidone (fenamidone), fenhexamid (fenhexamid), the pungent salt of biguanides (guazatine), hexachloro-benzene (hexachlorobenzene), own azoles alcohol (hexaconazole),
mould spirit (hymexazol), imazalil (imazalil), glyoxalin (imibenconazole), iminoctadine (iminoctadine), plant bacterium azoles (ipconazole), iprobenfos (iprobenfos), iprodione (iprodione), Isoprothiolane (isoprothiolane), iprovalicarb (iprovalicarb), isopyrazam, kasugarnycin (kasugamycin), kresoxim-methyl (kresoxim-methyl), mancopper (mancopper), mancozeb (mancozeb), maneb (maneb), mepanipyrim (mepanipyrim), mebenil (mepronil), metalaxyl (metalaxyl), metconazole (metconazole), Carbatene (metiram), SSF 126 (metominostrobin), nitrile bacterium azoles (myclobutanil), Dithane A40 (nabam), dimethylamino dithiocarbonic acid nickel (nickel bis (dimethyldithiocarbamate)), nitrothalisopropyl (nitrothal-isopropyl), nuarimol (nuarimol), octhilinone (octhilinone), ofurace (ofurace),
frost spirit (oxadixyl), oxycarboxin (oxycarboxin),
oxpoconazole fumarate (oxpoconazole fumarate), pefurzoate, penconazole (penconazole), Pencycuron (pencycuron), Rabcide (phthalide), disease spends spirit (piperalin), polyoxin (polyoxins), probenazole (probenazole), Prochloraz (prochloraz), procymidone (procymidone), propamocarb (propamocarb hydrochloride), propiconazole (propiconazole), Propineb (propineb), pyrazophos (pyrazophos), pyrifenox (pyrifenox), phonetic mould amine (pyrimethanil), pyroquilon (pyroquilon), benzene oxygen quinoline (quinoxyfen), pcnb (quintozene), Sulfur (sulfur), volution bacterium amine (spiroxamine), Tebuconazole (tebuconazole), tecnazene (tecnazene), tetraconazole (tetraconazole), probenazole (thiabendazole), thifluzamide (thifluzamide), thiophanate-methyl (thiophanate-methyl), tmtd (thiram), tolelofos-methyl (tolclofos-methyl), toluene flusulfamide (tolylfluanid), triazolone (triadimefon), toriadimenol, triazoxide (triazoxide), tricyclazole (tricyclazole), tridemorph (tridemorph), fluorine bacterium azoles (triflumizole), triforine (triforine), triticonazole (triticonazole), valida (validamycin), vinclozolin (vinclozolin), zineb (zineb), ziram (ziram), copper 8-hydroxyquinolinate (oxine-copper).
Bactericide: streptomycin (streptomycin), terramycin (oxytetracycline), oxolinic acide (oxolinic acid).
Nematocide: aldoxycarb (aldoxycarb), fosthiazate (fosthiazate), fosthietan (fosthietan), oxamyl (oxamyl), fenamiphos (fenamiphos).
Miticide: Amitraz (amitraz), fenisobromolate (bromopropylate), chinomethionat (chinomethionat), chlorobenzilate (chlorobezilate), clofentezine (clofentezine), nitrile pyrrole mite ester (cyenopyrafen), plictran (cyhexatine), dicofol (dicofol), everywhere gram (dienochlor), second mite azoles (etoxazole), fenazaquin (fenazaquin), fenbutatin oxide (fenbutatinoxide), fenpropathrin (fenpropathrin), fenproximate, halfenprox (halfenprox), Hexythiazox (hexythiazox), milbemectin (milbemectin), propargite (propargite), pyridaben (pyridaben), pyrimidifen (pyrimidifen), tebufenpyrad (tebufenpyrad).
Insecticide: Avermectin (abamectin), orthene (acephate), Acetamiprid (acetamipirid), azinphos-methyl (azinphos-methyl),
worm prestige (bendiocarb), Benfuracard micro (benfuracarb), bensultap (bensultap), Biphenthrin (bifenthrin), Buprofezin (buprofezin), butocarboxim (butocarboxim), carbaryl (carbaryl), carbofuran (carbofuran), carbosulfan (carbosulfan), cartap (cartap), chlorantraniliprole (chlorantraniliprole), capillary (chlorfenapyr), chlopyrifos (chlorpyrifos), chlorfenviphos (chlorfenvinphos), chlorfluazuron (chlorfluazuron), clothianidin (clothianidin), ring worm hydrazides (chromafenozide), chlorpyrifos-methyl (chlorpyrifos-methyl), cyanogen insect amide (cyantraniliprole), cyfloxylate (cyfluthrin), betacyfluthrin (beta-cyfluthrin), cypermethrin (cypermethrin), cyromazine (cyromazine), cyhalothrin (cyhalothrin), gamma cyhalothrin (lambda-cyhalothrin), decis (deltamethrin), diafenthiuron (diafenthiuron), diazinon (diazinon), diacloden, diflubenzuron (diflubenzuron), dimethylvinphos (dimethylvinphos), difenolan (diofenolan), disulfoton (disulfoton), Rogor (dimethoate), EPN, S-sumicidin (esfenvalerate), ethiofencarb (ethiofencarb), second worm nitrile (ethiprole), ether chrysanthemum ester (etofenprox), etrimfos (etrimfos), sumithion (fenitrothion), Bassa (fenobucarb), fenoxycarb (fenoxycarb), fenpropathrin (fenpropathrin), sumicidin fenvalerate), ethiprole (fipronil), Flubendiamide (Flubendiamide), flucythrinate (flucythrinate), flufenoxuron (flufenoxuron), trifluoro chrysanthemum ester (flufenprox), taufluvalinate (tau-fluvalinate), Fonofos (fonophos), Carzol (formetanate), formothion (formothion), furathiocarb (furathiocarb), chlorine worm hydrazides (halofenozide), HEXAFLUMURON (hexaflumuron), hydramethylnon (hydramethylnon), Imidacloprid (imidacloprid), isofenphos (isofenphos), indoxacarb (indoxacarb), Mobucin (isoprocarb),
azoles phosphorus (isoxathion), lufenuron (lufenuron), malathion (malathion), the methaldehyde (metaldehyde), acephatemet (methamidophos), methidathion (methidathion), methacrifos (methacrifos), metalcarb, Methomyl (methomyl), methoprene (methoprene), methoxychlor (methoxychlor), methoxyfenozide (methoxyfenozide), nuvacron (monocrotophos), muscalure (muscalure), Nitenpyram (nitenpyram), omethoate (omethoate), oxydemeton_methyl (oxydemeton-methyl), oxamyl (oxamyl), parathion (parathion), parathion-methyl (parathion-methyl), permethrin (permethrin), phenthoate dimephenthoate cidial (phenthoate), phoxim (phoxim), thimet (phorate), Phosalone (phosalone), phosmet (phosmet), phosphamidon (phosphamidon), Aphox (pirimicarb), pirimiphos-methyl (pirimiphos-methyl), Profenofos (profenofos), pymetrozine (pymetrozine), pyraclofos (pyraclofos), Nylar (pyriproxyfen), rotenone (rotenone), sulprofos (sulprofos), silafluofene (silafluofen), multiple killing teichomycin (spinosad), sulfotep (sulfotep), sulfone worm pyridine (sulfoxaflor), tebfenozide, fluorobenzene urea (teflubenzuron), tefluthrin (tefluthorin), terbufos (terbufos), Ravap (tetrachlorvinphos), thiodicarb (thiodicarb), Diacloden (thiamethoxam), thiofanox (thiofanox), thiometon (thiometon), Tolfenpyrad (tolfenpyrad), tralomethrin (tralomethrin), chlorophos (trichlorfon), triazuron, triflumuron (triflumuron), vamidothion (vamidothion).
Pesticide activity component beyond compd A may be used alone, can also be two or more kinds in combination.Relative to the present composition, the total content of the pesticide activity component beyond compd A is generally 0.05 ~ 25 quality %.The lower limit of total content is preferably more than more than 0.1 quality % or 1 quality %.The upper limit of total content is more preferably below below 20 quality % or 15 quality %.
The polar solvent used in the present composition is not particularly limited, and water solubility when being generally 20 DEG C is the polar solvent of more than 1g/L, is preferably the polar solvent of more than 2g/L, is more preferably the polar solvent of more than 4g/L.As the example of polar solvent, ketone, N-alkyl pyrrolidone, ring-type urea, carboxylic acid amide, lactone, nitrogen-containing aromatic compound, cyclic amine, methyl-sulfoxide and carbonic ester can be enumerated.These polar solvents can use a kind or be mixed with two or more.In addition in order to dissolved compound A, relative to the present composition, the total content of polar solvent needs more than use 7.5 quality %, if but content likely crystallization in dilution at most.From the view point of preventing crystallization, the total content of polar solvent needs to be below 67.5 quality %.Therefore, the total content of polar solvent is 7.5 ~ 67.5 quality %.
As ketone, the C such as such as acetone, methyl ethyl ketone, methyl n-pro-pyl ketone, methyl n-butyl ketone, methyl iso-butyl ketone (MIBK), methyl-n-amyl ketone, methyl n hexyl ketone, methyl n heptyl ketone, metacetone, ethyl normal-butyl ketone, diη-propyl ketone, diisopropyl ketone, diisobutyl ketone, diacetone alcohol, acetylacetone,2,4-pentanedione, acetonyl acetone, Mesityl oxide, acetophenone and phorone can be enumerated
3 ~ 95 ~ 7 yuan of cyclic ketone such as chain ketone and cyclopentanone, cyclohexanone, methyl cyclohexanone, cycloheptanone and isophorone.
As N-alkyl pyrrolidone, the N-C such as such as METHYLPYRROLIDONE, N-ethyl-2-pyrrolidone, N-octyl group-2-Pyrrolidone and N-dodecyl-2-Pyrrolidone can be enumerated
1 ~ 12alkyl-2-Pyrrolidone.
As ring-type urea, such as DMI and N can be enumerated, 5 ~ 6 yuan of ring-type ureas such as N '-dimethyl propylidene urea.
As carboxylic acid amide, the C such as such as DMF, DMA, N, N-dimethyl lactamide, N, N-dimethyloctanamide, spectrasolv DMDA and N, N-dimethyl lauramide can be enumerated
1 ~ 12carboxylic acid amide (carbon number of carboxylic acid is preferably 1 ~ 12, and carboxylic acid is preferably aliphatic carboxylic acid).
As lactone, 4 ~ 7 yuan of annular lactones such as such as beta-propiolactone, beta-butyrolactone, gamma-butyrolacton, gamma-valerolactone, δ-valerolactone, γ-hexalactone, δ-caprolactone, 6-caprolactone, γ-heptalactone, γ-octalactone and δ-octalactone can be enumerated.
As nitrogen-containing aromatic compound, such as pyrroles can be enumerated, 1-methylpyrrole, 3-methylpyrrole, 1-N-ethyl pyrrole N-, 2-N-ethyl pyrrole N-, 2, 4-dimethyl pyrrole, 2, 5-dimethyl pyrrole, 1-methylpyrazole, 3-methylpyrazole, 1-methylimidazole, 1-ethyl imidazol(e), 1-isopropylimdazole, pyridine, 2-picoline, 3-picoline, 4-picoline, 2-ethylpyridine, 3-ethylpyridine, 4-ethylpyridine, 2, 3-lutidines, 2, 4-lutidines, 2, 5-lutidines, 2, 6-lutidines, 3, 4-lutidines, 3, 5-lutidines, 2-formylpyridine, 3-formylpyridine, 4-formylpyridine, 2-acetylpyridine, 3-acetylpyridine, 4-acetylpyridine, pyridazine, 3-methyl pyridazine, 4-methyl pyridazine, pyrimidine, 4-methylpyrimidine, 2-methylpyrazine, 2, 3-dimethyl pyrazine, 2, 5-dimethyl pyrazine and 2-ethyl pyrazine etc. comprise 5 ~ 6 yuan of cyclic nonaromatics of more than 1 nitrogen-atoms.
As cyclic amine, such as pyrrolidines can be enumerated, 1-crassitude, 1-ethyl pyrrolidine, 1-acetyl pyrrole alkane, piperidines, 1-methyl piperidine, 2, 6-lupetidine, 3, 5-lupetidine, 1-ethyl piperidine, 1-formylpiperidine, 1-acetyl piperidine, morpholine, 4-methyl morpholine, 2, 6-thebaine, 4-ethyl morpholine, 4-acyl group morpholine (such as 4-N-formyl morpholine N-, 4-acetyl morphine, 4-propionyl morpholine, 4-butyryl morpholine, 4-valeryl morpholine, 4-hexanoyl morpholine, 4-oenanthyl morpholine, 4-decoyl morpholine, 4-nonanoyl morpholine, 4-caprinoyl morpholine, 4-undecanoyl morpholine and 4-lauroyl morpholine etc.), 1-methyl piperazine, 1, 4-lupetazin, 1-ethyl piperazidine and 1-formyl piperazine etc. comprise 5 ~ 6 yuan of saturated cyclic amine of more than 1 nitrogen-atoms.
As carbonic ester, the carbonic acid C such as such as ethylene carbonate, propylene carbonate, carbonic acid 1,2-Aden's ester and trimethylene carbonate can be enumerated
2 ~ 4alkylene ester.
The non-polar solven used in the present composition is not particularly limited, and water solubility when being generally 20 DEG C is less than the non-polar solven of 1g/L, is preferably less than the non-polar solven of 0.7g/L, is more preferably the non-polar solven being less than 0.5g/L.As the example of non-polar solven, dimethylbenzene, alkyl (C can be enumerated
9 ~ 13deng) benzene, phenyl xylyl ethane, dimethylnaphthalene, alkyl (C
1, C
3or C
12 ~ 14deng) naphthalene, alkyl biphenyl, alkyl diphenyl base alkane and boiling point be the mixture etc. of the aromatic hydrocarbons such as aliphatic hydrocarbon, kerosene such as the aromatic hydrocarbons such as the aromatic hydrocarbon of 150 ~ 350 DEG C, machine oil, normal paraffin, different alkane and cycloalkanes and aliphatic hydrocarbon.These non-polar solvens can be used alone, and also can be mixed with two or more.Relative to the present composition, the total content of non-polar solven is generally 5 ~ 70 quality %.The lower limit of total content is preferably more than 10 quality %, is more preferably more than 15 quality %.The upper limit of total content is preferably below 65 quality %, is more preferably below 60 quality %.
The surfactant used in the present composition can enumerate such as following (A), (B), (C), (D) and (E).
(A) nonionic surfactant:
(A-1) polyethylene glycol type surfactant: can enumerate such as, polyxyethylated (C
12 ~ 18) ether, the ethylene oxide adduct of alkyl naphthol, polyoxyethylene (single or two) alkyl (C
8 ~ 12) phenyl ether, polyoxyethylene (single or two) alkyl (C
8 ~ 12) formaldehyde condensation products of phenyl ether, polyoxyethylene is (single, two or three) phenyl ether, polyoxyethylene is (single, two or three) benzyl phenyl ether, polyoxypropylene is (single, two or three) benzyl phenyl ether, polyoxyethylene is (single, two or three) styrylphenyl ether, polyoxypropylene is (single, two or three) phenyl ether, polyoxypropylene is (single, two or three) benzyl phenyl ether, polyoxypropylene is (single, two or three) styrylphenyl ether, polyoxyethylene is (single, two or three) formaldehyde condensation products of styrylphenyl ether, polyoxypropylene is (single, two or three) styrylphenyl ether formaldehyde condensation products, polyoxyethylene polyoxypropylene block polymer, alkyl (C
12 ~ 18) polyoxyethylene polyoxypropylene block polymer ether, alkyl (C
8 ~ 12) phenyl polyoxyethylene polyoxypropylene block polymer ether, polyoxyethylene two phenyl ether, polyoxyethylene resin acid ester, polyoxyethylene fatty acid (C
12 ~ 18) monoesters, polyoxyethylene fatty acid (C
12 ~ 18) diester, polyoxyethylene sorbitan fatty acid (C
12 ~ 18) ester, fatty acid glyceride ethylene oxide adduct, Emulsifier EL-60 ether, polyoxyethylene hardened castor oil ether, polyoxypropylene castor oil ether, polyoxypropylene hardened castor oil ether and Polyoxyethylatad Rape Oil ether, alkyl (C
12 ~ 18) amine ethylene oxide adduct and fatty acid (C
12 ~ 18) acid amides ethylene oxide adduct etc.
(A-2) EPE polyol EPE: can enumerate such as, fatty acid glyceride, polyglyceryl fatty acid ester, pentaerythritol fatty ester, polyoxyethylensorbitan fatty acid (C
12 ~ 18) ester, sorbitan fatty acid (C
12 ~ 18) ester, sucrose fatty ester, polyol alkyl ether and Marlamid etc.
(A-3) alkyne series surfactant: can enumerate such as, the ethylene oxide adduct of acetylenediol, acetylene alcohol, acetylenediol and the ethylene oxide adduct etc. of acetylene alcohol.
(A-4) other surfactant: can enumerate such as, alkyl glycoside etc.
(B) anionic surfactant:
(B-1) carboxylic acid type surfactant: can enumerate such as, copolymer, the N-methyl-fatty acid (C of the copolymer of the copolymer of the copolymer of the copolymer of the copolymer of the copolymer of polyacrylic acid, polymethylacrylic acid, poly, maleic acid and alkene (such as isobutene and diisobutylene etc.), acrylic acid and itaconic acid, methacrylic acid and itaconic acid, maleic acid and cinnamic copolymer, acrylic acid and methacrylic acid, acrylic acid and methyl acrylate, acrylic acid and vinyl acetate, acrylic acid and maleic acid
12 ~ 18) sarcosinate, resin acid and fatty acid (C
12 ~ 18) etc. the salt of carboxylic acid and these carboxylic acids.
(B-2) sulfuric acid ester type surfactant: can enumerate such as, alkyl (C
12 ~ 18) sulfuric ester, polyxyethylated (C
12 ~ 18) ether sulfuric ester, polyoxyethylene (single or two) alkyl (C
8 ~ 12) phenyl ether sulfuric ester, polyoxyethylene (single or two) alkyl (C
8 ~ 12) sulfuric ester of polymer of phenyl ether, polyoxyethylene is (single, two or three) phenyl ether sulfuric ester, polyoxyethylene is (single, two or three) benzyl phenyl ether sulfuric ester, polyoxyethylene is (single, two or three) styrylphenyl ether sulfuric ester, polyoxyethylene is (single, two or three) sulfuric ester of the polymer of styrylphenyl ether, the sulfuric ester of polyoxyethylene polyoxypropylene block polymer, sulfated oil, sulfated fatty acid ester, the sulfuric esters such as sulfated fatty acid and sulphation alkene, and the salt of these sulfuric esters.
(B-3) sulfonic acid type surfactant: can enumerate such as, paraffin (C
12 ~ 22) sulfonic acid, alkyl (C
8 ~ 12) benzene sulfonic acid, alkyl (C
8 ~ 12) formaldehyde condensation products, the formaldehyde condensation products of cresol sulfonic acid, the alpha-olefin (C of benzene sulfonic acid
14 ~ 16) sulfonic acid, dialkyl group (C
8 ~ 12) sulfosuccinic acid, lignin sulfonic acid, polyoxyethylene (single or two) alkyl (C
8 ~ 12) phenyl ether sulfonic acid, polyxyethylated (C
12 ~ 18) ether sulfosuccinic acid half ester, naphthalene sulfonic acids, (single or two) alkyl (C
1 ~ 6) naphthalene sulfonic acids, the formaldehyde condensation products of naphthalene sulfonic acids, (single or two) alkyl (C
1 ~ 6) formaldehyde condensation products, the formaldehyde condensation products of creasote sulfonic acid, the alkyl (C of naphthalene sulfonic acids
8 ~ 12) diphenyl ether disulfonic acid, イ ゲ Port Application T (trade name), the sulfonic acid such as copolymer of polystyrolsulfon acid and styrene sulfonic acid and methacrylic acid and the salt of these sulfonic acid.
(B-4) phosphate-type surfactant: can enumerate such as, alkyl (C
8 ~ 12) phosphate, polyxyethylated (C
12 ~ 18) ether phosphate, polyoxyethylene (single or two) alkyl (C
8 ~ 12) phenyl ether phosphate, polyoxyethylene (single, two or three) alkyl (C
8 ~ 12) phosphate of polymer of phenyl ether, polyoxyethylene is (single, two or three) phenyl ether phosphate, polyoxyethylene is (single, two or three) benzyl phenyl ether phosphate, polyoxyethylene is (single, two or three) styrylphenyl ether phosphate, polyoxyethylene is (single, two or three) phosphate of the polymer of styrylphenyl ether, the phosphate of polyoxyethylene polyoxypropylene block polymer, phosphatid ylcholine, the phosphates such as phosphatidyl ethanol imines and condensed phosphoric acid (such as tripolyphosphate etc.), and the salt of these phosphates.
As the salt in above-mentioned (B-1) ~ (B-4), alkali metal (lithium, sodium and potassium etc.), alkaline earth metal (calcium and magnesium etc.), ammonium and various amine (such as alkylamine, Cycloalkyl amine and alkanolamine etc.) etc. can be enumerated.
(C) cationic surfactant:
Can enumerate such as, alkylamine salt and alkyl quaternary ammonium salts etc.
(D) amphoteric surfactant:
Can enumerate such as, betaine type amphoteric surfactant and amino acid type surfactant etc.
(E) other surfactant:
Can enumerate such as, silicone based surfactants and fluorine system surfactant etc.
In above-mentioned surfactant, expect the surfactant using following (1) ~ (4).
(1) polyoxyalkylene aryl phenyl ether: can enumerate such as, polyoxyethylene (list, two or three) phenyl ether, polyoxyethylene (list, two or three) benzyl phenyl ether, polyoxyethylene (list, two or three) styrylphenyl ether, polyoxypropylene (list, two or three) phenyl ether, polyoxypropylene (list, two or three) benzyl phenyl ether and polyoxypropylene (list, two or three) styrylphenyl ether.
(2) formaldehyde condensation products of polyoxyalkylene aryl phenyl ether: can enumerate such as, the formaldehyde condensation products of polyoxyethylene (list, two or three) styrylphenyl ether and polyoxypropylene (list, two or three) styrylphenyl ether formaldehyde condensation products.
(3) polyoxyalkylene vegetable oil: can enumerate such as, Emulsifier EL-60 ether, polyoxyethylene hardened castor oil ether, polyoxypropylene castor oil ether, polyoxypropylene hardened castor oil ether and Polyoxyethylatad Rape Oil ether.
(4) polyoxyethylene polyoxypropylene block polymer: can enumerate such as, molecular weight is 1500 ~ 20000, and ethylene oxide moieties is the polyoxyethylene polyoxypropylene block polymer of 10 ~ 85% relative to the content of molecular entities.More specifically, can enumerate such as, エ パ Application 410 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 420 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 450 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 485 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 610 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 680 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 710 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 720 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 740 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 750 (trade name/the first industrial pharmaceutical (strain)), エ パ Application 785 (trade name/the first industrial pharmaceutical (strain)), エ パ Application U103 (trade name/the first industrial pharmaceutical (strain)), エ パ Application U105 (trade name/the first industrial pharmaceutical (strain)), エ パ Application U108 (trade name/the first industrial pharmaceutical (strain)), ト キ サ ノ Application PE-61 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-62 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-64 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-68 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-71 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-74 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-75 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-78 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-108 (trade name/Sanyo changes into industry (strain)), ト キ サ ノ Application PE-128 (trade name/Sanyo changes into industry (strain)), プ Le ロ ニ ッ Network PE3100 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE4300 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE6100 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)) プ Le ロ ニ ッ Network PE6200 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE6400 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE6800 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE8100 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE9200 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE9400 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ ロ ニ ッ Network PE10100 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network PE10500 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network RPE2520 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), プ Le ロ ニ ッ Network RPE3110 (trade name/ビ ー エ ー エ ス エ Off ジ ャ パ Application (strain)), ニ ュ ー カ Le ゲ Application 5050PB (trade name/this grease of bamboo (strain)), ニ ュ ー カ Le ゲ Application 70100PB (trade name/this grease of bamboo (strain)), ペ ポ ー Le B-182 (eastern nation chemical industry (strain)), ペ ポ ー Le B-184 (eastern nation chemical industry (strain)), ペ ポ ー Le B-188 (eastern nation chemical industry (strain)) etc.
In the surfactant of above-mentioned (1) ~ (4), preferably polyoxyalkylene aryl phenyl ether or polyoxyalkylene vegetable oil, more preferably polyoxyethylene list styrylphenyl ether, polyoxyethylene diphenylethyllene phenyl ether, polyoxyethylene tri-styryl base phenyl ether, Emulsifier EL-60 ether or polyoxyethylene hardened castor oil ether.
Surfactant can be used alone, and also two or more kinds may be used.When also with 2 kinds of surfactants, be preferably the combination of following (a) ~ (d), be particularly more preferably the combination of (e) ~ (i).
(a) polyoxyalkylene aryl phenyl ether and alkyl (C
8 ~ 12) benzene sulfonate
The formaldehyde condensation products of (b) polyoxyalkylene aryl phenyl ether and alkyl (C
8 ~ 12) benzene sulfonate
(c) polyoxyalkylene vegetable oil and alkyl (C
8 ~ 12) benzene sulfonate
(d) polyoxyethylene polyoxypropylene block copolymer and alkyl (C
8 ~ 12) benzene sulfonate
(e) polyoxyethylene (list, two or three) styrylphenyl ether and calcium salt of dodecylbenzene sulfonate
The formaldehyde condensation products of (f) polyoxyethylene (list, two or three) styrylphenyl ether and calcium salt of dodecylbenzene sulfonate
(g) Emulsifier EL-60 ether and calcium salt of dodecylbenzene sulfonate
(h) polyoxyethylene hardened castor oil ether and calcium salt of dodecylbenzene sulfonate
(i) polyoxyethylene polyoxypropylene block copolymer and calcium salt of dodecylbenzene sulfonate
Relative to the present composition, the total content of surfactant is generally 2 ~ 30 quality %.The lower limit of total content is preferably more than 5 quality %, is more preferably more than 10 quality %.The upper limit of total content is preferably below 25 quality %, is more preferably below 20 quality %.
In addition about surfactant, to strengthen for the purpose of the desinsection of the present composition, acaricidal activity, also can use as adjuvant.In addition, as other adjuvant, vegetable oil and mineral oil can be enumerated.Can use containing these adjuvants in advance in pesticidal emulsifiable composition, also may be combined in the dilution of this pesticidal emulsifiable composition and use.
As the auxiliary element that can use further in the present composition, can enumerate such as, antifreezing agent, pH adjusting agent, decomposition preventing agent, defoamer and preservative etc.
Emulsibility composition of the present invention can adopt following methods to manufacture.Such as, by obtaining as the compd A of active ingredient and surfactant dissolves in polar solvent and non-polar solven.
The present composition can adopt following method to use: be such as diluted with water to 10 ~ 5000 times of degree, uses sprayer etc. to intersperse among crop, trees or their methods of soil of growing; Helicopter etc. is used, the method being diluted with water to about 2 ~ 100 times to scatter from aerial.
Embodiment
Next enumerate embodiment, comparative example and test example and in further detail the present invention is described, but the present invention is not limited to this.In addition, below in " part " refer to mass parts.
(embodiment 1)
By compd A substance (purity: 99.6%) 5.02 parts, polyoxyethylene styryl phenyl ether (trade name: ソ ル ポ ー Le T-20, east nation's chemical industry (strain) system) 5 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 5 parts, cyclohexanone 25 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 59.98 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 2 ~ 30)
Operate similarly to Example 1, each constituent shown in showing the 1st mixes, and obtains pesticidal emulsifiable composition.
[table 1]
Table 1
1st table
[table 2]
Table 2
1st table (Continued)
[table 3]
Table 3
1st table (Continued)
[table 4]
Table 4
1st table (Continued)
[table 5]
Table 5
1st table (Continued)
[table 6]
Table 6
1st table (Continued)
[table 7]
Table 7
1st table (Continued)
(embodiment 31)
By compd A substance (purity: 99.6%) 10.04 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-42, east nation's chemical industry (strain) system) 5 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 5 parts, cyclohexanone 55 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 24.96 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 32)
Replace 5 parts, the Emulsifier EL-60 ether of embodiment 31, add polyoxyethylene polyoxypropylene block copolymer (trade name: エ パ Application 740, first industrial pharmaceutical (strain) is made) 5 parts, in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 33)
By compd A substance (purity: 99.6%) 10.04 parts, polyoxyethylene styryl phenyl ether (trade name: ソ ル ポ ー Le T-20, east nation's chemical industry (strain) system) 10 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 10 parts, methyl-sulfoxide 45 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 24.96 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 34)
Replace 10 parts, the polyoxyethylene styryl phenyl ether of embodiment 33, add the formaldehyde condensation products (trade name: ソ ル ポ ー Le F-24 of polyoxyethylene styryl phenyl ether, east nation's chemical industry (strain) system) 10 parts, in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 35)
Replace 10 parts, the polyoxyethylene styryl phenyl ether of embodiment 33, add 10 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-30, eastern nation chemical industry (strain) makes), in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 36)
By compd A substance (purity: 99.6%) 10.04 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-30, east nation's chemical industry (strain) system) 10 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 10 parts, METHYLPYRROLIDONE 20 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 49.96 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 37)
Replace the METHYLPYRROLIDONE 20 parts of embodiment 36, add N, N '-dimethyl propylidene urea 20 parts, in addition, similarly operates, and obtains pesticidal emulsifiable composition.
(embodiment 38)
By compd A substance (purity: 99.6%) 10.04 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-30, east nation's chemical industry (strain) system) 10 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 10 parts, 1,3-dimethyl-2-imidazolinone 25 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 44.96 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 39)
Replace the DMI 25 parts of embodiment 38, add N-ethyl-2-pyrrolidone 25 parts, in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 40)
By compd A substance (purity: 97.3%) 10.28 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-30, east nation's chemical industry (strain) system) 10 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 5 parts, 4-acetyl morphine 35 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 39.72 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 41)
Replace 10 parts, the Emulsifier EL-60 ether of embodiment 40, add 10 parts, polyoxyethylene hardened castor oil ether (trade name: ニ ッ コ ー Le HCO-20, daylight ケ ミ カ Le ズ (strain) make), in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 42)
By compd A substance (purity: 97.3%) 10.28 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-30, east nation's chemical industry (strain) system) 10 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 5 parts, 4-N-formyl morpholine N-35 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 39.72 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 43)
Replace 10 parts, the Emulsifier EL-60 ether of embodiment 42, add 10 parts, polyoxyethylene hardened castor oil ether (trade name: ニ ッ コ ー Le HCO-20, daylight ケ ミ カ Le ズ (strain) make), in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 44)
By compd A substance (purity: 97.3%) 10.28 parts, Emulsifier EL-60 ether (trade name: ソ ル ポ ー Le CA-30, east nation's chemical industry (strain) system) 10 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 5 parts, mixture (the trade name: Armid FMPC of morpholine derivative and carbonic ester, Akzo Nobel society system) 40 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 34.72 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 45)
Replace 10 parts, the Emulsifier EL-60 ether of embodiment 44, add 10 parts, polyoxyethylene hardened castor oil ether (trade name: ニ ッ コ ー Le HCO-20, daylight ケ ミ カ Le ズ (strain) make), in addition, similarly operate, obtain pesticidal emulsifiable composition.
(embodiment 46)
By compd A substance (purity: 99.6%) 5.02 parts, polyoxyethylene styryl phenyl ether (trade name: ソ ル ポ ー Le T-20, east nation's chemical industry (strain) system) 5 parts, calcium dodecyl benzene sulfonate (trade name: ソ ル ポ ー Le EX-15, east nation's chemical industry (strain) system) 5 parts, cyclohexanone 5 parts and aromatic hydrocarbon (trade name: カ Network タ ス Off ァ イ Application SF-02, JX day ore deposit day stone エ ネ ル ギ ー (strain) is made) 79.98 parts mix, obtain pesticidal emulsifiable composition.
(embodiment 47 ~ 70)
Operate in the same manner as embodiment 46, each constituent shown in showing the 2nd mixes, and obtains pesticidal emulsifiable composition.
[table 8]
Table 8
2nd table
[table 9]
Table 9
2nd table (Continued)
[table 10]
Table 10
2nd table (Continued)
[table 11]
[table 11]
2nd table (Continued)
[table 12]
[table 12]
2nd table (Continued)
(comparative example 1)
Mixture (the trade name: ソ ル ポ ー Le 3353 of polyoxyethylene styryl phenyl ether and polyether polyols is disperseed in 56.86 parts, water, east nation's chemical industry (strain) system) 3 parts, silicon-type defoamer (trade name: KM-73, SHIN-ETSU HANTOTAI's chemical industry (strain) is made) 0.1 part, propane diols 10 parts and compd A substance (purity: 99.6%) 10.04 parts, use 0.8-1.2mm φ bead 200g sand mill (ア イ メ ッ Network ス (strain) system) to carry out case of wet attrition, obtain and pulverize 80 parts, slurry.In addition, 1 is made in 19.55 parts, water, 2-benzisothiazole-3-ketone (trade name: PROXEL GXL, ア PVC シ ア (strain) makes) 0.05 part, xanthan gum (trade name: KELZAN ASX, CP Kelco society system) 0.1 part, smectite clay (trade name: VEEGUM R, R.T.Vanderbilt society system) 0.3 part disperse successively, obtain dispersion medium 20 parts.80 parts, above-mentioned pulverizing slurry and dispersion medium 20 parts is mixed, obtains uniform aqueous suspension shape composition pesticide 100 parts.
The outward appearance of (test example 1) pesticidal emulsifiable composition
The outward appearance of the pesticidal emulsifiable composition obtained by embodiment by visualization, is judged according to following benchmark.Show the result in the 3rd table.
Zero: transparent clarification
×: gonorrhoea
The emulsion stability of (test example 2) water diluent
In 100mL graduated cylinder, add 3 degree of hard water 100mL, add each 1mL of pesticidal emulsifiable composition obtained by embodiment, this graduated cylinder is put upside down and makes its emulsification equably.After this dilution is left standstill 24 hours at 30 DEG C, measure precipitum amount (mL).Show the result in the 3rd table and the 4th table.
[table 13]
[table 13]
3rd table
[table 14]
[table 14]
4th table
(test example 3) potency test to palm thrips female adult pest
In the styrene cup (lid diameter 7.5cm, height 4cm) of lid being stamped core perforate, add running water, lay filter paper to draw running water.Filter paper is placed absorbent cotton (5cm × 5cm), absorbent cotton is got wet, load the leaf dish (diameter 3cm) be made up of cucumber leaf thereon.Put 10 palm thrips female adult pest at Ye Panshang, use rotary distribution tower, liquid is all scattered process (2.5mg/cm by every 1 test chamber equably
2).Liquid employs the pesticidal emulsifiable composition dilute with water will obtained by embodiment and comparative example, the Concentration Modulation of compd A is become the liquid of 12.5ppm.Investigation was being carried out after 3 days, obtained dead worm rate by following calculating formula.In addition, test and carry out with 2 district's systems.
Dead worm rate (%)={ dead borer population/(dead borer population+existence borer population) } × 100
Show the result in the 5th following table.
[table 15]
Table 15
5th table
(test example 4) potency test to T.urticae Koch female adult pest
In the styrene cup (lid diameter 7.5cm, height 4cm) of lid being stamped core perforate, add running water, lay filter paper to draw running water.Filter paper loads the leaf dish (2cm × 2cm) be made up of Kidney bean leaf.Put 10 T.urticae Koch female adult pest at Ye Panshang, use rotary distribution tower, liquid is all scattered process (2.5mg/cm by every 1 test chamber equably
2).Liquid employs the pesticidal emulsifiable composition dilute with water will obtained by embodiment and comparative example, the Concentration Modulation of compd A is become the liquid of 25ppm.Investigation was being carried out after 2 days, and the calculating formula recorded by test example 3 obtains dead worm rate.In addition, test and carry out with 2 district's systems.Show the result in the 6th following table.
[table 16]
Table 16
6th table
Industry utilizability
The present composition can be used in pest, particularly insect, the preventing and kill off of mite.
Claims (22)
1. a pesticidal emulsifiable composition, it comprises: (Z)-[5-(3,5-dichlorophenyl)-5-trifluoromethyl-4,5-dihydro is different
azoles-3-base]-N-(methoxyimino methyl)-2-methyl benzamide, polar solvent, non-polar solven and surfactant.
2. pesticidal emulsifiable composition according to claim 1, relative to the quality of pesticidal emulsifiable composition, the content of described polar solvent is 7.5 ~ 67.5 quality %.
3. pesticidal emulsifiable composition according to claim 1 and 2, described polar solvent is be selected from more than at least a kind in ketone, N-alkyl pyrrolidone, ring-type urea, carboxylic acid amide, lactone, nitrogen-containing aromatic compound, cyclic amine, methyl-sulfoxide and carbonic ester.
4. pesticidal emulsifiable composition according to claim 1 and 2, described polar solvent is for being selected from 5 ~ 7 yuan of cyclic ketone, N-C
1 ~ 12alkyl pyrrolidone, 5 ~ 6 yuan of ring-type ureas, C
1 ~ 12carboxylic acid amide, 4 ~ 7 yuan of annular lactones, 5 ~ 6 yuan of cyclic nonaromatics comprising more than 1 nitrogen-atoms, 5 ~ 6 yuan of saturated cyclic amine comprising more than 1 nitrogen-atoms, methyl-sulfoxide and carbonic acid C
2 ~ 4more than at least a kind in alkylene ester.
5. pesticidal emulsifiable composition according to claim 4, described in comprise more than 1 nitrogen-atoms 5 ~ 6 yuan of saturated cyclic amine be 4-acyl group morpholine.
6. pesticidal emulsifiable composition according to claim 1 and 2, described polar solvent is for being selected from cyclohexanone, N-methyl-pyrrolidon, N-ethyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolinone, N, N '-dimethyl propylidene urea, N, more than at least a kind in dinethylformamide, DMA, 6-caprolactone, 1-methylimidazole, 4-acetyl morphine, 4-N-formyl morpholine N-, methyl-sulfoxide and propylene carbonate.
7. pesticidal emulsifiable composition according to claim 1, described polar solvent is cyclohexanone, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 22.5 ~ 67.5 quality %.
8. pesticidal emulsifiable composition according to claim 1, described polar solvent is METHYLPYRROLIDONE, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
9. pesticidal emulsifiable composition according to claim 1, described polar solvent is N-ethyl-2-pyrrolidone, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
10. pesticidal emulsifiable composition according to claim 1, described polar solvent is DMI, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
11. pesticidal emulsifiable compositions according to claim 1, described polar solvent is N, N '-dimethyl propylidene urea, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
12. pesticidal emulsifiable compositions according to claim 1, described polar solvent is DMF, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 12.5 ~ 62.5 quality %.
13. pesticidal emulsifiable compositions according to claim 1, described polar solvent is DMA, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 7.5 ~ 62.5 quality %.
14. pesticidal emulsifiable compositions according to claim 1, described polar solvent is 6-caprolactone, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 42.5 ~ 57.5 quality %.
15. pesticidal emulsifiable compositions according to claim 1, described polar solvent is 1-methylimidazole, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 17.5 ~ 62.5 quality %.
16. pesticidal emulsifiable compositions according to claim 1, described polar solvent is 4-acetyl morphine, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 22.5 ~ 62.5 quality %.
17. pesticidal emulsifiable compositions according to claim 1, described polar solvent is 4-N-formyl morpholine N-, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 12.5 ~ 67.5 quality %.
18. pesticidal emulsifiable compositions according to claim 1, described polar solvent is methyl-sulfoxide, and relative to the quality of pesticidal emulsifiable composition, the content of this polar solvent is 17.5 ~ 67.5 quality %.
19. pesticidal emulsifiable compositions according to any one in claim 1 ~ 18, described non-polar solven is aromatic hydrocarbon.
20. pesticidal emulsifiable compositions according to any one in claim 1 ~ 19, described surfactant is be selected from more than a kind in polyoxyalkylene aryl phenyl ether, the formaldehyde condensation products of polyoxyalkylene aryl phenyl ether, polyoxyalkylene vegetable oil and polyoxyethylene polyoxypropylene block copolymer.
21. pesticidal emulsifiable compositions according to claim 20, described surfactant is be selected from more than at least a kind in polyoxyalkylene aryl phenyl ether and polyoxyalkylene vegetable oil.
22. pesticidal emulsifiable compositions according to claim 20, described surfactant is be selected from more than at least a kind in polyoxyethylene list styrylphenyl ether, polyoxyethylene diphenylethyllene phenyl ether, polyoxyethylene tri-styryl base phenyl ether, Emulsifier EL-60 ether and polyoxyethylene hardened castor oil ether.
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| JP2013200042 | 2013-09-26 | ||
| PCT/JP2014/051699 WO2014119519A1 (en) | 2013-01-29 | 2014-01-27 | Emulsifying pesticide composition having high emulsion stability |
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| CN104955331A true CN104955331A (en) | 2015-09-30 |
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| JP (1) | JP6323677B2 (en) |
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| CN107549173A (en) * | 2017-08-31 | 2018-01-09 | 陕西康禾立丰生物科技药业有限公司 | A kind of Pesticidal combination containing Fu oxazole acid amides |
| CN108770843A (en) * | 2018-05-25 | 2018-11-09 | 浙江新安化工集团股份有限公司 | A kind of spray adjuvants and preparation method thereof and include its spray liquid |
| CN112218531A (en) * | 2018-05-28 | 2021-01-12 | 日产化学株式会社 | Emulsifiable composition of agricultural chemicals |
| CN112889817A (en) * | 2019-12-04 | 2021-06-04 | 竹本油脂株式会社 | Emulsifier composition for fatty acid alkyl ester and composition comprising the same |
| CN114745954A (en) * | 2019-12-05 | 2022-07-12 | 住友化学株式会社 | Liquid pesticide composition |
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| CN105873438A (en) * | 2014-01-31 | 2016-08-17 | 日产化学工业株式会社 | Liquid pesticide composition |
| JP6867607B2 (en) | 2016-07-13 | 2021-04-28 | 日産化学株式会社 | Aqueous suspension pesticide composition |
| JP7296319B2 (en) * | 2017-10-30 | 2023-06-22 | 日本曹達株式会社 | Pesticide emulsion composition |
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| JP7417409B2 (en) | 2019-12-05 | 2024-01-18 | 住友化学株式会社 | Liquid pesticide composition |
| WO2022138821A1 (en) * | 2020-12-25 | 2022-06-30 | 日産化学株式会社 | Dispersible concentrated agrochemical formulation |
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Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2014119519A1 (en) | 2017-01-26 |
| WO2014119519A1 (en) | 2014-08-07 |
| JP6323677B2 (en) | 2018-05-16 |
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