CN1049282A - Preparations having functions of cleaning and care of skin - Google Patents

Abstract

A kind of preparations having functions of cleaning and care of skin is used to make clean the teeth element, five in one of paste and washes clean element and improve looks plain.It is characterized in that this law comprises that to extract aminoacid and be neutralized into fatty acid potassium from the cystine waste liquid be general activating agent, do not contain filler, the water yield is few, is prescription and a whole set of preparation technology of above-mentioned three kinds of elements of effective ingredient entirely.Its product is miniature efficient, only with the amount of existing like product 1/5～1/4, promptly plays same result of use, and each element has the purposes more than three kinds at least, all more than ministry standard, primary raw material is twice laid to every index, and cost is low, volume is little, and is in light weight, easy to carry.

Description

Skin protection three plain method for makings are washed in miniature high-efficiency multi-function play

The present invention relates to a kind of preparations having functions of cleaning and care of skin, belong to daily chemical industry product manufacturing technology field, be mainly used to make paste element (toothpaste) five in one that cleans the teeth and wash clean element and improve looks plain.

At present, the toothpaste of selling on the domestic and international market, shampoo, hair conditioner, vanishing cream etc. are of a great variety, title is different, with countless changes, but change ten thousand times without leaving the original aim or stand, toothpaste is primary raw material with the surfactant of sodium salt class, abrasive, sweeting agent, spice, Herba Menthae etc. all, for catering to the psychology of consumer, most manufacturers heavily are its objective of the struggle in a large number to manage, so excipient such as cellulose, the rubber powders etc. of adopting increase viscosity and expand its volume so that it adsorbs a large amount of moisture content more; Shampoo is then many to be primary raw material with AES and 6501, includes the moisture content more than 80%, in order to increase its viscosity and to expand a large amount of Sal of the necessary again interpolation of its volume; The primary raw material of vanishing cream mostly is stearic acid octadecanol, monoglyceride, glycerol etc., and emulsifying agent is cation or anion surfactant, and the content of water is about about 80%.No matter existing above-mentioned daily chemical product is toothpaste, shampoo hair conditioner or vanishing cream, all exist the problem of a universality to be: surfactant mostly be the sodium salt powdery and content low, can not be general, the water yield is big.Must add certain invalid filler of paying effect to a certain degree that very causes in order to reach certain denseness and to expand volume, as adding cellulose in the toothpaste, with Sal etc., the effectiveness and the usefulness that have so just reduced finished product are single in the shampoo; In order to reach certain result of use, just must be many, so develop to the direction of big bottle of bassoon on the packaging with (comprising kind and quantity), if any the toothpaste 150 gram/pipes that weigh, shampoo weighs 500 gram/bottles, and increasing trend is arranged, bring a lot of troubles so just for packing, transportation, march, tourism: carry inconvenience, packing is easily broken or the like, though fractional pack was once arranged, but, because packing charges increases, seem very uneconomical again because of have more than is needed just empty several times.Be eliminated again so this fractional pack is very fast.

Edit through looking into national daily chemical industry scientific and technological information station " detergents and cosmetic digest " editorial office, the 1986 annual theme index that 1986 the 6th phases of detergents and cosmetic digest (bimonthly) of scientific and technical literature publishing house December in 1986 publication on the 23rd step on "; " daily chemical industry editorial office edits at national daily chemical industry scientific and technological information station, scientific-technical information of Ministry of Light Industry institute is published, the good institute of the graduate willow of Shanghai Petrochem. General Plant that 1986 the 6th phases were gone up publication is write, be entitled as " preparation and application that aminoacid is surfactant ", this bimonthly second phase in 1987 is gone up be entitled as " application of the composite abrasive of toothpaste " that the Yao Huanxin of the Hefei daily-use chemical industry head factory of publication writes, " amorphous silica and the transparent toothpaste " that the Feng Lanbin of the Shanghai Toothpaste Factory that the third phase in the same year is upward published writes, the data such as " inorganic salt are to the surfactant Effect on Performance " that the Chen Yongxuan of Foochow soap factory that the 6th phase of the same year is upward published writes is all found the toothpaste (clean the teeth element) identical or similar with the present invention with article, hair-washing hair-care element (washing clean element), vanishing cream (skin-care agent) is not especially seen and was mentioned what above-mentioned three kinds of products can be used with a kind of surfactant.

For adapting to particularly athlete of people, pressing for of soldier and traveller's daily life, the object of the present invention is to provide a kind of utilize produce waste liquid that cystine discharged extract with in and amino-acid, fatty-acid potassium and with this as general surfactant, the volume that the manufacturing water content does not add invalid filler less is little, consumption is few, efficiently, multi-functional, packed and transported, carry all miniature very easily element that cleans the teeth, five in one (hair washing, hair care, have a bath, wash one's face, scrape beard) wash clean element and oil type, half oil type, the method of three kinds of these three kinds of paste elements of model skin-care agent of powder type.

Belong to gang's element according to the characteristic of amino acid surfactant and sodium salt potassium salt and can replace this ultimate principle and the fact mutually under certain condition, at the subject matter that exists in the prior art, be engaged in the practical experience of daily chemicals research and production decades in conjunction with the inventor, basic design of the present invention is: that discharges when producing cystine wherein contains tens seed amino acids, and originally environment was had in the waste liquid of pollution and extract aminoacid and be neutralized into fatty acid potassium, with this general purpose table surface-active agent as three kinds of products of the present invention, scientifically adjust prescription, make each product all only contain active ingredient, do not add any invalid even deleterious filler, keeping under the prerequisite of certain denseness, add water less as far as possible, to reach as long as with the known technology like product Just can rise result of use equally.And can one-object-many-purposes, promptly realize the purpose of miniature high-efficiency multi-function.

Preparations having functions of cleaning and care of skin of the present invention (hereinafter to be referred as three plain method for makings) is characterized in that with the aminoacid that extracts from the cystine waste liquid and is neutralized into fatty acid potassium as the general purpose table surface-active agent, moisture is few, non-filler, be equipped with other different active ingredients and can make the miniature high-efficiency multi-function element that cleans the teeth respectively, hair washing, hair care, wash one's face, have a bath, scraping the beard five in one washes clean element and improves looks plain these three kinds of paste elements, their prescription is respectively: (1) amino-acid, fatty-acid potassium 17～18%, aluminium hydroxide 9～11%, natural whiting 38～42%, chlorophyll 0.4～0.6%, glycerol 18～22%, glucide 1～2%, spice 4～6%, finish and dial extracting solution 0.9～1.1%, water 4～5%; (2) amino-acid, fatty-acid potassium 70～75%, glycerol 3～3.5%, salicylic acid 0.2～0.3%, spice 0.9～1.1%, antiseptic 0.25～0.35%, water 22～23%; (3) amino-acid, fatty-acid potassium 0.9～1.1%, octadecanol 7～9%, monoglyceride 7～9%, glycerol 28～32%, antiseptic 0.25～0.35%, spice 0.9～1.1%, fat acid zinc 18～22%, silicone oil 14～15%, water 15～16% (more than be by weight); Its technical process is: 1. the cystine waste liquid is handled through alkalescence, acidity, desulfuration and condensation reaction and extracted aminoacid and be neutralized into fatty acid potassium, 2. in above-mentioned surfactant, add other raw materials by above-mentioned prescription respectively, 3. 90～100 ℃ of heating stir after mixing, and limit heating edge restir is 4. according to the known technology grinding → degassing or cooling → container sterilization → fill → product inspection separately.The above-mentioned technical process of extracting aminoacid and be neutralized into fatty acid potassium from the cystine waste liquid is: 1. basic treatment: add 70～80% in the cystine waste liquid, concentration is 30% alkali liquor, also amount of makeup water is till hearing the abnormal smells from the patient of no ammonia with olfactory sensation at any time to boil 12 hours, and filter with the filter press meter cold slightly back; 2. acidic treatment: processing industry hydrochloric acid to its pH value is 6 in the liquid after filter, and removes impurity through sedimentation and filtration, and continuation processing industry hydrochloric acid to its pH value is 2 in the liquid after the removal of impurity again, heat 80 ℃ one hour.Slowly add 3～4% zinc powders after cold slightly, treated that hydrogenization finished in static 2 hours after, add 3.5～5% activated carbon again, then sedimentation and filtration; 3. desulfuration is handled: it is that alkali liquor to its pH value of 30% is 4 that the liquid that takes out above-mentioned post precipitation adds 12.5～13.7% concentration, add 0.14～0.16% Cu-lyt., adding concentration again and be alkali liquor to its pH value of 30% is 11, and add 0.75～1.5% precipitation of calcium carbonate when not having muddy phenomenon again and filter and measure its amino nitrogen for 60 ℃ with post-heating one night, its value is that sulfide has been removed in about 0.5% i.e. expressions; 4. condensation and neutralization reaction are handled: with sebific duct slowly add in the above-mentioned clear liquor 5～7% chlorine acyls also stirring make it carry out condensation reaction, the temperature that condensation begins back liquid can raise automatically, temperature is 16 ℃ when beginning as condensation, then condensation reaction needs to carry out under 24～26 ℃ of temperature conditions, as too high available ice or cold water cooling and stirring incessantly, at any time be that 30% alkali liquor is adjusted its pH value with concentration, make it to remain on 11, condensation reaction is finished a static night behind the post-heating to 30 ℃, it is 1 that reprocessing industry hydrochloric acid makes its pH value, at this moment liquid is analysed to open and is divided into three layers, the upper strata is a condensation substance, the middle level is a saline, lower floor is a salt, following two layers saline and salt and the condensation substance on upper strata is heated to 80 ℃ in emitting are washed with clear water and are eliminated 3～4 times, are 8～8.5 to be the amino-acid, fatty-acid potassium of active quantities 60% toward the pH value that neutralizes of hydro-oxidation potassium wherein then.(above-mentioned percentage ratio is except that active quantities and alkaline concentration, all the other be all add the weight/cystine waste liquid initial weight of composition) prescription of above-mentioned cosmetology element, promptly change its silicone oil into 7.5～8.5% in the prescription (3), and the corresponding increase water yield, promptly become half oil type and improve looks plain; And wherein ester acid zinc changes 10～11% into, and adding 10～11% titanium dioxides more then becomes powder type cosmetology element.

Outstanding advantage of the present invention is: the used surfactant of the present invention is environment is had the aminoacid that extracts the waste liquid of pollution and is neutralized into fatty acid potassium from factory's discharging of producing cystine, so not only raw material be easy to get (factory that the whole nation produces cystine is a lot) can twice laid, and can curb environmental pollution, the more important thing is by the decision of amino acid whose many peculiar properties and to have the unexistent characteristic of many other surfactants with this surfactant that makes.As the zest minimum to skin, toxicity is minimum, and certain sterilizing power is arranged, and strong foaming power can make hair keep soft.Can be in various products general and content can increase, wash clean cellulose content up to more than 70% as five in one among the present invention, thereby can make finished product moisture few, non-filler, even active ingredient concentrates, not only volume is miniature, and render a service and increase, use known technology like product Can play equal result of use, though like this with fractional pack also than existing big pack durable.This just gives consumer, and particularly soldier, athlete, traveller bring many convenience; Owing to be twice laid, do not contain filler again, save packing and freight charges, thereby cost can reduce greatly.Because scientific formulation, reasonable, all contain certain medicine again, through detecting repeatedly, every quality index and sanitary index are all more than ministry standard, but and the equal one-object-many-purposes of these three kinds of products, as the element that cleans the teeth is mainly used in and brushes teeth, have clean the teeth, the function of tooth protection, deodorization, pain relieving, simultaneously also can be used for treating the wet foot pruritus of foot, five in one is washed clean element and is mainly used in hair washing, takes care of hair, washes one's face, has a bath, and with clean the teeth that be used in plain 1: 1 can anti-dandruff, stopping head itching then can be used for scraping beard with improving looks to be used in plain 1: 1.The cosmetology element is mainly used in tender skin, delays the youth, brightens wrinkle resistant, anti-chap, and has three kinds of models to select arbitrarily according to different sexes, age, and men and women, old and young are all suitable.Former Chemical Factory of Daily Use need not increase and change any equipment can update to old product, and can produce multiple product simultaneously, free from environmental pollution.

Most preferred embodiment of the present invention is:

The plain prescription that cleans the teeth is: amino-acid, fatty-acid potassium 17.5%, and aluminium hydroxide 10%, natural whiting 40%, chlorophyll 0.5%, glycerol 20%, glucide 1.5%, fruit flavouring spice 5% is finished and is dialled extracting solution 1%, water 4.5%; The prescription that five in one is washed clean element is: amino-acid, fatty-acid potassium 72.5%, and glycerol 3%, salicylic acid 0.3%, delicate fragrance type spice 1%, the third fat fourth fat mixes 0.3%, water 22.9%; The plain prescription of improving looks is: amino-acid, fatty-acid potassium 1%, octadecanol 8%, monoglyceride 8%, glycerol 30%, propylparaben fourth fat mixes 0.3%, international fragrant perfume 1%, ester acid zinc 20%, silicone oil 14.5%, vitamin E 0.5%, lanoline 1%, water 15.7%; Extracting aminoacid and be neutralized in the technology of fatty acid potassium from the cystine waste liquid, the concentration that adds for the first time is that 30% alkali liquor amount ratio is 75%.The zinc powder amount ratio that adds gets 3.5%, and activated carbon gets 4%, and Cu-lyt. gets 0.15%, and the chlorine acyl gets 6%.

Change as the embodiment of the invention:

1, the amino-acid, fatty-acid potassium that cleans the teeth in the plain prescription can replace with sodium lauryl sulfate, and reduces proportion.Aluminium hydroxide can replace with amorphous silica, and natural whiting can replace with crystalline calcium carbonate or phosphorus hydrogen calcium, and back two kinds replace content constant.

2, five in one is washed in the clean plain prescription can increase by 0.1% quinine or hydroxyquinoline, corresponding minimizing water 0.1%, and amino-acid, fatty-acid potassium can replace with the mixed surfactant that amino-acid, fatty-acid potassium cooperates at 1: 1 with AES.

3, octadecanol can replace with hexadecanol in the plain prescription of cosmetology, and ester acid zinc can replace with sour magnesium of ester or ester acid calcium, and amino-acid, fatty-acid potassium can replace with sodium lauryl sulfate.

4, improve looks and to change its silicone oil into 7.5～8.5% in the plain prescription, and increase water accordingly and then become half oil type and improve looks plain; Wherein ester acid zinc changes 10～11% into, adds 10～11% titanium dioxide again, then becomes the powder type and improves looks plain.

5, extract aminoacid and be neutralized into fatty acid potassium and can change into from the cystine waste liquid: from useless silkworm silk or osseocolla or Pilus Sus domestica or hair wastes, extract aminoacid and be neutralized into fatty acid potassium.

Claims (3)

1, a kind of preparations having functions of cleaning and care of skin (hereinafter to be referred as three plain method for makings), comprise batching, agitating heating, grind, the degassing, fill, technical processs such as product inspection, of the present invention three plain method for makings, it is characterized in that with the aminoacid that from the cystine waste liquid, extracts and to be neutralized into fatty acid potassium be the general purpose table surface-active agent, moisture is few, non-filler, be equipped with other different active ingredients and can make the miniature high-efficiency multi-function element that cleans the teeth respectively, five in one is washed clean element and is improved looks plain, their prescription is respectively: (1) amino-acid, fatty-acid potassium 17～18%, aluminium hydroxide 9～11%, natural whiting 38～42%, chlorophyll 0.4～0.6%, glycerol 18～22% glucide 1～2%, spice 4～6% is finished and is dialled extracting solution 0.9～1.1%, water 4～5%; (2) amino-acid, fatty-acid potassium 70～75%, glycerol 3～3.5% salicylic acids 0.2～0.3%, spice 0.9～1.1%, antiseptic 0.25～0.35%, water 22～23%; (3) amino-acid, fatty-acid potassium 0.9～1.1% octadecanol 7～9%, monoglyceride 7～9%, glycerol 28～32%, antiseptic 0.25～0.35%, spice 0.9～1.1%, ester acid zinc 18～22%, silicone oil 14～15%, vitamin E 0.4～0.6%, lanoline 0.9～1.1%.Water 15～16% (above all by weight); Its technical process is: 1. the cystine waste liquid is handled through alkalescence, acidity, desulfuration and condensation reaction and extracted aminoacid and be neutralized into fatty acid potassium, 2. add other raw materials by above-mentioned prescription in above-mentioned surfactant respectively, heating 90～100 ℃ and limit heating edge restir stir after 3. mixing; 4. according to separately the known technology grinding → degassing → or cooling → container sterilization → fill → product inspection.

2, according to claim 1 three plain method for makings, it is characterized in that the above-mentioned technical process of extracting aminoacid and be neutralized into fatty acid potassium from the cystine waste liquid is: 1. basic treatment: add concentration in the cystine waste liquid and be 30% alkali liquor 70～80%, also amount of makeup water is till the abnormal smells from the patient of no ammonia at any time to boil 12 hours, and filter with the filter press meter cold slightly back; 2. acidic treatment: processing industry hydrochloric acid to its pH value is 6 in the liquid after filter, remove impurity through sedimentation and filtration, continuing processing industry hydrochloric acid to its pH value in the liquid after the removal of impurity again is 2, heat 80 ℃ one hour, slowly add 3～4% zinc powders after cold slightly, treated in static 2 hours to add 3.5～5% activated carbon again after hydrogenization finishes, then sedimentation and filtration; 3. desulfuration is handled: it is 30% alkali liquor that the liquid that takes out above-mentioned post precipitation adds 12.5～13.75% concentration, to its pH value be 4, add 0.14～0.16% Cu-lyt., adding concentration again and be alkali liquor to its pH value of 30% is 11, and when not having muddy phenomenon, add 0.75～1.5% calcium carbonate again, precipitate a night with 60 ℃ of after-filtration of post-heating and measure its amino nitrogen content; 4. condensation and neutralization reaction are handled: slowly add 5～7% chlorine acyls and stirring with sebific duct in above-mentioned clear liquor, regulate the temperature that it raises voluntarily with ice or cold water, condensation is carried out in 24～26 ℃, at any time be that 30% alkali liquor is adjusted its pH value and made it to remain on 11 with concentration, after condensation is finished, a static liquid after being heated to 30 ℃, it is 1 that reprocessing industry hydrochloric acid makes its pH value, analyse out emit after the layering in lower floor's saline and the remaining condensation substance of salt pair be heated to 80 ℃ of reuse clear water and wash and eliminate 3～4 times, to eliminate in the after-condensation thing hydro-oxidation potassium pH value that neutralizes be 8～8.5 to be the amino-acid, fatty-acid potassium of active quantities 60% toward washing.

3, according to claim 1 three plain method for makings, it is characterized in that changing its silicone oil into 7.5～8.5% in the above-mentioned prescription (3) also increases water accordingly, then become half oil type improve looks plain and wherein ester acid zinc change 10～11% into and add 10～11% titanium dioxides again, promptly become the powder type and improve looks plain.