CN104927213A - High polymer material used for engineering cable and preparation method thereof - Google Patents
High polymer material used for engineering cable and preparation method thereof Download PDFInfo
- Publication number
- CN104927213A CN104927213A CN201510401992.3A CN201510401992A CN104927213A CN 104927213 A CN104927213 A CN 104927213A CN 201510401992 A CN201510401992 A CN 201510401992A CN 104927213 A CN104927213 A CN 104927213A
- Authority
- CN
- China
- Prior art keywords
- parts
- macromolecular material
- engineering cable
- temperature
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high polymer material used for an engineering cable and a preparation method thereof. The high polymer material used for the engineering cable comprises 20-45 parts of polybutylene, 8-20 parts of polypropylene, 3-7 parts of sulfonated polyethersulfone, 5-15 parts of polyoxyethylene sorbide single palmitate, 4-12 parts of vinol cinnamate, 3-7 parts of titanium dioxide, 4-8 parts of antimonous oxide, 3-6 parts of triisopropyl borate, and 5-8 parts of laurinol polyether sodium sulfovinate. The preparation method comprises the steps of ball milling, heating and even stirring, two-screw squeezing, grain-sized dicing and high polymer material preparing. The high polymer material has the advantages that the tensile strength is strong, and the impact strength of notches is high; the high polymer material is suitable for an engineering cable industry.
Description
Technical field
The invention belongs to polymeric material field, relate to a kind of macromolecular material and preparation method thereof, particularly relate to a kind of engineering cable macromolecular material and preparation method thereof.
Background technology
Electric wire is the various motor of transmission of electric energy, transmission of information and manufacture, electrical equipment, the indispensable basic equipment of instrument, is the basic product that future is electrified, informationized society is necessary.Cable products material uses position and function by it, can be divided into electro-conductive material, insulating material, jacket material, shielding material, packing material etc.But wherein some material is that several structural part is general.Especially thermoplastic material, if as the changing section such as polyvinyl chloride, polyethylene Formulation Ingredients just can be used on insulation or sheath on.Extensively adopting resin as insulation and jacket material during electric wire manufactures, is all thermoplastics.Conventional has polyvinyl chloride, polyethylene, crosslinked polyethylene, foamed polyethylene, polypropylene, fluoroplastics, polystyrene, polymeric amide, polyimide and polyester etc.Therefore, macromolecular material has purposes widely in cable industry.Macromolecular material for engineering cable also needs to have good performance.
Summary of the invention
The technical problem solved: the Application Areas of engineering cable is very many, macromolecular material is an important material in engineering cable, can be used for cable insulation material, sheath material etc., macromolecular material for engineering cable needs to have good intensity, the object of the invention is openly a kind ofly to have macromolecular material of better shock-resistant characteristic and stretch-proof characteristic and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
The invention discloses a kind of engineering cable macromolecular material, described macromolecular material comprises the composition of following weight part:
Polybutene 20-45 part,
Polypropylene 8-20 part,
Sulfonated polyether sulfone 3-7 part,
TWEEN40 5-15 part,
Polyvinyl cinnamate 4-12 part,
Titanium dioxide 3-7 part,
Antimonous oxide 4-8 part,
Triisopropyl borate ester 3-6 part,
Laureth sodium sulfovinate 5-8 part.
Preferably, described a kind of engineering cable macromolecular material, comprises the composition of following weight part:
Polybutene 25-40 part,
Polypropylene 12-18 part,
Sulfonated polyether sulfone 4-6 part,
TWEEN40 7-13 part,
Polyvinyl cinnamate 6-10 part,
Titanium dioxide 4-6 part,
Antimonous oxide 5-7 part,
Triisopropyl borate ester 4-5 part,
Laureth sodium sulfovinate 6-7 part.
A preparation method for engineering cable macromolecular material, preparation method comprises the following steps:
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 80r/min-160r/min, and in ball mill, ratio of grinding media to material is 10:1-20:1, and Ball-milling Time is 30min-60min;
(2) stirring tank is started, in stirring tank, add polybutene 20-45 part, polypropylene 8-20 part, sulfonated polyether sulfone 3-7 part, TWEEN40 5-15 part, polyvinyl cinnamate 4-12 part, titanium dioxide 3-7 part, antimonous oxide 4-8 part, triisopropyl borate ester 3-6 part, laureth sodium sulfovinate 5-8 part, add mentioned component post-heating and stir;
(3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 11:1-15:1, twin screw extruder extrusion temperature is as follows: a district temperature 160-170 DEG C, two district's temperature are 175-185 DEG C, three district's temperature are 190-200 DEG C, and four district's temperature are 205-210 DEG C;
(4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Preferably, the preparation method of described a kind of engineering cable macromolecular material, in described step (1), drum's speed of rotation is 120r/min.
Preferably, the preparation method of described a kind of engineering cable macromolecular material, in described step (1), ball mill ratio of grinding media to material is 15:1.
Preferably, the preparation method of described a kind of engineering cable macromolecular material, in described step (3), double-screw extruder screw length-to-diameter ratio is 13:1.
Beneficial effect: by forming the processing steps such as ball milling, mixing, twin-screw extrusion to macromolecular material, the engineering cable macromolecular material of the present invention prepared has the advantages that shock resistance is high, tensile property is high, auxiliary material as cable material is used in cable material and sheath material, effectively can improve the respective strengths of engineering cable material, effectively improve the defect of conventional project cable.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 160r/min, and in ball mill, ratio of grinding media to material is 20:1, and Ball-milling Time is 60min; (2) stirring tank is started, in stirring tank, add polybutene 20 parts, polypropylene 8 parts, sulfonated polyether sulfone 7 parts, TWEEN40 5 parts, polyvinyl cinnamate 12 parts, titanium dioxide 3 parts, antimonous oxide 8 parts, triisopropyl borate ester 3 parts, laureth sodium sulfovinate 8 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 15:1, and twin screw extruder extrusion temperature is as follows: district's temperature 170 DEG C, and two district's temperature are 175 DEG C, three district's temperature are 200 DEG C, and four district's temperature are 210 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Embodiment 2
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 80r/min, and in ball mill, ratio of grinding media to material is 10:1, and Ball-milling Time is 30min; (2) stirring tank is started, in stirring tank, add polybutene 45 parts, polypropylene 20 parts, sulfonated polyether sulfone 3 parts, TWEEN40 15 parts, polyvinyl cinnamate 4 parts, titanium dioxide 7 parts, antimonous oxide 4 parts, triisopropyl borate ester 6 parts, laureth sodium sulfovinate 5 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 11:1, and twin screw extruder extrusion temperature is as follows: district's temperature 160 DEG C, and two district's temperature are 185 DEG C, three district's temperature are 190 DEG C, and four district's temperature are 205 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Embodiment 3
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 160r/min, and in ball mill, ratio of grinding media to material is 20:1, and Ball-milling Time is 60min; (2) stirring tank is started, in stirring tank, add polybutene 40 parts, polypropylene 12 parts, sulfonated polyether sulfone 4 parts, TWEEN40 13 parts, polyvinyl cinnamate 6 parts, titanium dioxide 6 parts, antimonous oxide 5 parts, triisopropyl borate ester 5 parts, laureth sodium sulfovinate 6 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 15:1, and twin screw extruder extrusion temperature is as follows: district's temperature 170 DEG C, and two district's temperature are 175 DEG C, three district's temperature are 200 DEG C, and four district's temperature are 210 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Embodiment 4
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 80r/min, and in ball mill, ratio of grinding media to material is 10:1, and Ball-milling Time is 30min; (2) stirring tank is started, in stirring tank, add polybutene 25 parts, polypropylene 18 parts, sulfonated polyether sulfone 6 parts, TWEEN40 7 parts, polyvinyl cinnamate 10 parts, titanium dioxide 4 parts, antimonous oxide 7 parts, triisopropyl borate ester 4 parts, laureth sodium sulfovinate 7 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 11:1, and twin screw extruder extrusion temperature is as follows: district's temperature 160 DEG C, and two district's temperature are 185 DEG C, three district's temperature are 190 DEG C, and four district's temperature are 205 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Embodiment 5
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 120r/min, and in ball mill, ratio of grinding media to material is 15:1, and Ball-milling Time is 45min; (2) stirring tank is started, in stirring tank, add polybutene 20 parts, polypropylene 8 parts, sulfonated polyether sulfone 7 parts, TWEEN40 5 parts, polyvinyl cinnamate 12 parts, titanium dioxide 3 parts, antimonous oxide 8 parts, triisopropyl borate ester 3 parts, laureth sodium sulfovinate 8 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 13:1, and twin screw extruder extrusion temperature is as follows: district's temperature 165 DEG C, and two district's temperature are 180 DEG C, three district's temperature are 195 DEG C, and four district's temperature are 210 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Comparative example 1
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 160r/min, and in ball mill, ratio of grinding media to material is 20:1, and Ball-milling Time is 60min; (2) stirring tank is started, in stirring tank, add polybutene 20 parts, polypropylene 8 parts, sulfonated polyether sulfone 7 parts, polyvinyl cinnamate 12 parts, titanium dioxide 3 parts, antimonous oxide 8 parts, triisopropyl borate ester 3 parts, laureth sodium sulfovinate 8 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 15:1, and twin screw extruder extrusion temperature is as follows: district's temperature 170 DEG C, and two district's temperature are 175 DEG C, three district's temperature are 200 DEG C, and four district's temperature are 210 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Comparative example 2
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 160r/min, and in ball mill, ratio of grinding media to material is 20:1, and Ball-milling Time is 60min; (2) stirring tank is started, in stirring tank, add polybutene 20 parts, polypropylene 8 parts, sulfonated polyether sulfone 7 parts, TWEEN40 5 parts, titanium dioxide 3 parts, antimonous oxide 8 parts, triisopropyl borate ester 3 parts, laureth sodium sulfovinate 8 parts, add mentioned component post-heating and stir; (3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 15:1, and twin screw extruder extrusion temperature is as follows: district's temperature 170 DEG C, and two district's temperature are 175 DEG C, three district's temperature are 200 DEG C, and four district's temperature are 210 DEG C; (4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
Tensile strength and the Izod notched Izod impact strength of the engineering cable macromolecular material of the above embodiments and comparative example are as follows:
| Tensile strength (MPa) | Izod notched Izod impact strength (J/m) | |
| Embodiment 1 | 27.1 | 62 |
| Embodiment 2 | 28.5 | 59 |
| Embodiment 3 | 32.3 | 78 |
| Embodiment 4 | 30.4 | 81 |
| Embodiment 5 | 35.8 | 89 |
The performance of comparative example is as follows:
| Tensile strength (MPa) | Izod notched Izod impact strength (J/m) | |
| Comparative example 1 | 22.8 | 42 |
| Comparative example 2 | 23.6 | 45 |
Claims (6)
1. an engineering cable macromolecular material, is characterized in that, described macromolecular material comprises the composition of following weight part:
Polybutene 20-45 part,
Polypropylene 8-20 part,
Sulfonated polyether sulfone 3-7 part,
TWEEN40 5-15 part,
Polyvinyl cinnamate 4-12 part,
Titanium dioxide 3-7 part,
Antimonous oxide 4-8 part,
Triisopropyl borate ester 3-6 part,
Laureth sodium sulfovinate 5-8 part.
2. a kind of engineering cable macromolecular material according to claim 1, it is characterized in that, described macromolecular material comprises the composition of following weight part:
Polybutene 25-40 part,
Polypropylene 12-18 part,
Sulfonated polyether sulfone 4-6 part,
TWEEN40 7-13 part,
Polyvinyl cinnamate 6-10 part,
Titanium dioxide 4-6 part,
Antimonous oxide 5-7 part,
Triisopropyl borate ester 4-5 part,
Laureth sodium sulfovinate 6-7 part.
3. a preparation method for engineering cable macromolecular material, is characterized in that, preparation method comprises the following steps:
(1) put in ball mill by titanium dioxide and antimonous oxide, drum's speed of rotation is 80r/min-160r/min, and in ball mill, ratio of grinding media to material is 10:1-20:1, and Ball-milling Time is 30min-60min;
(2) stirring tank is started, in stirring tank, add polybutene 20-45 part, polypropylene 8-20 part, sulfonated polyether sulfone 3-7 part, TWEEN40 5-15 part, polyvinyl cinnamate 4-12 part, titanium dioxide 3-7 part, antimonous oxide 4-8 part, triisopropyl borate ester 3-6 part, laureth sodium sulfovinate 5-8 part, add mentioned component post-heating and stir;
(3) material of step (2) is melt extruded on the twin screw extruder, double-screw extruder screw length-to-diameter ratio is 11:1-15:1, twin screw extruder extrusion temperature is as follows: a district temperature 160-170 DEG C, two district's temperature are 175-185 DEG C, three district's temperature are 190-200 DEG C, and four district's temperature are 205-210 DEG C;
(4) extruded stock is carried out pelletizing, be prepared into macromolecular material.
4. the preparation method of a kind of engineering cable macromolecular material according to claim 3, is characterized in that, in described step (1), drum's speed of rotation is 120r/min.
5. the preparation method of a kind of engineering cable macromolecular material according to claim 3, is characterized in that, in described step (1), ball mill ratio of grinding media to material is 15:1.
6. the preparation method of a kind of engineering cable macromolecular material according to claim 3, is characterized in that, in described step (3), double-screw extruder screw length-to-diameter ratio is 13:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510401992.3A CN104927213A (en) | 2015-07-10 | 2015-07-10 | High polymer material used for engineering cable and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510401992.3A CN104927213A (en) | 2015-07-10 | 2015-07-10 | High polymer material used for engineering cable and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104927213A true CN104927213A (en) | 2015-09-23 |
Family
ID=54114651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510401992.3A Pending CN104927213A (en) | 2015-07-10 | 2015-07-10 | High polymer material used for engineering cable and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104927213A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905623A (en) * | 2016-08-23 | 2017-06-30 | 南通久聚高分子科技有限公司 | A kind of engineering cable macromolecular material |
| WO2018058272A1 (en) * | 2016-09-27 | 2018-04-05 | 崔楠 | Polymer material for use in engineering cables |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589069A (en) * | 2013-11-26 | 2014-02-19 | 青岛科技大学 | High-shock resistance polypropylene/polybutylene composite material as well as preparation method and purposes thereof |
-
2015
- 2015-07-10 CN CN201510401992.3A patent/CN104927213A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589069A (en) * | 2013-11-26 | 2014-02-19 | 青岛科技大学 | High-shock resistance polypropylene/polybutylene composite material as well as preparation method and purposes thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905623A (en) * | 2016-08-23 | 2017-06-30 | 南通久聚高分子科技有限公司 | A kind of engineering cable macromolecular material |
| WO2018058272A1 (en) * | 2016-09-27 | 2018-04-05 | 崔楠 | Polymer material for use in engineering cables |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104163990A (en) | Preparation method of polytetrafluoroethylene modified polypropylene composite material | |
| CN103396658B (en) | A kind of Polyethylene naphthalate resin composition and preparation method thereof | |
| CN104592730B (en) | A kind of polylactic acid/polyester alloy and preparation method thereof | |
| CN105924715A (en) | High-temperature-resisting, insulating and inflaming-retarding power cable material and preparing method thereof | |
| CN106009196A (en) | Anti-static macromolecular power cable material and preparation method thereof | |
| CN104086924A (en) | Carbon fiber-reinforced thermoplastic resin composite material and preparation method thereof | |
| CN103351525A (en) | High-gloss flame-retardant polypropylene composite material and preparation method thereof | |
| CN105694423A (en) | A modified polyphenylene oxide material with high strength and low dielectric loss and a preparing method thereof | |
| CN104927213A (en) | High polymer material used for engineering cable and preparation method thereof | |
| CN104861596A (en) | High-property polyester alloy material and preparation method thereof | |
| CN104227865A (en) | Preparation of continuous glass fiber reinforced polyamide material | |
| CN103525089A (en) | Special packaging material for insulated gate bipolar transistor (IGBT) and preparation method thereof | |
| CN113045819B (en) | Glass microsphere filled polypropylene composition and preparation method thereof | |
| CN101382626A (en) | Optical cable foaming packing gasket granule material and method for producing same | |
| JPS6246925B2 (en) | ||
| CN109102929A (en) | A kind of resistance to oxidation cable and its production method | |
| CN115651316A (en) | Rice hull filled PP composite material and preparation method thereof | |
| CN114015223A (en) | PC/PBT alloy material and preparation method and application thereof | |
| CN104513467A (en) | Polycarbonate (PC) blended alloy material | |
| CN103265806A (en) | Preparation method of flame retardant glass fiber reinforcement polyphenyl ether composite material | |
| CN105778239A (en) | Ceramic polyolefin flame-retardant fire-resistant cable material | |
| CN105754237A (en) | Environment-friendly oil-proof locomotive cable material | |
| CN110473666A (en) | A kind of Welded Electrical Signal Copper Platinum Wire Transmission Line | |
| CN109735068A (en) | Mesohigh electric product PBT environment-friendly engineering plastics | |
| CN108752891A (en) | A kind of thermosetting plastics and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150923 |