CN104927227A - Method for producing anti-static sheet material through filling waste PVC thin film with fly ash - Google Patents
Method for producing anti-static sheet material through filling waste PVC thin film with fly ash Download PDFInfo
- Publication number
- CN104927227A CN104927227A CN201410100486.6A CN201410100486A CN104927227A CN 104927227 A CN104927227 A CN 104927227A CN 201410100486 A CN201410100486 A CN 201410100486A CN 104927227 A CN104927227 A CN 104927227A
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- China
- Prior art keywords
- parts
- flyash
- coupling agent
- waste pvc
- pvc film
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
- C08J2491/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
The invention discloses a method for producing an anti-static sheet material through filling a waste PVC thin film with fly ash, and is characterized in that the anti-static sheet material is prepared from the following raw materials in parts by mass: 100 parts of the waste PVC thin film, 15-25 parts of the fly ash, 8-10 parts of DOP, 3-8 parts of M-50 petroleum ester, 2-3 parts of a dioctyltin dilaurate stabilizer, 3-5 pats of epoxy soybean oil, 2-3 parts of CPE, 2-3 parts of ACR, 3-5 parts of a flame retardant hexabromo-benzene, 1-1.5 parts of a non-ionic antistatic agent HZ-1, 0.2-0.5 part of triglyceryl stearate, 5-8 parts of a flame retardant chlorinated paraffin, 2-3 parts of a silane coupling agent, and 1-2 parts of a titanate coupling agent. The sheet material prepared by the method has the advantages of low cost, easily available raw material, high economic benefits and the like.
Description
Technical field
The invention belongs to Recycle of Waste Plastics field, particularly relate to the method that flyash fills waste PVC film production Antistatic sheet.
Background technology
Polyvinyl chloride (also known as PVC), it is the thermoplastic resin be polymerized under initiator effect by vinylchlorid, for the white powder of amorphous structure, the degree of branching is less, its matter is hard, poorly soluble, but organic and mineral acid, alkali, salt are stablized, and chemical stability reduces with the rising of use temperature, there is the features such as difficult combustion, acid and alkali-resistance, antimicrobial, wear-resisting, heat retention and good springiness.Because its quantity is large, pollute heavy and become one of main products of current regeneration.
At present, the report that relevant PVC recycles is more, strongly limit it to further develop, but prior art is all filling-modified with the material such as processing aid, xylon, although the application of different field can be met, also good Social benefit and economic benefit is achieved, but still the demand in indivedual field can not be met, and to material source, there is very large dependency, as xylon source direct relation its economic benefit, the recycling as the PVC film of colliery application is then affected because of the restriction of weighting agent.
In order to overcome above-mentioned defect, the present invention proposes the method that flyash fills waste PVC film production Antistatic sheet, in order to solve the pollution problem of flyash and coal mine waste PVC plastic, finding also there is no the report of this technology through retrieval.
Summary of the invention
The object of the invention is to: provide a kind of flyash to fill the method for waste PVC film production Antistatic sheet, take flyash as weighting agent, waste PVC film is raw material, reaches the object of the recycling of waste PVC film and flyash, increases economic efficiency.
To achieve these goals, the present invention adopts following technical scheme:
Flyash fills the method for waste PVC film production Antistatic sheet, and it is characterized in that: in mass parts, this Antistatic sheet is made up of following raw material:
Further, in described CPE, cl content is 30 ~ 35%.
In described fire retardant clorafin, chlorinity is more than 65% solid.
Flyash fills the method for waste PVC film production Antistatic sheet, it is characterized in that: the concrete steps of the method are as follows:
1) pulverize, after 20 ~ 150 mesh sieves through pulverizer after flyash drying;
2) use silane coupling agent and titanate coupling agent at 80 ~ 90 DEG C, stir 30 minutes with flyash;
3) flyash of coupling agent treatment is put into homogenizer together with other component to stir, churning time is 30 ~ 40 minutes;
4) forcing machine extruding pelletization, then through aftershaping of colding pressing.
Compared with prior art, beneficial effect of the present invention is: simultaneously treated coal ash and waste PVC film, has that cost is low, economic benefit and a high advantage of social benefit.
Embodiment
Below in conjunction with specific examples, technical scheme of the present invention is described further.
Embodiment 1
Flyash fills the method for waste PVC film production Antistatic sheet, and in mass parts, this Antistatic sheet is made up of following raw material:
Waste PVC film 100 parts, 20 parts, flyash, DOP9 part, M-50 phenyl alkylsulfonate 5 parts, tin dilaurate dioctyl tin stablizer 2.5 parts, epoxy soybean oil 4 parts, CPE2.5 part, ACR2.5 part, fire retardant hexabromobenzene 4 parts, non-ionic antistatic agent HZ-11.2 part, glycerol stearate 0.3 part, fire retardant clorafin 6 parts, silane coupling agent 2.5 parts, titanate coupling agent 1.5 parts.
Further, in described CPE, cl content is 35%.
In described fire retardant clorafin, chlorinity is more than 65% solid.
Flyash fills the method for waste PVC film production Antistatic sheet, and concrete steps are as follows:
1) pulverize, after 20 ~ 150 mesh sieves through pulverizer after flyash drying;
2) use silane coupling agent and titanate coupling agent at 80 ~ 90 DEG C, stir 30 minutes with flyash;
3) flyash of coupling agent treatment is put into homogenizer together with other component to stir, churning time is 30 ~ 40 minutes;
4) forcing machine extruding pelletization, then through aftershaping of colding pressing.
Embodiment 2
Flyash fills the method for waste PVC film production Antistatic sheet, and in mass parts, this Antistatic sheet is made up of following raw material:
Waste PVC film 100 parts, 15 parts, flyash, DOP8 part, M-50 phenyl alkylsulfonate 3 parts, tin dilaurate dioctyl tin stablizer 2 parts, epoxy soybean oil 3 parts, CPE2 part, ACR2 part, fire retardant hexabromobenzene 3 parts, non-ionic antistatic agent HZ-11 part, glycerol stearate 0.2 part, fire retardant clorafin 5 parts, silane coupling agent 2 parts, titanate coupling agent 1 part.
Further, in described CPE, cl content is 30%.
In described fire retardant clorafin, chlorinity is more than 65% solid.
Flyash fills the method for waste PVC film production Antistatic sheet, and concrete steps are as follows:
1) pulverize, after 20 ~ 150 mesh sieves through pulverizer after flyash drying;
2) use silane coupling agent and titanate coupling agent at 80 ~ 90 DEG C, stir 30 minutes with flyash;
3) flyash of coupling agent treatment is put into homogenizer together with other component to stir, churning time is 30 ~ 40 minutes;
4) forcing machine extruding pelletization, then through aftershaping of colding pressing.
Embodiment 3
Flyash fills the method for waste PVC film production Antistatic sheet, and in mass parts, this Antistatic sheet is made up of following raw material:
Waste PVC film 100 parts, 25 parts, flyash, DOP10 part, M-50 phenyl alkylsulfonate 8 parts, tin dilaurate dioctyl tin stablizer 3 parts, epoxy soybean oil 5 parts, CPE3 part, ACR3 part, fire retardant hexabromobenzene 5 parts, non-ionic antistatic agent HZ-1 1.5 parts, glycerol stearate 0.5 part, fire retardant clorafin 8 parts, silane coupling agent 3 parts, titanate coupling agent 2 parts.
Further, in described CPE, cl content is 32%.
In described fire retardant clorafin, chlorinity is more than 65% solid.
Flyash fills the method for waste PVC film production Antistatic sheet, and concrete steps are as follows:
1) pulverize, after 20 ~ 150 mesh sieves through pulverizer after flyash drying;
2) use silane coupling agent and titanate coupling agent at 80 ~ 90 DEG C, stir 30 minutes with flyash;
3) flyash of coupling agent treatment is put into homogenizer together with other component to stir, churning time is 30 ~ 40 minutes;
4) forcing machine extruding pelletization, then through aftershaping of colding pressing.
After tested, the performance index of product of the present invention are as follows:
Table 1-performance index
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Body resistivity/Ω cm | 10 11 | 10 10 | 10 11 |
| Oxygen index | 27.1 | 28.2 | 27.6 |
Can find out from upper table 1, the sheet material adopting technical solution of the present invention to produce has good static resistance and flame retardant resistance.
Claims (4)
1. flyash fills the method for waste PVC film production Antistatic sheet, and it is characterized in that: in mass parts, this Antistatic sheet is made up of following raw material:
Waste PVC film 100 parts, 15 ~ 25 parts, flyash, DOP8 ~ 10 part, M-50 phenyl alkylsulfonate 3 ~ 8 parts, tin dilaurate dioctyl tin stablizer 2 ~ 3 parts, epoxy soybean oil 3 ~ 5 parts, CPE2 ~ 3 part, ACR2 ~ 3 part, fire retardant hexabromobenzene 3 ~ 5 parts, non-ionic antistatic agent HZ-11 ~ 1.5 part, glycerol stearate 0.2 ~ 0.5 part, fire retardant clorafin 5 ~ 8 parts, silane coupling agent 2 ~ 3 parts, titanate coupling agent 1 ~ 2 part.
2. flyash as claimed in claim 1 fills the method for waste PVC film production Antistatic sheet, it is characterized in that: in described CPE, cl content is 30 ~ 35%.
3. flyash as claimed in claim 1 fills the method for waste PVC film production Antistatic sheet, it is characterized in that: in described fire retardant clorafin, chlorinity is more than 65% solid.
4. flyash as claimed in claim 1 fills the method for waste PVC film production Antistatic sheet, it is characterized in that: the concrete steps of the method are as follows:
1) pulverize, after 20 ~ 150 mesh sieves through pulverizer after flyash drying;
2) use silane coupling agent and titanate coupling agent at 80 ~ 90 DEG C, stir 30 minutes with flyash;
3) flyash of coupling agent treatment is put into homogenizer together with other component to stir, churning time is 30 ~ 40 minutes;
4) forcing machine extruding pelletization, then through aftershaping of colding pressing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410100486.6A CN104927227A (en) | 2014-03-18 | 2014-03-18 | Method for producing anti-static sheet material through filling waste PVC thin film with fly ash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410100486.6A CN104927227A (en) | 2014-03-18 | 2014-03-18 | Method for producing anti-static sheet material through filling waste PVC thin film with fly ash |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104927227A true CN104927227A (en) | 2015-09-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410100486.6A Pending CN104927227A (en) | 2014-03-18 | 2014-03-18 | Method for producing anti-static sheet material through filling waste PVC thin film with fly ash |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104927227A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860331A (en) * | 2016-04-20 | 2016-08-17 | 广德天运新技术股份有限公司 | Preparation method for producing nano composite PVC (polyvinyl chloride) sheet by using waste PVC |
| CN105968627A (en) * | 2016-04-20 | 2016-09-28 | 广德天运新技术股份有限公司 | Nano composite type PVC sheet material produced from waste PVC |
-
2014
- 2014-03-18 CN CN201410100486.6A patent/CN104927227A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860331A (en) * | 2016-04-20 | 2016-08-17 | 广德天运新技术股份有限公司 | Preparation method for producing nano composite PVC (polyvinyl chloride) sheet by using waste PVC |
| CN105968627A (en) * | 2016-04-20 | 2016-09-28 | 广德天运新技术股份有限公司 | Nano composite type PVC sheet material produced from waste PVC |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150923 |